• Title/Summary/Keyword: 열구조 안정성

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The Study on the Synthesis of Propellant with High Nitrogen Content (고질소 추진물질 합성 연구)

  • Lee, Woonghee;Kim, Minjun;Park, Youngchul
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.3
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    • pp.96-102
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    • 2015
  • Traditional propellants emit toxic gases such as carbon dioxide and hydrogen chloride during combustion which are harmful to the environment. This study established a synthetic process of a high nitrogen containing derivative of tetrazine, 3,3-Azobis(6-Amino-1,2,4,5-Tetrazine) (DAAT), which can be applied as solid fuels for a solution to environmental concerns. Also, this paper described the detailed process and the analytic results of properties, which were not mentioned in previous reports. The compound was characterized by NMR, IR spectroscopy, and thermal, impact, and friction stability were measured. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAAT were calculated using Gaussian 09 and EXPLO5 programs.

Preparation of RGO coated TiO2 for improved electrical conductivity (전기 전도성 향상을 위한 RGO가 코팅된 TiO2 제조)

  • Kim, Su-Deok;Choe, Jin-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.192.1-192.1
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    • 2016
  • 타이타늄은 밸브 메탈의 일종으로, 다양한 전해질 조건에서 양극산화되어 이산화 타이타늄($TiO_2$)을 형성한다. 이산화 타이타늄은 저렴한 가격, 풍부함, 무독성, 높은 안정성 등 다양한 장점을 지닌다. 또한 리튬 이온의 삽입/탈리 이후에도 구조적인 변화가 적은 성질과 비교적 높은 방전 전압(1.0-2.5 V vs Li/Li+)으로 인해 그래파이트를 대체할 리튬이온 전지의 전극재료로써 연구되어 왔다. 하지만 낮은 이온 및 전기 전도도로 인해 다양한 분야에서의 활용에 한계가 있어왔다. 이러한 한계 극복을 위해, 이산화 타이타늄에 전도성이 높은 탄소 계열의 물질을 코팅하는 방법이 고려되었다. 그래핀 산화물은 강한 산을 이용하여 그래파이트를 산화시킨 물질로, 많은 산소작용기를 함유하고 있어 탄소 고유의 전기전도성을 갖지 못한다. 환원 그래핀 산화물(reduced graphene oxide)는 빛, 열, 화학 작용울 통해 그래핀 옥사이드를 환원시켜 산소작용기를 없앤 물질로, 환원과정에서 전기전도성을 회복한다. 이에 본 연구에서는 이산화 타이타늄에 환원 그래핀 산화물(reduced graphene oxide)를 코팅하여 전기 전도도를 향상시키고. 이에 대한 활용 분야를 연구하고자 하였다.

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Structure Design and Thermal Analysis of Cryogenic Cooling System for a 1500 A, 400 mH Class HTS DC Reactor (1500 A, 400 mH급 초전도 직류 리액터용 극저온 냉각 시스템 구조 설계 및 열 해석)

  • Quan, Dao-Van;Le, Tat-Thang;Sung, Hae-Jin;Park, Min-Won;Yu, In-Keun
    • Journal of Korea Society of Industrial Information Systems
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    • v.23 no.1
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    • pp.31-41
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    • 2018
  • This paper discusses a structure design and thermal analysis of cryogenic conduction cooling system for a high current HTS DC reactor. Dimensions of the conduction cooling system parts including HTS magnets, bobbin structures, current leads, support bars, and thermal exchangers were calculated and drawn using a 3D CAD program. A finite element method model was built for determining the optimal design parameters and analyzing the thermo-mechanical characteristics. The operating current and inductance of the reactor magnet were 1,500 A, 400 mH, respectively. The thermal load of the HTS DC reactor was analyzed for determining the cooling capacity of the cryo-cooler. Hence, we carried out the operating test of conduction cooling system of the 1st stage area with high current flow. The cooper bars was cooled down to 40 K and HTS leads operated stably. As a experiment result, the total heat load of the 1st stage area is 190 W. The study results can be effectively utilized for the design and fabrication of a commercial HTS DC reactor.

