• Title/Summary/Keyword: 열분석적 특성

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A study on comparing short-term wind power prediction models in Gunsan wind farm (군산풍력발전단지의 풍력발전량 단기예측모형 비교에 관한 연구)

  • Lee, Yung-Seop;Kim, Jin;Jang, Moon-Seok;Kim, Hyun-Goo
    • Journal of the Korean Data and Information Science Society
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    • v.24 no.3
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    • pp.585-592
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    • 2013
  • As the needs for alternative energy and renewable energy increase, there has been a lot of investment in developing wind energy, which does not cause air pollution nor the greenhouse gas effect. Wind energy is an environment friendly energy that is unlimited in its resources and is possible to be produced wherever the wind blows. However, since wind energy heavily relies on wind that has unreliable characteristics, it may be difficult to have efficient energy transmissions. For this reason, an important factor in wind energy forecasting is the estimation of available wind power. In this study, Gunsan wind farm data was used to compare ARMA model to neural network model to analyze for more accurate prediction of wind power generation. As a result, the neural network model was better than the ARMA model in the accuracy of the wind power predictions.

Syntheses and Characterizations of Position Specific Functionalized Graphenes (위치 선택적 관능기화 그래핀의 합성과 특성분석)

  • Heo, Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.218-224
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    • 2013
  • Graphene oxide (GO) was prepared by the Hummers and Offeman method from graphite. Two different types of functionalized graphene sheets (FGSs) were synthesized by using GO. Hexamethylamine (HDA) substituted vertically to the graphene sheet (Ver-HDA-GS) was synthesized from HDA and epoxy group in GSs. Whereas, horizontally substituted hexadecanol (HDO) to the GS(Hor-HDO-GS) was synthesized from HDO and alcohol groups via reduced GO (RGO), respectively. The structures of the GO, RGO, Ver-HDA-GS, and Hor-HDO-GS were identified by Fourier transform infrared (FTIR). In addition, we examined the thermal stability and morphology. Atomic force microscope (AFM) disclosed that Ver-HDA-GS consisted of one- or two-layer graphene regions. However, the Ver-HDA-GS layers showed average thickness of 1.76 nm. The thermal stabilities of the FGSs were better than those of the GO and RGO. The Ver- HDA-GS was well dispersed in common solvents such as dimethyl sulfoxide (DMSO), toluene, chloroform, and decalin.

Development of a Real-Time Thermal Performance Diagnostic Monitoring System Using Self-Organizing Neural Network for KORI-2 Nuclear Power Unit (자기학습 신경망을 이용한 원자력발전소 고리 2호기 실시간 열성능 진단 시스템 개발)

  • Kang, Hyun-Gook;Seong, Poong-Hyun
    • Nuclear Engineering and Technology
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    • v.28 no.1
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    • pp.36-43
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    • 1996
  • In this work, a PC-based thermal performance monitoring system is developed for the nuclear power plants. The system performs real-time thermal performance monitoring and diagnosis during plant operation. Specifically, a prototype for the KORI-2 nuclear power unit is developed and examined in this work. The analysis and the fault identification of the thermal cycle of a nuclear power plant is very difficult because the system structure is highly complex and the components are very much inter-related. In this study, some major diagnostic performance parameters are selected in order to represent the thermal cycle effectively and to reduce the computing time. The Fuzzy ARTMAP, a self-organizing neural network, is used to recognize the characteristic pattern change of the performance parameters in abnormal situation. By examination, this algorithm is shown to be able to detect abnormality and to identify the fault component or the change of system operation condition successfully. For the convenience of operators, a graphical user interface is also constructed in this work.

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Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.37-43
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    • 2005
  • [ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

Enhancing Adhesion between Polyphenylene Sulfide Fabric and Polytetrafluoroethylene Film for Thermally Stable Air Filtration Membrane (열안정 공기 여과막용 폴리페닐렌 설파이드 원단과 폴리테트라플루오로에틸렌 필름 사이의 접착력 향상)

  • Jin Uk Kim;Hye Jeong Son;Sang Hoon Kang;Chang Soo Lee
    • Membrane Journal
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    • v.33 no.4
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    • pp.201-210
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    • 2023
  • Dust filter membranes play a crucial role in human life and various industries, as they contribute to several important aspects of human health, safety, and environmental protection. This study presents the development of a polysulfone@polyphenylene sulfide/polytetrafluoroethylene (PSf@PPS/ePTFE) composite dust filter membrane with excellent thermal stability and adhesion properties for high-temperature conditions. FT-IR analysis confirms successful impregnation of PSf adhesive onto PPS fabric and interaction with ePTFE support. FE-SEM images reveal improved fiber interconnection and adhesion with increased PSf concentration. PSf@PPS/ePTFE-5 exhibits the most suitable porous structure. The composite membrane demonstrates exceptional thermal stability up to 400℃. Peel resistance tests show sufficient adhesion for dust filtration, ensuring reliable performance under tough, high-temperature conditions without compromising air permeability. This membrane offers promising potential for industrial applications. Further optimizations and applications can be explored.

UV-Curing System for the Filament Winding of Large Diameter Pipe (대구경 파이프용 필라멘트 와인딩을 위한 UV 경화시스템)

  • Choi, Jae-Wan;Kim, Se-Il;Chung, Yong-Chan;Chun, Byaung-Chul
    • Clean Technology
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    • v.16 no.4
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    • pp.245-253
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    • 2010
  • Optimum conditions for UV-radiated photopolymerization of unsaturated polyester that could be used as protecting layer of large diameter pipe were investigated in this paper. UV photopolymerization method was selected to solve the problems, arising when thermal polymerization by organic peroxide was used, such as the instability of peroxide initiator, the evolution of volatile organic compound, and thermal deformation of product. Two of the photo-initiators (Irgacure 819 and Darocure 1173) well known for its penetrating ability deep into the polymer layer were selected, and the optimum conditions for photopolymerization (1.5 phr initiator content, 1:1.2 initiator ratio, Ga lamp for UV source) were found from the thermal and mechanical test results of the resultant UP polymers. In addition, composite materials containing UP polymer and glass fiber were tested for hardness, impact strength, and flexural strength to find that the impact strength of composite significantly improved.

