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Electrical Characterization of c-Si Solar Cell with Various Emitter Layer

  • Park, Jeong-Eun;Byeon, Seong-Gyun;Lee, Yeong-Min;Park, Jun-Seok;Lee, Min-Ji;Im, Dong-Geon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.413-413
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    • 2016
  • 태양전지 제작 시 에미터층을 형성하는 도핑 공정의 최적화는 캐리어 수집 확률 증가와 함께 결정질 실리콘 태양전지 고효율화를 위해 매우 중요하다. 본 연구에서는 결정질 실리콘 태양전지 다이오드의 다양한 도핑 공정으로 제작된 p-n 접합에 대한 전기적 특성 분석을 진행하였다. 도핑 공정의 경우 선 증착-후 확산 공정 시간과 가스량을 변화시켜 다양한 에미터층을 제작하였다. 선 증착 시간 변화를 주는 경우 선 증착 공정을 $825^{\circ}C$로 고정한 뒤 시간을 7분에서 17분까지 변화하고 후 확산 공정을 $845^{\circ}C$, 14분으로 고정하였다. 후 확산 시간 변화를 주는 경우는 선 증착 공정을 $825^{\circ}C$, 12분으로 고정한 뒤 후 확산 공정을 $845^{\circ}C$로 고정 하고 시간을 9분에서 19분까지 변화시켰다. 선 증착 공정을 $845^{\circ}C$ 12분, 후 확산 공정을 $845^{\circ}C$, 14분으로 고정 한 뒤 선 증착 시 POCl3양을 400 ~ 1400 SCCM까지 변화시켰고, 후 확산 시 산소량을 0 ~ 1000 SCCM까지 가변한 조건에서 에미터층에 대한 특성을 분석하였다. 결과적으로 선 증착 공정 $825^{\circ}C$ 12분, 후 확산 공정 $845^{\circ}C$ 14분에서 SCR(Space Charge Region)에서 3.81의 가장 낮은 이상 계수 값을 나타내었다. 이는 p-n접합의 내부결함이 줄어들어 태양전지의 캐리어 수명이 증가됨을 보였다. 선 증착 공정 중 $POCl_3$ 주입량 800 SCCM, 후 확산 공정 중 산소량 400 SCCM에서 $15.9{\mu}s$로 가장 높은 캐리어 수명을 나타내었다. Suns-VOC 측정 결과 $POCl_3$ 주입량 800 SCCM, 산소량 400 SCCM에서 619mV로 가장 높은 개방전압을 얻을 수 있었다.

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An Analysis of Characteristic for Hydrologic Weather Parameters through the Various Statistical Methods (각종 통계학적 방법을 통한 주요 수문기상인자의 특성 분석 -서울지점을 중심으로-)

  • Lee, Jae-Joon;Kwak, Chang-Jae;Jang, Joo-Young
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.1245-1249
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    • 2009
  • 본 연구에서는 우리나라 수문기상인자의 특성변화 분석의 필요성을 지각하여 국내 기상관측소 중 관측년수가 30년 이상인 관측소 63개 지점에 대한 수문기상인자 중 연평균기온, 연평균상대습도, 연강수량, 연증발량, 연일조시간, 연강수계속시간, 연강수일수, 연적설일수, 연신적설일수 등의 자료를 수집하고 기본통계량에 해당하는 평균, 표준편차, 왜곡도, 변동계수를 통하여 수문기상인자의 경년적 변화를 파악하였다. 또한 각종 통계학적 기법을 이용하여 이들 수문기상인자의 경향성, 주기성, 변동성 등을 분석하였으며, 그 결과는 우리 나라를 대표할 수 있는 서울지점을 중심으로 정리하였다. 기본통계량을 분석한 결과 연강수량, 연강수일수, 연강수계속시간의 표준편차와 변동계수가 다른 수문기상인자 비해 상대적으로 큰 것으로 나타나 강수관련 인자들의 경년별 변화가 두드러짐을 알 수 있다. 또한 선형회귀분석과 5년 이동평균 결과 연강수량과 연평균기온은 증가, 연평균상대습도, 연일조시간, 연강수일수, 연증발량은 감소하는 경향을 보였다. Mann-Whitney Test, Wald-Wolfowitz Test, Hotelling-Pabst Test, Wavelet Method와 같은 통계학적기법으로 동질성, 독립성, 검정, 경향성 검정을 수행한 결과 연강수량, 연증발량, 연강수계속시간, 연강수일수, 연적설일수, 연신적설 일수 인자가 각각의 검정에서 동질성 및 독립성을 보였고, 경향성 검정에서는 연평균기온, 연평균상대습도, 연적설일수 인자가 신뢰수준 내에서 유의함을 보였고, 주기성 검정결과 본 연구에 채택한 9개의 수문기상인자들의 연속된 주기성은 나타나지 않았다.

