• Title/Summary/Keyword: 쌍극자

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이중 전자주입층을 사용한 유기발광소자의 계면쌍극자 효과에 의한 전자주입 효율 향상 메커니즘

  • Hwang, Jeong-Hyeon;Chu, Dong-Cheol;Kim, Tae-Hwan;Seo, Ji-Hyeon;Kim, Yeong-Gwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.121-121
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    • 2010
  • 유기발광소자의 발광 효율을 향상하기 위해 발광층에서 전자와 정공의 효율적인 재결합이 중요하기 때문에 발광층에서 재결합 확률을 높이기 위한 전하의 효율적인 주입과 전송에 대한 연구가 많이 진행되고 있다. 본 연구에서는 전자주입효율을 향상하기 위하여 강한 전자 받게 역할을 하는 플러렌 (C60)과 무기물 절연층인 cesium flouride (CsF) 층을 조합한 무기물 이중 전자주입층을 삽입한 녹색 유기발광소자를 제작하였고, 녹색 유기 발광 소자에 사용하여 발광효율의 변화를 관찰하였다. 큰 쌍극자 모멘트를 갖는 CsF 층은 전기전도성이 좋은 C60 층과 Al 층 사이에 삽입되어 전자의 주입장벽을 낮추어 전자주입 효율을 향상하는 역할을 한다. C60만으로 이루어진 단층 전자 주입층으로 구성된 유기발광 소자는 Al 음극전극과 C60 계면사이에 거칠기가 크기 때문에 누설전류의 크기가 커지며 Al 과 플러렌 C60 의 공유결합 형성으로 인해 전자의 주입이 오히려 저하되는 현상을 보였다. 무기물 절연층인 CsF 층을 C60 과 Al 사이에 삽입한 유기발광소자에서 C60 층은 Cs 원자가 유기물층 내부로 확산되는 것을 감소하였다. 매우 얇은 CsF층을 Al층과 C60층 사이에 삽입함으로써 C60과 Al 사이의 공유결합을 없애고 누설전류를 줄이고 전자주입장벽을 낮추어 전자주입효율이 향상하였다. 전자주입 향상으로 인해 발광층 내에서 전자와 정공간의 비율이 개선되어 유기발광 소자의 발광효율도 증가되고 색안정성이 향상되는 것을 관찰할 수 있었다.

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Frture mapping and deep-seated ground water exploration in the crystalline rocks by integrated geophysical techniques (종합적 물리탐사에 의한 파쇄대 및 심부 지하수 탐사)

  • 정승환;김정호;조인기;전정수
    • The Journal of Engineering Geology
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    • v.2 no.2
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    • pp.113-130
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    • 1992
  • Groundwater in crystalline basement is controlled primarily by tectonic fractures. It is evident that the delineation of the heavily faulted area and/or fractures deeply developped should be considerable value in deep-seated low enthalphy geothermal water. Electrical and electromagnetic methods have effectively been employed to map hydraulic faults and shear zones for groundwater exploration. In this study VLi; dipoledipole resistivity, controlled source audio~frequency magneto-telluric(CSAMT) and magnetic methods were applied in the Bomun resort area, adjacent to Kyongju city, southeastern part of Korea. The integrated geophysical tools employed in this experiment can be manifested themselves as: 1. Magnetic high for granite intrusions which is more favorable for geothermal gradient increase in depth. 2. VLF cross-over trends for mapping linear shallow conductive fractures and shear zones. 3. Dipole-dipole resistivity distributions for the deep-seated(less than 500m in depth) fractures and shear zones. The dipole-dipole resistivity field data were inverted to the true resistivity distribution with two-dimensional automatic inversion program based on the finite-difference method. 4. CSAMT provides an efficient way of delineating fractures and fault zones if the depth is greater than about 500m.

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Magnetic Field Inversion and Intra-Inversion Filtering using Edge-Adaptive, Gapped Gradient-Nulling Filters: Applications to Surveys for Unexploded Ordnance (UXO)

  • Rene, R.M.;Kim, K.Y.;Park, C.H.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.9-14
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    • 2006
  • Estimations of depth, magnetic orientation, and strength of dipole moments aid discrimination between unexploded ordnance (UXO) and non-UXO using magnetic surveys. Such estimations may be hindered by geologic noise, magnetic clutter, and overlapping tails of nearby dipole fields. An improved method of inversion for anomalies of single or multiple dipoles with arbitrary polarization was developed to include intra-inversion filtering and estimation of background field gradients. Data interpolated to grids are flagged so that only nodes nearest to measurement stations are used. To apply intra-inversion filtering to such data requires a gapped filter. Moreover, for data with significant gaps in coverage, or along the edges or corners of survey areas, intra-inversion filters must be appropriately modified. To that end, edge-adaptive and gapped gradient-nulling filters have been designed and tested. Applications are shown for magnetic field data from Chongcho Lake, Sokcho, Korea and the U. S. Army's Aberdeen Proving Ground in Maryland.