The Characteristic of Dyeing and Mechanical Properties of Draw Textured Yarn with High Oriented Yarn (고속방사소재 가연사의 물성 및 염색 특성)

  • Kim, Su-A;Lee, Min-Su;Kang, Ji-Man;Lee, Jun-Hee
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.86-86
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    • 2012
  • 고속방사소재는 연신공정이 없이 6,000m/min이상의 고속방사공정만이 있으므로 원가절감이 되고, 빠른 냉각, 높은 변형속도 등으로 섬유의 결정화도, 분자와 결정의 배향 및 모폴로지(morphology) 변화 등의 기계적 및 섬유상의 특성이 종래의 원사와는 다르게 된다. 방사속도가 증가함에 따라 배향도가 증가하면서 결정영역 또한 증가한다. 또한 기존 연신사에 비해 큰 결정크기를 갖는데 방사속도에 에 따른 방사응력의 증가가 응력유도 결정화도를 유발하여 결정크기 및 결정화도를 증가시키고,따라서 고분자의 용융점도를 고온측으로 이동시키는 현상을 나타내게 한다. 즉, 고속방사에 있어서는 연신에 필요한 임계응력 이상의 과도한 응력이 가해짐으로 인해 결정구조가 일반 연신사에 비해 현저히 발달한다는 것을 알 수 있다. 고속방사 원사를 통일한 조건으로 염색하는 경우 기존의 연신사보다 염착량이 많아 농색으로 염색이 가능하고 염착속도도 빠른 특징을 갖는 데이는 고속방사 원사의 비결정 배향이 낮고 느슨한 구조를 갖기 때문에 염료의 침투가 용이한 것으로 해석되고 있다. PET 섬유는 방사 후 형태안정성을 부여하기 위해서 염색 전처리 공정에서 열을 가하게 된다. 이런 과정에서 섬유의 미세구조가 변하게 되는데,특히 고속방사의 경우 섬유 형성과정이 연신사와는 다르므로 열에 의한 구조 변화와 이에 따른 염색성 변화에 대해 검토해 보는 것은 고속방사의 응용면에서 꼭 필요하다. 본 연구에서는 고속방사소재의 가장 단점인 잔류신도, 저수축현상, stiff감을 보완하면서 고속방사소재의 장점인 심색성을 부각시켜 차별화된 복합사 제조기술을 개발하기 위해 그 기술개발이 기초 연구로서 일반 일반 DTY사와 고속방사소재인 HOY사를 이용한 DTY사의 물성 및 염색 특성을 비교분석 하고자 한다.

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Multiple-Channel using Asymmetric Spacing Structure (ASS) Polycrystalline Silicon (Poly-Si) Thin-Film Transistors (TFTs) (비대칭 스페이싱 다중채널 구조를 이용한 다결정 실리콘 박막 트랜지스터)

  • Song, Seung-Min;Choi, Sung-Hwan;Han, Min-Koo
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1414-1415
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    • 2011
  • 높은 게이트와 드레인 바이어스 스트레스 조건에서 신뢰성을 높이기 위해 비대칭 스페이싱 다중채널 구조 (ASS) 를 이용한 다결정 실리콘 박막 트래지스터 (poly-Si TFTs) 를 제안하였다. 이것은 어떠한 추가공정 없이 제작할 수 있고 채널 가운데 부분의 넓은 공간을 이용하여 소자안의 유도된 열을 방출할 수 있기 때문에 기존의 트랜지스터에 비해 47%의 문턱전압감소와 3%의 이동도 변화 감소를 보인다. 이 실험결과는 제안된 소자구조가 기존의 소자에 비해 높은 게이트와 드레인 바이어스 조건에서 전기적 특성이 더 안정적이라는 것을 보여준다.

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Evaluation of Signal Stability of Fiber Optic Sensors with respect to Sensor Packaging Methods in Long-Term Monitoring (장기 모니터링 환경에서 센서 패키징 방법에 따른 광섬유 센서의 신호 안정성 평가)

  • Kang, Donghoon;Kim, Heon-Young;Kim, Dae-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.4
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    • pp.281-287
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    • 2016
  • Fiber Bragg grating (FBG) sensors are applied in structural health monitoring (SHM) in various application fields because of their ease of multiplexing and capability of performing absolute measurements. Moreover, the packaging methods of FBG sensors accelerate their commercialization rapidly. However, long-term SHM exposes the FBG sensors to cyclic thermal loads, and a investigation is required because it finally leads to the signal instability of the FBG sensors. In this study, the effects of sensor packaging methods two methods are generally used for the FBGs: (bonding both sides of the FBG or bonding the FBG directly on signal stability of FBG sensors are investigated. Tests are conducted on specimens in a thermal chamber, over a temperature range from $-20^{\circ}C$ to $60^{\circ}C$ for 300 cycles. Signal characteristics such as Bragg wavelength, light intensity and full width at half maximum are examined and are compared with those of the FBG sensors, obtained in a previous study under direct bonding conditions. From the comparison, it is observed that the FBG sensors with bonding on both sides of the FBG demonstrate higher signal stabilities when exposed to cyclic thermal loads during long-term SHM. Consequently, it guarantees more effectiveness when packaging the FBG sensors.

