• Title/Summary/Keyword: 열분석적 특성

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Effect of Magnesium Oxide on Physical and Chemical Properties of FKM Elastomer (FKM Elastomer의 물리적 및 화학적 성질에 미치는 산화마그네슘의 영향)

  • Lee, Chang-Seop;Choi, Gi-Tae;Choi, Han-Hwal
    • Elastomers and Composites
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    • v.38 no.1
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    • pp.57-64
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    • 2003
  • Metal oxide(MgO) was added to FKM rubber in order to develop automotive fuel hose which ran show elastic characteristics under extreme condition. Cure characteristics, physical properties, thermal resistance and fuel resistance of FKM compounded rubber with MgO were investigated. MgO was mixed to FKM rubber materials within the range of $0{\sim}20phr$. From the test results of rheological properties and Mooney viscosity, the $t_{s2}$, $T_{c90}$ values increased as the MgO contents increased in FKM rubber compounding. Hardness and 100% modulus of FKM compounded rubber slightly increased, but tensile strength and elongations at break slightly decreased. From the test results of thermal resistance of rubber specimens at 130, 150, and $170^{\circ}C$ for 70 hrs, the changing rate of physical properties was found to be relatively small. Fuel resistance tests were carried out for fuel A, B, C and D at $40^{\circ}C$ for 70hrs, and the results showed that the changing rate in physical properties was found to increase from Fuel A to D, Furthermore thermal properties of FKM compounded rubber containing MgO were also investigated by using TGA/DSC. The optimum mixing ratio of additive to FKM rubber to get the maximum effect on thermal resistance and fuel resistance, within the range of desirable specification for rubber material, was determined to be 6 phr for MgO.

Computationally Efficient ion-Splitting Method for Monte Carlo ion Implantation Simulation for the Analysis of ULSI CMOS Characteristics (ULSI급 CMOS 소자 특성 분석을 위한 몬테 카를로 이온 주입 공정 시뮬레이션시의 효율적인 가상 이온 발생법)

  • Son, Myeong-Sik;Lee, Jin-Gu
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.11
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    • pp.771-780
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    • 2001
  • It is indispensable to use the process and device simulation tool in order to analyze accurately the electrical characteristics of ULSI CMOS devices, in addition to developing and manufacturing those devices. The 3D Monte Carlo (MC) simulation result is not efficient for large-area application because of the lack of simulation particles. In this paper is reported a new efficient simulation strategy for 3D MC ion implantation into large-area application using the 3D MC code of TRICSI(TRansport Ions into Crystal Silicon). The strategy is related to our newly proposed split-trajectory method and ion-splitting method(ion-shadowing approach) for 3D large-area application in order to increase the simulation ions, not to sacrifice the simulation accuracy for defects and implanted ions. In addition to our proposed methods, we have developed the cell based 3D interpolation algorithm to feed the 3D MC simulation result into the device simulator and not to diverge the solution of continuous diffusion equations for diffusion and RTA(rapid thermal annealing) after ion implantation. We found that our proposed simulation strategy is very computationally efficient. The increased number of simulation ions is about more than 10 times and the increase of simulation time is not twice compared to the split-trajectory method only.

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Vegetation Cover Type Mapping Over The Korean Peninsula Using Multitemporal AVHRR Data (시계열(時系列) AVHRR 위성자료(衛星資料)를 이용한 한반도 식생분포(植生分布) 구분(區分))

  • Lee, Kyu-Sung
    • Journal of Korean Society of Forest Science
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    • v.83 no.4
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    • pp.441-449
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    • 1994
  • The two reflective channels(red and near infrared spectrum) of advanced very high resolution radiometer(AVHRR) data were used to classify primary vegetation cover types in the Korean Peninsula. From the NOAA-11 satellite data archive of 1991, 27 daytime scenes of relatively minimum cloud coverage were obtained. After the initial radiometric calibration, normalized difference vegetation index(NDVI) was calculated for each of the 27 data sets. Four or five daily NDVI data were then overlaid for each of the six months starting from February to November and the maximum value of NDVI was retained for every pixel location to make a monthly composite. The six bands of monthly NDVI composite were nearly cloud free and used for the computer classification of vegetation cover. Based on the temporal signatures of different vegetation cover types, which were generated by an unsupervised block clustering algorithm, every pixel was classified into one of the six cover type categories. The classification result was evaluated by both qualitative interpretation and quantitative comparison with existing forest statistics. Considering frequent data acquisition, low data cost and volume, and large area coverage, it is believed that AVHRR data are effective for vegetation cover type mapping at regional scale.