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시아노에틸화한 폴리비닐알콜의 표면사이징에 따른 종이의 유전적 성질 향상

  • 서만석;이학래
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.04a
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    • pp.89-89
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    • 2001
  • 종이는 목재섬유와 물의 현탁액을 스크련을 통해 균일하게 분산시킨 판상섬유 제품 으로서 가격이 저렴하고, 열, 전기절연성, 필터기능, 난연성 및 폐기성이 우수하여 다양한 분 야에서 활용되고 있다. 특히 최근에는 종이의 고부가가치화, 차별화를 위하여 내열성, 전기 절연성, 내수성, 기계적 특성, 내약품성, 생체적응성을 지닌 다양한 기능지가 개발되어 식품, 전기, 전자, 건축, 화학, 의료 관련 산업에 있어서 주요 재료로 이용되고 있다. 특히 전기, 전 자산업 발전과 더불어 전기절연성이 우수한 종이의 역할과 수요는 크게 증대되고 있으며 산 업발전의 핵심적인 제품으로서 자리매김을 하고 있다. 하지만 국내의 경우 전기절연지와 관 련된 제품 및 생산기술 부족으로 전량을 수입에 의존하고 있는 실정이며, 그 수입량은 앞으 로 전기 및 전자 산업의 발전으로 인해 더욱 증가할 것으로 예상된다. 이러한 수입의존성을 극복하기 위해서는 전기절연지와 관련된 제품개발 및 생산기술에 관한 연구가 시급히 요청 되고 있다. 이러한 기술의 국산화는 수입 대체 효과 뿐만 아니라 관련 산업의 발전에도 기 여할 수 있을 것으로 예상되며 수출산업으로 성장할 수 있을 것으로 예상된다. 종이의 전기적 성질은 유전상수, 유전손실율과 같은 유전적 특성과 전기저항, 절연 파괴강도의 기계적 특성으로 구분할 수 있다. 종이의 전기적 성질 가운데 유전율은 전기장 에 대한 종이의 물리화학적인 반응으로 일반적으로 종이의 밀도와 종이를 구성하는 성분의 쌍극자 모멘트에 비례하며 온도에 따라서도 변화한다. 일반적으로 온도가 상승하면 열에너 지를 얻게된 쌍극자가 전기장에 배열됨으로써 유전율이 상승하지만 온도가 유리전이점 이상 으로 높아질 경우 열적 교란에 의해서 분극 능력이 감소하게 되어 유전완화 현상이 나타난 다. 전기절연지로 사용될 종이의 절연특성을 이해하기 위해서는 사용환경에 따른 유전적 특 성 및 tan$\delta$에 관한 연구가 펼요하다. 본 연구에서는 종이의 유전특성을 개선하기 위해서 펼름형성능력이 우수한 polyvinyl alcoholCPV A)과 aery lonitrile을 이용하여 시아노에틸화한 P PYA의 표면처리에 따른 종이의 유전적 특성의 변화를 검토하였다. 그 결과 PYA에 도입된 시아노에틸기에 의해 유전율을 증가시킬 수 있음을 확인하였다. 또 본 연구에 적용된 시험 범위에서는 온도상승에 따라 유전율이 상승하였다.

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Study on Availability about the Dielectric Constant of SiOC Thin Film (SiOC 박막의 허용 가능한 유전상수 설정에 대한 연구)

  • Oh, Teresa
    • Journal of the Korean Vacuum Society
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    • v.19 no.5
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    • pp.347-352
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    • 2010
  • To research the reduction of the dielectric constant depending on the ionic and electronic effects, the dielectric constant of SiOC film was obtained by C-V measurement using the structure of metal/SiOC film/Si, and $n^2$ calculated by the refractive index. The dielectric constant of SiOC film consists with dipole, ions and electrons. However, the dipole moment is ignored in the effect of dielectric constant in SiOC film. THe SiOC film was deposited by the plasma energy, and the gas precursor was dissociated and recombined. Therefore, the dielectric constant of the deposited film consisted of the polarity with ions. THe dielectric constant decreased after annealing process, because of the evaporation of OH hydroxyl group with polarity. The ideal SiOC film as low-k materials was annealed film with lowering the polarity, which is suitable for physical-chemical and electrical properties as an inter layer dielectric materials.

Resistivity Tomography in an Inclined Borehole to Surface Purvey Using a Pole-dipole Array (단극-쌍극자 배열을 이용한 경사시추공-지표 탐사에서 전기비저항 토모그래피)

  • Park Jong-Oh;Kim Hee-Joon;Park Chung-Hwa
    • The Journal of Engineering Geology
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    • v.16 no.3 s.49
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    • pp.255-263
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    • 2006
  • In an electrical tomographic survey using an inclined borehole with a pole-dipole array, we must consider several factors: a singular point associated with zero potential difference, a spatial discrepancy between electrode and nodal point in a model due to a inclined borehole, and a variation of geometric factors in connection with a irregular topography. Singular points which are represented by the normal distance from current source to the ground surface can be represented by serveral regions due to a irregular topography of ground surface. The method of element division can be applied to the region in which the borehole is curved, inclined or the distance between the electrodes is shorter than that of nodal points, because the coordinate of each electrode cannot be assigned directly to the nodal point if several electrodes are in an element. Test on a three-dimensional (3-D) synthetic model produces good images of conductive target and shoves stable convergence.

