• Title/Summary/Keyword: 염화철

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Studies on the Leaching Constituent of Submerged Soil -I. Effects of Potassium Salts on Leaching of Minerals in Submerged Soil (논 토양성분(土壤成分)의 용탈(溶脫)에 관(関)한 연구(硏究) -I. 논 토양성분(土壤成分)의 용탈(容脫)에 미치는 가리염(加里塩)의 영향(影響))

  • Kim, Kwang-Sik;Kim, Yong-Woong
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.1
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    • pp.36-41
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    • 1983
  • These studies were carried out to investigate the effects of potassium salts on the changes of chemical properties in submerged soil. Rice plants were cultured in submerged soil using potassium salts. Obtained results were as follows. In the submerged soil cultured with rice plants the value of pH was higher in the potassium chloride plot than in the potassium sulfate plot. The leaching of cations such as calcium, magnesium, potassium and ammonium were higher in the potassium chloride plot than in the potassium sulfate plot. On the other hand, the leaching of phosphate ion was slightly higher in the potassium sulfate plot than in the potassium chloride plot. The leaching of iron was higher in the planted plot than in the non-planted plot, but that of silica was higher in the non-planted plot than in the planted plot. However, the leaching of iron and silica was not affected by potassium salts.

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Deicing Performance of Environment-friendly Deicing Agents (친환경 제설제인 CMO의 성능평가 분석)

  • Lee, Seung-Woo;Woo, Chang-Wan;Kim, Jong-Oh;Park, Hee-Mun
    • International Journal of Highway Engineering
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    • v.7 no.3 s.25
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    • pp.53-62
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    • 2005
  • Efficient snow-removing work is one of important processes of winter road management. Calcium chloride has been used as a typical deicing agent in Korea. It presents superial performance as snow deicing agents, however it has been known to give serious environmental problem and to deteriorate durability of concrete structure in road by corrosion. The environment-friendly road deicing agents made from the waste material which is liquid phase organic matter that is Ca Mg and reactant of organic acid (nitric acid and propionic acid) have been introduced by number of researchers. They indicated the calcium magnesium salt of organic acids have advantage over the calcium choride in terms of lower production unit cost by resources recycling and can solve environmental problem and durability deterioration of structures. In this study, the deicing performance of calcium magnesium salt of organic acids(CMO) is investigated based on the series of experiments including the test for heat of dissolution, freezing point, ice melting test and ice penetration test.

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Effects of Surface Material of Forms on Durability of Offshore Concrete (구조물의 표면마감 특성이 해양콘크리트의 내구성에 미치는 영향)

  • Park, Sang-Joon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.233-240
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    • 2008
  • This paper presents an experimental study on the air contents and the chloride penetration in offshore concrete depending on the types of forms. Three types of concretes(plain, MSF, and FA concretes) with four kinds of forms(wood, coating wood, steel, and polypropylene film) were investigated. The test results show that the air contents in the concrete cured with steel and polypropylene forms were higher than those with wood and coating wood forms. The concrete with wood forms has the least air content. The variation of chloride ingress time was large depending on the types of forms on the same concrete, i.e. 13.2, 20.3, and 17.7% for Plain, MSF, and FA concretes, respectively. Consequently, the surface conditions of forms should be considered for design of durable concrete.

Recovery of Iron-Nickel Alloy Etching Waste Solution in Pilot Scale (파일럿 규모에서 철-니켈 합금 에칭폐액 재생)

  • Chae, Byungman;Kim, Dae-Weon;Hwang, Sung-Ok;Kim, Deukhyeon;Lee, Sangwoo
    • Clean Technology
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    • v.23 no.4
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    • pp.393-400
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    • 2017
  • In this study, we have developed a process for separating and recovering Ni and Fe in solution through a new solvent instead of TBP and Alamine336, which are solvents used in the conventional solvent extraction method. Experimental conditions were optimized through lab test and a $10L\;h^{-1}$ pilot plant was constructed for commercialization. In addition, the process data for mass production were obtained through pilot experiment and it was confirmed that there is no problem in product quality that can be used through the corrosion test of ferric chloride.

