• Applied Chemistry for Engineering
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• v.18 no.4
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• pp.376-380
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• 2007

Used polyurethane (PU) was chemically degraded by the treatment with flame retardants such as tris(1,3-chloro-2-propyl) phosphate (TCPP), triethyl phosphate (TEP), and trimethyl phosphate (TMP). Analysis of FT-IR and P-NMR showed that the degraded products (DEP) contained oligourethanes. Rigid polyurethane foam was produced using the DEP as flame retardants. The flammability and thermal stability of recycled rigid polyurethane were investigated. The mechanical properties such as compressive strength of recycled polyurethane were also studied. The recycled polyurethane reduced flammability and enhanced thermal stability over intrinsic polyurethane. Mechanical strength of recycled polyurethane also shows as high as that of intrinsic polyurethane. In order to evaluate flame retardant properties of the recycled polyurethane foams with various amounts of DEP, heat release rate (HRR) of the foam was measured by cone calorimeter. Scanning electron micrograph of recycled PU showed a uniform cell morphology as a intrinsic PU.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.493-499
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• 2009

The properties of polystyrene and styrenic copolymer nanocomposites containing carbon nanotubes (CNT) and nanoclays were studied. Polystyrene and styrenic copolymer containing styrene and vinylbenzyl trimethylammonium chloride (SVTAC) were synthesized by emulsion polymerization. Polystyrene/CNT/clay and SVTAC/CNT/clay nanocomposites with various concentrations of CNT and different types of clay were prepared via mixing of polystyrene emulsion and clay. SVTAC/CNT nanocomposites showed a better electrical conductivity than PS/CNT nanocomposites. Nanocomposites with more surfactant during polymerization showed a better electrical conductivity than the ones with less surfactant. These indicated the positive effect of comonomer and surfactant on the electrical conductivity. Transmission electron microscopy (TEM) was used to analyze the state of CNT dispersion. TEM results showed that CNT loading, comonomer composition and amount of surfactant affected the final dispersion of CNT in nanocomposites. In order to confirm the effects of CNT loading, comonomer composition and the amount of surfactant on the thermal and dynamic mechanical properties, DSC and DMA analyses were conducted.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.22 no.2
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• pp.151-159
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• 2004

The diversity, expansion of human activity and rapid urbanization make modem society to faced with problems like damage of nature and drain of natural resources. Under these circumstances rapid and accurate change detection techniques, which can detect wide range utilization changes, are needed for efficient management and utilization plan of national territory. In this study to perform change detection from remote sensing images, space analysis technique contained in Geographic Information System is applied. And from this technique, the software. that can execute new change detection algorithm, query, inquiry and analysis, is produced. This software is on the basis of graphic user interface and has many functions such as format conversion, grid calculation, statistical processing, display and reference. In this study, simultaneously change detection for multi-temporal satellite images can be performed and integrated one change image about four different periods was produced. Further more software user can acquire land cover change information for an specific area through querying and questioning about yearly changes. Finally making of every application module for change detection into one window based visual basic program, can be produced user convenience and automatic performances.

• Korean journal of food and cookery science
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• v.28 no.6
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• pp.711-719
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• 2012

The collagens from squid (Todarodes pacificus) skin and Alaska pollack (Theragra chalcogramma) skin were extracted and their physicochemical properties were investigated. The yield was improved with the increase of NaOH concentration and was increased Neutrase than Alcalase in enzymatic hydrolysates. Protein and collagen contents from Alaska pollack skin were 38.3~62.7% and 13.1~28.9%, respectively. All enzymatic hydrolysates also showed high antioxidant activities as NaOH concentration decrease. Composition of their amino acids was mainly glycine and proline. The spectrum of FT-IR of the collagen showed wavenumber at $1,631cm^{-1}$, $1,549cm^{-1}$, $1,234cm^{-1}$ and $3,322cm^{-1}$ representing the regions of amide I, amide II, amide III and amide A, respectively. The decomposition temperature for the collagen was in the range of $300^{\circ}C$ and showed relatively good enough for their thermal stabilities.

• Fire Science and Engineering
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• v.29 no.6
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• pp.40-44
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• 2015

National and international standards for curtain wall glass are focused on wind pressure and insulation performance, but disasters such as fires and earthquakes are not considered. Failure of curtain wall glass during a fire in a skyscraper increases the loss of lives and property due to the spread of fire. Therefore, the fire resistance of curtain wall glass should be investigated, and technology to prevent glass failure should be developed to prevent fire damage due to spreading fire. It is important to predict the starting point of cracks and the cause of glass failure to prevent it effectively using the limited water in a skyscraper. In this study, double glazed glass was exposed to a radiator in an experiment performed to analyze the thermal characteristics. The results show that glass that was not directly exposed to high temperature and pressure was broken. To identify this failure case, numerical analysis was performed. Three glass specimens were installed in an ISO 9705 room and exposed to radiation using a radiator, and a thermocouple was used to measure the temperature on the surface of the glass. Widely used double glazed glass was analyzed for weakness to fire.

