• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.281-286
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• 2009

Bitumen extraction and sulfur removal from Athabasca oil sand were conducted using water in sub- and supercritical condition. Bitumen yield in micro reactor was investigated in the pressure range of 15~30 MPa, the temperature of 360 and $380^{\circ}C$ and water density $0.074{\sim}0.61g/cm^3$ for 0~120 min. Bitumen yield increased with reaction pressure irrespective of temperature and dramatically increased in especially supercritical region due to hydrogen formed from water gas shift reaction. Total amount of gas product decreased with reaction pressure but the portion of sulfur and hydrogen increased a little with increasing pressure to 25 and 30 MPa. It is seen that supercritical condition was favourable to the hydrogen formation and sulfur removal. Bitumen yield and sulfur removal from original oil sand reached a maximum 22% and 40% respectively in supercritical condition(the reaction time of 60 min at $380^{\circ}C$ and 25 or 30 MPa).

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.31 no.7
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• pp.85-93
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• 2003

Droplet vaporization at various ambient pressures is studied numerically by formulating one dimensional evaporation model in the mixture of hydrocarbon fuel and air. The ambient pressure ranged from atmospheric conditions to the supercritical conditions. The modified Soave-Redlich-Kwong state equation is used to account for the real gas effects in the high pressure condition. Non-ideal thermodynamic and transport properties at near critical and supercritical conditions are considered. Some computational results are compared with Sato's experimental data for the validation of calculations. The comparison between predictions and experiments showed quite a good agreement. The droplet lifetime increases with increasing pressure at temperature lower than the critical temperature, however, it decreases with increasing pressure at temperature higher than the critical temperature. The solubility of nitrogen can not be neglected in the high pressure and it becomes higher as the temperature and the pressure go up.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.678-683
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• 2012

Ceria is one of the most important catalytic materials which can be used in three-way catalysts, waste water treatment, petroleum refining, etc. So far, many methods have been studied to produce ceria nanoparticles. In this study, ceria nanoparticles were prepared via solvothermal synthesis using supercritical methanol in short reaction time using a batch reactor. The size of synthesized ceria nanoparticles in supercritical methanol is 6 nm without capping agent, which is smaller than that made in supercritical water at the same conditions of $400^{\circ}C$ and 30 MPa. Size difference results from density and critical point difference between water and methanol and slow reaction rate at the surface of ceria particles in supercritical methanol which reduces crystal growth rate. Several organic compounds were added to modify the surface of ceria nanoparticles, and in-situ surface modification was confirmed by FT-IR and TGA analysis. Surface modified ceria nanoparticles have excellent dispersibility in organic solvent. Size and shape of surface modified ceria particles can be controlled by adjusting molar ratio of modifier to precursor and selection of modifier.

• Elastomers and Composites
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• v.34 no.3
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• pp.239-246
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• 1999

Side wall samples from a used automotive tire were subjected to subcritical and supercritical decomposition and extraction with three solvents, water, 28% ammonia solution and ammonia. For 6mm cube samples the rate of supercritical extraction with water followed a first-order kinetics with an activation energy of 140 kJ/mol. Solvent power of 28% ammonia so lotion at supercritical condition was found to be higher than supercritical water at initial extraction as pressure decreased. These phenomena were considered to be an effect of ammonia involved in water.

• Applied Chemistry for Engineering
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• v.16 no.1
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• pp.28-33
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• 2005

A resource recovery technique using sub- and supercritical water hydrolysis was applied to recover amino aicds from waste fish entrails. The effect of reaction parameters such as temperature and time necessary for the control of reaction towards optimum yield of amino acids was investigated using semi-batch and batch reactors. Results showed a maximum yield of total amino acids (137 mg/g-dry entrails) from waste fish entrails at T=$250^{\circ}C$ (P=4 MPa) and reaction time of 60 min in a batch reactor. Under supercritical conditions (e.g., T=$400^{\circ}C$, P=45 MPa), the yield decreased due to rapid decomposition compared to production rate of amino acids. As a result, the low temperature and the short reaction time were needed to produce a maximum yield of amino acids.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.11
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• pp.699-707
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• 2017

This study presents a comparative thermodynamic analysis of subcritical and transcritical organic Rankine cycles for the recovery of low-temperature heat sources considering nine substances as the working fluids. The effects of the turbine inlet pressure, source temperature, and working fluid on system performance were all investigated with respect to metrics such as the temperature distribution of the fluids and pinch point in the heat exchanger, mass flow rate, and net power production, as well as the thermal efficiency. Results show that as the turbine inlet pressure increases from the subcritical to the supercritical range, the mismatch between hot and cold streams in the heat exchanger decreases, and the net power production and thermal efficiency increase; however, the turbine size per unit power production decreases.

• KSBB Journal
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• v.19 no.6 s.89
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• pp.421-426
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• 2004

The extraction and separation of isoflavones from Korean soybean were peformed by various mechanical and chemical extraction methods. They included solvent extraction, stirring, supersonification and sub/supercritical water extraction. From the experimental results of the variation of solvent extraction by change in composition, the increase in extraction of a specific compound by stirring or supersonic energy, and the application of supercritical fluid with superior solvating power over solvents, the sonification was the most desirable extraction method in extracting aglycone isoflavones, daidzein and genistein from Korean soybean.

• Clean Technology
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• v.13 no.1 s.36
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• pp.46-53
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• 2007

We depolymerized PET in supercritical methanol and observed the yield of DMT at various reaction conditions. At subcritical state below $240^{\circ}C$, the yield of DMT was very low, about only 50%. It increased dramatically to 80% at supercritical state above $260^{\circ}C$, thereafter the increasing rate was reduced significantly. Similarly, at subcritical state of 6.89 MPa, the DMT yield was only 50%, but it increased abruptly to 85% at supercritical state of 10.34 MPa, yielding no further increase above the pressure. Within 10 minutes after the beginning of the reaction, the DMT yield reached 80%, indicating that the significant portion of the reaction has proceeded, and then, the yield increased slowly. The methanol/PET ratio of 8 showed the maximum DMT yield. We found the optimum depolymerization condition fur PET methanolysis is temperature $300^{\circ}C$, pressure 10.34 MPa, reaction time 40 minutes, and methanol/PET ratio of 8.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.3
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• pp.277-284
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• 1986

A numerical procedure (integral method) for calculating the interacting turbulent boundary layer is set up. With this method, some free interactions with various upstream conditions are simulated in order to investigate the influence of upstream state on the interacting turbulent boundary layer. The results obtained by this numerical simulation can be summarized as follows; Free interaction of upstream unstabilized (or separated) turbulent boundary layer is subcritical regardless of its external Mach number, while free interaction of upstream stabilized turbulent boundary layer has two different characteristics (subcritical, supercritical) according to the external Mach number.

• Journal of Power System Engineering
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• v.5 no.1
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• pp.11-20
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• 2001

Super-critical type steam power plant, which operates with steam pressure above the super-critical point, has a good reputation recently and is adopted as a new standard of the Korean Electric Power Corporation. The reason for the good reputation lies in it's superior power efficiency. However, the field data of the new power plant for the verification of it's performance are still insufficient, and more empirical data are needed to acquire technologies on the effective operation of it. In this study, the authors analyzed the field test data on power efficiencies got in a super-critical type steam power plant, and evaluated the excellency of the new plant by comparing the efficiency data with the one got in a conventional sub-critical type steam power plant.