• Title/Summary/Keyword: 열분석적 특성

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Chemorheological Behavior of Cyanate Ester Resin and Properties of Carbon Fiber Reinforced Polymer Composites (시아네이트 에스터 수지의 화학유변학적 거동 및 탄소섬유강화 고분자 복합재료의 물성)

  • Na, Hyo Yeol;Yoon, Byung Chul;Kim, Seung Hwan;Lee, Seong Jae
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.133-140
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    • 2013
  • Carbon fiber reinforced polymer (CFRP) composites consist of carbon fibers in a polymer matrix. Recently, CFRP composites having high thermal stability and low outgassing are finding their use in high performance materials for aerospace and electronics applications under high temperature and high vacuum conditions. Cyanate ester resin is one of the most suitable matrix resins for this purpose. In this study, proper combination of cyanate ester and catalyst, curing behavior, and cure cycle were determined by chemorheology. Optimum condition was found to be catalyst content of 100 ppm and curing temperature of $150^{\circ}C$. Thermal stability and outgassing of cured resin composition were analyzed and the results showed thermal decomposition temperature of $385^{\circ}C$ and total mass loss of 0.29%. The CFRP prepregs and subsequent composites were fabricated by predetermined resin composition and the cure condition. Tensile moduli of the composites were compared with theoretical models and the results were very consistent.

Analysis of Heat Island Characteristics Considering Urban Space at Nighttime (도시공간을 고려한 야간시간대의 열섬특성 분석)

  • Song, Bong-Geun;Park, Kyung-Hun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.15 no.1
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    • pp.133-143
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    • 2012
  • The purpose of this study is to investigate the characteristics of urban heat island considering urban space at nighttime. We used to analyze landuse and landcover data of 1:1,000 scale, DTM, and surface temperature extracted ASTER image satellite of nighttime. According to the analytical results, heat intensity in single-family residential is higher than that in industrial area, public facility area, and commercial area because the anthropogenic heat by energy consumption is released. Likewise, the temperature difference were big in the buildings of industrial area depending on operating hours. Meanwhile, green and river area had cooling impacts mitigating the urban heat island. Therefore, we have to mitigate heat intensity through constructing green space and waterfront area. As mentioned above, we think that the results of this study will be used as base data for effective spatial planning when formulating development planning to mitigate urban heat island at nighttime.

Glycerol Steam Reforming for Hydrogen Production on Metal-ceramic Core-shell CoAl2O4@Al Composite Structures (금속-세라믹 Core-Shell CoAl2O4@Al 구조체를 적용한 불균일계 촉매의 글리세롤 수소전환 반응특성)

  • Kim, Jieun;Lee, Doohwan
    • Clean Technology
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    • v.21 no.1
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    • pp.68-75
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    • 2015
  • In this study, we investigated the structure and properties of a highly heat conductive metal-ceramic core-shell CoAl2O4@Al micro-composite for heterogeneous catalysts support. The CoAl2O4@Al was prepared by hydrothermal surface oxidation of Al metal powder, which resulted in the structure with a high heat conductive Al metal core encapsulated by a high surface area CoAl2O4 shell. For comparison, CoAl2O4 was also prepared by co-precipitation method and also utilized for a catalyst support. Rh catalysts supported on CoAl2O4@Al and CoAl2O4 were prepared by incipient wetness impregnation and characterized by N2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), CO chemisorption, and temperature-programmed reduction (TPR). The properties of catalysts were investigated for glycerol steam reforming reaction for hydrogen production at 550 ℃. Rh/CoAl2O4@Al exhibited about 2.8 times higher glycerol conversion turnover frequency (TOF) than Rh/CoAl2O4 due to facilitated heat transport through the core-shell structure. The CoAl2O4@Al and CoAl2O4 also showed some catalytic activities due to a partial reduction of Co on the support, and a higher catalytic activity was also found on the CoAl2O4@Al core-shell than CoAl2O4. These catalysts, however, displayed deactivation on the reaction stream due to carbon deposition on the catalysts surface.

