• Elastomers and Composites
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• v.34 no.3
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• pp.199-211
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• 1999

In this work, the effects of the addition of epoxy on the properties of PVC-sol sealants were investigated. PVC-sol was plasticized with dioctyl phthalates(DOP). Two kinds of epoxy resins having different epoxy equivalent weight (E.E.W.) were used. It was found that the properties of the PVC-sol sealants were significantly affected by the contents and types of the added epoxy resins. The viscosity behaviors of the epoxy-modified sealants, in the case of epoxy A addition, the viscosity was decreased with increasing the epoxy contents, but In the case of $CaCO_3$ addition, the viscosity was increased with increasing the $CaCO_3$ contents. The viscosity of epoxy modified sealants aged at $45^{\circ}C$ waterbath was decreased with increasing epoxy contents, since the epoxy acted on the sealants as a stabilizer. The thermal stability of the PVC-sol sealants was slightly improved by adding epoxy. The tensile strength and elongation of sealants modified with epoxy A(two functionalities of epoxy) were increased with increasing the epoxy contents up to a certain epoxy contents but was decreased with further increasing the epoxy contents. In the case of $CaCO_3$ addition, the tensile strength of sealants were decreased with increasing the $CaCO_3$ contents. In view of the electrical properties, such as tan ${\delta}$($0.1{\pm}0.04$) and ${\epsilon}_r$($0.5{\pm}0.04$), it was found that the epoxy modified sealants were as good as insulators.

• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.465-471
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• 2009

To prevent the explosive spalling of the high strength concrete and control the rise of temperature in the steel rebar during fire, a fiber cocktail method has been proposed simultaneously with the use of polypropylene and steel fiber. After applying the fiber cocktail (polypropylene and steel fibers) into the mixture of high strength concrete with a compressive strength of between 40 and 100 MPa and evaluating the thermal properties at elevated temperatures, the fire test was carried out on structural members in order to evaluate the fire resistance performance. Two column specimens were exposed to the fire without loading for 180 minutes based on the standard curve of ISO-834. No explosive spalling has been observed and the original color of specimen surface was changed to light pinkish grey. The inner temperature of concrete dropped rapidly starting from 60mm deep. After 60 minutes of exposure to the fire, the temperature gradient of fiber cocktail reinforced high strength concrete was measured as 2.2oC/mm, which is approximately 5 times less than that of normal concrete. The final temperatures of steel rebar after 180 minutes of fire test resulted in 488.0oC for corner rebar, 350.9oC for center rebar, and 419.5oC for total mean of steel rebar. The difference of mean temperature between corner and center rebar was 137.1oC The tendency of temperature rise in concrete and steel rebar changed between 100oC and 150oC The cause of decrease in temperature rise was due to the water vaporization in concrete, the lower temperature gradient of the concrete with steel and polypropylene fiber cocktails, the moisture movement toward steel rebars and the moisture clogging.

• Journal of the Korean Magnetics Society
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• v.15 no.3
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• pp.167-171
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• 2005

Detailed aspects of the charge disproportionation (CD) transition for a polycrystalline $La_{1/3}Sr_{2/3}FeO_{2.96}$ were studied with the X-ray diffraction, $M\ddot{o}ssbauer$ spectroscopy, and SQUID magnetometer. The crystal structure was found to be rhombohedral with a space group R/3c. The lattice parameters were $a_R=5.4874\;\AA,\;and\;a_R=60.07^{\circ}$, respectively. $M\ddot{o}ssbauer$ spectra were taken within a wide range of temperature from 4.2 K up to room temperature. In the low temperature region, the spectra were comprised of two superimposed sextets which originated from $Fe^{3+}\;and\;Fe^{5+}$, respectively. This was the antiferromagnetic mixed valence state produced by the charges disproportionated into two different species. In the high temperature region, however, only a singlet from $Fe^{3.6+}$ was observed, indicating that it was a paramagnetic averaged valence state. The CD transition occurred in the temperature range from 175 K to 200 K, in which the two phases coexisted. The origin for the CD transition was explained by the thermally generated fast hopping of electrons. Hysteresis loop showed that there existed a strong antiferromagnetic interaction among magnetic ions. As the temperature increased thru the CD transition temperature, it was very likely that the interaction between $Fe^{3+}\;and\;Fe^{5+}$ was replaced by a more stronger one.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1999.10a
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• pp.1-2
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• 1999

