• Polymer(Korea)
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• v.34 no.5
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• pp.430-433
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• 2010

The gasket materials of for the lithium ion battery requires chemical resistance to electrolyte, electrical insulating, compression set, anti-contamination and low temperature property. To check the special characteristics of fillers which are applied to rubber for gasket, compound of EPDM, NBR and FKM (fluoro elastomer) were made by adjusting weights of carbon black and silica additive. Using these compounds, we had done tests of long-term stability against electrolyte, compression set and low-temperature property with considering operating condition of the lithium ion battery. From this test, we investigated the physical and chemical characteristics of rubber with using of carbon black and silica additive in each.

• Elastomers and Composites
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• v.45 no.3
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• pp.212-216
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• 2010

The materials of the lithium ion battery gasket require chemical resistance to the electrolyte, electrical insulating, compression set, anti-contamination and heat resistance. To estimate suitability for rubber which has better performance to compression set than PFA, each compound were made with various rubbers, such as EPDM, NBR, FKM, FVMQ, VMQ and we checked the characteristics of each compound. Samples from each compound was deposited in Propylene Carbonate and tested for changing of Hardness and Volume during 1,000 hr with $80^{\circ}C$. EPDM and VMQ showed good performance to chemical resistance to the electrolyte, and also we could get the values over $10^{10}{\Omega}cm$ on volume resistance basis in electrical insulating. EPDM and VMQ were judged as the most suitable material.

• Polymer(Korea)
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• v.35 no.4
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• pp.342-349
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• 2011

The effect of the amount of vinyltriethoxysilane (VTEOS) in precipitated silica filled silicone rubbers was extensively investigated in terms of the change of mechanical properties, heat resistance, oil resistance, compression set, resilience, and curing characteristics. As the content of VTEOS increased from 0 to 2.0 phr, the hardness of the silicone rubber increased, however, tensile strength, elongation at break, and tear strength decreased. From heat resistance test, the change of mechanical properties was pronounced for silicone rubber treated with more VTOES. The best heat resistance was achieved at 2.0 phr VTOES. In addition, oil resistance was proportionally improved with VTEOS content. From oil resistance test. it was found that the decrease in hardness and maximum elongation was reduced for VTEOS-added systems. Finally, resilience, compression set, degree of cure and crosslink density were significantly enhanced with the amount of VTEOS.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.395-399
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• 2011

Material of the gasket for lithium ion battery requires the chemical resistance, the electrical insulting property, the compression set, the anti-contamination level and the low temperature resistance. We compounded ethylene propylene diene monomer (EPDM), which showed widely different solubility parameter index, with adjusting the amount of metal oxide as an activator. We did long-term test and compression set against an electrolyte with consideration for operating conditions in lithium-ion battery. In these tests, we checked the physical, chemical characteristics and the effect to lithium ion battery with different kinds of activators. In case of rubber with ZnO as an activator, through 1000 h depositing test in propylene carbonate which is one of representative solvents, we could get the satisfying characteristics and result. However, $Zn^{2+}$ had eluted in the ion elution test. So, ZnO should be limited in EPDM compound for the gasket material in lithium-ion battery.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.14 no.11
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• pp.1153-1160
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• 2004

In contemporary society, vibration and noise in the road nearby buildings have become social problems as vehicles operation has increased. Especially. in the case of the building used to art performance, available suitability of the building is tested by the indoor noise class. Therefore, the Purpose of this paper is the measurement of the structure-borne noise of Seoul Art Center nearby Umyeonsan tunnel and analyzing the effects of countermeasure to it. To measure the effects of countermeasure, not only structure-borne noise is measured, but also the vibration is measured, before and after the construction of Pavement using pad and porous asphalt. Consequently, the sound pressure level in art center 1st floor is reduced after mat pavement method, structure-borne noise that was high In 25Hz wide-band before pavement decreased regardless of experimental vehicle's velocity Using porous asphalt pavement the noise was reduced about 3 dB(A).

