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Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Evaluation of Indoor Mold Exposure Level in dwelling Using DNA-Based Mold Assessment Method (DNA 기반 곰팡이 평가기법을 활용한 주택의 실내 곰팡이 노출수준 평가)

  • Hwang, Eun-Seol;Seo, Sung Chul;Lee, Ju-Yeong;Ryu, Jung-min;Kwon, Myung-Hee;Chung, Hyen-Mi;Cho, Yong-Min;Lee, Jung-Sub
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.4
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    • pp.382-392
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    • 2018
  • Objective: Allergic diseases such as asthma due to fungal exposure in houses have increased, and proper management is urgent. Mold can grow in the air, floor, walls, and other areas according to environmental conditions, and there are many limitations to the conventional methodology for examining fungal exposure. For this reason, the degree of fungal contamination is being evaluated by ERMI (Environmental Relative Moldiness Index), a quantitative analysis method proposed by the EPA. In this study, we compared ERMI values between water-damaged dwellings and non-damaged ones to evaluate the effectiveness of Korean ERMI values. We also explored the association of ERMI values with the level of airborne mold and characteristics of dwellings. Methods: Floor dust was collected after installing a Dustream collector on the suction port of a vacuum cleaner. The collected samples were filtered to remove only 5 mg of dust, and DNA was extracted using the FastDNA SPIN KIT protocol. Results: The ERMI values were found to be 19.6 (-6.9-58.8) for flooded houses, 7.5 (-29.2-48.3) for leaks/condensation, and 0.8 (-29.2-37.9) for non-damaged dwellings. The airborne concentration of mold for flooded, leakage or condensed, and non-damaged houses were $684CFU/m^3$, $566CFU/m^3$, and $378CFU/m^3$, respectively. The correlation between ERMI values and the levels of airborne mold was low (R = 0.038), but a weakly significant association of the ERMI values with the concentration of particulate matter ($PM_{10}$) was observed as well(R=0.231,P<0.05). Conclusions: Our findings show that the reference value using ERMI can be used to distinguish water-damaged and non-damaged dwellings. It is believed that ERMI values could be a promising tool for assessing long-term fungal exposure in dwellings.

Preliminary Evaluation of Domestic Applicability of Deep Borehole Disposal System (심부시추공 처분시스템의 국내적용 가능성 예비 평가)

  • Lee, Jongyoul;Lee, Minsoo;Choi, Heuijoo;Kim, Kyungsu;Cho, Dongkeun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.491-505
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    • 2018
  • As an alternative to deep geological disposal technology, which is considered as a reference concept, the domestic applicability of deep borehole disposal technology for high level radioactive waste, including spent fuel, has been preliminarily evaluated. Usually, the environment of deep borehole disposal, at a depth of 3 to 5 km, has more stable geological and geo-hydrological conditions. For this purpose, the characteristics of rock distribution in the domestic area were analyzed and drilling and investigation technologies for deep boreholes with large diameter were evaluated. Based on the results of these analyses, design criteria and requirements for the deep borehole disposal system were reviewed, and preliminary reference concept for a deep borehole disposal system, including disposal container and sealing system meeting the criteria and requirements, was developed. Subsequently, various performance assessments, including thermal stability analysis of the system and simulation of the disposal process, were performed in a 3D graphic disposal environment. With these analysis results, the preliminary evaluation of the domestic applicability of the deep borehole disposal system was performed from various points of view. In summary, due to disposal depth and simplicity, the deep borehole disposal system should bring many safety and economic benefits. However, to reduce uncertainty and to obtain the assent of the regulatory authority, an in-situ demonstration of this technology should be carried out. The current results can be used as input to establish a national high-level radioactive waste management policy. In addition, they may be provided as basic information necessary for stakeholders interested in deep borehole disposal technology.