시간과 공간의 구애를 받지 않는 양질의 음성, 화상, 문자정보의 교환을 위한 노력으로 디지털 휴대폰과 휴대용 컴퓨터가 등장하면서 음성과 문자정보의 교환분야에 커다란 진보를 이룩하였다. 그러나 현재는 휴대폰이 음성정보에 문자정보교환이 추가된 상황이기 때문에, 아직도 관련 정보교환기술 및 기기개발이 진행되고 있다. 앞으로 휴대폰과 휴대용 컴퓨터의 기능을 통합하고 화상정보까지 결합된 휴대용 정보기기를 위해서는 전자회로의 집적화 및 통신속도 증대가 필수적이다. 또한 이들 휴대용 정보기기를 구동시키기 위한 전력도 증가될 것으로 예측되기 때문에, 현재 전원으로 사용되는 2차전지보다 에너지 밀도가 더욱 증패된 전지가 요구될 것으로 예상된다. 그리고 내연기관의 배기에 의해 발생되는 환정오염문제를 해결하기 위한 방법중의 일환으로 전기자동차 개발이 진행되고 있으며, 이들 전기자동차에 2차전지를 장착하기 위해서 경제성이 있고, 고속충전이 가능하고, 안전성이 높은 고에너지 밀도의 2차 전지 개발이 요구되고 있다. 현재 2차전지는 음극재료나 양극재료에 따라 낚축전지, 니켈/카드륨(Ni/Cd) 전지, 니켈/수소(Ni/MH) 전지, 라륨 2 차전지등이 있으며, 전극재료의 고유특성에 의해 전위와 애너지 밀도가 결정된다. 특히 리튬 2차전지는 리튬의 낮은 산화환원전위와 분자량으로 인해 에너지 밀도가 높기 때문에 앞에서 언급한 휴대용 전자기기의 구동전원으로 많이 사용되고 있다. 리튬 2차전지는 음극 재료가 금속리튬인 경우는 리튬금속으로, 탄소재료인 경우는 리튬이온이라 하며, 한편으로 전해질이 고체 고분자이거나 혹은 역체 유기용매와 리튬염을 고분자와 혼성시킨 겔(gel)인 경우는 고분자로, 전해짙이 리튬염이 전리되어 있는 유동성 액체일 경우는 고분자를 생략하여 구분하고 있다. 즉 리튬금속 2 차전지(LB), 리튬이온 2 차전지(LIB), 리튬금속 고분자 2차전지(LPB), 리튬 이온 고분자 2차전지(LIPB)로 크게 구분된다. 금속리듐을 음극으로 사용하고 전해질로는 리튬염이 전리되어 있는 액체유기용매 를 사용한 리튬금속 2차전지는, 금속리튬전극이 충방전 과정을 반복하면서, 전리된 리튬이 균일하게 산화환원되지 못하고 표변에서 양극방향으로 성장하는 수지상 (dendrite) 현상으로 인해 안전성 확보에 문게가 있었다. 리튬과 알루미늄 합금형태로 음극에 사용한 동전형 전지는 상용화 되었지만, 이러한 단점을 개선하기 위해 리튬이온이 금속으로 석활되는 환원반응전위보다 높은 전위에서 전극재료가 충전되면서 리튬이온이 저장되고, 방전되면서 배출되는 탄소를 음극재료로, 그리고 리튬이온이 충방 전시 가역적으로 삼입 탈리되는 층상의 리튬금속산화물을 양극으로 구성하고, 엑체 전해질과 다공성 고분자 분리막을 사용한 것이 LIB이다. LIB에서 리튬이온의 이동이 가능한 액체전해질의 가능을 고분자 전해질이 대신함으로서 보다 높은 안정성을 확보 한 전지가 LIPB 이다. 또한 고분자 전해질을 사용한 경우 금속리튬상에서의 수지상 성장이 저하되는 현상이 관찰됨으로서, 이론용량이 3,860mAh/g 에 달하는 리튬금속 혹은 합금을 고분자 전지에서 음극으로 사용하고자 하는 2 차전지가 LPB 이다. 리튬 2차전지는 비록 1989년 액체전해질을 사용한 금속리튬 2차전지의 실패전력을 안고있지만 궁극적으로는 이론적으로 최대의 에너지밀도를 가지고 있는 LPB를 지 향할 것으로 예상되지만 가까운 장래에 실현되기는 어려울 것이다. 따라서 향후의 라튬 2차전지의 전개방향은 현재의 LIB를 고분자 전해질을 채용하는 LIPB로 진행시커면서 저가의 전극재료개발을 지속적으로 추진할 것으로 예상된다. 현재 리튬 2차전지는 소형전지에 국한되고 있지만 전기자동차나 전력저장용으로 이를 대형화시커기 위해서는 열적특성이 우수하고 저가인 전극재료개발이 선행되야하기 때문에, 저가의 탄소재료와 코발트산화물을 대신할 수 있는 철, 망칸 또는 니켈산 화물의 개발이 필요하다.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.3
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• pp.1033-1041
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• 2014

