• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.4
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• pp.227-236
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• 2016

In the present experimental study, the effect of gas- and liquid-injected methods on the formation of bubble and liquid slug at the merging micro T-junction of a square microchannel with dimensions $600{\mu}m{\times}600{\mu}m$ was investigated. Nitrogen and water were used as test fluids. The superficial velocities of the liquid and gas were in the range of 0.05 - 1 m/s, and 0.1 - 1 m/s, respectively, where the Taylor flow was observed. The bubble length, liquid slug length, bubble velocity, and bubble generation frequency were measured by analyzing the images captured using a high-speed camera. Under similar inlet superficial velocity conditions, in the case of gas injection to the main channel at the merging T-junction (T_gas-liquid), the lengths of the bubble and liquid slug were longer, and the bubble generation frequency was lower than in the case of liquid injection to the main channel at the merging T-junction (T_liquid-gas). On the other hand, in both cases, the bubble velocity was almost the same. The previous correlation proposed using experimental data for T_liquid-gas had predicted the present experimental data of bubble length, bubble velocity, liquid slug length, and bubble generation frequency for T_gas-liquid to be ~24%, ~9%, ~39%, ~55%, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.1
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• pp.77-82
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• 2010

Our study aims to understand the flow of liquid in an open-top rectangular microchannel that can be used in micro total analysis systems ($\mu$-TAS) because it has advantages in terms of light transmission and energy efficiency. We measured the liquid velocity using particle tracking technique and conducted a simulation with computational fluid dynamics by altering the area of channel cross section and channel length for the capillary-driven flow in the open-top rectangular microchannel. When liquid water drops to an entrance of the fabricated microchannel with a height of 20 μm and a width of 20 ${\mu}m$, it flows along the microchannel by only capillary force. In the wetting behavior of the liquid, important parameters of this flow are channel size, contact angle and liquid properties such as surface tension and viscosity, which are used to control the flow of liquid in the microchannel.

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.706-711
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• 2016

Characteristics of solid circulation rate in the liquid-solid circulating fluidized beds with viscous liquid medium were investigated. Effects of primary and secondary liquid velocities, particle size, liquid viscosity and height of solid particles piled up in the solid recycle device on the solid circulation rate were considered. The solid circulation rate increased with increasing primary and secondary liquid velocities, liquid viscosity and height of solid particles in the downcommer, but it decreased with increasing particle size. The particle rising velocity in the riser decreased with increasing the ratio of $U_{L1}/U_{L2}$ and particle size. The slip velocity of liquid and particle, $U_L/U_S$, decreased with increasing liquid viscosity but it increased with increasing particle size. The values of solid circulation rate were well correlated in terms of operating variables and dimensionless groups.

• Water for future
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• v.22 no.4
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• pp.435-440
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• 1989

An analytical equation was formulated using the continuity, momentum, and energy equations for the trensients generated in an initially empty piping with a sudden contraction subject to rapid filling with liquid. Also, two mathematical models, MOC and RCT were applied to this particular piping to reveal that the rigid column method is less applicable than the method of characteristics to the piping.

• Journal of the Korean Electrochemical Society
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• v.13 no.3
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• pp.181-185
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• 2010

Polyaniline-ionic liquid composite was prepared and investigated its physical and electrochemical properties. The quasi-solidification was presented in imidazolium-based ionic liquid (1-methly-3-propylimidazolium iodide, PMI-I) containing above 30 wt% of polyaniline (emeraldine base), which exhibited around 80% decrease of conductivity compared to pristine ionic liquid, resulting in fibril structure trough ${\pi}-{\pi}$ self-assembled of imidazolium aromatic ring of ionic liquid on polyaniline framework.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.446-455
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• 2023

A mathematical model for predicting the liquid circulation velocity in an airlift reactor was developed based on the mechanical energy balance of the fluid circulation loop. The model considered the energy loss due to a 90° turn, the energy loss due to friction, and the energy loss due to the change in cross-sectional area at each part of the reactor. The model that separately considered the loss coefficients related to friction, direction change, and cross-sectional area change was able to predict the liquid circulation velocity better than the previous model using lumped parameters. The liquid circulation velocity was measured by the tracer pulse method. Most of our experimental results obtained in external-loop airlift reactors, which had the top and bottom connecting pipes, as well as other investigators' results obtained in various types of airlift reactors, were well predicted by the developed model with an error within 20%. Useful empirical equations for the loss coefficient related to the 90° turn of the circulating fluid were obtained in external and internal-loop airlift reactors and used to predict the liquid circulation velocity.