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Measurement of Formaldehyde Emissions during Hot-Pressing of Particleboard Bonded with Melamine-Urea-Formaldihyde Resin (요소-멜라민수지로 접착된 파티클보드의 열압동안 포름알데히드 배출량 측정)

  • Lee, Jong-Kyu;Oh, Yong-Sung
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.65-72
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    • 2004
  • A melamine-urea-formaldehyde (MUF) resin, based on 5 percent melamine addition of the resin solids weight, was synthesized in the laboratory for particleboard (PB) manufacture. Laboratory PBs were made with the MUF resin at three press times (3, 4, 5 min) and two resin application rates (6, 8 percent). Enclosed caul system was used for collecting the exhaust gases materials generated during the hot-pressing of PBs. Exhaust gases materials generated inside the enclosed caul during the hot-pressing of PBs were collected in a controlled air stream. Formaldehyde from the exhaust gases collected was determined per a chromotropic method of the National Institute of Occupational Safety and Health Method 3500. The measurement results showed that formaldehyde emissions during the hot-pressing of PB significantly increased with increasing press time, and MUF resin application rates. PB' performance test results showed that internal bond (IB) of PB made with 3-minute press time exceeded the minimum requirement for KS F 3104 PB type 8.0.

Management Period Setting Study of through Analysis of the Growth Amount after Planting of Deciduous Broadleaf Species Planted in Ecological Restoration Sites (생태복원지에 식재된 낙엽활엽수종의 이식 후 생장량 분석을 통한 관리기간 설정 연구)

  • Lee, Soo-Dong;Bae, Soon-Hyoung
    • Korean Journal of Environment and Ecology
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    • v.36 no.5
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    • pp.496-506
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    • 2022
  • The growth of trees planted through transplantation rapidly decreases immediately after planting due to extreme disturbances such as root cutting and crown damage. Although the growth rate is recovered as time elapses, the time required to restore the original growth varies by species. Therefore, it is necessary to set an appropriate tree management period for survival after transplantation by analyzing each species' annual growth change. In this study, we analyzed the growth amount of deciduous broad-leaf species planted in the area where the riparian ecological belt was formed and proposed the management period based on the results. Slowed growth immediately after planting is a common phenomenon due to root cutting and pruning, the pre-works performed to increase tree survival rate during the transplantation process. Afterward, the original growth rate is recovered as time passes, but the time required may vary depending on the species and planting environment. Most of the trees showed a rapid decrease in growth immediately after transplantation. After that, although it is different for each species, most of them showed a gradual recovery from 2 years onwards. The analysis of the growth rate by tree species confirmed that it took 2 to 4 years, depending on the tree species, to recover the growth level before transplantation after a rapid decrease in growth immediately after transplantation. The results suggest that improving the defect rate of planted trees is necessary to meet the project objectives: ecological restoration and pollutant reduction. It requires setting a tree management period of at least two years and creating an appropriate base environment.

The Study on the Realtime Evaluation of NH3 Absorption Efficiency Using Chemical Gas Sensor (가스센서를 활용한 암모니아 가스의 실시간 흡수 효율 평가에 관한 연구)

  • Lim, Jung-Jin;Kim, Han-Soo;Kim, Sun-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.4
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    • pp.233-239
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    • 2013
  • This study was carried out to develop the realtime evaluation system of $NH_3$ absorption efficiency with gas sensors which were installed on the inlet and outlet of lab-scale scrubber system. The $NH_3$ absorption amount, calculated by sensor outcomes for 3 hr, 6 hr, and 12 hr of absorption process, was compared with the results analysed by Indo-phenol method for the absorption solution. Even though the difference between two methods was about 20%, the correlation coefficient between the two results was very high, more than 0.99. In addition, we could find very good correlation between pH, absorption amount and reaction time. Also we could find out the breakthrough time in the middle of absorption process. With more diverse experiment in the future, we can make gas sensor system for the realtime evaluation of the odor and/or air pollution treatment efficiency.

