• Title/Summary/Keyword: 염소 이온 확산계수

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Probability-Based Durability Analysis of Concrete Structures under Chloride Attack Environments (염해를 받는 콘크리트 구조물의 확률론적 내구성 해석)

  • Kim, Jee-Sang;Jung, Sang-Hwa;Kim, Joo-Hyung;Lee, Kwang-Myong;Bae, Su-Ho
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.239-248
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    • 2006
  • Recently, a variety of researches has been carried out to obtain a more controlled durability and long-term performance of concrete structures under chloride attack environments. In particular, new procedures for probability-based durability analysis/design have been noticed to be very valuable for the enhancement of service life of concrete structures. Although there is still a lack of relevant data, this approach has been successfully applied to some new concrete structures. In this paper, the diffusion equation based on Fick's second law has been solved with a time dependent diffusion coefficient and the probabilistic analysis of the durability performance has been carried out by using a Monte Carlo Simulation. From the results, the influence of each parameter on the durability of concrete structures was investigated and the new procedure for durability analysis was demonstrated in terms of chloride penetration data from various concrete structures. The new procedure might be very useful in designing important concrete structures and help to predict the remaining service life of existing concrete structures under chloride attack environments.

Advective-diffusive Characteristics of Waste Landfill Liner to Inorganic Chemicals (매립지 차수재의 무기화합물에 대한 이류-확산 특성)

  • 장연수;류정훈;류정훈
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.5-11
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    • 2004
  • Characteristics of advective-diffusive transport of inorganic chemicals in clayey soils as well as in two hardened barrier materials of silica and lime are analyzed from the laboratory column test and compared with those of pure diffusive column test. The results show that the average dispersion coefficients of three materials are $4.39\times l0^{-10}\textrm{m}^2 /s,\; 1.98\times l0^{-10}\textrm{m}^2 /s,\; 1.99\times l0^{-10}\textrm{m}^2 /s$, respectively, and the value of clay is higher than that of hardened barrier materials. There was no significant difference between the dispersion coefficients of advective-diffusive column tests and the effective diffusion coefficients from the pure diffusive column tests, if advective velocity was lower than l0$^{-7}$$m^2$/s. The range of dispersion coefficients of advective-diffusive column tests was narrower than that of diffusion coefficients of pure diffusion tests.

Transport Coefficients and Effect of Corrosion Resistance for SFRC (강섬유 보강 콘크리트의 수송계수 및 부식저항효과)

  • Kim, Byoung-Il
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.867-873
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    • 2010
  • This study investigated the corrosion properties of reinforced concrete with the addition of steel fibers. The transport properties of steel fiber-reinforced concrete such as permeable void, absorption by capillary action, water permeability and chloride diffusion were first measured to evaluate the relationship with the corrosion of steel rebar. Test results showed a slight increase on the compressive strength with the addition of steel fibers as well as considerable improvement of penetration resistance to mass transport of harmful materials into concrete. The addition of steel fibers in reinforced concrete accelerated the initiation of steel corrosion contrary to the expected results based on the measured transport properties. The NaCl ponding surface showed the spalling failure due to the corrosion expansion of steel fibers and the cut-surface around the steel rebar showed the localized steel fiber's corrosion. The wet-dry cycling with high chloride ions as well as high temperature seems to induce the increase of salt crystallization on the pores continually and the increased pressure with the steel fiber's corrosion on the pores caused the spalling failure on the exposed surface. The microcracking on the surface therefore accelerated the movement of water, chloride ions and oxygen into the embedded steel rebar. The mechanism affecting corrosion of embedded steel reinforcement with steel fibers in this study are not yet fully understood and require further study comprising of accurate experimental design to isolate the effect of steel fiber's potential mechanism on the corrosion process.