• Membrane Journal
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• v.28 no.3
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• pp.214-219
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• 2018

In the present study, superflux nickel capillary supports for gas and vapor separation membranes were prepared by a combined process of NIPS and sintering. Nickel capillary precursors were prepared by NIPS process from PSf-Ni-DMAC-PEG400 dope solution and was sintered at various temperatures in $H_2$ atmosphere to reliably produce Ni capillary support. The optimized Ni capillary support has an outer and inner diameters of 722 and $550{\mu}m$, and its thickness was $94{\mu}m$. It has 3-dimensional pore channel network and its porosity and mean pore diameter was 26% and $4{\mu}m$, respectively. Also, its mechanical strength was tested in tensile mode: its fracture load was 2.84 kgf and the fracture elongation was 13%. Finally, its single gas permeance was measured: He, $N_2$, $O_2$, and $CO_2$ permeance was 432,327, 281,119, 264,259, and 193,143 GPU, respectively. The superflux behavior could be explained from viscous flow through the macropores having a diameter of $4{\mu}m$ and narrow thickness. It could be concluded that the superflux behavior of the Ni capillary support was from the 3-D pore channel network and the small thickness.

• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.503-509
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• 1985

Sixteen organochlorine pesticides extracted out from the crops and cleaned by solvent-solvent partitioning and Florisil column chromatography were determined by gas-liquid chromatography. The majority of the pesticides were well separated by being eluted through 5% QF-1 column and some of them through 3% OV-17 column and 2.596 DC-200/2.5% QF-1 column, and the eluted pesticides were detected by $^{63}Ni$ electron capture detector. The linear calibration curves were obtained for the most of pesticides while some curves were slightly deviated from the linearity. In the determination of 16 pesticides added to thirteen kinds of crops, the recoveries were showed over 85% for the most cases and the relative standard deviations of 5 analyses were less than 12.1%. The results were within the criteria of the AOAC method.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.985-991
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• 1996

In chromatographic separation, HETP(height equivalent to a theoretical plate) is a useful quanititive parameter and it is wildely designated as column efficiency. The effects of operating conditions (sample concentration, injection volume, flow rate and mobile phase composition) on HETP were investigated in perparative liquid chromatography (PLC). Water and organic modifier of methanol were used as mobile phase. The sample of thymidine was injected into preparative C18 columns. The system was run by a isocratic mode in 1.5~5.5ml/min. The larger amounts of sample and higher flow rates of mobile phase increased HETP, which means that column efficiencies were worse. As the weight of sample injected into a chromatographic system could be prepared with different concentrations and injection volumes, for the same amount of sample, HETP was approximately increased two times with the ten-fold injection volume. HETP was mainly affected by the resistance of stationary and mobile phase mass transfer in the intraparticle section of packings at higher velocities.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.9 no.4
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• pp.135-143
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• 1989

The experimental study on the shape and behavior of bubbles in U-tube deep shaft of 32m has been performed. According to the results in this paper, the equivalent spherical diameter of bubbles was 0.422-0.722cm and the shape of bubbles was almost ellipsoidal for bubbles to be generated ta single-orifice of diameter 0.06cm in the downcomer of the deep shaft system. Gas hold-up and gas-liquid contact area of bubbles in the deep shaft was decreased in accordance with depth, Also downcomer velocity of bubbles was slower than circulation velocity of liquid and riser velocity of bubbles was fast than circulation velocity. The bubble-size-distribution of bubbles in the deep shaft was the logarithmic probability distribution. The number of bubbles in the deep shaft was decreased in accordance with depth and the number of bubbles in the downcomer is more than the bubbles in the riser.