Mechanical Stability Analysis of PCB and Component for Launch and On-orbit Environment based on Fatigue Failure Theory and FEM (피로파괴 이론과 FEM에 기초한 발사 및 궤도 환경에서의 기판 및 소자의 구조건전성 분석)

  • Jeong, Suk-Yong;Oh, Hyun-Ung;Lee, Kyung-Joo;Kim, Byoung-Soo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.10
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    • pp.952-958
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    • 2011
  • On-board IR calibration device has been developed for calibration of spaceborne image sensor. It is composed of a blackbody to provide two different radiance temperatures, tilt mirror with a function of stow and deploy to view the blackbody during the calibration and on-board calibration control unit to control the function of the blackbody and tilt mirror. In this paper, to guarantee the structural safety of the unit, the structural and thermal analysis including a thermo-elastic analysis for verifying structural safety on the soldered part of chips have been performed. In addition, safety margin of the chips on the PCB obtained from the conventional analytical method has been compared to the results from the FEM analysis.

Application of SARIMA Model in Air Cargo Demand Forecasting: Focussing on Incheon-North America Routes (항공화물수요예측에서 계절 ARIMA모형 적용에 관한 연구: 인천국제공항발 미주항공노선을 중심으로)

  • SUH, Bo Hyoun;YANG, Tae Woong;HA, Hun-Koo
    • Journal of Korean Society of Transportation
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    • v.35 no.2
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    • pp.143-159
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    • 2017
  • For forecasting air cargo demand from Incheon National Airport to all of airports in the United States (US), this study employed the Seasonal Autoregressive Integrated Moving Average (SARIMA) method and the time-series data collected from the first quarter of 2003 to the second quarter of 2016. By comparing the SARIMA method against the ARIMA method, it was found that the SARIMA method performs well, relatively with time series data highlighting seasonal periodic characteristics. While existing previous research was generally focused on the air passenger and the air cargo as a whole rather than specific air routes, this study emphasized on a specific air cargo demand to the US route. The meaningful findings would support the future research.

Classification of Land Cover over the Korean Peninsula Using Polar Orbiting Meteorological Satellite Data (극궤도 기상위성 자료를 이용한 한반도의 지면피복 분류)

  • Suh, Myoung-Seok;Kwak, Chong-Heum;Kim, Hee-Soo;Kim, Maeng-Ki
    • Journal of the Korean earth science society
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    • v.22 no.2
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    • pp.138-146
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    • 2001
  • The land cover over Korean peninsula was classified using a multi-temporal NOAA/AVHRR (Advanced Very High Resolution Radiometer) data. Four types of phenological data derived from the 10-day composited NDVI (Normalized Differences Vegetation Index), maximum and annual mean land surface temperature, and topographical data were used not only reducing the data volume but also increasing the accuracy of classification. Self organizing feature map (SOFM), a kind of neural network technique, was used for the clustering of satellite data. We used a decision tree for the classification of the clusters. When we compared the classification results with the time series of NDVI and some other available ground truth data, the urban, agricultural area, deciduous tree and evergreen tree were clearly classified.

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Interfacial Characterization of Mineralized Carbon Nanotubes (광물화된 탄소나노튜브 첨가재의 계면 특성화)

  • Park, Chanwook;Jung, Jiwon;Yun, Gunjin
    • Composites Research
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    • v.31 no.5
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    • pp.282-287
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    • 2018
  • In this paper, we explore interfacial properties of the mineralized CNTs when they are employed as reinforcing fillers in a polymer nanocomposite using molecular dynamics (MD) simulations. Recently, several studies on mineralizing carbon nanotubes (CNTs) with an aid of nitrogen doping to CNTs have been reported. However, there is a lack of studies on the reinforcing effects of the mineralized CNTs when it is employed as a filler of nanocomposites. Silica ($SiO_2$) is used as a mineral material and poly (methyl metacrylate) (PMMA) is used as a polymer matrix. Pull-out simulations are conducted to obtain the interfacial energy and the interfacial shear stress. It was found that the silica mineralized CNTs have higher interfacial interaction with the polymer matrix. In the future, by examining various thermomechanical properties of the mineralized-CNT-filler/polymer nanocomposites, we will search for potential applications of the novel reinforcing filler.

