• Economic and Environmental Geology
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• v.51 no.2
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• pp.113-120
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• 2018

Radioactive cesium($^{137}Cs$) can be released into the environment through severe nuclear accidents such as the Chernobyl and Fukushima, The $^{137}Cs$ is one of major monitoring radionuclides due to its chemical toxicity, ${\gamma}$ radiation and long half-life($t_{1/2}=30.2yrs$). It has been known well that illite adsorb selectively and strongly the cesium due to frayed edge sites. The quantity of the FES in the illite could be controlled by weathering processes. Therefore, this study was modified illite samples through artificial weathering in the laboratory to increase sorption efficiency for cesium. Abundant interlayer cations(i.e., K, Ca) were eluted within 1 day, while Si and Al were gradually released from the crystal structure. In addition, broad peaks of XRD indicated the occurrence of chemical weathering. The cesium sorption distribution coefficients increased up to approximately 2 times after the weathering. These results suggested that sorption capacity of illite could be enhanced for cesium through artificial weathering under low temperature.

• Applied Biological Chemistry
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• v.30 no.1
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• pp.1-8
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• 1987

The distribution of the surface charges in two kinds of peats and their physico-chemical properties have a been studied by means of the potentiometric titration and by ion adsorption in different strength of electrolytes. The organic matter contents were 43.3% and 53.7% in Yeong Yang peat and Peong Tack peat, respectively. Their X-ray diffractograms showed that quartz was dominant in both peats, and illite, kaolinite, hydrated-halloysite and feldspars were contained in a trace. Total acidic group contents was 1.257me/g in Poeng Tack peat that was a little more than of Peong Yang heat were pKa values of Yeong Yang and Poeng Tack peat were 13.1 and 12.65, respectively. The titration curves at different ionic strength of electrolytes crossed at pH 3.9 and 4.4 in Yeong Yang peat, and pH 3.8 and 4.0 in Peong Tack peat. The pH ranges of suspensions when the net surfacecharge of the peats varied from positive to negative value were $pH\;4.55{\sim}5.20\;(NaCl)$ and $pH\;3.95{\sim}5.70\;(CaCl_2)$ in Yeong Fang peat, and $pH\;4.15{\sim}5.40\;(NaCl)$ and $pH\;3.80{\sim}4.15\;(CaCl_2)$ in Peong Tack peat. Therefore it is apparent that the zero point of charge of these peats was about pH 4.0.

• Journal of Food Hygiene and Safety
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• v.23 no.3
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• pp.218-221
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• 2008

The levels of sulfites in wooden chopsticks were analyzed using two different methods, distillation-alkali titration and ion chromatography. According to the two methods, Sulfur dioxide($SO_2$) was validated by 0.6 and 0.2 ${\mu}ml$ of limit of detection(LOD), 1.8 and 0.5 ${\mu}ml$ of limit of quantification, (LOQ) and a $R^2>0.998$ for linearity, respectively. The recoveries of $SO_2$ from food simulants spiked ar levels of 100 ppm were 70.2-100.2%. 158 samples of wooden chopsticks were monitored the migrated amounts of sulfites. Sulfites were detected in 30 samples in ranged of 0.6 to 15.5 ppm. Maximum migration level, 15.5 ppm of sulfites was considered giving no harmful effect to human since it was reached 5.5% of estimated SML.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.4
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• pp.239-246
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• 2012

This study was performed to investigate the removal characteristics and mechanism of heavy metals using pellet-type ceramics(ZS ceramics), in which natural zeolite was mixed and calcined with converter slag. The optimal calcination temperature range was measured to be $600{\sim}800^{\circ}C$. The calcination time had little effect on the removal of heavy metal in acid wastewater. The adequate dose of ceramics was shown to be 2~5% for removal of heavy metals in acid wastewater. The maximum removal capacity of ZS ceramics for heavy metals were observed to be Al 84.7 mg/g, Cd 37.3 mg/g, Cr 81.7 mg/g, Cu 55.6 mg/g, Fe 57.2 mg/g, Mn 32.1 mg/g, Ni 38.0 mg/g, Pb 71.6 mg/g, Zn 46.3 mg/g. The pH played a pivotal role in the removal of heavy metals by ZS ceramics. The analysis results of mechanism exhibited that the ZS ceramics could act as a multi-functional ceramics for removal of heavy metals in acid wastewater by adsorption, ion-exchange, or precipitation.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.2
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• pp.200-205
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• 2011

This study was conducted to find the physico-chemical properties and the amino acid content of the pigs hoof hydrolysate, keratin protein and to investigate its fertilizer effect on the growth of crops. The keratin proteins such as pigs hoof were alkali-hydrolyzed to produce the hydrolysates. The chemical properties of the hydrolysate of pigs hoof was 6~7 of pH and $10{\sim}15dS\;m^{-1}$ of EC. Total amino acid contents released from the pigs hoof were 10.18%, respectively. The pot experiment was carried out for the cultivation of lettuce. The treatment design of these pot cultivation was composed of Control (compost + NPK), PHH-0.5, PHH-1.0, PHH-2.0 (${\times}2,000$ ; 1,000 ; 500 diluted solution of pig hoof hydrolysate). After lettuce cultivation, the pH values in all treatment soils were decreased than those in initial soils, and the exchangeable cation value was higher than that of control. In all PHH treatments, lettuce growth was better in the leaf length by 6~16% and the leaf width by 4~15% than in control. Therefore, the PHH solutions manufactured by hydrolysis process had plenty of amino acids, and among them PHH had the most abundant nutrients and amino acids with highest growth and yield effect on lettuce.