Mechanical Properties And Chlorde Penetration Resistance of Shotcrete according to Mineral Admixture Types and Supplemental Ratio (광물성 혼화재료의 종류 및 혼입율에 따른 숏크리트의 역학적 특성 및 염해 저항성)

  • Han, Seung-Yeon;Yun, Kyong-Ku;Nam, Kyeong-Gung;Lee, Kyeo-Re;Eum, Young-Do
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4960-4968
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    • 2015
  • In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

Evaluation on the Chloride Ion Diffusion Coefficient of Mortar Depending on Replacement Ratio of Recycled Fine Aggregate (순환잔골재 치환율에 따른 모르타르의 염화물이온확산계수 평가)

  • Lee, Sang-Yun;Yoo, Jae-Chul;Kim, Gyu-Yong;Yoon, Min-Ho;Nam, Jeong-Soo;Choi, Hyeong-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.479-485
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    • 2016
  • This paper presents an experimental study conducted to investigate the effect of recycled fine aggregate (RFA) on the mechanical properties and chloride diffusion behavior of mortar. The test results revealed that the addition of RFA plays an important role in the mechanical properties and pore structures of the investigated mortar specimens as well as chloride diffusion behavior. The mechanical properties such as compressive strength and flexural strength of recycled fine aggregate mortar (RFAM) were gradually decreased as RFA replacement ratio increase. The pore structure of RFAM was examined by permeability tests. The RFAM showed a increment in the permeability according to replacement ratio increase of RFA. But the chloride diffusion coefficient of RFAM was almost same up to 50% replacement ratio of RFA due to a chloride binding phenomenon of RFAM which may compensate the higher permeability of RFAM.

Evaluation of Relationship between Strength and Resistance to Chloride in Concrete Containing Fly Ash with Ages (Fly Ash를 혼입한 콘크리트의 재령에 따른 강도와 염화물 저항능력간의 상관관계 평가)

  • Yoon, Yong-Sik;Park, Jae-Sung;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.53-60
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    • 2017
  • Fly ash(FA) which is a byproduct in the coal combustion in thermal power plant contributes to pore structure densification due to pozzolanic reaction, and this leads to long-term strength development and excellent resistance to chloride penetration. In the work, compressive strength and chloride resistance in OPC(Ordinary Portland Cement) and FA-based concrete are evaluated, and the relationships are investigated considering ages. For the work, 3 different W/B (Water to Binder) ratios of 37%, 42%, and 47% are prepared, and 3 substitution ratio of fly ash(0%, 30%, and 50%) are considered as well. At the age of 28 days and 180 days, test results of compressive strength, diffusion coefficients based on Tang's method, and passed charges referred to ASTM C 1202 and KS F 2711 are obtained. With increasing replacement ratio of FA and decreasing W/B, the resistances to chlorides(diffusion coefficient and passed charge) are improved, and the results at the age of 180 days decrease to only 15% level at the age of 28 days due to pozzolanic reaction in FA 50 mixture, which shows that resistance to chloride is much dependent on age effect than strength development. After 180 days, more clear linear relationships are observed between strength and resistance to chloride.

Effect of Initial Flexural Crack on Resistance to Chloride Penetration into Reinforced Concrete Members (초기 휨균열이 철근콘크리트 부재의 염화물침투저항성에 미치는 영향)

  • Yang, Eun Ik;Jin, Sang Ho;Kim, Myung Yu;Choi, Yoon Suk;Han, Sang Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.79-87
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    • 2011
  • In this study, the chloride penetration tests were performed for the initially cracked reinforced concrete members. The chloride diffusion characteristics and the critical crack width are compared, and the properties of self-healing are investigated. According to the test results, the chloride penetration resistance was greatly reduced as the surface crack width increased. When the mineral admixtures are added, the chloride penetration resistance of uncracked specimens were effectively increased, however, in case of the blast furnace slag and fly ash, the cracked specimens showed the more reduced resistance than OPC case, inversely. Also, the critical width was $29{\mu}m$, on average, for immersion test. The crack width with $4{\sim}15{\mu}m$ was restored by self-healing, The parts restored by self-healing were seemed to be visually restored, however, the chloride penetration resistance was not restored, perfectly.