A design of silicon based vertical interconnect for 3D MEMS devices under the consideration of thermal stress (3D MEMS 소자에 적합한 열적 응력을 고려한 수직 접속 구조의 설계)

  • Jeong, Jin-Woo;Kim, Hyeon-Cheol;Chun, Kuk-Jin
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.2
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    • pp.112-117
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    • 2008
  • Vertical interconnection scheme using novel silicon-through-via for 3D MEMS devices or stacked package is proposed and fabricated to demonstrate its feasibility. The suggested silicon-through-via replaces electroplated copper, which is used as an interconnecting material in conventional through-via, with doped silicon. Adoption of doped silicon instead of metal eliminates thermal-mismatch-induced stress, which can make troubles in high temperature MEMS processes, such as wafer bonding and LP-CVD(low pressure chemical vapor deposition). Two silicon layers of $30{\mu}m$ thickness are stacked on the substrate. The through-via arrays with spacing $40{\mu}m$ and $50{\mu}m$ are fabricated successfully. Electrical characteristics of the through-via are measured and analyzed. The measured resistance of the silicon-through-via is $169.9\Omega$.

Synthesis and Characteristics of Aminated Poly(arylene ether sulfone) as Thermostable Anion Exchanger (내열성 음이온교환수지로서 Aminated Poly(arylene ether sulfone)의 합성과 물성)

  • 손원근;유현지;황택성;김동철;김상헌;송해영
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.1-8
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    • 2002
  • In this study, poly(arylene ether sulfone) (PAES) having thermal stability and excellent mechanical properties was synthesized to be useful for the matrix of anion exchange resin. $1^{\circ}$-Aminated poly(arylene ether sulfone) ($1^{\circ}$-APAES) was prepared by reduction reaction after lithiation of PAES. Then $3^{\circ}$-APAES was Prepared by alkylation of the amino group of $1^{\circ}$-APAES. The structures of PAES and APAESs were confirmed with FT-IR and $^1H-NMR$ spectroscopy. Also, thermal properties of the resins were characterized by DSC and TG analysis. The introduction of amine groups in PAES resulted in the increase of glass transition temperature and decrease of initial thermal degradation temperature. The ion exchange capacities of $1^{\circ}$-APAES and $1^{\circ}$-APAES were 1.19 and 1.45 meq/g, respectively.

Studies on the Preparation of Anion Exchange Membrane through Blending of the Poly(ethylenimine) and the Poly(vinyl alcohol) (폴리비닐알코올과 폴리에틸렌이민과의 혼합을 통한 음이온교환막의 제조 연구)

  • Kim, Sung-Pyo;Kim, Baek-Kyun;Lee, Hak-Min;Rhim, Ji-Won;Jeong, Sung-Il
    • Membrane Journal
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    • v.20 no.4
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    • pp.335-341
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    • 2010
  • This study focuses on the investigation of the anion exchange membrane through blending poly(ethylenimine) (PEI) and poly(vinyl alcohol) (PVA) varying the mixing ratio. To characterize the resulting membranes, the water content, contact angle, FT-IR, thermal gravimetric analysis, ion exchange capacity, ion conductivity and elastic modulus were measured. The PVA / PEI = 90 / 10 membrane showed the ion conductivity, $5.16{\times}10^{-2}S/cm$ and simultaneously the contact angle, $78.3^{\circ}$. According to TGA measurement, the resulting membranes seemed durable at room temperature. Through the modulus test, the mechanical properties increased with increasing PVA content and apparently the membranes looked very robust.