The responses of Growth and Physiological traits of Acer triflorum on Calcium Chloride ($CaCl_2$) Concentration (염화칼슘 농도에 따른 복자기의 생장 및 생리적 반응 특성)

  • Kwon, Min-Young;Kim, Sun-Hee;Sung, Joo-Han
    • Korean Journal of Environment and Ecology
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    • v.28 no.5
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    • pp.500-509
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    • 2014
  • To prevent freezing of the road by fallen snow, Calcium chloride($CaCl_2$) as a deicer is used to very often and it can be harmful to roadside trees. This study was conducted to investigate the effects of Calcium chloride($CaCl_2$) as a deicer on growth and physiological traits of Acer triflorum according to different concentration of $CaCl_2$. We measured growth, chlorophyll contents, gas exchangement characteristics, chlorophyll fluorescence and mineral nutrition concentration in plant and soil. The experimental group was composed of four treatments including 0mM(control), 9mM(0.5 %), 18mM(1.0 %), 54mM(3.0 %). Before germinating new shoot, the dissolution of $CaCl_2$ was irrigated twice interval of a week. At 30 days after treatment, all treatments decreased total cholorophyll content, photosynthetic rate, transpiration rate, stomatal conductance and photochemical efficiency($F_v/F_m$) with increasing concentration of $CaCl_2$ and especially, they significantly reduced in 3.0 % treatment. In contrast, chlorophyll a/b ratio increased with an increase of $CaCl_2$ concentration and water use efficiency increased in 1.0 % and 3.0 % treatments. At 50 days after treatment, all treatments were decreased in chl a, chl b, total chlorophyll content, carotenoid content, photosynthetic capacity, photochemical efficiency($F_v/F_m$) and quantum yield of photosystem II(${\Phi}_{PSII}$) compared with control and 3.0 % treatments were withered. $Ca^{2+}$ and $Cl^-$ were accumulated in leaves and soil, which inhibited water absorption and electron transport and it caused the reduction of height growth rate more than 50 %. Although there was a little difference according to time and $CaCl_2$ concentration, all treatments decreased in growth rate and physiological activity slowed down. As time passed, these results got worse. Therefore we need to take a measure earlier in order to minimize damage of trees.

Salmonella Typhimurium SL1344 Utilizing Human Transferrin-bound Iron as an Iron Source Regardless of Siderophore-mediated Uptake (Salmonella Typhimurium SL1344의 사람의 트렌스페린(hTf)에 부착된 철 이용에 관한 연구)

  • Choe, Yunjeong;Yoo, Ah Young;Kim, Sam Woong;Hwang, Jihwan;Kang, Ho Young
    • Journal of Life Science
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    • v.27 no.1
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    • pp.72-77
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    • 2017
  • Inorganic iron is essential for various metabolic processes, including RNA synthesis, electron transport, and oxygen detoxification in microorganisms. Many bacterial pathogens compete for iron acquisition in diverse environmental condition such as host. Salmonella Typhimurium SL1344 also requires inorganic iron as a cofactor for growth. When a M9 minimal liquid medium was supplemented with ethylenediamine di-o-hydroxyphenylactic acid (EDDA) which acts as an iron-chelating agent, growth of Salmonella Typhimurium SL1344 in the supplemented medium was completely arrested by deficient of useful iron under iron-depleted condition. However, a number of siderophores, which are small, high-affinity iron chelating compounds secreted by microorganisms such as bacteria and fungi, were produced for utilization of restricted iron under iron-depleted condition. A M9 minimal liquid medium complemented with human transferrin (hTf)-iron complex turned completely off production of siderophores, but growth of Salmonella Typhimurium SL1344 maintained level similar to compare one complemented with iron (III) chloride (FeCl3). This means that human transferrin (hTf)-bound iron can utilize via directly interaction with Salmonella Typhimurium SL1344 without productions of siderophores. Through construction and analysis of negative mutant for utilization of human transferrin (hTf)-bound iron, we confirm that the bacterium can directly use human transferrin (hTf)-bound iron without extracellularly intermediated carriers such as siderophores.

Application Study of Raman Micro-Spectroscopy for Analysis on Corrosion Compound of Iron Artifacts (철제유물 부식화합물 분석의 표준데이터 확보를 위한 라만 분광법 적용성 연구)

