• Title/Summary/Keyword: 연료적 특성

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Fabrication and Characteristics of Anode-Supported Tube for Solid Oxide Fuel Cell (습식법에 의한 고체산화물 연료전지용 연료극 지지체관의 제조 및 특성 연구)

  • Kim, Eung-Yong;Song, Rak-Hyeon;Im, Yeong-Eon
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.659-664
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    • 2000
  • To develop anode-supported tubular cell with proper porosity, we have investigated the anode substrate and t the electrolyte-coated anode tube. The anode substrate was manufactured as a function of carbon content in the range of 20 to 50 vol.%. As the carbon COntent increased, the porosity of the anode substrate increased slightly and the carbon c content with proper porosity is found to be 30 vol.%. The anode-supported tube was fabricated by extrusion process a and the electrolyte layer was coated on the anode tube by slurry coating process. The anode-supported tube was cofired successfully at $^1400{\circ}C$ in air. The porosity of the anode tube was 35%. From the gas permeation test, the anode t tube was found to be porous enough for gas supply. On the other hand, the anode-supported tube with electrolyte layer indicated a very low gas permeation rate. This means that the coated electrolyte was dense.

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A System Simulation Model of Proton Exchange Membrane Fuel Cell for Residential Power Generation for Thermal Management Study (가정용 연료전지 시스템의 열관리 해석을 위한 시스템 운전 모델 개발)

  • Yu, Sang-Seok;Lee, Young-Duk;Ahn, Kook-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.1
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    • pp.19-26
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    • 2010
  • A PEMFC(proton exchange membrane fuel cell) is a good candidate for residential power generation to be coped with the shortage of fossil fuel and green house gas emission. The attractive benefit of the PEMFC is to produce electric power as well as hot water for home usage. The thermal management of PEMFC for RPG is to utilize the heat of PEMFC so that the PEMFC can be operated at its optimal efficiency. In this study, thermal management system of PEMFC stack is modeled to understand the dynamic response during load change. The thermal management system of PEMFC for RPGFC is composed of two cooling circuits, one for controling the fuel cell temperature and the other for heating up the water for home usage. The different operating strategy is applied for each cooling circuit considering the duty of those two circuits. Even though the capacity of PEMFC system (1kW) is enough to supply hot domestic water for residence, heat-up of reservior takes some hours. Therefore, in this study, time schedule of the simulation reflects the heat-up process. Dynamic responses and operating strategies of the PEMFC system are investigated during load changes.

Corrosion resistance and cell performance of CrN-coated stainless steels as a metal bipolar plate for DMFC (CrN 코팅 STS 금속분리판의 부식 특성과 DMFC 성능 평가)

  • Lee, Se-Hee;Park, Young-Chul;Lim, Seongyop;Kim, Sang-Kyung;Jung, Doo-Hwan;Choi, Se-Young;Peck, Dong-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.137.2-137.2
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    • 2010
  • 본 연구는 스테인리스 스틸(STS)을 직접메탄올 연료전지(DMFC)용 바이폴라 플레이트에 적용하기 위한 것이다. 약산성의 연료전지 환경에서 부식저항성을 향상시키고자 오스테나이트계 STS 316L과 페라이트계 STS 430에 UBM(unbalanced magnetron) DC sputter로 CrN 코팅막을 제작하였다. CrN이 코팅된 스테인리스 스틸은 부식특성, 접촉 저항 및 접촉각 등을 측정하여 무 코팅의 스테인리스 스틸과 특성을 비교하였다. 그리고 이들 재료의 연료전지(DMFC) 적용 가능성을 알아보기 위하여 단위전지로 제작하여 연료전지 성능 등을 측정하고 평가하였다. 무 코팅 스테인리스 스틸(STS 316L, STS 430)과 CrN 코팅 스테인리스 스틸의 부식저항 특성은 동전위와 정전위 실험으로 조사하였다. 동전위 부식 실험은 -0.4~1.0 V로 0.001 M의 황산용액 또는 메탄올을 첨가하여 질소 또는 공기의 환경에서 실험을 실시하였으며, 정전위 부식 실험은 0.4 V 또는 0.6 V에서 진행하였다. 연료전지의 단전지 측정은 실제 DMFC의 운전조건에서 실시하였다. 부식실험과 단전지 실험 전/후 메탈 바이폴라 플레이트의 조직 변화는 SEM을 통해 관찰하였고, 부식산화물의 화학적 조성과 메탈 바이폴라의 표면은 EDS를 이용하여 측정하였다.

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Combustion Characteristics of Hybrid Rocket Fuel with Tapered Grain Port Shape (경사진 포트 형상을 가진 하이브리드 로켓 연료의 연소 특성)

  • Kim, Jae-Woo;Kim, Soo-Jong;Kim, Jin-Kon;Sung, Hong-Gye;Moon, Hee-Jang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.511-514
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    • 2009
  • In this study, the combustion characteristics of hybrid rocket fuel with tapered grain port were studied. The regression rate was increased about 17.5% by using the convergence port shape fuel. On the other hand, in case of divergence port shape fuel, any notable difference of regression rate was not observed when compared with regression rate of the cylindrical port shape fuel. Also, in case of convergence port shape fuel, characteristic velocity efficiency was increased. From these results, one can notice that convergence port shape of hybrid rocket fuel can be effective configuration in terms of improvement of combustion efficiency and performance.