• Korean Journal of Agricultural and Forest Meteorology
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• v.20 no.2
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• pp.205-213
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• 2018

Development and validation of crop models often require measurements of biomass for the crop of interest. Considerable efforts would be needed to obtain a reasonable amount of biomass data because the destructive sampling of a given crop is usually used. The Kinect sensor, which has a combination of image and depth sensors, can be used for estimating crop biomass without using destructive sampling approach. This approach could provide more data sets for model development and validation. The objective of this study was to examine the applicability of the Kinect sensor for estimation of chinese cabbage fresh weight. The fresh weight of five chinese cabbage was measured and compared with estimates using the Kinect sensor. The estimates were obtained by scanning individual chinese cabbage to create point cloud, removing noise, and building a three dimensional model with a set of free software. It was found that the 3D model created using the Kinect sensor explained about 98.7% of variation in fresh weight of chinese cabbage. Furthermore, the correlation coefficient between estimates and measurements were highly significant, which suggested that the Kinect sensor would be applicable to estimation of fresh weight for chinese cabbage. Our results demonstrated that a depth sensor allows for a non-destructive sampling approach, which enables to collect observation data for crop fresh weight over time. This would help development and validation of a crop model using a large number of reliable data sets, which merits further studies on application of various depth sensors to crop dry weight measurements.

• Membrane Journal
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• v.19 no.2
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• pp.96-103
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• 2009

A series of organic-inorganic composite membranes from poly(vinyl chloride) (PVC) graft copolymer electrolyte and heteropolyacid (HPA) were prepared for proton conducting membranes. First, poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of PVC. HPA nanoparticles were then incorporated into the PVC-g-PSSA graft copolymer though the hydrogen bonding interactions, as confirmed by FT-IR spectroscopy. The proton conductivity of the composite membranes increased from 0.049 to 0.068 S/cm at room temperature with HPA contents up to 0.3 weight traction of HPA, presumably due to both the intrinsic conductivity of HPA particles and the enhanced acidity of the sulfonic acid of the graft copolymer. The water uptake decreased from 130 to 84% with the increase of HPA contents up to 0.45 of HPA weight traction, resulting from the decrease in number of water absorption sites due to hydrogen bonding interaction between the HPA particles and the polymer matrix. Thermal gravimetric analysis (TGA) demonstrated the enhancement of thermal stabilities of the composite membranes with increasing concentration of HPA.

• Membrane Journal
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• v.23 no.2
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• pp.151-158
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• 2013

The effect of layered double hydroxides (LDH) on the gas separation properties of ethylene vinyl acetate copolymer was investigated. Mg-Al LDH/EVA nanocomposite membranes were prepared from solution intercalation using organically modified LDH (DS-LDH). Dodecyl sulfate (DS)-LDH was obtained by the intercalation of DS anion in the interlayer. The nanocomposite structure has been elucidated by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). XRD pattern clearly shows that the DS-LDH layers are disorderly well dispersed in the EVA matrix. The maximum tensile strength and elongation of the LDH/EVA nanocomposite membrane were found with the LDH content 3 wt%. The thermal properties of nanocompostie membrane were enhanced by the incorporation of LDH in EVA matrix. Gas permeation of LDH/EVA nanocomposite membranes with LDH contents of 1, 3, 5 wt% was studied for $O_2$ and $CO_2$ single gases. The presence of 3 wt% LDH decreased $O_2$ permeability by up to 53% compared to the EVA membrane. In spite of barrier property of nanocomposite membrane, however, the gas permeability for $CO_2$ was increased due to its strong affinity with the residual OH groups on the LDH.

• Korean Journal of Remote Sensing
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• v.31 no.5
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• pp.371-384
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• 2015

Although GOCI has potential for land surface monitoring, there have been only a few cases for land applications. It might be due to the lack of reliable land products derived from GOCI data for end-users. To use for land applications, it is often essential to provide cloud-free composite over land surfaces. In this study, we proposed a cloud detection method that was very important to make cloud-free composite of GOCI reflectance and vegetation index. Since GOCI does not have SWIR and TIR spectral bands, which are very effective to separate clouds from other land cover types, we developed a multi-temporal approach to detect cloud. The proposed cloud detection method consists of three sequential steps of spectral tests. Firstly, band 1 reflectance threshold was applied to separate confident clear pixels. In second step, thick cloud was detected by the ratio (b1/b8) of band 1 and band 8 reflectance. In third step, average of b1/b8 ratio values during three consecutive days was used to detect thin cloud having mixed spectral characteristics of both cloud and land surfaces. The proposed method provides four classes of cloudiness (thick cloud, thin cloud, probably clear, confident clear). The cloud detection method was validated by the MODIS cloud mask products obtained during the same time as the GOCI data acquisition. The percentages of cloudy and cloud-free pixels between GOCI and MODIS are about the same with less than 10% RMSE. The spatial distributions of clouds detected from the GOCI images were also similar to the MODIS cloud mask products.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.137-147
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• 1999

Fluidized-bed thermal desorber coupled with a heat pipe was investigated for the remediation of soil contaminated with diesel oils. Thermal gravimetric analysis by Cahn-balance indicated that the desorption of diesel oils from the soil particles was mainly governed by the internal diffusion at low concentration of less than 0.5 wt. % of oils in the soil particles. In fluidized-bed experiments. increase of fluidizing gas velocity reduced the residual oils of the contaminated soils, the increase of soil feed rate decreased efficiency of fluidized-bed desorber. A mathematical model was developed by incorporating Fickian diffusion kinetics into the Kunii-Levenspiel model Simulation results showed reasonable agreement for the performance of fluidized-bed thermal desorber.