• Title/Summary/Keyword: 연료-질소산화물

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Air Pollution and Its Effects on E.N.T. Field (대기오염과 이비인후과)

  • 박인용
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1972.03a
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    • pp.6-7
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    • 1972
  • The air pollutants can be classified into the irritant gas and the asphixation gas, and the irritant gas is closely related to the otorhinolaryngological diseases. The common irritant gases are nitrogen oxides, sulfur oxides, hydrogen carbon compounds, and the potent and irritating PAN (peroxy acyl nitrate) which is secondarily liberated from photosynthesis. Those gases adhers to the mucous membrane to result in ulceration and secondary infection due to their potent oxidizing power. 1. Sulfur dioxide gas Sulfur dioxide gas has the typical characteristics of the air pollutants. Because of its high solubility it gets easily absorbed in the respiratory tract, when the symptoms and signs by irritation become manifested initially and later the resistance in the respiratory tract brings central about pulmonary edema and respiratory paralysis of origin. Chronic exposure to the gas leads to rhinitis, pharyngitis, laryngitis, and olfactory or gustatory disturbances. 2. Carbon monoxide Toxicity of carbon monoxide is due to its deprivation of the oxygen carrying capacity of the hemoglobin. The degree of the carbon monoxide intoxication varies according to its concentration and the duration of inhalation. It starts with headache, vertigo, nausea, vomiting and tinnitus, which can progress to respiratory difficulty, muscular laxity, syncope, and coma leading to death. 3. Nitrogen dioxide Nitrogen dioxide causes respiratory disturbances by formation of methemoglobin. In acute poisoning, it can cause pulmonary congestion, pulmonary edema, bronchitis, and pneumonia due to its strong irritation on the eyes and the nose. In chronic poisoning, it causes chronic pulmonary fibrosis and pulmonary edema. 4. Ozone It has offending irritating odor, and causes dryness of na sopharyngolaryngeal mucosa, headache and depressed pulmonary function which may eventually lead to pulmonary congestion or edema. 5. Smog The most outstanding incident of the smog occurred in London from December 5 through 8, 1952, because of which the mortality of the respiratory diseases increased fourfold. The smog was thought to be due to the smoke produced by incomplete combustion and its byproduct the sulfur oxides, and the dust was thought to play the secondary role. In new sense, hazardous is the photochemical smog which is produced by combination of light energy and the hydrocarbons and oxidant in the air. The Yonsei University Institute for Environmental :pollution Research launched a project to determine the relationship between the pollution and the medical, ophthalmological and rhinopharyngological disorders. The students (469) of the "S" Technical School in the most heavily polluted area in Pusan (Uham Dong district) were compared with those (345) of "K" High School in the less polluted area. The investigated group had those with subjective symptoms twice as much as the control group, 22.6% (106) in investigated group and 11.3% (39) in the control group. Among those symptomatic students of the investigated group. There were 29 with respiratory symptoms (29%), 22 with eye symptoms (21%), 50 with stuffy nose and rhinorrhea (47%), and 5 with sore thorat (5%), which revealed that more than half the students (52%) had subjective symptoms of the rhinopharyngological aspects. Physical examination revealed that the investigated group had more number of students with signs than those of the control group by 10%, 180 (38.4%) versus 99 (28.8%). Among the preceding 180 students of the investigated group, there were 8 with eye diseases (44%), 1 with respiratory disease (0.6%), 97 with rhinitis (54%), and 74 with pharyngotonsillitis (41%) which means that 95% of them had rharygoical diseases. The preceding data revealed that the otolaryngological diseases are conspicuously outnumbered in the heavily polluted area, and that there must be very close relationship between the air pollution and the otolaryngological diseases, and the anti-pollution measure is urgently needed.

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Nonthermal Plasma-assisted Diesel Reforming and Injection of the Reformed Gas into a Diesel Engine for Clean Combustion (디젤의 청정연소를 위한 저온 플라즈마 연료개질 및 개질가스의 디젤엔진 첨가에 관한 연구)

  • Kim, Seong-Soo;Chung, Soo-Hyun;Kim, Jin-Gul
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.394-401
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    • 2005
  • A nonthermal plasma-assisted fuel reformer was developed and the effects of operating variables on the performance of this reformer were studied. The $H_2$-rich reformed gas from the reformer was injected into a diesel engine under an idle condition and the effects of the amount of injected gas on the NO and soot reduction were investigated. It was found that with increasing electric power consumption, the degree of facility of ignition of the reforming reaction in the reformer could be enhanced. The performance of the reformer including $H_2$ concentration, $H_2$ recovery, and energy conversion was affected only by the O/C mole ratio. This was because the equilibrium reaction temperature was governed by the O/C mole ratio. With increasing O/C mole ratio, the $H_2$ recovery and energy conversion passed through the maximum values of 33.4% and 66%, respectively, at an O/C mole ratio between 1.2 and 1.5. The reason why the $H_2$ recovery and energy conversion increased with increasing O/C mole ratio when the O/C mole ratio was lower than $1.2{\sim}1.5$ appeared to be that the complete oxidation reaction occurred more enough with increasing O/C mole ratio in this low O/C mole ratio range and accordingly the reaction temperature increased. Whereas the reason why the $H_2$ recovery and energy conversion decreased with increasing O/C mole ratio when the O/C mole ratio was higher than $1.2{\sim}1.5$ appeared to be that the complete oxidation reaction was further advanced and the $H_2$ recovery and energy conversion decreased. As the weight ratio of reformed diesel to total diesel which entered the diesel engine was increased to $18.2{\sim}23.5%$, NO and soot reduction efficiencies increased and reached as values high as 68.5% and 23.5%, respectively.