• Elastomers and Composites
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• v.46 no.2
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• pp.152-157
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• 2011

Effects of CR contents in NR/CR blends on the vulcanization kinetics and miscibility were studied by dynamic DSC and TGA, as well as the mechanical properties. While the vulcanization activation energy showed a constant value of $77.5{\pm}2.5$ kcal/mol regardless of CR contents, reaction rate, however, was observed to be somewhat lowered at increased CR contents. Partial miscibility was found between NR and CR phases at lower CR content of 3 wt%, but immiscibility was observed at higher CR content of 21 wt%. Mechanical properties were also affected by this miscibility, showing linear increase of compression set but decrease of tensile strength with CR contents in the blends.

• Elastomers and Composites
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• v.37 no.2
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• pp.107-114
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• 2002

This paper discusses the accelerated heat aging tests were carried out to predict the useful life of EPDM isolating rubber components of ventilation fan motor for clean room. 20% compression set results changes as the threshold are used for assessment of the useful life and the time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. The useful life at variable temperatures and activation energy are obtained from the Arrhenius relationship. An accelerated test program to assess useful life can be represented an appreciable investment in time was designed. We also considered the effect of antioxidant agents.

• Elastomers and Composites
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• v.36 no.3
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• pp.188-194
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• 2001

Thermoplastic elastomers based on dynamically vulcanized NR/TOR/PP (rubber/PP=70/30) blends were prepared in a Haake banbury mixer. Effect of TOR content on the mechanical, dynamic mechanical and thermal stability of the rubber/plastic blends was characterized by UTM, DMTA, and TGA. On the addition of trans-polyoctylene rubber(TOR) to the rubber phase, there was a decrease in compression set and increase in tensile properties, hardness and dynamic properties as well as thermal stability or the elastomeric blends. Improvements in the properties were believed to be due to an increase in crosslink density of the rubber phase and increase in homogeneity of the blends.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.149-154
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• 2011

In order to explore properties of various rubber compounds after thermal aging under the condition similar to the operating environment of a fuel cell-stack, heat resistance and compression set of those compounds were investigated for a long term operation in $H_2SO_4$, $H_2O$, and LLC (ethylene glycol : $H_2O=50:50$) solution. It was assumed that aging Acrylonitrile butadiene rubber (NBR) and Elthylene Propylene diene rubber (EDPM) compound in the solution resulted in discoloration as time passed. It was also found that hydrolysis was developed on the Silicone rubber (VMQ) compound intentionally aged under acidic condition by means of TGA, SEM, and EDS analysis.

• Composites Research
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• v.34 no.3
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• pp.192-198
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• 2021

Due to enormous market growing of electric vehicles without combustion engine, reducing unwanted BSR (buzz, squeak, and rattle) noise is highly demanded for vehicle quality and performance. Particularly, innerbelt weatherstrips which not only block wind noise, rain, and dust from outside, but also reduce noise and vibration of door glass and vehicle are required to exhibit high damping properties for improved BSR performance of the vehicle. Thermoplastic elastomers (TPEs), which can be recycled and have lighter weight than thermoset elastomers, are receiving much attention for weatherstrip material, but TPEs exhibit low material damping and compression set causing frictional noise and vibration between the door glass and the weatherstrip. In this study, high damping EPDM (ethylene-propylene-diene monomer)/PP (polypropylene) thermoplastic vulcanizates (TPV) were investigated by varying EPDM/PP ratio and ENB (ethylidene norbornene) fraction in EPDM. Viscoelastic properties of TPV materials were characterized by assuming that the material damping is directly related to the viscoelasticity. The optimum material damping factor (tanδ peak 0.611) was achieved with low PP ratio (14 wt%) and high ENB fraction (8.9 wt%), which was increased by 140% compared to the reference (tanδ 0.254). The improved damping is believed due to high fraction of flexible EPDM chains and higher interfacial slippage area of EPDM particles generated by increasing ENB fraction in EPDM. The stick-slip test was conducted to characterize frictional noise and vibration of the TPV weatherstrip. With improved TPV material damping, the acceleration peak of frictional vibration decreased by about 57.9%. This finding can not only improve BSR performance of electric vehicles by designing material damping of weatherstrips but also contribute to various structural applications such as urban air mobility or aircrafts, which require lightweight and high damping properties.