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Oxide Films Formed on Hot-Dip Aluminized Steel by Plasma Electrolytic Oxidation and Their Films Growth Stages (플라즈마 전해 산화법에 의해 용융알루미늄도금 강판 상 형성한 산화층과 그 성장 과정)

  • Choe, In-Hye;Kim, Chang-Min;Park, Jun-Mu;Park, Jae-Hyeok;Hwang, Seong-Hwa;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.165-165
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    • 2017
  • 지난 수 십 년 동안, 전 세계적으로 자원의 소비가 급격히 증가하게 되면서 최근 자원 고갈은 물론 환경오염이 커다란 이슈로 문제가 되고 있다. 이에 따라 재료 관련 분야에 있어서는 보다 효율적이고 친환경적인 방법으로 자원을 활용해야 된다는 필요성이 대두되었고 이와 같은 관점에서 목적하는 성분이 우수하고 환경 친화적인 표면처리 재료 개발연구가 활발하게 진행되고 있는 실정이다. 그 중 플라즈마 전해 산화(Plasma Electrolytic Oxidation, PEO)는 알루미늄, 마그네슘 등의 경금속의 경도를 향상시키고 높은 내마모성, 내식성을 갖게 하는 표면처리로써 그 관심이 증가하고 있다. 이 플라즈마 전해 산화는 일반적으로 공정비용 대비 효과적이고 환경 친화적이며 코팅 성능 면에서 우수하다고 알려져 있다. 이러한 고유한 특성으로 인해 플라즈마 전해 산화 코팅은 최근 몇 년 동안 기계, 자동차, 우주항공, 의학 및 전기 산업 등의 분야에서 그 적용이 점차 증가하고 있는 상황이다. 한편, 플라즈마 전해 산화 코팅을 하는 모재들의 경우 부동태 산화피막을 용이하게 형성할 수 있는 특성의 모재에 한정되고 있어서 그 응용확대에 한계가 있는 것이 사실이다. 따라서 본 연구에서는 플라즈마 전해 산화법을 사용하여 용융알루미늄도금 강판 상에 산화피막 형성을 시도하였다. 전원공급 장치의 양극은 전해질 속에 잠겨있는 작동전극에 연결하고 음극은 대전극 역할을 하는 스테인레스강 전해질 용기에 연결되었다. 전해질은 Sodium Aluminate 및 기타 첨가제를 함유한 것을 사용하였고 온도는 열교환기를 사용하여 $30^{\circ}C$ 이하로 유지되었다. 또한 여기서 전류밀도는 $5{\sim}10A/dm^2$, 실험 주파수는 700Hz, Duty cycle은 30 및 90%의 각 조건에서 공정처리 시간을 각각 30분 및 60분 동안 진행하였다. 이와 같은 조건에서 형성한 막들에 대해서는 주사형전자현미경(SEM)을 이용하여 코팅 막의 표면 및 단면의 모폴로지를 관찰하였음은 물론 EDS 및 XRD 측정을 통하여 원소조성분포 및 결정구조를 각각 분석하였다. 또한 이 코팅 막들에 대한 내식성은 5% 염수분무 환경 중 노출시험(Salt spray test), 3% NaCl 용액에서의 침지 시험 및 전기화학적 동전위 양극분극(Potentiodynamic Polarization) 시험을 진행하여 평가하였다. 이상의 실험결과에 의하면, 제작조건별 플라즈마 전해 산화 코팅 막의 모폴로지 및 결정구조가 상이하게 나타나는 것을 알 수 있었다. 코팅 막의 모폴로지 관찰 결과, 공정 시간에 비례하여 표면에 존재하는 원형 기공의 수는 감소하였으나 그 크기가 커지고 크레이터의 직경 또한 커진 것이 확인되었다. 이 기공은 마이크로 방전에 의해 형성된다고 알려져 있는데 공정 시간이 증가함에 따라 코팅 두께가 점차 증가하여 마이크로 방전의 빈도수가 줄어들고 그 강도는 증가하게 되어 기공 크기가 증가한 것으로 사료된다. 또한 공정시간이 긴 시편에서 표면에 크랙이 다수 존재하는 것으로 확인되었다. 이것은 방전에 의해 고온이 된 소재가 차가운 전해질과 만나게 되어 생긴 큰 온도구배로 인해 강한 열응력이 발생하여 균열을 초래한 것으로 보인다. 조성원소 분석 결과 원형 기공 주변의 크레이터 영역에는 알루미늄이 풍부하였으며 그 주변에 결절상을 갖는 구조에서는 전해질 성분의 원소가 포함되어 있는 것이 확인되었다. 이러한 코팅 막의 표면 특성은 내식성에 영향을 주게 된 원인으로 사료된다. 동전위 분극측정 결과에 의하면 플라즈마 전해 산화 공정 시간이 길어질수록 부식전류밀도가 증가하였다. 이것은 공정시간이 길어짐에 따라 강한 방전이 발생하여 기공의 크기가 증가하고 크랙이 발생하게 되면서 내식성이 저하된 것으로 판단된다. 종합적으로 재료특성 분석 및 내식성 평가를 분석한 결과, 플라즈마 전해 산화의 공정 시간이 너무 길게 되면 오히려 내식성은 저하되는 것이 확인되었다. 이상의 연구를 통하여 고내식 특성을 갖는 플라즈마 전해 산화 막의 유효성을 확인하였으며 용융알루미늄강판 상에 실시한 플라즈마 전해 산화 처리에 대한 기초적인 응용 지침을 제시할 수 있을 것으로 사료된다.

