• Journal of Korean Society of Coastal and Ocean Engineers
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• v.14 no.4
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• pp.319-321
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• 2002

Recently, the injection of cement stabilizer is used as one of ways to improve soft sea-bottom. However, this method makes an argument with $Cr^{6+}$subject to emerge to the seawater from the cement stabilizer. To investigate the amount of$Cr^{6+}$field measurements were carried out in Ochun harbor of Chunsoo Bay. The analysis shows the amount of $Cr^{6+}$in the seawater met the demand of environmental criterion.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.501-506
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• 1996

원자력발전소의 2차 냉각계통 제염 공정인 EPRI/SGOG 공정에서는 EDTA를 제염제로 사용하고 있다. EDTA는 수용액 상에서는 20$0^{\circ}C$까지 안정하며 제염후 존재하는 유리 EDTA (EDTA-2NH$_4$)는 시멘트 수화반응에 의해 생성되는 Ca이온과 결합하여 EDTA-Ca 착이온이 형성된다. 따라서 CSH(Calcium Silicate Hydrate)겔의 형성을 억제함으로써 시멘트 경화반응을 지연시킨다. 현재 우리나라에서는 EDTA가 함유한 제염폐액의 처리방법의 미결정으로 인하여 자체 저장하고 있으나 고화체의 최종 처분조건을 만족하며 감용률을 최대화 할 수 있는 처리방법이 필요하다. 본 연구에서는 유리 EDTA가 소석회의 발생을 억제시켜 경화반응에 영향을 주는 점을 고려하여 유리 EDTA 용액에 소석회로 전처리 하여 시멘트 고화한 고화체의 물성시험을 수행하였다. 연구결과 EDTA와 소석회 반응 몰비가 1이 되게 전처리할 경우 시멘트에 대한 물의 배합비는 27%이상이 되어야 하며, 유리 EDTA 함량이 20wt%인 용액에서 폐액/시멘트/소석회비가 33.4/65/1.6일때 최대의 감용률을 나타내는 건전한 고화체의 조성비를 얻었다.

• Economic and Environmental Geology
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• v.39 no.6 s.181
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• pp.699-710
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• 2006

Batch scale experiments to investigate the efficiency of the solidification process for metal mine tailing treatment were performed. Portland and MSG (micro silica pouting) cements were used as solidifier and three kinds of mine tailings (located at Gishi, Daeryang, and Aujeon mine) were mixed with cements to paste solidified matrices. Single axis com-pressible strengths of solidified matrices were measured and their heavy metal extraction ratios were calculated to investigate the solidification efficiency of solidified matrices created in experiments. Solidified matrices ($5cm{\times}5cm{\times}5cm$) were molded from the paste of tailing and cements at various conditions such as different tailing/cement ratio, cement/water ratio, and different cement or tailing types. Compressible strengths of solidified matrices after 7, 14, and 28 day cementation were measured and their strengths ranged from 1 to $2kgf/mm^2$, which were higher than Korean limit of compressible strength for the inside wall of the isolated landfill facility ($0.21kgf/mm^2$). Heavy metal extractions from intact tailings and powdered matrices by using the weak acidic solution were performed. As concentration of extraction solution for the powdered solidified matrix (Portland cement + Gishi tailing at 1:1 w.t. ratio) decreased down to 9.7 mg/L, which was one fifth of As extraction concentration for intact Gishi tailings. Pb extraction concentration of the solidified matrix also decreased to lower than one fourth of intact tailing extraction concentration. Heavy metal extraction batch experiments by using various pH conditions of solution were also performed to investigate the solidification efficiency reducing heavy metal extraction rate from the solidified matrix. With pH 1 and 13 of solution, Zn and Pb concentration of solution were over the groundwater tolerance limit, but at pH $1{\sim}13$ of solution, heavy metal concentrations dramatically decreased and were lower than the groundwater tolerance limit. While the solidified matrix was immerged Into very acidic or basic solution (pH 1 and 13), pH of solution changed to $9{\sim}10$ because of the buffering effect of the matrix. It was suggested that the continuous extraction of heavy metals from the solidified matrix is limited even in the extremely high or low pH of contact water. Results of experiments suggested that the solidification process by using Portland and MSG cements has a great possibility to treat heavy metal contaminated mine tailing.

