• Title/Summary/Keyword: 알칼리계

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Dielectric and Piezoelectric Properties of Alkaline Lead-free Piezoceramic-epoxy Composites (알칼리계 무연 압전 세라믹과 에폭시 복합소재의 유전 및 압전 특성)

  • Yoon, Chang-Ho;Le, Duc Thang;Heo, Dae-Jun;Ahn, Kyoung-Kwan;Lee, Jae-Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.6
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    • pp.420-425
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    • 2012
  • Lead-free piezoelectric ceramic/epoxy composites with '0-3' connectivity were prepared by cold-pressing with a temperature controlled curing method. A ceramic powder with a composition of $(Na_{0.51}K_{0.47}Li_{0.02})(Nb_{0.8}Ta_{0.2})O_3$ was synthesized by a conventional solid state reaction route. The dielectric and piezoelectric properties of ceramic/epoxy composites were characterized as a function of the volume fraction (${\phi}$) of piezoelectric ceramics, which was varied from 70 to 95 vol%. The results indicated that the piezoelectric properties of composites were significantly affected by the volume fraction of ceramics. In terms of the piezoelectric properties, specimens showed the best performance at ${\phi}$= 85 vol%, resulting in the piezoelectric constant $d_{33}$ of 39 pC/N and the figure of merit as a piezoelectric energy harvester ($d_{33}{\cdot}g_{33}$) of 1.24 $pm^2/N$.

Regulation of Intracellular pH by SHC1 in Saccharomyces cerevisiae (효모에서 SHC1 유전자의 이온 농도 조절에 의한 세포내 pH 항상성 유지)

  • 하승길;전준철;최의열
    • Korean Journal of Microbiology
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    • v.38 no.3
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    • pp.168-172
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    • 2002
  • Budding yeasts maintain an effective system to regulate intracellular pH in response to environmental pH fluctuation. In a previous study we reported that SHC1 plays a role in cell growth at alkaline condition, not at acid pH. We constructed a null mutant deleted an entire open reading frame for SHC1. To test whether the retardation in cell growth was caused by the absence of intracellular pH buffering capacity, we measured intracellular pH with a pH-sensitive fluorescent dye, C.SNARE. The intracellular pH of the mutant cell was much higher than that of wild-type cells, indicating that the mutant cells lack some types of buffering capacity. We also investigated the level of $Na^+ and K^+$ content with atomic mass spectroscopy after alkali shock. Wild-type cell showed a higher level of intracellular K^+$ content, whereas there was no difference in $Na^+$ level. The result suggested that K^+$ is more important in the regulation of intracellular pH in yeasts.

Characteristics of Fixed Aerosol Auto Fire-Extinguishing Systems (고체에어로졸 자동소화장치 특성)

  • Choi, Byoung-O;Hong, Chang-Su;Kwon, Seong-Won;Park, Sun-Gyu
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.11a
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    • pp.277-282
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    • 2008
  • We developed fixed aerosol auto fire-extinguishing systems which are different from fire suppression systems like powder extinguisher or halon extinguishing system, etc. Fixed aerosol auto fire-extinguishing substances which are including solid alkali salts generated by combustion of solid composition. It represents high fire suppression ability due to particle friendly auto fire-extinguishing systems for the reason of excluding toxic substances in it's composition.

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Hydrolysis of Vinylsulfonyl Reactive Dyes (III) ―Formation of Mixed Dimers― (Vinylsulfone계 반응성 염료의 가수분해(III) ―혼합이량체의 형성―)