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Analysis of Heat Transfer Characteristics on Multi-layer Insulating Curtains Coated with Silica Aerogel (실리카 에어로겔이 흡착된 다겹보온커튼의 전열 특성 분석)

  • Jin, Byung-Ok;Kim, Hyung-Kweon;Ryou, Young-Sun;Lee, Tae-Seok;Kim, Young-Hwa;Oh, Sung-Sik;Kang, Geum-Choon
    • Journal of Bio-Environment Control
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    • v.28 no.3
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    • pp.273-278
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    • 2019
  • The multi-layer insulating curtains used in the experiment was produced in six combinations using non-woven fabric containing aerogel and compared and analyzed by measuring heat flux and heat perfusion rates due to weight, thickness and temperature changes. Using silica aerogel, which have recently been noted as new material insulation, this study tries to produce a new combination of multi-layer insulating curtains that can complement the shortcomings of the multi-layer insulating curtains currently in use and maintain and improve its warmth, and analyze the thermal properties. The heat flux means the amount of heat passing per unit time per unit area, and the higher the value, the more heat passing through the multi-layer insulating curtain, and it can be judged that the heat retention is low. The weight and thickness of multi-layer insulation curtains were found to be highly correlated with thermal insulation. In particular, insulation curtains combined with aerogel meltblown non-woven fabric had relatively higher thermal insulation than insulation curtains with the same number of insulation materials. However, the aerogel meltblown non-woven fabric is weak in light resistance and durability, and there is a problem that the production process and aerogel are scattering. In order to solve this problems, the combination of expanded aerogel non-woven fabric and hollow fiber non-woven fabric, which are relatively simple manufacturing processes and excellent warmth, are suitable for use in real farms.

Hydrothermal Alteration of Miryang Pyrophyllite Deposit (밀양납석광상의 열수변질 특징)

  • Moon, Dong Hyeok;Kwak, Kyeong Yoon;Lee, Bu Yeong;Koo, Hyo Jin;Cho, Hyen Goo
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.3
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    • pp.265-277
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    • 2015
  • Hydrothermal alteration patterns and environment are studied by mineral assemblages and chemical analyses of surface and core samples from Miryang pyrophyllite deposit. The alteration zones of this deposit can be divided into three zones on the basis of mineral assemblage; advanced argillic, phyllic, and propylitic zone. Advanced argillic zone mainly consists of pyrophyllite-dickite (-quartz) and corresponds to principal mining ore. The common mineral assemblage of phyllic zone and propylitic zone are sericite-quartz-dickite and chlorite-quartz, respectively. Horizontal and vertical alteration patterns and major element geochemistry indicate that pyrophyllite ores have been formed several times by hydrothermal alteration. And it also suggests that the huge ore bodies may be extended from the deeper part of recent quarries to the south-southeastern direction. The paragenesis of ore minerals and polytype (2M) suggest that ore deposit was formed at about $300-350^{\circ}C$.