Rapid urbanization of Korea was an unprecedented example in the world and urban population increased significantly. As a result, unbalanced distribution of population is serious problem in Korea because approximately 50% of the population is concentrated in the capital area that is 10% of nation's territory, thereby occurring various urban problems including UHI. Hence, Sejong Special Autonomous City was inaugurated officially on 2 July 2012 in order to decentralize population of capital area and induce more balanced regional development. The Sejong City has been changed drastically over a period of years as developed practically since the late 2000's and is expected to have new problems of urbanization. The land cover change due to urbanization is the main cause of UHI that urban area is significantly warmer than its surrounding areas and UHI is not only affecting urban climate change but also natural environment. So the purpose of this research is to analyze level of urbanization and UHI effect and to provide the correlation analysis between Land Surface Temperature and spectral indices. To achieve this, satellite imagery from LANDSAT were used. NDVI, NDBI, and UI were calculated using red, near-infrared, mid-infrared ($0.63{\mu}m-1.75{\mu}m$) images and LST was retrieved utilizing thermal infrared ($10.4{\mu}m-12.5{\mu}m$) image. Based on each index and LST, Changes of NDVI, UI and UHI through TVI were analyzed in Sejong City. UHI effect increased around newly constructed multi-functional administrative city, the correlation between LST and NDVI was negative and UI was strong positive.

• Economic and Environmental Geology
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• v.41 no.2
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• pp.165-172
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• 2008

Kaolinite [$Al_2Si_2O_5(OH)_4$] used in these experiments was synthesized at 250$^{\circ}C$ for 36 hrs by a hydrothermal process from amorphous $Al(OH)_3$ and $SiO_2$. The change of the mineralogical properties of the phase synthesized were observed in the pH range 2 to 9. The synthetic kaolinite were characterized by the analytical methods of XRD, IR, DIA, and FE-SEM. Kaolinite was obtained in a wide range of pH. The phases with high- to midium- defect kaolinite with high thermal stability were obtained from the acidic conditions and high-defect kaolinite with low thermal stability from the basic conditions. These variations of kaolinite properties appears to be related to the pH dependence of kaolinite surface speciation. The peaks intensity and resolution of the kaolinite decrease according to the alkalinity of the solution by the results of the IR testing. And the peak intensity increases in the 60 to 70$^{\circ}C$ range due to dehydration reaction observed by TG-DTA. Such phenomena was the result of increase of unreacted amorphous materials in the high pH condition, which could be identified by FE-SEM.

• Spatial Information Research
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• v.14 no.1 s.36
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• pp.163-176
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• 2006

The concept of 'spatial association' explains spatial distribution pattern of geographical phenomenon based on similarity with neighborhoods, as in the Tobler's Law of Geography: 'Everything is related to everything else, but near things are more related than distant things.' In this study, we develop a time-series exploratory analysis tool for discovering temporal patterns of spatial association by combining spatial statistics and geo-visualization, and thus present a possibility to support spatial decision-making process. As for the spatial proximity weight matrix indispensable to measuring global and local spatial association, we employ a variety of flexible weighting schemes using geometric characteristics of areal unit. In addition, we renovate the existing visualization methods for more effective understanding of the procedures and results of time-series analysis on spatial association: for instance, temporal parallel coordinate plot with box plot, animated map for spatial association, and 3D Moran scatterplot. The feasibility of our system is verified by time-series analysis experiments on the spatial association of land price fluctuation rate for all administrative units in Korea, $1995{\sim}2004$.

• Journal of the Korean association of regional geographers
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• v.22 no.1
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• pp.120-134
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• 2016

This study aims to investigate the hierarchical stepwise migration and its influences on regions (metropolitan areas, cities and counties of Korea administrative district) through analyzing the city rank-size and the changes of natural increase of population. The result shows that the inter-regional migration has been associated to the decrease of the population and the decline of NIR in the regions where outflows have been persisted. Also, theses demographic events have sequentially occurred through the hierarchy of settlement system: gradually from rural (gun) and lower ranked regions in the system of city rank-size, to urban (si) and regions in the high ranks in the system. Based on the result of this study, it is possible to understand and expect the major origins of inter-regional migration, the presence of the hierarchical stepwise migration and most significantly, the spatial expansion of depopulation problems.