Estimation of Critical Chloride Content for Corrosion of Reinforcing Steel in Concrete by Field Exposure Experiment (현장 폭로실험에 의한 콘크리트 중 철근의 부식 임계 염화물량 평가)

  • Yu, Kyung-Geun;Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Kim, Jee-Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.585-588
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    • 2008
  • To predict the service life of reinforced concrete structures exposed to chloride environment, quantitative measures of material properties such as the critical chloride content for corrosion in concrete and the diffusion coefficient of chloride ions of concrete and the surface chloride content of the concrete are essential. However, it should be noted that they are influenced by several factors such as concrete mix proportions, cement type, and environmental conditions, etc. Thus, the purpose of this research is to estimate more actually the critical chloride content for corrosion of the reinforcing steel in concrete by field exposure experiment. For this purpose, the prism concrete test specimens were made for water-cement(W/C) ratios of 31%, 42%, 50%, and 70%, and then the field exposure experiment for them were conducted at Youngduk of the east coast for about 3 years. During the test, corrosion monitoring by half cell potential method was carried out to detect the time to initiation of corrosion for test specimens and its chloride content was evaluated by breaking the concrete test specimens when corrosion of the reinforcing steel in concrete was perceived. It was observed from the test results that the critical chloride content for corrosion of reinforcing steel in concrete would be dependent on W/C ratio and almost irrespective of concrete cover.

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An Evaluation on the Chloride Resistance of Concrete Footing at Coastal Area -Comparision of Performance in Korea Building Code(KBC)- (해안인접지역 기초 구조물콘크리트의 내염해 성능 평가 -건축구조기준과의 성능비교-)

  • Park, Yong-Kyu;Yoon, Gi-Won;Kim, Hyun-Woo;Kim, Yong-Ro;Song, Young-Chan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.148-149
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    • 2016
  • In this paper, the increase in chloride resistance of footing concrete at coastal area was evaluated by replacement of Mineral Admixture. In KBC 2009, the footing concrete's minimum specific concrete strength at coastal area is determined to 35MPa. However, this is criteria only based on the strength aspect. Thus, it is not considered to increase the chloride resistance by replacement of Mineral Admixture. According to the test results of chloride ions penetration resistance, 35MPa class concrete with OPC 100% shown inaccessible state. Low-strength (24~30MPa class) concretes with Mineral Admixture, however, presented better performances. In addition, chloride diffusion coefficient tests showed identical appearance. Therefore, the current KBC's chloride resistance criteria based on only concrete strength has to review for the reason it can cause many problems (ex. cost increases by growing concrete strength and the environmental issues by a lot of cement use).

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Reliability based durability assessment of marine concrete structures (해양 콘크리트 구조물의 신뢰성 기반한 내구성 평가)

  • Song, Ha-Won;Lim, Dong-Woo;Pack, Seung-Woo;Lee, Chang-Hong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.497-500
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    • 2008
  • In order to prevent deterioration of reinforced concrete structures exposed to marine environment, performance based durability design than the design by conventional deemed-to-satisfy rule should be concerned. For example, even though chloride threshold level, which is a major parameter for durability design, is defined as a 1.2 $kg/m^3$ in the Korean concrete specification, it shows that the chloride threshold level leads to over design in its real application so that realistic value should be determined for the performance design. In this paper, not only the probabilistic properties of chloride threshold level obtained from published data are taken into account, but also the experimental results of the probabilistic properties using surface chloride content, diffusion coefficient, cover depth are considered in the assessment utilizing the concept of performance based durability design. In computation, the Monte Carlo Simulation (MCS) is used to perform an assessment due to chloride attack for a target submerged tunnel box. This study found that the specification on current chloride threshold level should be modified for more rational and accurate assessment and design.

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