• The Journal of the Petrological Society of Korea
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• v.23 no.2
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• pp.31-43
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• 2014

The Yeongdeok granite emplaced in the eastern Yeongyang subbasin is typically a medium- to coarse-grained massive biotite granite. It intruded into Precambrian schist & gneiss complex and is unconformably overlain by Cretaceous sedimentary rocks. In this study, we attempt to investigate the magma type which formed Yeongdeok granite and estimate the emplacement depth using Al-in-hornblende geobarometer to mineral composition. According to the magma fractionation, $TiO_2$, $Al_2O_3$, $Fe_2O_3{^*}$, FeO, $Fe_2O_3$, MnO, MgO, CaO, $Na_2O$ and $P_2O_5$ show positive trend but $K_2O$ indicate negative trend with $SiO_2$ contents. Those are identified as calc-alkaline series in AFM diagram and show the chemical characteristics of the I-type magma through the oxidation tendency of the iron ion and the portion of the alkaline composition. When calculated using the equation of Hollister et al. (1987), the emplacement depths of the Yeongdeok granite range from 8.98 to 17.19 km and average depth was estimated 13.03 km approximately.

• Journal of the Mineralogical Society of Korea
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• v.17 no.3
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• pp.235-243
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• 2004

Illite has been known to adsorb Cs preferentially to other alkali cations, especially at lower Cs concentration due to the frayed edge site. This frayed edge site was only verified by isotherm experiments, but not by other analytical methods. To investigate the Cs sorption properties on the surface of illite, artificially weathered illite with increasing frayed edge sites was reacted with Cs at different solution concentrations. The illite was weathered f3r 1 hour, 2 days, 14 days in 0.001 M HCl solution. With increasing reaction time, increasing amount of K in solution was observed, indicating formation of frayed edges by weathering, which was also verified by XRD, SEM, and TEM analysis. Original and weathered illites were converted to the homoionic Na form and reacted with $10^{-3}$ / ～ $10^{-7}$ M CsCl solutions for 24 hour. The aspect of Cs sorption was clearly distinguished around $10^{-5}$ M Cs concentration. The relative Cs amount sorbed on illite at low concentration (<10$^{-5}$ M) was higher than high concentration and increased with decreasing Cs concentration. In general, the amount of sorbed Cs increases with increasing weathering time and this trend is more noticeable at lower concentration while not much differentiated with weathering time at high concentration. These results indicate that the selective Cs sorption site exists in illite at low concentration, known as frayed edge site, and the number of those sites increases with weathering time.

• Journal of the Korea Concrete Institute
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• v.21 no.6
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• pp.713-718
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• 2009

Advanced industries-IT, BT, NT and ET are rapidly developing in 21 century. And the cement industry is becoming the principal factor in air pollution because of the creation of $CO_2$ during manufacturing. Also, the cement industry will be faced with a crisis due to the exhaustion of natural resources. In this study, nano cement by Bottom-up method of a chemical synthesis was developed. The generation of $CO_2$ during the plasticization process of cement manufacturing was avoided. The purpose was to produce building materials that have both high strength and durability as the high value-added growth engine industry of the 21 century. The nano cement was developed using hydrothermal synthesis. This is a method of mixing after ripening, by manufacturing the high density gel and low gel, which does not require special test equipment or pressure conditions to produce. Particle size, SEM, EDX, and porosity tests were conducted. This study investigated the compressive strength of concrete with various compositions. Specimens were tested for compressive strength at 3, 7, 14 and 28 days. The medium-sized (50% by weight) cement particles created by chemical synthesis were less than 168 nm. The compressive strength of the mortar prepared using this cement was 53.9 MPa. But it was judged that succeeding study will be necessary for development of nano building materials with high ability and economical analysis.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.237-244
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• 2015

Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

• Korean Journal of Ecology and Environment
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• v.36 no.3 s.104
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• pp.242-256
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• 2003

This study aimed to determine the relationship between rainfall-discharge patterns and maior aquatic environmental factors in a river-type reservoir. Specifically, daily monitoring was conducted in Paltang Reservoir from January 1999 to December 2001. Observation of the daily changes of the environment factors showed that natural meteorological factors and hydrological factors causing the change of water discharge had a major effect on the aquatic environment. Rainfall was the main source of hydrological changes, with its frequency a possible direct variable governing the range of discharge changes. Rainfall was weak in November${\sim}$May and heavy in June${\sim}$October (heavist in summer). The range of water discharge was greatest during summer (July to September) and lowest during winter (January to February). A principal component analysis (PCA) showed that aquatic environmental factors could be classified into three different types in the pattern of annual variation. First, type I included water temperature, turbidity, water color and organic matter (COD), which increased with increasing water discharge. Second, type ll consisted of DO and pH, which decreased with increasing water discharge. Third, type III included conductivity, alkalinity and chloride ion, which showed middle values with increasing water discharge. Monthly variation of aquatic environments explained by the first two dimensions of the PCA suggests that aquatic environments of Paltang Reservoir may have annual cycle typical of river-type reservoirs depending on hydrological factor such as water discharge.