• Korean Journal of Remote Sensing
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• v.26 no.5
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• pp.571-580
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• 2010

Coastal shoreline movement due to erosion and deposition is a major concern for coastal zone management. Shoreline is changed by nature factor or development of coastal. Change of shoreline is threatening marine environment and destroying. Therefore, we need monitoring of shoreline change with time series analysis for coastal zone management. In this study, we analyzed the shoreline change using airphotograph, LiDAR and satellite imagery from 1971 to 2009 in Uljin, Gyeongbuk, Korea. As a result, shoreline near of the nuclear power plant show linear pattern in 1971 and 1980, however the pattern of shoreline is changed after 2000. As a result of long-term monitoring, shoreline pattern near of the nuclear power plant is changed by erosion toward sea. The pattern of shoreline near of KORDI until 2003 is changed due to deposition toward sea, but the new pattern toward land is developed by erosion from 2003 to 2009. The shoreline is changed by many factors. However, we will guess that change of shoreline within study area is due to construction of nuclear power plant. In the future work, we need sedimentary and physical studies.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.100-100
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• 2017

하천에 유입된 오염물질의 2차원 혼합거동은 하천 주흐름에 의한 이송현상과 유속 성분의 수심평균 값에 대한 공간적 편차로부터 야기되는 분산현상으로 설명 할 수 있다. 이는 3차원 이송확산 방정식으로부터 수심 적분된 2차원 이송-분산 방정식으로 수학적 유도가 가능하며, 수심방향으로 적분하는 과정에서 발생되는 농도의 분산항은 Taylor Dispersion 개념에 기초하여 종방향 및 횡방향의 2차원 분산계수로 표현된다. Fischer(1978)는 연직방향 유속분포로부터 2차원 분산계수를 추정하는 해석해를 수학적으로 유도하였으나, 실제 하천에서 정밀한 연직방향 유속분포를 계측하는 것은 많은 비용 및 노동력을 초래한다. 따라서 선행 연구자들은 2차원 혼합모형의 분산계수를 산정하고자 실험적 방법으로써 추적자실험을 수행하였다. 추적자실험은 추적자 물질을 수체에 주입한 후 농도의 변화를 관측함으로써 추적자물질이 하천에서 이송 및 분산되는 과정을 이해하는데 유용하다. 기존의 추적자실험은 고정된 위치에서 농도를 계측하여 시계열적인 농도의 변화를 관측한 후, 오염운 동결가정을 통해 종,횡방향 분산계수의 산정이 가능하지만, 오염물질 농도의 공간적 분포를 얻기에는 한계가 있다. 본 연구에서는 기존의 추적자실험법의 한계를 극복하고자 형광물질을 이용한 추적자실험을 수행함과 동시에 드론에 장착된 디지털카메라를 이용하여 항공영상을 취득 및 분석하여, 하천에 주입된 형광물질의 농도분포를 시공간적으로 추출하는 기법을 개발하고, 이를 바탕으로 오염물질의 2차원 혼합거동을 분석하였다. 본 실험은 한국건설기술연구원의 안동하천실험센터의 A3실험수로에서 수행되었으며, 실험수로는 평균 하폭 5 m, 평균 수심 0.44 m, 유량 $0.96m^3/s$의 실제 소규모 하천과 유사한 축척을 가지고 있다. 추적자물질은 Rhodamine WT 용액이 사용되었으며, 실험수로 내 설치된 15개의 형광광도계(YSI-600OMS)를 이용하여 농도를 측정하였다. 항공영상의 취득을 위해 이용된 드론은 DJI-Phantom 3 Professional 이며, 3840x2160의 해상도로 초당 30 frame의 동영상으로 취득되었다. 영상의 정합 및 좌표화를 위해 RTK-GPS를 이용하여 12개의 지상 기준점의 좌표를 취득한 후, 사영변환을 통해 영상좌표를 지상좌표로 변환하였다. 영상의 픽셀값을 농도장으로 변환하기 위해 각 RGB 밴드의 픽셀값을 통계적으로 분석하여 농도장으로 변환하였으며, 영상으로부터 얻은 농도장은 형광광도계에 의해 실측된 농도와 결정계수 0.9이상의 수준으로 정확도를 나타냈다.