• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.549-552
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• 2008

Corrosion of reinforcing steel is prohibited under normal condition by the alkalinity of the pore water in the concrete. But the probability of steel corrosion becomes higher when the chloride ions are introduced into the concrete. Steel corrosion is decisive factor for the determination of service life of the marine concrete structures because chloride ions are abundant in the sea. In this paper, chloride penetration analysis for the rectangular pier in the marine environment is performed considering the diffusion movement of chlorides. Result reveals that the chloride concentration in the corner bar is higher than that of in the side bar with rectangular pier. Also the time to the specified accumulation of chloride in the corner bar is much shorter than that in the side bar. Because the corrosion initiation time of corner bar is half as much as that of side bar, service life for the rectangular pier in marine environment should be determined with respect to the coner bar.

• Journal of Dental Rehabilitation and Applied Science
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• v.25 no.4
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• pp.361-374
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• 2009

For successful osteogenesis around the implants, interaction between implant surface and surrounding tissue is important. Biomechanical bonding and biochemical bonding are considered to influence the response of adherent cells. But the focus has shifted surface chemistry. The purpose of this study is to evaluate the MC3T3-E1 osteoblast like cell responses of magnesium (Mg) ion implanted titanium surface produced using a plasma source ion implantation method. Commercially pure titanium disc was used as substrates. The discs were prepared to produce four different surface, A: Machine turned surface, B: Mg implanted surface, C: sandblasted surface, D: sandblasted and Mg implanted surface. MC3T3 El osteoblastic like cells were cultured on the disc specimens. Cell adhesion, proliferation, differentiation, and synthesis of extracellular matrix were evaluated. The cell adhesion morphology was evaluated by SEM. RT PCR assay was used for assessment of cell adhesion, proliferation and differentiation. ALP activity was measured for cell differentiation. The results of this study were as follows: 1. SEM showed that cell on Mg ion groups was more proliferative than that of non Mg ion groups. On the machine turned surface, cell showed some degree of contact guidance in aligning with the machining grooves. 2. In RT PCR analysis, osteonectin and c-fos mRNA were more expressed on sandblasted and Mg ion implanted group. 3. ALP activity was not significantly different among all groups. Within the limitations of this study, the following conclusions were drawn: It might indicate Mg ion implanted titanium surface induce better bone response than non Mg ion groups.

• The Korean Journal of Food And Nutrition
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• v.6 no.1
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• pp.8-15
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• 1993

We have examined the utility of alkaline ionic water for processing water In order to compare with piped tap water in cooking rice, making kimchi, making bean curd, raising bean sprouts and parboiling spinach. And we have estimated the quality of them. The result of the examination was as follow. A rice cooked with alkaline ionic water had pale yellow color, and had good quality in polish, viscocity, taste, odour and retrogradation as compared with a rice cooked of piped tap water. In the case of a water kimchi, refreshing taste and other kinds of taste were good. Unpleasant taste and smell have decreased. Fresh colour of a Chinese cabbage were maintained long because of the prevention of destruction of chlorophyll. In the case of bean sprouts, sprouting rate was promoted up to 2∼3% during the period of 2∼3 days as compared with that treated with piped tap water And the growth state was good and the contents of vitamin C were high as compared with those with piped tap water. In the case of parboiling of green spinach, the alkaline ionic water helped keeping the chlorophyll of spinach. In the case of bean curd, soft taste, polish, smell and total taste were good. The Utility value of alkaline ionic water for the processing of soft bean curd was recognized by making it soften.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.311-312
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• 2001

암모니아는 무색의 기체이지만 자극성이 크면서 부식성이 있고 수용액이 알칼리성인 대표적인 악취물질이다. 보통의 경우는 굴뚝 등에서 배출가스의 형태로 대량 방출되기도 하지만 자연상태에서도 여러가지 생물학적 또는 화학적 반응 등을 통하여 생성되므로, 일상적인 생활 공간에서도 쉽게 검출될 수 있는 물질이다. 대기 중 암모니아의 농도는 기체상 시료를 직접 분석하는 가스 크로마토그래피와 시료를 액체상으로 변환시킨 후 암모늄 양이온의 농도를 분광광도법이나 중화적정법으로 측정한다. (중략)

• Journal of Bio-Environment Control
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• v.11 no.4
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• pp.188-192
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• 2002

High concentrations of HCO$_3$$^{[-10]}$ (bicarbonate ion) in hydroponic water lead to high pH and to change in solubility, and consequently inhibition of absorption of available iou. An adequate and practical method is needed to remove HCO$_3$$^{[-10]}$ in the water fur hydroponics. to compare the efficiency of HCO$_3$$^{[-10]}$ removal, the effect of injecting HNO$_3$, H$_3$PO$_4$ or H$_2$SO$_4$ was tested. Acid injection was effective to remove HCO$_3$$^{[-10]}$ Based on the assumption that an equivalent of HCO$_3$$^{[-10]}$ ion is neutralized by an equivalent of acid, KHCO$_3$ was dissolved in a double distilled water at 50, 100, 150, 200 or 250 mg.L$^{[-10]}$ concentration and either HNO$_3$, H$_3$PO$_4$ or H$_2$SO$_4$ was injected at a certain ratio, and the resulting pH change and HCO$_3$$^{[-10]}$ ion removal was measured. According to the results obtained, HCO$_3$$^{[-10]}$ in hydroponic water was titrated, and concentration of the residual HCO$_3$$^{[-10]}$ ion well correlated with the amount of acid injected.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.914-919
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• 2019