• Journal of the Korean GEO-environmental Society
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• v.15 no.12
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• pp.35-42
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• 2014

The efforts to reduce carbon emission have been made in many aspects and in road, the study to develop the construction method which will replace asphalt and cement is also underway. But given the low cost and high performance offered by cement, among many solidification agents, it's difficult to seek the competent alternative. Polymeric material has been used in various ways for its advantages including lightweight and easy process for complex function and generates less carbon emission, and thus it would possibly be efficient if it replaces soil pavement using cement. This study, using three different types of organic polymeric solidification agents with different solidification principle, is intended to identify the difference in strength depending on curing method, natural dry or oven dry. Applicability of organic polymeric solidification agents to walkway and bike lane was investigated and as a result of unconfined strength test, all of them satisfied the minimum strength requirements of bike lane. Furthermore, strength characteristics of soil pavement depending on variation of water content was evaluated to identify the relationship, thereby appropriate curing method using organic polymeric solidification agent is proposed.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.2
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• pp.74-77
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• 2005

The injection of cement stabilizer is used as one of ways to stabilize soft sea-bottom. However, this method makes an argument for the possibility of releasing heavy metals from the cement stabilizer to the seawater. To investigate the effect of the cement stabilizer on the seawater, field measurements were carried out in Ocheon harbor of the Chunsoo Bay. Although the highest concentrations of dissolved heavy metals were found in the surface seawater of the injection point and the metal concentrations decreased with distances, the levels of heavy metals in all the seawater met the demand of environmental criteria of Korea, US and UK.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2009.06a
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• pp.109-110
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• 2009

"드럼 코아시편 채취장치" 는 침출/내수성 시험, 압축강도 측정시험, 열 순환 시험등 의 파괴적 물성시험을 수행하기 위해서 경질(시멘트 고화체) 및 연질(파라핀왁스) 등의 방사성폐기물드럼으로부터 코아 시료를 채취하는 장비이다, 시편채취의 최대길이는 860 mm 이며 코아 시편의 직경은 50~200 mm 이며 일반적으로 "방사성폐기물 고화체의 물성시험"에 사용되는 시편은 실험실적으로 제조한 소규모 모의 고화체 시편과 고화공정에서 직접 채취한 소규모 시편, 200L 드럼으로부터 코아시편을 채취 가공하여 만든 시편과 같이 3종류가 있다. 고화공정에서 발생되는 고화체는 일반적으로 200 L 드럼에 주입되며, 고화체의 균일성 정도는 고화공정의 특성, 폐기물/고화매질 혼합비, 200 L 고화체 드럼의 냉각방식에 따라 다르다. 따라서, 실험실에서 제조한 시편과 공정에서 채취한 소규모시편은 실제 고화공정을 대표할 없으며 또한 실제 발생된 고화체의 조성과도 동일하다고 볼 수 없다. 따라서 200 L 드럼으로부터 코아시편을 채취하여 만든 시편이 고화공정과 고화체를 대표할 수 있는 시편으로 볼 수 있다 그러므로 고화체 및 고화공정을 대표할 수 있는 코아시편을 채취할 수 있는 장치를 제작하여 다양한 코아시편을 200 L 고화체 드럼으로부터 수직 코아시편을 채취할 필요가 있으며 실험에서 코아시편 채취속도와 연관된 Z-AXIS 의 Rpm은 운전범위는 0-2000 Rpm 이나 이때 너무 빠른 속도는 기계에 치명적인 손상을 초래 할 수 있으므로 위험한 것으로 나타났으며 500-1000 Rpm 의 속도가 적합한 것으로 시험되었으며 시편을 절삭하는 Spindle의 Rpm은 운전범위는 0-1500Rpm 이나 무리한 운전을 피해 가장 적절한 Speed로 운전해야하며 시험결과 500-800Rpm 이 최적운전범위로 나타났다 또한 시멘트고화체에서의 코아 채취시험에서는 Spindle의 속도는 500 Rpm, Z -AXIS 의 Rpm은 900 Rpm이 가장 적합한 것으로 나타났으며 성능평가시험을 통하여 비트부의 절삭속도와 Z축의 이동속도에 관한 그라프를 획득하였으며 시편의 크기에 따라서 Spindle의 속도를 증감하여야함을 확인할 수 있었다.