Precise Deterioration Diagnosis and Restoration Stone Suggestion of Jungdong and Banjukdong Stone Aquariums in Gongju, Korea (공주 중동 및 반죽동 석조의 정밀 손상도 진단과 복원석재 제안)

  • Jo, Young Hoon;Lee, Myeong Seong;Choi, Gi Eun;Lee, Chan Hee
    • Korean Journal of Heritage: History & Science
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    • v.44 no.3
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    • pp.92-111
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    • 2011
  • This study focus on the restoration stone selection of break-out part based on material characteristics analysis and the conservational safety diagnosis using various nondestructive techniques for Jungdong and Banjukdong Stone Auariums. As a result, the original rocks of the stone aquariums body are porphyritic granodiorite with magnetite-series having igneous lineation, microcline phenocryst, veinlet and basic xenolith. As a result of the provenance presumption of the host rock, a rock around Gamgokri area in Nonsan City was identified the genetically same rock. Therefore, the rock is appropriate for restoration materials of the break-out part. The deterioration assessment showed that the stone aquariums were highly serious scaling, scale off and blackening. Particularly, the front face of Banjukdong stone aquarium needs reinforcement of structural crack (760mm) caused from igneous lineation of biotite. Blackening contaminants on the stone aquariums surface occurred by combining iron oxide, manganese oxide and clay mineral. Also, major factors of efflorescence contaminants were identified as calcite (Jungdong stone aquariums) and gypsum (Banjukdong stone aquariums). The physical characteristics of stone aquariums appeared that the original and new stone is third (moderately weathered) and second grade (slightly weathered), respectively. This study sets up an integrated conservation system from material analysis to restoration stone selection and conservational safety diagnosis of Jungdong and Banjukdong stone aquariums.

The Design of the Obstacle Avoidances System for Unmanned Vehicle Using a Depth Camera (깊이 카메라를 이용한 무인이동체의 장애물 회피 시스템 설계)

  • Kim, Min-Joon;Jang, Jong-Wook
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2016.10a
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    • pp.224-226
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    • 2016
  • With the technical development and rapid increase of private demand, the new market for unmanned vehicle combined with the characteristics of 'unmanned automation' and 'vehicle' is rapidly growing. Even though the pilot driving is currently allowed in some countries, there is no country that has institutionalized the formal driving of self-driving cars. In case of the existing vehicles, safety incidents are frequently happening due to the frequent malfunction of the rear sensor, blind spot of the rear camera, or drivers' carelessness. Once such minor flaws are complemented, the relevant regulations for the commercialization of self-driving car and small drone could be relieved. Contrary to the ultrasonic and laser sensors used for the existing vehicles, this paper aims to attempt the distance measurement by using the depth sensor. A depth camera calculates the distance data based on the TOF method calculating the time difference by lighting laser or infrared light onto an object or area and then receiving the beam coming back. As this camera can obtain the depth data in the pixel unit of CCD camera, it can be used for collecting depth data in real-time. This paper suggests to solve problems mentioned above by using depth data in real-time and also to design the obstacle avoidance system through distance measurement.

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Analysis of Automotive HMI Characteristics through On-road Driving Research (실차 주행 연구를 통한 차량별 HMI 특성 분석)

  • Oh, Kwangmyung
    • Journal of the HCI Society of Korea
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    • v.14 no.2
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    • pp.49-60
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    • 2019
  • With the appearance of self-driving cars and electric cars, the automobile industry is rapidly changing. In the midst of these changes, HMI studies are becoming more important as to how the driver obtains safety and convenience with controlling the vehicle. This study sought to understand how automobile manufacturers understand the driving situation, and how they define and limit driver interaction. For this, prior studies about HMI were reviewed and 15 participants performed an on-road study to drive vehicles from five manufacturers with using their interfaces. The results of the study confirmed that buttons and switches that are easily controlled by the user while driving were different from manufacturer to manufacturer. And there are some buttons that are more intensively controlled and others that are difficult to control while driving. It was able to derive 'selection and concentration' from Audi's vehicle, 'optimization of the driving ' from BMW's, 'simple and minimize' from Benz's vehicle, 'remove the manual distraction' from the vehicle of Lexus, and 'visual stability' from KIA's vehicle as the distinctive keywords for the HMI. This shows that each manufacturer has a different definition and interpretation of the driver's driving control area. This study has a distinct value in that it has identified the characteristics of vehicle-specific HMI in actual driving conditions, which is not apparent in appearance. It is expected that this research approach can be useful to see differences in interaction through actual driving despite changes in driving environment such as vehicle platooning and self-driving technology.

