• Title/Summary/Keyword: 시차열분석

Search Result 223, Processing Time 0.031 seconds

The Study of Analytical Chemistry of the Modification of Manganese Dioxide (III). Quntitative Determination of Pyrolusite by Differential Heating Curves (변태 이산화망간의 분석 화학적 연구 (제3보) 시차 열곡선에 의한 Pyrolusite의 정량)

  • Kim Chan-Ho
    • Journal of the Korean Chemical Society
    • /
    • v.17 no.2
    • /
    • pp.122-125
    • /
    • 1973
  • A study on the endothermic peak of transformation of the pyrolusite was made by using differential thermal curves for analytical reproducibility, and it was done in quantity on range from 50 mg to 450 mg of pyrolusite species. The separation of ${\alpha}-MnO_2$ peak was impossible due to the overlapping between $\alpha$ and pyrolusite peaks, and the pyrolusite was determined among the species, ${\gamma}-MnO_2$ and ${\delta}-MnO_2$, with an error ranging from $5{\%}$ to $10{\%}$.

  • PDF

Periimplantitis Detection in Dental X-Ray Image by Structure Analysis (구조적 분석을 통한 임플란트 주위염 분리에 관한 연구)

  • 장창일;안용학;채옥삼
    • Proceedings of the Korean Information Science Society Conference
    • /
    • 2001.04b
    • /
    • pp.514-516
    • /
    • 2001
  • 본 논문은 시차를 두고 촬영된 두 장의 치과용 디지털 X-Ray 영상으로부터 임플란트 시술환자에서 자주 발생하는 임플란트 주위염을 검출하는 자동화된 시계열 분석 방안을 제안한다. 분석자에 따라서 결과의 차이를 보이는 수동적인 시계열분석방법의 문제점을 극복하고 보다 객관적이고 정략적인 결과를 얻는 방안을 제시한다. 보다 신속하고 정확한 검출을 위해서 본 연구에서는 치아의 구조 분석을 통해서 환부 탐색 영역을 줄이고 작은 변화도 민감하게 검출할 수 있는 환부영역을 분리할 수 있는 방안을 제안한다. 또한 분리된 환부의 특성을 수치적으로 표현할 수 있는 방안도 함께 제시된다.

  • PDF

Microstructure Observation of Pd-Cu-Ga system Dental Alloy in Clinical Heat Treatment (치과용 Pd-Cu-Ga 계 함금의 임상조건에 따른 미세조직 관찰)

  • 김기주;이진형
    • Journal of Biomedical Engineering Research
    • /
    • v.20 no.4
    • /
    • pp.443-449
    • /
    • 1999
  • 현재 시판되고 있는 치과용 76.5%Pd-11.6%Cu-7.2^%GarP 합금의 주조상태 및 임상열처리에 따른 미세조직의 변화를 X-선 회절기, 광학현미경, 시차열분석기를 이용하여 관찰하였다. 주조상태, 탈개스 및 세리믹소성처리 후 미세조직은 Pd고용체와 금속간화합물 Pd2Ga으로 구성되어 나타났고, 이들 상들은 열처리에 따라 상당한 변화를 보였다. 또한 Pd은 아르곤 분위기 내의 산소와 반응하여 산화물 형성 및 분해로 인해 질량변화곡선(TG)이 변하였고, 시차열분석(DTA)에서는 약 815$^{\circ}C$ 정도에서 Pd2Ga에 기인하는 흡열피크를 확인하였다. 이러한 실험의 결과들은 Cu가 이원계 Pd-Ga 합금의 Ga의 고용량을 낮추어 공정반응이 저 Ga 쪽으로 이동하기 때문인 것으로 설명하였다. 그러나 앞으로 보다 명확한 상변태 규명을 위해서 TEM등의 분석장비를 사용하여 체계적인 연구가 요구된다.

