• Title/Summary/Keyword: 연속회수

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Design of Recycle Bubble Column Reactor for Continuous Enzymatic Hydrolysis of Cellulose (섬유소의 연속 효소 가수분해를 위한 순환식 기포탑 반응기의 설계)

  • 김춘영;홍석표정봉우이태원
    • KSBB Journal
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    • v.5 no.1
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    • pp.59-67
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    • 1990
  • Enzymatic hydrolysis of insoluble cellulose was performed in a bubble column with tangential flow ulrafiltration membrane unit. The reactor was operated in a batch mode as well as semi-continuous and continuous with continuous removal of products through the tangential flow ultrafiltration membrane. The optimum superficial gas velocity was 1-3cm / sec so as to avoid bubble coalescence and enzyme denaturation. In continuous and selni-cotinuous process, the conversion was gradually increased but the total reduced sugar concentration was drcastically dereased with the dilution rate. It was concluded that the bubble column attaching tangential flow ultrafiltration membrane unit was effective on continuous hydrolysis of cellulose and recovery of enzyme.

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Preparation and Characterization of Ultra-fine PAI Continuous Fibers Using Electrospinning Process (전기방사 공정을 이용한 극세 PAI 연속사 제조 방법에 관한 연구)

  • Lee, Jae-Rock;Ji, Seung-Yong;Hong, Young-Taik;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.331-334
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    • 2006
  • In this study, the ultra-fine fibers (UFs) having an alignment were prepared by electrospinning process, using different collectors made from various materials and collecting methods. A spinning solution was prepared by dissolving poly(amide-co-imide) (PAI) in NMP. The UFs were prepared by using various collectors and collecting methods, and the fibrous shapes were observed by SEM. As a result, a sort of materials of collectors and the collecting methods had not influenced on the average diameters of fibers but the forms of them. The just accumulated UFs on the collectors formed net structures, which had no alignment. On the contrary, the continuously collected UFs formed long fibers with alignment. It was found that the water collector played the roles of the fiber haul, temporary collector, moving path of fibers, and caused some friction between fibers and water, attributed to the formation of continuous UFs at a suitable collecting speed.

Selective Continuous Adsorption and Recovery for Gold-Cyanide Complex in Industrial Wastewater Using Dowex 21K XLT Resin (Dowex 21K XLT 수지를 이용한 산업폐수 내의 금-시안 착화합물의 선택적인 연속흡착 및 회수)

  • Jeon, Choong
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.3
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    • pp.35-39
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    • 2015
  • Continuous adsorption and recovery characteristics for gold and lead-cyanide complexes in industrial wastewater were investigated by the Dowex 21K XLT resin. The Dowex 21K XLT resin could continuously remove over 95% for gold-cyanide complex until 520 bed volumes at the 0.5 mL/min of influent flow rate, however, could not remove lead-cyanide complex at all. The 96% of gold-cyanide complex adsorbed onto Dowex 21K XLT resin could be recovered by mixed solvent with HCl and acetone (7:3 ratio) within 8 bed volumes. Also, the bed volume for gold-cyanide complex using secondly reused Dowex 21K XLT resin was maintained as the 490, therefore, continuous process using Dowex 21K XLT resin can be sufficiently applied to the industrial wastewater containing gold ions.

Recovery of Nickel from Waste Pickling Solution with Column Extractor (컬럼식 연속추출장치에 의한 산세폐액중 Ni의 회수)

  • 김성규;이화영;오종기
    • Resources Recycling
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    • v.7 no.1
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    • pp.27-33
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    • 1998
  • A study on thc recovcry oi nickel from waste pickling solutions removed li-ee nil~ica cid and hydmflnoric acid is carried out with pulsed column extractor for thc industrial application. The ~esults show that thc Iron and chromium arc efteclively elunmatcd from the waste solution by precipitalion as the form of hydraxidc with thc adjustment of pH with CaCO;, whlle the nickel is not prcc~pitatcd. Thc cxlraction eficicncy ol nickel with column cxtraclor generally improves 8s the pulse velosity (product of amplmde and frequency) incrcascs, optimum pcrfarmancc typically occuring slightly below an amplihldefrecluency product which results in flooding the column because of excessive emulsiIicalian And the nickel loaded in the organic is erfeclively conce~~trtratebdy ZM H2S0,, ~ I It he stlipping stage. The solubility of NiSO, in the H,SO, solution dccreaaes w~th thc higher H,SO, concentralion and appears to be 55 grL in the 2M HSO* solulian.