A study on the flow characteristics in a MILD combustion waste incinerator with the change of flue gas recirculation inlet location (MILD 연소 폐기물 소각로에서 배기가스 재순환 흡입구 위치에 따른 유동 특성 연구)

  • Ha, Ji Soo;Shim, Sung Hun;Jung, Eung Ho
    • Journal of Energy Engineering
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    • v.23 no.3
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    • pp.51-57
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    • 2014
  • A MILD(Moderate and Intense Low oxygen Dilution) combustion, which is effective in the reduction of NOx, is considerably affected by the recirculation flow position of hot exhaust gas to the combustion furnace. A numerical analysis was accomplished to elucidate the flow characteristics in the MILD combustion incinerator for several cases with or without exhaust gas recirculation. It could be seen from the result of the present numerical study that the flow recirculation could be observed in the upper region over the vertical dividing wall for the case without exhaust gas recirculation. The optimal position of exhaust gas recirculation position was derived by the comparison of %RMS of x directional velocity for the cases with exhaust gas recirculation. The case with the exhaust gas recirculation position at the upper right of free board was the most effective with the smallest value of 57.4% RMS.

Experimental Study on Thermal NOx and CO Emission in a Laboratory-Scale Incinerator with Reversed Secondary Air Jet Injection (역방향 2차 공기 주입 방식을 적용한 소각 연소로의 Thermal NOx 및 CO 배출특성에 대한 축소모형실험 연구)

  • Choi, Chonggun;Choi, Woosung;Shin, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.8
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    • pp.503-510
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    • 2016
  • Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

A review on the Plan for the Further Reinforcement of the NOx Emission Limit for Marine Diesel Engine (선박에서 배출되는 NOx의 배출량 규제에 대한 대응 방안 고찰)

  • Jang M.S.;Kim S. H.;Kang K.S.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.4
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    • pp.174-179
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    • 2004
  • Domestic marine diesel engine makers reduce the NOx emission mostly by applying low NOx fuel nozzle and injection timing retard. However, it is necessary to develop high efficient technology (EGR, DWI and SCR, etc.) to reduce NOx emission in order to prepare for the further reinforcement of the NOx emission limit. Also, in the near future, IMO will restrict additively THC, PM and CO with NOx. Therefore, domestic engine makers have to prepare for it and the relevant government ministries should give a sufficient support to these technology research and establish or amend the relevant law, which should include the excursion riverboat.

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Characteristics of UBC and NOx Emission in Air Staging Combustion (공기 다단 연소 기법 적용에 따른 미연탄소분 및 질소산화물 배출특성)

  • Kim, Jeong Woo;Lim, Ho;Go, Young Gun;Jeon, Chung Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.10
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    • pp.637-644
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    • 2016
  • The purpose of this study is to understand the characteristics of unburned carbon (UBC) and NOx emissions for pulverized coal when air staging combustion is applied. A two-staged drop tube furnace capable of applying air staging combustion was designed and installed. The combustion of sub-bituminous (Tanito) has been investigated. UBC and the NOx concentration were measured under various temperatures and stoichiometric ratios in unstaged and staged combustion. As a result, UBC decreased and the NOx concentration increased with an increase in stoichiometric ratio and temperature. In particular, the NOx reduction mechanism was activated when the temperature in the fuel rich zone increased. Both UBC and the NOx concentration decreased as the temperature increased in the fuel rich zone. A high NOx reduction effect was obtained, compared to the UBC increase, when the air staging technique was applied.

A Study on the Emission Characteristics of LNG-diesel Dual-fuel Engine for Euro 2 Standard (Euro 2 기준 LNG-경유 혼소엔진의 배출가스 특성에 관한 연구)

  • Cho, Gyu-Baek;Kim, Chong-Min;Kim, Dong-Sik;Kim, Hong-Suk
    • Journal of the Korean Institute of Gas
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    • v.15 no.1
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    • pp.9-14
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    • 2011
  • Heavy duty diesel engine has relatively small portion of whole vehicles due to long drive distance and large engine displacement, but largely influences atmosphere environment. City buses changed to CNG (Compressed Natural Gas) bus with Korea-Japan Worldcup. Heavy duty truck and intercity bus, however, were impossible to use CNG because those kinds of vehicles had long drive distance and CNG station was installed mainly at the around of the bus garage of city. Insulation container storing the natural gas as a liquid makes heavy duty truck and intercity bus possible to use the natural gas. Drive using diesel is possible where is hard to recharge the gas. With LNG (Liquefied Natural Gas), the dependence on oil is largely decreased, PM (Particulate Matter) and NOx which is chronic disadvantage of diesel is remarkably reduced and finally $CO_2$, the representative green house gas, is reduced over 10%.