  • PDF

A Study on the Crystallization of Amorphous Pb-Sb-Au Alloys (비정질 Pb-Sb-Au합금의 결정화 과정에 관한 연구)

  • 김종오
    • Electrical & Electronic Materials
    • /
    • v.2 no.2
    • /
    • pp.137-142
    • /
    • 1989
  • Piston and anvil법으로 제작한 (P $b_{0.75S}$ $b_{0.25}$)$_{45}$A $u_{55}$ 비정질의 결정화 과정을 시차열분석(DTA), X-선 회절, 전기저항의 온도 및 시간변화를 측정하여 결정화과정을 조사하였다. 두단계의 상변태를 거쳐 결정화가 되는데 첫번째 변태온도는 52.deg.C이며 A $u_{2}$Pb의 결정상이 나타난다. 두번째 변태온도는 253.deg.C이며 AuS $b_{2}$의 결정상이 나타난다. 일차변태는 핵생성 및 성장 반응에 의하여 이루어졌으며 이때의 활성화 에너지는 1.38Kcal/mol이다.다.

  • PDF

Precedence Analysis of Traffic Safety Facilities Installation for Traffic Accidents (교통안전시설 설치의 교통사고 발생에 대한 선행성 분석)

  • Joo, Il-Yeob
    • Korean Security Journal
    • /
    • no.55
    • /
    • pp.31-55
    • /
    • 2018
  • The purpose of this study is to analyze the precedence analysis of traffic safety facilities installation for traffic accidents. The main results were as follows. First, the precedence of the number of traffic safety signs installation for the number of traffic accident is follows. The number of traffic safety signs[total number] (time precedent 1), the number of traffic safety signs[attention] (time precedent 7), the number of traffic safety signs[regulation] (time precedent 7), the number of traffic safety signs[indication] (time precedent 4) precede the number of traffic accidents as negative(-) relationship. Second, the number of traffic signal equipments[pedestrian lamp] (time precedent 2) precedes the number of traffic accidents as negative(-) relationship. Third, the precedence of the increase/decrease rate of traffic safety facilities installation for the increase/decrease rate of traffic accident is follows. The increase/decrease rate of traffic safety signs[total number] (time precedent 1), the increase/decrease rate of traffic safety signs[attention] (time precedent 1), the increase/decrease rate of traffic safety signs[indication] (time precedent 1), the increase/decrease rate of traffic safety signs[auxiliary] (time precedent 1) precede the increase/decrease rate of traffic accidents as negative(-) relationship. Fourth, the increase/decrease rate of traffic signal equipments[pedestrian lamp] (time precedent 0) accompanies the increase/decrease rate of traffic accidents as positive (+) relationship.

Analysis of Groundwater Recharge Characteristics Using Relationship between Rainfall and Groundwater Level (강우량과 지하 수위를 이용한 지하수 함양특성 분석)

  • Lee, Dong-Ryul;Gu, Ho-Bon
    • Journal of Korea Water Resources Association
    • /
    • v.33 no.1
    • /
    • pp.51-59
    • /
    • 2000
  • A dynamic model, which combined time series model with distributed-lag model, is applied to understand the relationship between rainfall and groundwater level. In the model, rainfall with distribution lags and past groundwater level as a dependent variables were used to estimate present groundwater level. The distribution of the lagged rainfall effects for groundwater levels was modeled by Almon polynomials. The model was applied to Banglim and Tanbu groundwater stations in Pyungchang river and Bocheong stream watershed which are representative basins for International Hydrological Program (IHP). The dynamic model represents observed groundwater levels very well and can be used to predict the levels. The model parameters reflect hydraulic characteristics of aquifer. In addition, from the parameters it appears that the increase in groundwater level due to rainfall takes place significantly within first two days of the rainfall event. The rainfall of the order of 18mm/day and 30mm/day at Banglim and Tanbu, respectively, had no significant effect on the groundwater levels.

  • PDF

Evaluation on Fire Test for the Concrete Filled Steel Tube Column -Fire Damage Evaluation on Steel Tube and Concrete after a Fire Test- (콘크리트충전 강관기둥의 내화실험에 대한 고찰 -재하가열실험후의 강관 및 콘크리트 화재손상평가를 중심으로-)

  • Park, Ki-Chang;Choi, Sung-Mo;Kim, Dong-Kyu
    • Journal of Korean Society of Steel Construction
    • /
    • v.12 no.6
    • /
    • pp.759-767
    • /
    • 2000
  • In this study, the time dependent internal stress changes of a Concrete Filled Steel Tube(CFT) column during a fire test were quantitatively analyzed. The strain ratio of a CFT column on the different loads was measured by tensile strength tests in terms of yield strength, tensile strength average extensibility and elasticity modulus. To understand the internal material properties change of concrete in CFT column damaged due to a fire, the compressive strength and elastic modulus tests were measured on a core sample from the center of the steel tube after the fire test. The elastic modulus test measured the strain from the stress. To determine the fire temperature of the test material, a differential thermal analysis was done. From the tested result, the gained data were conducted and an analysis method was suggested. The purpose of this work is to suggest a basic data for structure regulation enactments of the internal fire design of CFT.