Preparation of Mesoporous and Spherical-shaped Silica Particles by Spray Pyrolysis (분무열분해 공정을 이용한 메조기공을 가지는 실리카 구형입자의 제조)

  • Baek, Chul-Min;Jung, Kyeong Youl;Park, Kyun Young;Park, Seung Bin;Cho, Sung Baek
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.880-885
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    • 2008
  • Spray pyrolysis was applied to prepare spherical silica particles with mesopores of a regular structure. The physical properties such as surface area, pore size, pore structure, particle size, and morphology were studied by BET, SEM, SAXS, and DLS analysis. At a fixed gas flow rate, the BET surface area changed from 200 to $1,290m^2/g$ as changing the CTAB/TEOS molar ratio from 0.05 to 0.3. At a fixed CTAB/TEOS ratio, the surface area of silica particles was varied from 1,062 to $1,305m^2/g$ with changing the gas flow rate from 10 to 40 l/min. The average pore size measured by BJH desorption was about $21{\sim}23{\AA}$ and not significantly influenced by the CTAB/TEOS ratio and the gas flow rate. Finally, the highest surface area which was $1,305m^2/g$ were obtained when the CTAB/TEOS ratio and the gas flow rate were 0.2 and 20 l/min, respectively. According to SAXS analysis, the prepared silica particles showed a strong peak at $2{\theta}=2.6^{\circ}$ and two minor peaks around $2{\theta}=4.4^{\circ}$ and $5.1^{\circ}$, which are due to regular mesopores of hexagonal structure. The morphology of silica particles prepared were spherical shape and the average particle size was $1.0{\mu}m$.

Simulation of Particle Behaviors within a Multi-stage Impact Crusher using Discrete Element Method (이산요소법을 이용한 다단 임팩트 파쇄기 내 입자 거동 모사)

  • Yu, Myoungyuol;Lee, Hoon
    • Resources Recycling
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    • v.27 no.3
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    • pp.86-92
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    • 2018
  • The amount of construction waste generated is steadily increasing every year, and the Law for Promotion of Recycling is enacted. However, it is difficult to use it as a recycled aggregate for concrete, which is presented in the quality standard of recycled aggregate with high water uptake and low density due to low separation of aggregate between concrete and cement paste. Therefore, in this study, a multi-stage impact crusher was used to remove mortar, which is essential for improving the quality of recycled aggregate. In analyzing the characteristics of the equipment, the spectrum of energy generated in each part between the particle and the equipment was calculated by using DEM. In order to generate an effective separation phenomenon, it was confirmed that the operation condition of 900 RPM was appropriate based on the ratio of the number of collisions (L/H) of the low energy group (L) to the number of collisions of the high energy group (H).

A Study on 4P's of Developing Food Service Products - Focused on Gwangju, Jeonnam Area - (외식 상품 개발의 4P's에 관한 연구 - 광주, 전남 지역 중심으로 -)

  • Lee, Sun-Ho;Kim, Hee-Kee;Kong, Ki-Yul;Jeon, Kyung-Chul
    • Culinary science and hospitality research
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    • v.16 no.1
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    • pp.269-279
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    • 2010
  • This study investigates 4P's of developing food service products(Focused on Gwangju, Jeonnam area) and intends to set the direction for the relations between product, price, promotion, place and customer satisfaction and customer occupation. Statistical techniques employed includes reliability analysis and regression analysis. The study is based on the 220-questionnaire-survey conducted from July 6 to July 20, 2009 to five foodservice companies in Gwangju. The data collected of this study were analyzed with the frequency analysis, reliability analysis, and regression analysis using the SPSS 12.0 package program. The findings of this study are as follows. Firstly, there are significant product, price, promotion and place factors that affect customer satisfaction. Secondly, there are significant product, price, promotion and place factors that affect customer occupation. Thus, food service management needs to apply product, price, promotion and place strategies aggressively.

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A Study on the 3-month Prior Prediction of Chl-a Concentraion in the Daechong Lake using Hydrometeorological Forecasting Data (수문기상예측자료를 활용한 대청호 Chl-a 3개월 선행예측연구)

  • Kwak, Jaewon
    • Journal of Wetlands Research
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    • v.23 no.2
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    • pp.144-153
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    • 2021
  • In recently, the green algae bloom is one of the most severe challenges. The seven days prior prediction is in operation to issues the water quality warning, but it also needs a longer time of prediction to take preemptive measures. The objective of the study is to establish a method to conduct a 3-month prior prediction of Chl-a concentration in the Daechong Lake and tested its applicability as a supplementary of current water quality warning. The historical record of water quality in the Daechong Lake and seasonal forecasting of ECMWF were obtained, and its time-series characteristics were analyzed. The Chl-a forecasting model was established using a correlation between Chl-a concentration and meteorological factor and NARX model, and its efficiency was compared.