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A Study on Combustion Characteristics of End-Burning Hybrid Propulsion System with the Various Fuel (End-burning 하이브리드 추진시스템의 연료에 따른 연소특성 연구)

  • Lee Seung-Chul;Kim Jin-Kon;Kim Soo-Jong;You Woo-Jun;Lee Jung-Pyo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.323-326
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    • 2005
  • In this study, experimental studies were performed the combustion characteristics of end- burning hybrid propulsion system. PMMA, PE were used as fuel and gas oxygen as oxidizer. The regression rate depend on oxidizer flow rate also on thermodynamic properties of fuel. as result, empirical formula for regression rate was deduces with oxidizer flow rate and mass transfer coefficient B number.

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A study on the physical properties effect of additive on the Jet A-1 (첨가제를 이용한 Jet A-1 연료의 물성증대 효과 연구)

  • Joo, Hyeong-Uk;Joo, Hyun-Hye;Lee, Ji-Hun;Kwon, Tae-Soo;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.702-704
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    • 2011
  • For the representative of the poor performance of liquid fuel(Jet A-1), the physical properties effests of different additive ratios in the liquid fuel have been investigated. The mixed liquid fuel could be analyzed by principal factor of liquid fuel such as, density, viscosity and caloric value. This additives will be usefully applied to high energy density liquid fuel development.

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On the Consideration of CO and Soot Yield Concept in FDS Fire Field Model (FDS 화재해석 모델에 적용된 CO와 연기 생성율 개념에 대한 고찰)

  • Kim, Sung-Chan;Ko, Gwon-Hyun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2009.04a
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    • pp.93-99
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    • 2009
  • 본 연구는 ISO-9705 표준화재실의 40% 축소모형실험 결과와 FDS 화재해석 결과의 비교분석을 통하여 FDS 화재해석 모델에 적용된 CO 와 soot의 생성율(yield rate)에 기초한 접근방식의 타당성을 검토한다. 일반적으로 생성율은 연료적인 특성인 동시에 공간의 환기조건이나 열적조건등에 영향을 받게 된다. 그러나 FDS 해석에 적용되는 연료의 생성율은 환기량이 충분한 상태(well ventilated condition)에서 측정되어진 물성으로써 공간내부의 CO와 soot 농도는 연료의 종류와 화원의 크기에 의해서만 결정된다. 따라서 환기조건과 연료특성에 따른 화재공간 내부에서의 CO와 soot 농도를 측정하여 이 결과를 FDS 시뮬레이션 결과와 직접 비교함으로써 환기조건 및 연료종류에 따른 CO 와 soot의 생성율 개념의 타당성을 고찰해보고자 한다.

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Influence of Fuel Swirl Flow on NOx Emission in Swirl Combustor (스월연소기에서 연료스월유동이 NOx 배출에 미치는 영향)

  • Cho, Jin-Woo;Whang, Sang-Ho;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.7
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    • pp.70-75
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    • 2005
  • In this study, experimental investigations were conducted on NOx emission characteristics with fuel swirl flow in swirl combustor. Many types of vanes, which altered air and fuel swirl angles, were employed to verify the mixing processes. For strong air swirl, fuel counter-swirl resulted in relatively large turbulent intensity, high energy to the high frequency region and narrow width of high temperature region compared with co-swirl condition. These effects of fuel counter-swirl resulted in low NOx emission characteristics at strong air swirl condition. And NOx reduction mechanism was also discussed.

Analyses of Larg Cell Area MCFC System Dynamics (대면적 용융탄산염 연료전지 시스템 동특성 분석)

  • 강병삼;고준호;이충곤;임희천
    • Journal of Energy Engineering
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    • v.8 no.4
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    • pp.592-604
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    • 1999
  • The steady state and dynamic characteristics of large cell area MCFC stacks were analyzed to solve the problems such as temperature difference generated in stacks and pressure difference between anode and cathode. Manipulated variables (current density, duel utilization rate, oxidant utilization rate) and controlled variables (temperature difference, anode and cathode pressure difference) which had an important effect on the MCFC stack performance were determined using operation results of two types of MCFC stacks (5kW (3,000 $\textrm{cm}^2$, 20 ea). 3kW (6,000 $\textrm{cm}^2$, 5ea)). The stability and transfer function representing system dynamics were obtained by steady state gain rate which showed the relative change between MVs and CVs. The transfer function was a 3$\times$3 matrix and a typical first order system without time delay. The optimal operating condition of large cell area MCFC stacks could be determined by analyzing dynamic characteristics. In case of a 5 kW MCFC stack, pressurized operation with recycle flow should be used to control the outlet temperature less than 68$0^{\circ}C$ and to control the MCFC system effectively. MIMO control or decoupler should be used to remove the interaction between MVs and CVs. This result will be used as important data in determining the control structure design and operation mode of large cell area MCFC systems in the future.

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Spray Characteristics of the Rotating Fuel Nozzle with Orifice Geometry (회전연료노즐 형상변경에 따른 분무특성)

  • Jang, Seong-Ho;Choi, Hyun-Kyung;Lee, Dong-Hun;You, Gyung-Won;Choi, Seong-Man
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.240-243
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    • 2008
  • An experimental study was conducted to understand spray characteristics of rotating fuel nozzle by using high speed rotational system. The experimental apparatus consist of a fuel injection system, high speed rotational system, and acrylic case. The test is performed with several diameters and number of injection orifices. Spray characteristics such as droplet size and velocity are measured by PDPA(Phase Doppler Particle Analyzer). From the test results, we could understand the spray characteristics of rotating fuel nozzle with orifice number and diameter.

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