• Journal of the Korean Electrochemical Society
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• v.6 no.4
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• pp.229-235
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• 2003

A precursor of lithium manganese oxide was synthesized by mixing $(CH_3)_2CHOLi\;with\;Mn(CH_3COO)_2{\cdot}4H_2O$ in ethanol using a sol-gel method, then heat-treated at $400^{\circ}C\;and\;800^{\circ}C$ in air atmosphere. The condition of heat treatment was determined by thermogravimetric analysis/differential thermogravimetric analysis (TGA/DTA). The characterization of the lithium manganese oxide was done by X-ray diffraction (XRD) spectra and scanning electron microscopy (SEM). The electrochemical characteristics of lithium manganese oxide electrode for lithium ion battery were measured by cyclic voltammetry (CV), chronoamperometry and AC impedance method using constant charge/discharge process. The electrochemical behaviors of the electrode have been investigated in a 1.0M $LiClO_4/propylene$ carbonate electrolyte solution. The diffusivity of lithium ions, $D^+\;_{Li}\;^+$, as determined by AC impedance technique was $6.2\times10^{-10}cm^2s^{-1}$.

• Journal of the Korean Vacuum Society
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• v.7 no.1
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• pp.17-23
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• 1998

$Pb(Fe_{0.5}Nb_{0.5}O_3(PFN)$ thin films were prepared by rf magnetron co-sputtering method on $SiO_2/Si$, ITO/glass, and $Pt/Ti/SiO_2/Si$ substrates and post-annealed at the $N_2$ atmosphere by RTA(rapid thermal annerling). The degree of crystallinity of PFN films was identified on various substrates. Electrical properties of PFN films was characterized for $Pt/PFN/Pt/Ti/SiO_2/Si$ structure. The composition of PFN films was estimated by EPMA (electron probe micro analysis). PFN films would be crystallized better to perovskite phase on ITO/glass substrate than $SiO_2/Si$ substrate. This may be induced by the deformation of Pb deficient pyrochlore phase due to Pb diffusion into $SiO_2/Si$ substrate. PFN films on $Pt/Ti/SiO_2/Si$ substrate. PFN films with 5-10% Pb excess were crystallized to perovskite phase from $500^{\circ}C$ temperature. In summary, we show that Pb composition and annealing temperature were critically influenced on crystallinity to perovskite phase. When PFN film with 17% Pb excess was annealed at $600^{\circ}C$ at the $N_2$ atmosphere for 300kV/cm and 88. Its remnant polarization coercive field $2.0 MC/cm^2$ and 144kV/cm, respectively.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.3
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• pp.329-338
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• 2019

Suction of unsaturated bentonite buffers is a very important input parameter for hydro-mechanical performance assessment and design of an engineered barrier system. This study analyzed suction measurement techniques and constitutive models of unsaturated porous media reported in the literature, and suggested suction measurement techniques and constitutive models suitable for bentonite buffer in an HLW repository. The literature review showed the suction of bentonite buffer to be much higher than that of soil, as measured by total suction including matric suction and osmotic suction. The measurement methods (RH-Cell, RH-Cell/Sensor) using a relative humidity sensor were suitable for suction measurement of the bentonite buffer; the RH-Cell /Sensor method was more preferred in consideration of the temperature change due to radioactive decay heat and measurement time. Various water retention models of bentonite buffers have been proposed through experiments, but the van Genuchten model is mainly used as a constitutive model of hydro-mechanical performance assessment of unsaturated buffers. The water characteristic curve of bentonite buffers showed different tendencies according to bentonite type, dry density, temperature, salinity, sample state and hysteresis. Selection of water retention models and determination of model input parameters should consider the effects of these controlling factors so as to improve overall reliability.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.2B
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• pp.219-231
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• 2010