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Recovery of Gallium and Indium from Zinc Residues by Acid Leaching (산침출에 의한 아연제련잔사로부터 갈륨 및 인디움의 회수)

  • 이화영;김성규;오종기
    • Resources Recycling
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    • v.2 no.2
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    • pp.22-26
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    • 1993
  • The flowsheet for the recovery of gallium and indium from zinc residues has been established based on the sulfuric acid treatment. In comparison with the alkali treatment, the method proposed in this work allowed the recovery of indium together with gallium. The majority of iron contained in leach liquor could be removed through the two-stage neutrallization under oxidative or reductive atmosphere. Crude gallium and indium could be obtained through the alkali and/or acid leaching of the products generated from the above treatment. In addition, cementation of indium with zinc powders could also be used for the concentration of it from weak acid solutions.

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Language Models Using Iterative Learning Method for the Improvement of Performance of CSR System (연속음성인식 시스템의 성능 향상을 위한 반복학습법을 이용한 언어모델)

  • Oh Se-Jin;Hwang Cheol-Jun;Kim Bum-Koog;Jung Ho-Ynul;Chung Hyun-Yeol
    • Proceedings of the Acoustical Society of Korea Conference
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    • spring
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    • pp.82-85
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    • 1999
  • 본 연구에서는 연속음성인식 시스템의 성능 향상을 위하여 음성의 채록환경 및 데이터량 등을 고려한 효과적인 언어모델 작성방법을 제안하고, 이를 항공편 예약시스템에 적용하여 성능 평가 실험을 실시한 결과 $91.6\%$의 인식률을 얻어 제안한 방법의 유효성을 확인하였다. 이를 위하여 소량의 200문장의 항공편 예약 텍스트 데이터를 이용하여 좀더 강건한 단어발생 확률을 가지도록 하기 위해 일반적으로 대어휘 연속음성인식에서 많이 이용되고 있는 단어 N-gram 언어모델을 도입하고 이를 다양한 발성환경을 고려하여 1,154문장으로 확장한 후 동일 문장'을 반복 학습하여 언어모델을 작성하였다. 인식에 있어서는 오인식과 문법적 오류를 최소화하기 위하여 forward - backward pass 방법의 stack decoding알고리즘을 이용하였다. 인식실험 결과, 평가용 3인의 200문장을 각 반복학습 회수에 따라 학습한 각 언어모델에 대해 평가한 결과, forward pass의 경우 평균 $84.1\%$, backward pass의 경우 평균 $91.6\%$의 문장 인식률을 얻었다. 또한, 반복학습 회수가 증가함에 따라 backward pass의 인시률의 변화는 없었으나, forward pass의 경우, 인식률이 반복회수에 따라 증가하다가 일정값에 수렴함을 알 수 있었고, 언어모델의 복잡도에서도 반복회수가 증가함에 따라 서서히 줄어들며 수렴함을 알 수 있었다. 이상의 결과로부터 소량의 텍스트 데이터를 이용한 제한된 태스크에서 언어모델을 작성할 때 반복학습 방법이 유효함을 확인할 수 있다.