A Study on the Judgment of Fire Cause of Ballast for Fluorescent Lamp (형광등용 안정기의 화재원인 판정에 관한 연구)

  • 최충석;백동현
    • Fire Science and Engineering
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    • v.14 no.3
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    • pp.1-5
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    • 2000
  • In this paper, we analyzed the fire hazard of the ballast for fluorescent lamp used as the indoor lighting. In the result of being analyzed the ballast wire by stereo microscope, many melting points were discovered, it was impossible to judge a cause with the naked eye. In the Thermal-deteriorated ballast wire, elongation structure disappeared at above $700^{\circ}$, and it only showed the enlarged appearance of the copper particle. On the metallurgical microscope of short wire, as it was confirmed the regulation of the columnar structure and the void growth at the center of boundary-face, we found that electrical short-circuit generated. Also, it was confirmed the melted part on the analysis using SEM(scanning electron microscope). Not only CuL and Cuk line that is composition factor of copper but also OK line was observed uniformly on the spectra analysis using EDX(energy dispersive x-ray spectroscopy). It means that oxygen took part in reaction at the recombination process.

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Preparation and Characterization of Polysulfone Substrate for Reinforced Composite Membrane Fuel Cell Membrane (연료전지 전해질 복합막 제조를 위한 폴리설폰계 지지체의 제조와 물성)

  • Nam, Sang-Yong;Kim, Deuk-Ju;Hwang, Rae-Young;Kim, Hyoung-Juhn
    • Membrane Journal
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    • v.19 no.1
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    • pp.63-71
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    • 2009
  • In this study, polysulfone which has excellent mechanical and thermal stability with low cost was used for preparing a non-conducting polymer matrix as a reinforced composite membrane for fuel cell application. The membranes were prepared by phase separation method. Polymer concentration and retention time were controlled to investigate the effects on the membrane morphology. The resaltant membranes showed all sponge-like structure independent of polymer concentration. The mechanical and thermal stability were improved with increasing polymer concentration in contrast to the membrane porosity. As a result, the membranes prepared with the retention time for 2 mins using 20 wt% of polymer solution was suitable for a fuel cell compositite membrane providing optimum properties such as approximately 80% of high porosity, 1.3 MPa of tensile strength, and less than 1% of thermal shrinkage both machine and transverse direction.

Stabilization of the Time-variant Cointegrating Relations (시간가변적 공적분관계의 안정화)

  • Kim, Tae-Ho;Park, Ji-Won
    • The Korean Journal of Applied Statistics
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    • v.21 no.5
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    • pp.727-738
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    • 2008
  • If a cointegrating relation is affected by important economic and political events occurred in the sample period, the assumption of the time-invariant cointegrating vector is violated, which leads to the misrep-resentation of the actual relations between the variables. From such a viewpoint, this study utilizes the recursive estimation process in testing for the stability of the long-run equilibrium of the domestic stock market system and then attempts to develop the framework for stabilizing time-variant cointegraing relations by introducing the dummy variables where the structural changes are found to exist.

Multi-Objective Evaluation for Hybrid Use of Natural Energy in Power System (자연에너지 복합 이용시스템에 대한 다목적 평가)

  • Bae, Sang-Hyun;Lee, Jae-Youn
    • Solar Energy
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    • v.11 no.1
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    • pp.27-40
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    • 1991
  • Research and development works on practical application of natural energy utilization systems involving solar, wind and sea wave energies are under promoting for the purpose of improving the energy consumption structure. These natural energies, made available with the use of relatively simple apparatus, are clean economically efficient and highly effective in the conservation of environment. However, these natural energies also have low energy density, randomness and regional variations. To compensate for these characteristics, hybrid utilization of solar and wind energies is currently under study. The introduction of a plural number of the natural energy hybrid utilization systems into a specific area will affect the economic efficiency, reliability and environmental conservation. Evaluation method of such effects has been examined in this study. The present method consisted of the steps described below. First, available energy was calculated from insolation distribution and wind velocity distribution in the specified area, and then the effect on the configuration of the power system load was obtained. This was followed by the determination of the optimal power dispatch over the specified period and by evaluations in light of economic efficiency, reliability and environmental indices.

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