A mesocosm experiment considering water exchange was conducted to evaluate the change in the properties of contaminated coastal sediment. The contaminated coastal sediment sample was prepared by mixing with granulated coal ash(GCA), which is an alkaline industrial by-product. During one month of observation time, the phosphate concentration of the GCA sample case was measured to be 19.0 and 0.4 mg/L lower than that of the control sample at the pore water and overlying water, respectively. The hydrogen sulfide concentration of the GCA sample case was 5.0 mg/L, which is significantly lower than that of the control sample(112.5 mg/L). Further addition of GCA in the sediment reduced the concentrations of phosphate and hydrogen sulfide, and could enhance the adsorption reaction, when compared to the sediment without GCA. The dissolved oxygen concentration in the overlying water of the GCA sample was measured to be 3.47 mg/L higher than the control sample. From the above results, we confirmed that GCA is an effective material for reducing pollutants in coastal sediment.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.709-716
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• 2009

A Kinetics pathway of oxidation of Cefpodoxime Proxetil by permanganate in alkaline medium at a constant ionic strength has been studied spectrophotometrically. The reaction showed first order kinetics in permanganate ion concentration and an order less than unity in cefpodoxime acid and alkali concentrations. Increasing ionic strength of the medium increase the rate. The oxidation reaction proceeds via an alkali-permanganate species which forms a complex with cefpodoxime acid. The latter decomposes slowly, followed by a fast reaction between a free radical of cefpodoxime acid and another molecule of permanganate to give the products. Investigations of the reaction at different temperatures allowed the determination of activation parameters with respect to the slow step of proposed mechanism and fallows first order kinetics. The proposed mechanism and the derived rate laws are consistent with the observed kinetics.

• Nuclear Engineering and Technology
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• v.10 no.3
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• pp.153-163
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• 1978

The problems of solid waste disposal into the ground in connection with environmental aspects in the vicinity of a site would be very significant, though ground disposal for solid waste is safe and economical method. Studies of the waste-movement and migration of radionuclides (Sr-90 and Cs-137) for the disposal into the ground were performed under laboratory and field conditions. Affinity of the soils for radionuclide solution was higher than that in the acid solution. The sorption of radionuclides by the soils showed a time-dependent reation. The migration rates of radiostrontium and radiocesium were a range of 3.73$\times$10$^{-3}$ to 10.9$\times$10$^{-3}$ cm/day. The nuclides in the soil migrate much more slowly than the water, probably due to its high exchange capacity. The observed distribution of tritium was compared with that calculated by a mathematical model based on diffusivity. This study suggests that the tritiated water can be used to trace the movement of ground water.

• Ecology and Resilient Infrastructure
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• v.4 no.4
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• pp.193-199
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• 2017

In this study, changes of soil properties including soil texture, specific surface area, organic matter content, pH, cation exchange capacity and exchangeable cations content were investigated in response to strong acid or base accident. The properties changed significantly when the soil reacted with 10 M HCl or 1 M NaOH (i.e., when one gram of soil received 50 and 5 mmol of HCl or NaOH), respectively. When the soil reacted with 10 M HCl or 1 M NaOH solution, soil texture changed from sandy loam to loamy sand and specific surface areas decreased from $5.84m^2/g$ to 4.85 and $1.92m^2/g$, respectively. The soil organic matter content was reduced from 3.23% to 0.96 and 0.44%, and the soil pH changed from 5.05 to 2.35 and 10.65, respectively. The cation exchange capacity decreased from 10.27 cmol/kg to 4.52 and 5.60 cmol/kg, respectively. Especially, high concentrations of $Al^{3+}$ or $Na^+$ were observed in acidic or basic spills, respectively, which is likely to cause toxicity to terrestrial organisms. The results suggest that restoration of soil properties, as well as soil remediation, needs to be carried out to maintain the soil function in chemical spill sites.

• Journal of the Korean GEO-environmental Society
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• v.7 no.4
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• pp.35-41
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• 2006

This paper analyzed elution and ingredients of soil components which consist of soil and rocks in 6 regions in Yeongyang and Cheongsong to identify substantial matters that cause muddy water in Imha reservoir. We identified that more than 80% of major ingredients in collected soil and rocks are vermiculite(V), illite(I), kaolinite(Ka), quartz(Q), feldspar(F). Sodium and calcium are eluted in large quantities from soil of Sanseong and Cheongki. When calcium is in contact with water, much ions are eluted rapidly. We confirmed these ions are alkali minerals rising pH. We consider clay components distributed in Yeongyang as major cause of muddy water and rising pH of Imha reservoir because its ingredient calcite easily is dissolved in rainwater and splits other mineral particles into ${\mu}m$ sized particles.