  • Kim, In Hoi
    • Textile Coloration and Finishing
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    • v.6 no.4
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    • pp.9-16
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    • 1994
  • 알칼리 수용액 중에서의 Vinylsulfone(VS)계 반응성염료의 혼합상태의 가수분해 반응을 정량적으로 조사하였다. 혼합이량체의 생성 및 분해반응 속도상수를 각각의 염료의 가수분해반응에서 구한 속도상수를 이용하여 계산하였다. 단독이량체를 생성하는 염료들을 조합하였을 경우에는 혼합이량체가 생성되었다. C.I.Reactive Blue 19가 다른 VS계 염료들과 혼합되었을 경우에는 일반적으로 혼합이량체가 생성되었다. Blue 19와 Orange 16의 조합의 경우에는 낮은 염료농도에서만 혼합이량체가 생성되었으며, Red 22의 경우에는 단독 및 혼합이량체가 생성되지 않았다. 단독이량체가 생성되지않는 Orange 7는 다른 VS계 염료들과의 조합에서 혼합이량체를 생성함을 확인하였다. Yellow 17의 혼합이량체의 분해속도 상수값이 가장 큼을 알 수 있었다.

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Degradation Propeties of Alkali-Activated Alumino-Silicate Composite Body Exposed to High Temperature (알칼리 활성화 알루미노실리케이트계 경화체의 고온 열화 특성)

  • Kim, Won-Ki;Kim, Hong-Joo;Lee, Seung-Heun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.627-630
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    • 2005
  • This paper examines degradation properties of alkali-activated alumino-silicate composite body by NAS solution exposed to high temperature. Activators include sodium hydroxides and sodium silicate solution. In the result of experiment, flexural and compressive strength of AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than alumina cement base mortar. Particularly, In case of compressive strength, alumina cement base mortar was decreased by about $60\~70\%$. While, AAS base mortar exposed to high temperature ($400\~600^{\circ}C$) was higher than that curing by room temperature. The above results showed that AAS base inorganic binder has a good mechanical properties exposed to high temperature($400\~600$).

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Study on the Strength Properties of Binary Blended Geopolymer Concrete (2성분계 지오폴리머 콘크리트의 강도특성에 관한 연구)

  • Lee, Seung-Hoon;Park, Min-Su;Kim, Young-Su
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.276-277
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    • 2014
  • Recently, carbon dioxide emissions have increased in succession according to the development of industry. also, cement of construction materials is being increased carbon dioxide during the manufacturing process. it is predicted that amount of carbon dioxide will be produced about 10 % in the world. as a way of solve this problem, it is used to reduce the amount of cement and to replace cement using industrial by-products such as blast furnace slag, fly ash, and red-mud. but, these are not advanced in our country. Thus, the purpose of this study is to analyze the strength property of binary blended geopolymer concrete. So, this study carries out the basic performance test of concrete such as, slump, air content and compressive strength.

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The study on characteristics of electrodeposited Rh in Sulfate solution (황산염 기반의 로듐 도금 특성 연구)

  • Jeong, Sang-Il;Im, Seong-Bong;Lee, Ju-Yeol;Jang, Do-Yeon;Jeong, Yong-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.140-140
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    • 2012
  • 로듐은 열전도성 및 전기전도도가 우수할 뿐 아니라 산/알칼리에 잘 부식되지 않으며 강한 내구성을 지니고 있어서 장식 및 액세서리의 표면처리 및 각종 전기/전자산업의 부품으로 널리 이용되어지고 있다. 본 연구에서는 반도체 검사 장비인 프로브 카드에 조립되어 있는 프로브 니들의 내마모성을 향상시키기 위하여 로듐도금의 특성을 연구하였다. 로듐의 이온 공급원으로 Rhodium sulfate 를 사용하였다. 시편은 황동 시편($0.5cm{\times}2cm$)을 사용하였다. 로듐 도금 시 여러 가지 제어인자 중도금욕의 온도(상온, $40^{\circ}C$, $60^{\circ}C$)와 황산농도(10ml/l, 50ml/l, 100ml/l) 그리고 전류밀도(0.2ASD, 0.5ASD, 1.0ASD)를 변수로 하여 실험을 하였다. 각각의 변수에 따라 전류 효율 및 전착 속도를 분석하였으며, 현미경을 이용하여 표면을 관찰하였다. 그리고 비커스 경도계를 이용하여 경도를 측정하였다.