  • PDF

A Study on the Highest Exposure Temperatures of Exposed Reinforced Concrete Structures at Fire (화재에 노출된 철근콘크리트 구조물의 최고노출온도 추정을 위한 연구)

  • Kim, Seong Soo;Lee, Jeong Bae;Kim, Il Kon;Song, Jong Jin
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.17 no.2
    • /
    • pp.94-100
    • /
    • 2013
  • In this paper, Machinery analysis was conducted, in order to predict highest exposure temperatures and the analyze fire damage in the case of fire on reinforced concrete structure. After analyzing differential thermal of reference materials in accordance with temperature of concrete reference core specimen, it turned out that powerful endothermic peak came resulting from evaporation of capillary water and get water untill $200^{\circ}C$, another endothermic peak came resulting from decomposition of calcium hydroxide at $520^{\circ}C$, and then mass of reference materials remarkably decreased due to endothermic reaction. Another powerful endothermic reaction came after decomposition of calcite at $720^{\circ}C$. After analyzing X-ray diffraction of reference materials in accordance with temperature of concrete reference core specimen, it turned out that calcium hydroxide existed until the temperature of $400^{\circ}C$, but CH almost disappeared and CaO appeared from $600^{\circ}C$. The production increased in proportion to the temperature. This is because that calcium hydroxide and calcite are decomposed and CaO is produced when the temperature of concrete increases with fire. It is estimated that calcium hydroxide and calcite are utterly decomposed and peak disappears, and peak of CaO is remarkably formed instead, at the temperature of $700-800^{\circ}C$.

Assessment of Physicochemical Properties of Domestic Bentonite and Zeolite as Candidate Materials for a Engineered Barrier in a Radwaste Repository (방사성폐기물 처분장 공학방벽 재료로서의 국산 벤토나이트 및 제올라이트에 대한 물리화학적 특성 평가)

  • 정찬호
    • The Journal of Engineering Geology
    • /
    • v.9 no.2
    • /
    • pp.89-100
    • /
    • 1999
  • This study was carried out to assess the physicochemical properties of domestic bentonites and zeolites from Tertiary Formation as the candidate material for a engineered barrier of a radioactive waste repository. Natural bentonite and zeolite samples were collected from nine bentonite mines and six zeolite mines in Yeonil-Gampo area. The commercial products of bentonite and zeolite were obtained from local companies. The collected samples were investigated to study the following physicochemical properties: X-ray diffraction patterns, swelling, cation exchange capacity(CEC), specific surface area, montmorillonite content, pH, organic carbon content, thermal property, microstruciure and chemical composition. Based on the physicochemical properties of bentonite and zeolite, the bentonites from U-41 and G-46 mines and the zeolites from Daedo and Y-1 mines are regarded as the most desirable candidate materials.

  • PDF

An Experimental Study on Measurement of the Reaction Order of a Liquid Fuel with Various Components (혼합 액체연료의 화학반응차수 계측에 관한 실험적 연구)

  • Choi, Hyo-Hyun;Lim, Jun-Seok;Kim, Chul-Jin;Sohn, Chae-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2011.04a
    • /
    • pp.421-424
    • /
    • 2011
  • Thermal Analyses are conducted to measure various factors of a liquid fuel required for numerical analysis. Thermal Analyses are divided into two different methods of TGA (Thermo Gravimetric Analysis) and DSC (Differential Scanning Calorimetry). Non-isothermal experimental results are analyzed using by TGA. The results are filtered by a Freeman Carroll method. At the same time, chemical parameters of unknown liquid fuel, activation temperature and reaction order are measured to 6128.2 K and 1.4, respectively. Furthermore, the parameters can be obtained by various mathematical methods. It is found that tha parameters depend on the processing method.

  • PDF