The Reference Evapotranspiration Calculator Software (REF-ET) supports computational guidelines for the reference evapotranspiration using seventeen FAO Penman-Monteith (PM) equations simultaneously such as the ASCE and FAO standardized forms. The REF-ET can conveniently consider missing data predictions and regional site characterizations, when reference ET is computed on monthly, daily, and hourly time steps. The applicability of the REF-ET was estimated to simulate the reference ET using hourly weather data from Seoul weather station for 29 years. The result found that the FAO24-Rd and 1957-Makk equations closely concerned with solar radiation parameter which were the most highly correlated to reference ET computed by pan coefficient. In addition, the 1957-Makk equation was identified as the most correct computational method for reference ET by analysis of bias and root mean square error. The 1957-Makk equation could predict the reference ET within the error of less than 1.06 mm/day, though all the other equations tended toward overestimation of predicting the reference ET in comparison with refecence ET of pan. The results of this study suggest that the REF-ET will be applicable to support reference ET estimation for a variety of field condition and time-scale.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.11
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• pp.477-493
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• 2020

This study conducted a seasonal survey to analyze the spatio-temporal variations of marine environments and phytoplankton community in Gochang Coastal Waters (GCW) from August 2016 to April 2017. In the results, the water temperature ranged from 2.1℃ to 34.5℃, showing a large seasonal variation, but the salinity changed from 31.14 psu to 32.64 psu. Therefore, the seasonal variations of water types in GCW were mainly determined by water temperature. The phytoplankton community consisted of 53 genera and 86 species, showing a relatively simple distribution. The phytoplankton cell density ranged from 2.2 to 689.2 cells mL^-1, with an average of 577.2 cells mL^-1, which was low in autumn and high in winter. The seasonal succession of phytoplankton dominant species was mainly diatoms during the whole year, Leptocylindrus danicus, Chaetoceros curvisetus, Skeletonema costatum-ls in summer, Paralia sulcata, Eucampia zodiacus in autumn, S. costatum-ls, Thalassiosira nordenskioeldii in winter, and S. costatum-ls, Asterionella glacialis in spring. In other words, the phytoplankton community showed high diversity in GCW throughout the year. According to the PCA, GCW were easily heated and cooled by radiant energy at lower depth, and the seasonal distributions of phytoplankton were determined by the supply of nutrients by re-fuelling of surface sediments due to the seawater mixing such as tidal mixing.

• Journal of the Korean Magnetics Society
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• v.18 no.5
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• pp.195-199
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• 2008

Composites of $Fe_{93.5}Si_{6.5}$ powder and epoxy were prepared using a thermal curing process. Scanning electron microscope (SEM), vibrating sample magnetometer (VSM) and network analyzer were used to analyze the structure, electromagnetic properties and microwave absorption of the composites. Results show that the saturation magnetization depends on the fraction of the $Fe_{93.5}Si_{6.5}$ powder in the composite, which affects initial permeability. It is believed that the eddy current loss is a dominant factor over 1 GHz and that the resonance frequency of the composite decreases with increasing fractions of $Fe_{93.5}Si_{6.5}$ powder. Finally, reflection loss was calculated from the permeability and permittivity of these composites. Composite with 50 wt.% $Fe_{93.5}Si_{6.5}$ powder fractions and 5 mm thickness showed reflection loss below -20 dB from 3.66 GHz to 4.16 GHz. Therefore, it is believed that thin Fe-Si/epoxy composites may be a good candidate for microwave absorption application.

• Journal of Korean Society of Forest Science
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• v.102 no.3
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• pp.382-389
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• 2013

The present study grasped the operation characteristics and operation management of forest museums in Korea and analyzed satisfaction with the foregoing. In the results of a survey of forest museums' operation characteristics, with regard to groups to which exhibits were helpful, over half of respondents answered that the exhibits were helpful to students and many respondents had an opinion that all age groups should be equally considered as targets of exhibition. Among matters that were considered with regards to forest museums, accessibility showed the highest rate of answers followed by museum programs. The curator was needed for the majority of respondents were exhibits prior to the survey had the highest expectations for the medium. With regard to the operation management of forest museums, the expected value of periodic and extraordinary exhibitions was shown to be high and high and satisfaction was shown by the professionalism of staff. As for matters of forest museums that must be improved, attention should be paid to the development of programs in which users can participate, diverse exhibition media should be developed, and exhibition should be planned to fit the composition of exhibits. As for operation management, since exhibits were repeated every year, environments should be changed by exhibiting new exhibits or otherwise and active methods of improvement should be devised such as the utilization of broadcasting media for public relations.