Numerical Study on Towing Stability of LNG Bunkering Barge in Calm Water (LNG 벙커링 바지의 정수 중 예인안정성에 관한 수치연구)

  • Oh, Seung-Hoon;Jung, Dong-Ho;Jung, Jae-Hwan;Hwang, Sung-Chul;Cho, Seok-Kyu;Sung, Hong-Gun
    • Journal of Navigation and Port Research
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    • v.43 no.3
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    • pp.143-152
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    • 2019
  • In this paper, the towing stability of the LNG bunker barge was estimated. Currently, LNG bunkering barge is being developed for the bunkering of LNG (Liquefied Natural Gas), an eco-friendly energy source. Since the LNG bunkering barge assumes the form of a towed ship connected to the tow line, the towing stability of the LNG bunker barge is crucial f not only for the safety of the LNG bunker barge but also the neighboring sailing vessels. In the initial stages, a numerical code for towing simulation was developed to estimate the towing stability of the LNG bunkering barge. The MMG (Maneuvering Mathematical modeling Group) model was applied to the equations of motion while the empirical formula was applied to the maneuvering coefficients for use in the initial design stage. To validate the developed numerical code, it was compared with published calculation and model test results. Towing simulations were done based on the changing skeg area and the towing position of the LNG bunkering barge using the developed numerical codes. As a result, the suitability of the designed stern skeg area was confirmed.

Recent Progress and Perspectives of Solid Electrolytes for Lithium Rechargeable Batteries (리튬이차전지용 고체 전해질의 최근 진전과 전망)

  • Kim, Jumi;Oh, Jimin;Kim, Ju Young;Lee, Young-Gi;Kim, Kwang Man
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.87-103
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    • 2019
  • Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

The Study on Removing Paraloid B-72 from Painting Layer on Mural of Mireukjeon Hall at Geunsansa Temple (금산사 미륵전 벽화 채색층의 Paraloid b-72 제거방법과 안정성에 관한 연구)

  • Jin, Byung-Hyuk;Cho, Jae-Yeon;Park, Jin-Yeon;Han, Sung-Hee;Kim, Yong-Sun
    • Korean Journal of Heritage: History & Science
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    • v.50 no.3
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    • pp.88-109
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    • 2017
  • As the technique to remove Paraloid B-72, which is known as an irreversible material, the method using organic solvent and heating, though the ways vary depending on the kind of material to be removed, has been usually used, but it has yet to apply to mud mural because of the technical limit in processing and the potential risk of damage and, moreover, the removal efficiency which also remains unproven. Thus, in a bid to seek the way to safely remove Paraloid B-72 contained in mural, the test was conducted in a way of applying a compress method, which is deemed most efficient. The solvents which are proven to be Paraloid B-72 were applied to the absorbents such as active carbon fiber and methyl cellulose and then were eluted to the surface of mud mural sample which was prepared in the same size and condition for a certain time before evaluating the stability and removal efficiency. Such test was intended to identify the applicability to the mural of Mireukjeon Hall at Geunsansa Temple, which had been treated with Paraloid B-72 for preservation in the past. As a result, the way of mixing the absorbent such as active carbon fiber and Xylene alone or with other quick vaporable solvents proved to be most efficient in removing Paraloid B-72 from mud mural and particularly Acetone:Xylene(1:1wt%) was found to be the most stable among others. Such a test outcome is expected to be a useful data for removing Paraloid B-72 from the mural of Mireukjeon Hall at Geunsansa Temple as well as for restoring other mural cultural assets in the coming days.

Design and development of clear aligner management system using QR code (QR 코드를 활용한 투명 교정장치 관리 시스템 설계 및 개발)

  • Jang, Jin-Su;Son, Ho-Jung;Sim, Ji-Young;Kang, Sin-Yeong;Moon, Jun-Mo;Lee, Tae-Ro
    • Journal of Digital Convergence
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    • v.17 no.9
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    • pp.185-192
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    • 2019
  • The introduction of smart technology provides accuracy, safety, and efficiency to both physicians and patients. Although interest in a clear aligner is increasing among users worldwide, the current clear aligner requires a visit to the hospital every one or two weeks for replacement, which is a very cumbersome process. There is also confusion among dentists and patients because about 40 to 80 devices are made, and calibration is done based on the order and duration of the clear aligner. Therefore, this study designed and developed a clear aligner management system so that communication between the patient and dentist can be smoothly performed by inserting the QR code into the transparent correction device. As a result, the size of the QR code was recognized as $6{\ast}6mm^2$ which can be used in the oral and the recognition distance was 100% within 12 cm. Since the dentist can remotely manage the patient with the proposed system and improve the correction effect, it is possible to manage patients abroad, as well as domestically.