Effect of Thermal History on the Physical Properties of Nylon66 (열 이력이 나일론66의 물성에 미치는 영향)

  • Lee, Bom Yi;Jo, Chan Woo;Shim, Chang Up;Lim, Su Jung;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.90-95
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    • 2014
  • Nylon66 extrudates as a function of the extrusion number were prepared by a twin screw extruder. Chemical structures, thermal properties, melt index, crystal structures, mechanical properties such as the tensile strength, elongation at break and impact strength, and rheological property were measured by FT-IR, $^1H$-NMR, melt indexer, DSC, TGA, XRD, universal tensile tester, Izod impact tester, and rheometer. FT-IR and $^1H$-NMR characterizations indicated that the number of extrusions did not affect the chemical structure. The decrease in the molecular weight was checked by the melt index of extrudates. There were no effects of the thermal history on the melting and degradation temperature. The tensile and impact strength and modulus were found to be similar, regardless of the number of extrusions, but the elongation decreased significantly. The complex viscosity of extrudates at low frequencies decreased with the extrusion number. No structural changes after extrusion were confirmed from the fact that there was no change in the slope and shape of G'-G" plot.

Changes in Quality Characteristics of Seasoned Soy Sauce Treated with Superheated Steam and High Hydrostatic Pressure during Cold Storage (과열증기와 초고압 처리법을 적용한 간장 소스의 냉장저장 중 품질 특성 변화)

  • Choi, Yoon;Oh, Ji-Hye;Bae, In-Young;Cho, Eun-Kyoung;Kwon, Dae-Joong;Park, Hae-Won;Yoon, Sun
    • Korean journal of food and cookery science
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    • v.29 no.4
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    • pp.387-398
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    • 2013
  • Seasoned soy sauce is one of the popular seasoning sauces added to the Korean traditional foods such as Bulgogi, Galbi. However, industrially processed sauces have poor sensory quality because of heating treatment for sterilization. The purpose of this study was to develop seasoned soy sauce having fresh taste and good quality by applying superheated steam (SHS) and high hydrostatic pressure (HHP) technologies. To maintenance the sauce qualities, food materials such as apple, onion, and garlic were pretreated with SHS (heater $100^{\circ}C$, steam $280^{\circ}C$, 30 s~1 min 30 s) before mixing with other ingredients. During storage of 7 days, color, pH, and browning potential of SHS treated samples (apple, onion and garlic) did not change and also polyphenol oxidase was inactivated (p<0.05). The seasoned soy sauce including SHS treated materials was sterilized by thermal process ($85^{\circ}C$, 30min) or non-thermal process, HHP (550 MPa, $5{\sim}10^{\circ}C$, 3 min). In SHS+HHP treated sauce, salinity, sugar contents, lightness, viscosity did not change (p<0.05), and total viable cell counts were detected below 4 log cycle at $5^{\circ}C$ for 30 days. E.coli and B.cereus are not determined in all samples. In sensory evaluation, Bulgogi prepared with SHS+HHP treated sauce was more acceptable than others.

Hydrothermal Synthesis of Vanadium (IV) Dioxide and its Thermochromic Property (바나듐(IV) 이산화물의 수열합성 및 이의 열변색 특성)

  • Lee, Hun Dong;Son, Dae Hee;Lee, Won Ki;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.427-431
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    • 2015
  • In this study, vanadium dioxide ($VO_2$) powder well known as a thermochromic material was prepared from $V_2O_5$ powder and oxalic acid dihydrate by hydrothermal and calcination process at various conditions. The chemical bonding and crystal structures in addition to thermal property of samples were determined using FE-SEM, XRD, XPS, and DSC. Also, spectroscopic and thermochromic properties of film samples were analyzed by UV-Vis-NIR spectroscopy after the thin film was prepared from the sol dispersed with the size of below 50 nm by the ball-milling of powder sample. With increasing the calcination temperature, the phase transition temperature of samples increased from $40^{\circ}C$ to $70^{\circ}C$ due to the increase of particle size.

Synthesis of CO2 Adsorbent with Various Aminosilanes and its CO2 Adsorption Behavior (다양한 아미노실란을 이용한 이산화탄소 흡착제 합성 및 흡착 특성)

  • Jeon, Jae Wan;Ko, Young Soo
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.80-85
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    • 2016
  • The carbon dioxide adsorption behavior of silica with a large specific surface area and pore volume functionalized with aminosilane compounds via in-situ polymerization and functionalization method were investigated. The organosilanes include amino functional group capable of adsorbing carbon dioxide. Elemental analyzer, in situ FT-IR and thermogravimetric analyzer were used to characterize the sorbents and to determine their $CO_2$ adsorption behavior. Comparison of different aminosilane loading in the support revealed that polyaminosilane functionalization of 70% of the pore volume in the support was better in terms of the adsorption capacity and amine efficiency than that of 100% of the pore volume of the support. Furthermore, the sorbents showed a higher adsorption capacity at an adsorption temperature of $75^{\circ}C$ than at $30^{\circ}C$ due to the thermal expansion of synthesized polyaminosilanes inside the pore of silica. The N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS) sorbent with 70% of the pore volume functionalized showed the highest adsorption capacity of 9.2 wt% at $75^{\circ}C$.