• Journal of the Mineralogical Society of Korea
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• v.16 no.4
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• pp.321-331
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• 2003

We researched the variation of mineral composition with depth and the Cu adsorption behavior of Hwangto in the Okjong area, Hadong. The 4 Hwangto samples were collected from depth 10 cm, 25 cm, 2∼3 m and under 3 m from surface, and analyzed using the X­ray Diffractometer. The Hwangto samples were mostly composed of clay minerals such as kaolinite and halloysite. Two samples from 10 cm and 25 cm contained Fe or Al hydroxide minerals, for example goethite or gibbsite. As depth increases, the content of quartz decreases but that of kaolinite increases. The amount of Cu removal was rapidly rised from pH 4, and reached about 90％ at pH 6 and above 90％ at pH 7. It is regarded that the trend of Cu removal was affected by the difference in mineral composition. It was relatively well matched between experimental value and calculated value by MINTEQA2 program in the case of high Cu concentration. From this study the precipitation has important role for the removal of Cu ions, particularly in the case of high Cu concentration. However, it was discord between experimental value and calculated one in the dilute concentration circumstances. The reason may be the mistake in parameters, insufficient reaction time, and inadequate consideration of reaction site in mineral surface.

• Geophysics and Geophysical Exploration
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• v.21 no.2
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• pp.67-81
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• 2018

We acquired the magnetic and bathymetry data around the TA (Tofua Arc) 22 seamount in the Lau Basin for finding submarine hydrothermal deposits. From the data, we estimated the magnetic characteristics in the study area. The bathymetry shows that TA 22 seamount consists of the western and eastern summits. Each summit exhibits a caldera. The western caldera is smaller, but deeper than the eastern caldera. The slope gradients of the TA 22 are steeper around ~1000 m depth range and relatively gentle at the summit areas with the small difference of two calderas. The magnetic properties of TA 22 seamount present high anomalies at the summit and the vicinity of the caldera. Low magnetization zones appear over the outer flanks and center of the calderas. These magnetic patterns are similar to the previous studies which had represented high anomalies and low magnetization zones inside of the summit area or on the flank of the outside of the summit area. The results of the 2D magnetic forward modeling with seismic profiles show about 20 nT of RMSEs (root mean square error) between the modeled and observed values. The low RMSEs proposes a good correlation between the modeled 2D structure and the geophysical observation in this study area. Based on the modeling and magnetization distribution, hydrothermal deposits are predicted to be located at the inner area of the calderas or at small mounds around caldera rims.

• Journal of Digital Convergence
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• v.16 no.8
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• pp.169-179
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• 2018

Recently, web search query information has been applied in advanced predictive model research. Google dominates the global web search market in the Korean market; however, Naver possesses a dominant market share. Based on this characteristic, this study intends to compare the utility of the Korean web search query information of Google and Naver using predictive models. Therefore, this study develops three time-series predictive models to estimate the youth unemployment rate in Korea using the ARIMA model. Model 1 only used the youth unemployment rate in Korea, whereas Models 2 and 3 added the Korean web search query information of Naver and Google, respectively, to Model 1. Compared to the predictability of the models during the training period, Models 2 and 3 showed better fit compared with Model 1. Models 2 and 3 correlated different query information. During predictive periods 1 (continuous with the training period) and 2 (discontinuous with the training period), Model 3 showed the best performance. During predictive period 2, only Model 3 exhibited a significant prediction result. This comparative study contributes to a general understanding of the usefulness of Korean web query information using the Naver and Google search engines.