Selection of Factors for Performance Optimization on Non-esterified Bio-diesel Fuel Using Fractional Factorial Design (부분요인배치법을 이용한 비에스테르화 바이오 디젤유의 성능 최적화를 위한 인자 선정)

  • Jung, Sukho;Koh, Daekwon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.1
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    • pp.8-12
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    • 2015
  • Non-esterified bio-diesel fuel saves cost by no esterified process and its performance was more similar to diesel oil than esterified bio-diesel fuel when the fuel blended 95% diesel oil and 5% it was used on diesel engine with electronic control system. A performance optimization is necessary for application of non-esterified bio-diesel fuel blended with diesel oil 95% on the latest diesel engine. In this study, test using fractional factorial design was accomplished at 25% and 50% partial load in order to evaluate influence of controllable 6 factors on responses such as specific fuel consumption, nitrogen oxides and coefficiency of variation of indicated mean effective pressure as basic experiment for performance optimization of this fuel. It is cleared that the injection timing and common rail pressure of 6 factors are mainly effective and its effect level is different according to load.

Lean Combustion Characteristics with Hydrogen Addition in a LPG Fuelled Spark Ignition Engine (LPG엔진에서 수소연료 보조분사에 의한 희박연소특성 연구)

  • Oh, Seung-Mook;Kim, Chang-Up;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.2
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    • pp.114-120
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    • 2006
  • The basic effects of hydrogen addition for engine performance and emission were investigated in single cylinder research engine. Seven commercial injectors were tested to choose a suitable injector for hydrogen injection prior to its engine implementation. The hydrogen fuel leakage and flow rate were evaluated for each injector and KN3-1(Keihin, CO.) showed the best performance for hydrogen fuel. At the higher excess air ratio(${\lambda}=1.7$, 2.0), the better combustion stability was found with hydrogen addition even though its effect was small at lower excess air ratio (${\lambda}=1.0$, 1.3). Stable operation of the engine was even guaranteed at ${\lambda}=2.0$, if the amount of hydrogen gas was near 15% of total energy. In the lean region, ${\lambda}>1.3$, thermal efficiency was improved slightly while it was not clearly observed at ${\lambda}=1.0$, 1.3. It is considered that, in some cases, high temperature environment due to hydrogen combustion caused further heat loss to surroundings. Except for ${\lambda}=1.0$, with larger amount of hydrogen addition, CO was reduced drastically but it was emitted more at the leaner region. Nitric oxides(NOx) was increased a little more with hydrogen addition at ${\lambda}=1.0$, 1.3. However, at ${\lambda}>1.3$ its relative amount of emission was low. In addition, the amount of NOx was continuously decreased with hydrogen addition, but, at ${\lambda}=2.0$ the amount of NOx was lowered to 1/100 of that of ${\lambda}=1.0$. THC emission was significantly increased as air/fuel ratio was raised to leaner region due to misfire and partial burn.

Performance Prediction according to Equivalence Ratio Change in Simulated-EGR Compression Ignition Engine Containing CO2 (CO2를 포함한 Simulated-EGR 압축착화엔진에서 당량비 변화에 따른 성능 예측)

  • Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.25 no.1
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    • pp.21-26
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    • 2020
  • The objective of this work is to numerically reveal the effect of equivalence ratio change on the simultaneous reduction of NOX and soot emissions from the simulated-EGR compression ignition engine containing CO2. An experiment was conducted by using a single-cylinder common-rail injection system engine, an intake control system, and exhaust emissions analyzers. The numerical analysis results were validated under the same experimental conditions. To investigate the effect of equivalence ratio by simulated-EGR containing CO2, the O2, N2, and CO2 mole fraction were changed in the initial air conditions to the cylinder. The results were analyzed in terms of peak cylinder pressure, indicated mean effective pressure, indicated specific nitrogen oxide, and indicated specific soot. It was revealed that ignition delay characteristics and heat release rate (ROHR) characteristics were not significantly different according to the equivalence ratio. However, as the equivalence ratio increased from 0.68 to 0.83, the maximum combustion pressure and IMEP decreased by about 6.5% and 9.4%, respectively. In the case of ISFC, as is well known, the trend is opposite of IMEP. In the case of ISNO, as the equivalence ratio increased, less NO was generated, and as the equivalence ratio increased by 0.05, the ISSoot value of about 10% increased.