Dipole-Dipole Resistivity Survey on the Side of Han River near Nanjido Landfill (난지도에 인접한 한강변에서의 쌍극자-쌍극자 전기탐사)

  • Lee, Kiehwa;Kwon, Byung-Doo;Oh, Seok-Hoon;Kim, Cha-Seop
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.335-343
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    • 1996
  • The dipole-dipol electrical resistivity survey was conducted to investigate the probable contamination of the Han river by leachate from the near-by Nanjido Landfill. The survey line of 3 km was set along the unpaved road toward the Han river. For the convenience of the field work, the survey line was divided into four segments. The complete two-dimensional resistivity section was constructed by connecting the inversion result of each segment. Gravity survey was also carried out along the profile parallel to the resistivity line. Near surface resistivity generally appeared to be of very low value in most part of the survey area and the boundary between the alluvium layer and underlying basement rocks is well discriminated on the resistivity section. These results agree well with those of the preceding Schlumberger depth sounding made at adjacent area by Lee and fun (1995). The variation of thickness of the alluvium layer delineated by gravity anomaly profile also correlates well with the result of the resistivity survey on the qualitative basis. The problem of contamination by leachate from the Nanjido Landfill, where various waste materials have been dumped without any proper treatment facilities, has been remains unsolved yet. Therefore, we present the most probable passages of leachate flow based on the survey results and have briefly discussed about measure for contamination control. Considering the thickness of alluvium and the possible existence of fractured zone, the middle point between 1st and 2nd landfill and the midst of 1st landfill are the most hazardous regions to make leachates flow into the Han river. Since large amounts of leachates are observed from the test wells located on the lines extending from the border between the 1st and 2nd landfill and the middle of the lst landfill, contamination protection barriers are strongly recommended near these regions.

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Magnetic Field Dependence of the Activation Volume for Sr-ferrite Particles (Sr-페라이트 자성 입자의 활성화 부피의 자기장 의존성)

  • Kim, Hyeon Soo;Jeong, Soon Young;Kim, Kyung Min;Kwon, Hae-Woong
    • Journal of the Korean Magnetics Society
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    • v.26 no.6
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    • pp.196-200
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    • 2016
  • In this study the mechanisms of magnetization reversal and magnetic interaction effects on activation volumes for Sr-ferrite with different particle sizes are investigated. The activation volumes of C2 sample are larger than those of C3 sample in the range of low magnetic fields. But the fields above the coercivity of sample C2, the activation volumes of both samples are decreased linearly with increasing the applied magnetic field. These phenomena can be explained by the strengths of two critical fields representing the reverse domain nucleation field and the domain wall pinning field as well as the strength of dipolar interaction.

Ab Initio Studies on Hydrogen-Bonded Trimers Formed between Hydrogen Cyanide and Hydrogen Fluorides (시안화수소와 플루오르화수소와의 수소결합 삼합체들에 관한 Ab Initio 연구)

  • Rhee, Soon Ki;Lee, Hyun Jin
    • Journal of the Korean Chemical Society
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    • v.40 no.3
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    • pp.187-195
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    • 1996
  • Ab initio SCF calculations have been carried out for the five conceivable trimers formed between one hydrogen cyanide and two hydrogen fluorides using a basis set of TZ+P quality. Several ground state properties of these trimeric complexes have been evaluated, and compared with those of isolated monomers and appropriate dimers. Computed equilibrium geometries, stabilization energies, and dipole moments are given in order to suppliment the available experimental data. At this level of approximation, intramolecular bond distances are consistently shorter than experimental ones. However, intermolecular distances upon complex formation, and dipole moments are overestimated compared with experimental ones. HCN$(HF)_2$ trimer appears to be the most favourable among the five kinds of trimer complex, and also more stable than $(HCN)_2HF$. The typical features of the non-additivity of intermolecular interaction are relatively strong in the HCN$(HF)_2$ trimer.

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Electrical Resistivity Surveys in Yangsan Fault Area near Kyongju (경주 부근 양산단층 지역에서의 전기비저항 탐사)

  • Lee, Gi Hwa;Han, Won Seok
    • Journal of the Korean Geophysical Society
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    • v.2 no.4
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    • pp.259-268
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    • 1999
  • Electrical resistivity surveys were conducted in the areas between Buji-ri and Seoak-dong, and between Nawon-ri and Yangdong-ri, Kyongju in order to investigate the geoelectric structure of the nothren part of the Yangsan Fault. In the area between Buji-ri and Seoak-dong south of Kyongju, the fracture zone east of the inferred fault develops more deeply, without significant north-south variation in depth, than west. In the area between Nawon-ri and Yangdong-ri north of Kyongju, the fault zone seems to be developed along the Hyungsan-river, and the resistivity structure west of the river is more affected by the fracture zone than east. Interpreted section of dipole-dipole survey conducted in Homyung-ri shows vertical contact of the Yangsan Fault. It appears that the boundary between the northern and central segment of the Yangsan Fault is located in the north of study areas since there is no significant variation in electrical resistivity structure near Kyongju.

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