• Journal of the Korean Ceramic Society
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• v.39 no.12
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• pp.1138-1142
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• 2002

Slag cement and supersulfated slag cement were fabricated by mixing blast furnace slag and ordinary portland cement and adapted to solidify/stabilize heavy metal contained hazardous waste sludge. In case of slag cement, it showed continuous increase of their compressive strengths, which is attributed to the formation of the C-S-H, ettringite and monosulfate with STS sludge. However, BF and COREX sludge has a different shape and composition. therefore, adequate compressive strength could not be achieved with this slag cement. In case of the mixture of the each sludge like the STS-BF or the STS-COREX, the compressive strength over the standard level for disposing the wastes could be obtained with slag cement. The supersulfated slag cement that contain accelerators was very effective in solidifying the COREX sludge, which was difficult to solidify using different cement and obtained high compressive strength only for 3 days.

• Journal of the Korean GEO-environmental Society
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• v.13 no.6
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• pp.19-26
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• 2012

In this study, geotechnical tests including unconfined compression test were carried out to evaluate the ground improvement effect of the hardening agent, which has been developed by using inter-chemical reactions between slag, fly ash, phosphogypsum and bypass dust on the weathered granite soil and dredged marine clay. Test results show that the strength of weathered granite soil mixed with hardening agent B-2, which uses phosphogypsum as an activator, is higher than that of B-1, which uses bypass dust as an activator. Strengths of B-1 & B-2 hardening agent mixed soil show only 44%~60% of strength of OPC(Ordinary Portland Cement, OPC) mixed soil. However, since B-1 and B-2 agents are made of industrial by-products, they seem economically more effective than ordinary portland cement as well as other present hardening agents. Test results on dredged marine clay show that unconfined compression strength increases with amount of agent and curing days. Unconfined compression strength of 14% B-1 agent mixed soil increases linearly with curing days and reaches only 40% of OPC mixed soil. While unconfined compression strength of 14% B-2 agent mixed soil increases exponentially and reaches 133% of OPC mixed soil. Relationship between deformation modulus and unconfined compression strength of B-1 and B-2 mixed soil can be expressed as $E_{50}=(20{\sim}47)_{qu,28}$, which is similar with lower limit of OPC mixed dredged marine clay.

• Journal of the Korean Geosynthetics Society
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• v.11 no.3
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• pp.37-42
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• 2012

The cement paste is mostly used as the filling materials of bored pile in Korea. The use of filling material based on cement paste is inefficient at field construction because it needs a lot of the charging mass. In addition, it has environmental problem according to the large amount of cement use because its strength is also larger than criterion. The excavated soil with stabilizer can be used as the filling materials when the bored pile is constructed. Therefore, this paper describes field application of solidified soil for economical efficiency and environment-friendly. The injection capacity of solidified soil is compared with cement paste's based on unconfined compressive strength test and field load test, and the appropriate of test results is evaluated by design criterion. The evaluation result shows that the capacity of excavated soil with stabilizer is similar to cement paste and the solidified soil is able to apply as filling materials of bored pile because it is satisfied with design criterion.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2016.10a
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• pp.305-306
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• 2016