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Durability of Hydrophilic Alkali Silicate Impregnant of Concrete Structure (알칼리 실리케이트계 침투성 콘크리트 표면보호재의 내구특성)

  • Song, Hun;Lee, Jong-Kyu;Chu, Yong-Sik;Kim, Young-Yup
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.91-94
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    • 2007
  • It is essential every concrete structure should continue to perform its intended functions, that is maintain its required strength and durability, during the service life. However, deterioration occurs more progressively from the outside of concrete exposed to severe conditions. Deterioration in the concrete structure is due to carbonation and chloride ion attack. Therefore, concrete structure is needed to surface protection for increase durability using impregnant. Impregnant classify into two large groups in polymeric and silicate materials. Silicate impregnant is included silane and alkali silicate(sodium and lithium silicate). Thus, this study is concerned with carbonation and chloride ion resistance of self cleaning hydrophilic impregnant of concrete structure using lithium and potassium silicate. From the experimental test result, lithium and potassium silicate have a good properties as a carbonation and chloride ion resistance. Lithium and potassium silicate make good use of hydrophilic impregnant.

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Conversion of Woody Biomass for Utilization(III) - The Preparation of Dissolving Pulp by Oxygen·Alkali Method from Exploded Wood - (목질계 Biomass의 변환 이용(III) - 폭쇄처리재의 산소·알칼리법에 의한 용해용 펄프의 제조 -)

  • Lim, Bu-Kug;Yang, Jae-Kyung;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.4
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    • pp.68-74
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    • 1997
  • This research was studied dissolving pulp for rayon production, which is not KP, SP methods but steam explosion and oxygen alkali treatment. The variation of characterization in wood cellulose after steam explosion and oxygen alkali treatment this follows. In the oxygen alkali treatment of exploded pine wood, yield of dissolving pulp was lower than steam-exploded oak wood, and we have obtained dissolving pulp that high purity cellulose, but degree of polymerization was inclined to decrease less than 200. In the case of steam-exploded oak wood, degree of polymerization was higher than steam-exploded pine wood but purity of cellulose was lower than its.

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Mechanical Properties of Granulated Ground Blast Furnace Slag on Blended Activator of Sulfate and Alkali (황산염 및 알칼리계의 혼합 활성화제에 대한 고로슬래그미분말의 역학적 특성)

  • Kim, Tae-Wan;Jun, Yu-Bin;Eom, Jang-Sub
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.104-111
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    • 2015
  • This study shows the mechanical properties of alkali-activated slag cement (AASC) synthesized using sulfate with NaOH solution. The used sulfates were calcium sulfate ($CaSO_4$, denoted CS) and sodium sulfate ($Na_2SO_4$, denoted SS). The replacement ratio of sulfates was 2.5, 5.0, 7.5 and 10.0% by weight of slag. NaOH solution of 2M and 4M concentration was used. A sample was activated with sulfate and activated with blended activator (blending NaOH solution with sulfate) respectively. 24 mix ratios were used and the water-binder weight ratio for the test was set 0.5. This research carried out the compressive strength, flexural strength, ultrasonic pulse velocity (UPV), absorption and X-ray diffraction (XRD). In the case of samples with CS, sample with 7.5% CS, sample with 2M NaOH+5.0% CS and sample with 4M NaOH+5.0% CS showed the good performance in the strength development. In the case of samples with SS, sample with 10.0% SS, sample with 2M NaOH+7.5% SS and sample with 4M NaOH+2.5% SS obtained good performance in strength. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of samples indicated that the hydration products formed in samples were ettringite, CSH and silicate phases. In this study, it is indicated that when compared to the use of sulfate only, the use of both sulfate and NaOH solution makes mechanical properties of AASC better.