  • Park, Hyung Ho;Lee, Jae Sung;Yu, Jae Eun
    • 보존과학연구
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    • s.32
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    • pp.89-98
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    • 2011
  • It is quite difficult to identify its corrosion compound because they have a wide variety of crystal structures and they are mixed with two component. This study was conducted with the standard iron corrosion compounds through the analysis by Raman Micro-Spectroscopy, which aims to obtain standard Raman Data. To assess the reliability of standard iron corrosion compounds, SEM-EDS analysis and XRD analysis were conducted. Through SEM-EDS analysis, the elements of corrosion compound matched with those of standards iron corrosion compounds except Goethite. XRD analysis showed that the structures of corrosion compounds were identical to those of standard iron corrosion compounds, however, it was identified that Iron sulfate ($FeSO_4{\cdot}6H_2O$) is the Rozenite ($FeSO_4{\cdot}4H_2O$). Through Raman Micro-Spectroscopy analysis, the new peak was detected from the wavenumbers of hydroxide and iron oxide. It is considered that it is due to changes in the wavelength of the laser. As the wavenumbers of iron chloride and iron sulfate have been identified, eight kinds of Raman Data were obtained. It can be considered to contribute to cultral heritage for iron objects that Raman Micro-Spectroscopy analysis which is relatively easy to compare material properties and structures can be highly applicable to the research on cultural heritage with the limited amount of samples.

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Effect of sodium chloride on the growth, amino acid content, and fragrance patterns of Pleurotus ostreatus (염화나트륨 농도가 느타리 자실체의 아미노산과 향기성분에 미치는 영향)

  • Lee, Sang-Chul;Pyeon, Ha-Young;Park, Youn-Jin;Oh, Tae-Seok;Jang, Myoung-Jun
    • Journal of Mushroom
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    • v.19 no.4
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    • pp.310-315
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    • 2021
  • We investigated the effect of sodium chloride-associated abiotic stress on the development of Pleurotus ostreatus. We examined the growth characteristics of fruiting bodies, constituent amino acids, and fragrance pattern to determine the effect of culturing Pleurotus ostreatus on a sawdust substrate supplemented with sodium chloride in a dose-dependent manner. Pleurotus ostreatus fruiting bodies exhibited an increasing tendency towards augmented yields when grown in the presence of 0.5% sodium chloride as compared with that grown in the control group. However, increasing the supplementation of sodium chloride from 1.0 % to 2.0% resulted in significantly decreased yields of Pleurotus ostreatus fruiting bodies in these groups as compared with that in control groups. Further assessment revealed the presence of 14 types of amino acids in the fruiting bodies, including aspartate, threonine, serine, glycine, alanine, methionine, valine, isoleucine, leucine, phenylalanine, tyrosine, lysine, histidine, and arginine, at lower levels in all the sodium chloride-treated groups than in the control group; except for glutamic acid and proline. Similarly, fragrance pattern analysis of the Pleurotus ostreatus fruiting body by chromatography confirmed that the intensity of the substances presumed to be octane compounds, to which the unique flavor of mushrooms is attributed, was lower in all the sodium chloride-treated groups than in the control group.

Characterization of metal-containing activated carbon derived from phenolic resin (페놀 수지로부터 유도된 금속이 함유된 활성탄의 특성화)

  • Oh, Won-Chun;Jang, Won-Cheoul;Kim, Bum-Soo
    • Analytical Science and Technology
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    • v.14 no.4
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    • pp.349-355
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    • 2001
  • A series of micro- and mesoporous activated carbons were prepared from phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than $962.3m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides($CdCl_2$, $CuCl_2$). Pore evolvement was shown to be most effected by the incremental addition of metal chloride. From the thermodynamic DSC data, enthalpy formations(${\Delta}H$) of first endothermic reaction were increase with the incremental addition of metal chloride.

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An Experimental Study on Relation between Chloride Diffusivity and Microstructural Characteristics for GGBS Concrete (슬래그 미분말 혼합 콘크리트의 공극구조와 염화물 확산계수와의 관계에 대한 실험적 연구)

  • Kim, Tae-Sang;Jung, Sang-Hwa;Choi, Young-Cheol;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.639-647
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    • 2009
  • In order to evaluate the durability of reinforced concrete structures under chloride attack from sea water and frost damage, it is important to analyze both the microstructural characteristics of concrete and its diffusion resistance of concrete against chloride ingress. In this study, a relation between micro-pore structures of concrete obtained by the Mercury Intrusion Porosimetry and accelerated chloride diffusivity as well as long term chloride diffusivity were studied for ground granulated blast furnace slag(GGBS) concrete. Different water-cement ratio of 40, 45, 50% and different unit cement concrete of 300, 350, 400 or 450 kg/$m^3$ of the GGBS concrete along with OPC concrete were used and freeze and thawing, and the change in diffusivity and microstructure were observed for both GGBS concrete and damaged GGBS concrete due to rapid freezing and thawing.