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Analysis of a Continuous and Instantaneous Vacuum Drying System for Drying and Separation of Suspended Paricles in Waste Solvent (폐용제에 함유된 입자의 건조 및 분리용 연속식 순간 진공건조시스템 해석)

  • 구재현;이재근
    • Resources Recycling
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    • v.9 no.4
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    • pp.28-36
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    • 2000
  • This study describes to analyze the characteristics for separation and recovery of both the dried particles and the purified solvent from the waste solvent through the vaporization process by the continuous and instantaneous vacuum drying system. The vacuum drying system for the waste solvents recovery consists of a feeding pump, a double pipe heat exchanger, a vacuum spray chamber, and a condenser. The vacuum drying system heats the waste solvent to the vapor in the double pipe heat exchanger and the expanded vapor is sprayed at the end of the tube. The vaporized solvent in the condenser are recovered. The particles in the waste solvent are separated and dried from the vapor in the vacuum spray chamber. Performance evaluation of the vacuum drying system was conducted using the mixture of the dried pigment particles and benzene or alkylbenzene as test samples. For the mixture of 10 wt% pigment particles an 90% benzene, the recovery efficiency of benzene was 88% with the purity of 99% and the recovery efficiency of dried particles was 94% with the moisture of 1.1 wt%. The size of pigment particles was decreased from $6.5\mu\textrm{m}$ to $5.6\mu\textrm{m}$ in diameter due to high speed spraying and dispersion in the vacuum drying system during drying process. Therefore, the vacuum drying system showed to be an effective method for separating particles and solvent in the waste solvent.

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Recovery of Silver from Artificial Photographic Wastewater by Continuous Flow Electrolytic Process (순환공정법(循環工程法)을 적용(適用)한 인공(人工) 사진폐액(寫眞廢液)으로부터의 전해채취(電解採取)에 의한 은(銀)의 회수(回收))

  • Chung, Won-Ju;Kim, Dong-Su
    • Resources Recycling
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    • v.16 no.1 s.75
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    • pp.68-72
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    • 2007
  • The influences of reduction time, potential difference and ionic concentration flow rate have been investigated on the electrolytic recovery of silver from artificial photographic wastewater in continuous flow reactor system. As the initial concentration of silver ion and applied potential were increased, the amount of silver recovered was observed to be raised. Also, the electrolytically recovered material from artificial wastewater was proved to be pure silver based on the qualitative analyses by EPMA and XRD.

Semi-Continuous Electrowinning of LiCl-$Li_2O$ Molten Salt (LiCl-$Li_2O$ 용융염에서의 리튬의 반연속적 전기정련)

  • Jin-Mok, Hur;Chung-Seok, Seo;Sun-Seok, Hong;Dae-Seung, Kang;Seong-Won, Park
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.211-217
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    • 2004
  • A Li recovery technology has been developed and related experimental verification efforts were carried out to improve the economical viability and environmental friendliness of the 'Advanced Spent Fuel Conditioning Process' being developed at KAERI. This technology is characterized by the combination of 1) the electrolysis of $Li_2O$ in a molten salt by using a porous non-conducting magnesia container at the cathode, 2) the separation of the Li in the container from the molten salt by elevating the container above the level of a molten salt, 3) the transport of the Li in the container by using a vacuum siphon to a separated reservoir. Li was semi-continuously recovered from a LiCl-$Li_2O$ molten salt with a more than 95% yield by using the developed technology.

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A review on Separation Technologies for Lithium Recovery from Waste Solutions in Recycling Process of Waste Battery (폐배터리 재활용 공정 폐액 중 리튬 회수를 위한 분리 기술 고찰)

  • Song, Daesung;Kim, Eunkyu;Vu, Thang-Toan
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.473-477
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    • 2022
  • In this study, candidate technologies for lithium recovery from the process waste liquid generated in the waste battery recycling process were reviewed, and technologies applicable to the process from the commercialization point of view were reviewed from a qualitative point of view. The evaporation method is difficult to apply because it requires a large-scale land and shows a low recovery rate due to the loss of Li during the concentration process. In the case of precipitation, a commercially available technology shows a high recovery rate due to the high Li/Na selectivity of phosphoric acid, but there are disadvantages in that the process is complicated due to the use of expensive phosphoric acid, requiring a recovery step, and continuous operation is impossible because solids are handled in the Li concentration process. In the case of solvent extraction, if we find an inexpensive extractant with high Li/Na selectivity, continuous operation is possible with the method used in extraction of other metals in the previous step, and when Li is concentrated, continuous operation is possible because it is in a liquid state. If it shows a similar recovery rate compared to precipitation technology, commercialization will be the most likely.