Effects of Nutrient Concentration and Hydraulic Retention Time on the Removal of N and P by Phragmites japonica Steudel (영양염류의 유입농도와 수리학적 체류시간에 따른 달뿌리풀(Phragmites japonica Steudel)의 질소와 인 제거능)

  • 신정이;차영일
    • Korean Journal of Environmental Biology
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    • v.17 no.2
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    • pp.153-158
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    • 1999
  • Uptakes of N and P by Phragmites japonica Steudel. are determined in continuous flow tanks as a function of hydraulic retention time (HRT, days) and nutrient concentration (NC). Results show that the uptake was higher at shorter HRT and higher nutrient concentration, and the regression equations were estimated. Mean above ground biomass of Phragmites japonica in the middle reaches of Sagimak stream was 335.92 g/$m^2$, and estimated uptake by this vegetation were 7.31~20.15 NH$_4$-N, 31.15~95.84 NO$_3$-N, and 4.09~11.48 PO$_4$-P mg/$m^2$/day in Sagimak stream, respectively when HRT was 1~5 days. According to this study, it is concluded that Phragmites japonica Steudel. are suitable for water quality improvement of stream through nutrient uptake at short HRT and high concentration.

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Construction Method of Time-dependent Origin-Destination Traffic Flow for Expressway Corridor Using Individual Real Trip Data (실제 통행기록 자료를 활용한 고속도로 Corridor 시간대별 O-D 구축)

  • Yu, Jeong Whon;Lee, Mu Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2D
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    • pp.185-192
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    • 2011
  • More practical outputs and insights can be obtained through transportation analysis considering the time-dependent traffic movements. This study proposes a method of constructing time-dependent O-D trip tables for expressway corridor using real-world individual trip data. In this study, time-dependent O-D trip tables for the nationwide highway network are constructed based on toll collection system data. The proposed methodology is to convert nationwide time-dependent O-D trip tables into Korean expressway corridor O-D trip tables in order to deal with the computational complexity arising from simulating a large-scale traffic network. The experiment results suggest that actual individual trip record data can be used to effectively construct time-dependent O-D trip tables. They also imply that the construction of time-dependent O-D trip tables for the national highway networks along with those for Korean expressway developed in this study would make transportation analysis more practical and applicable to real-time traffic operation and control.

A Study on Ways to Improve Benefits of Travel-time in Analyzing the Economic Efficiency (경제성분석시 통행시간절감편익 개선방안에 관한 연구)

  • Lee, Sooil;Lee, Seungjae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.3D
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    • pp.263-270
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    • 2010
  • This research has reviewed the ways to improve the benefits of shortening of transit hours among the benefit items in analysis of economic efficiency. The existing way of calculating the benefits of shortening the transit hours in analysis of economic efficiency has been using O/D in peak to multiply by 365. This method has a problem of not considering the change of traffic according to the month and the day of the week. To improve such problem, the volume of traffics at 361 regular research branches of the chronological statistics of traffic volume was used to analyze the pattern change of traffic volume per day of the week and per month by t-test and cluster analysis. The results show a difference in traffic volume according to the day of the week and the month. In the research example, a supposed O/D and network were used to apply weight per day of the week and per month to see a slight difference with the existing method of calculating benefits of shortening the transit hours. This signifies the necessity to study about the weight to consider the change pattern of traffic volume.

Effects of Gas Retention Time and Filling Depth of a Compost Biofilter on Removal of Vapor Phase Gasoline (가솔린휘발가스 제거를 위한 퇴비 바이오필터의 체류시간 및 충전깊이의 영향)

  • Namkoong, Wan;Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.3
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    • pp.124-130
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    • 2000
  • This study was conducted to evaluate effects of gas retention time and filling depth of a compost-based biofilter on removal of vapor phase gasoline and to suggest operational improving method. Gas empty bed retention times(EBRTs) were 4, 10, and 20 minutes, respectively. EBRT of over 10 minutes was required in both cases of TPH(total petroleum hydrocarbons) and BTEK (bezene, toluene, ethylbenzene, and xylene). Filling depths were 25, 50, 75, and 100cm, respectively. To treat gasoline TPH effectively, controlling other operational parameters including EBRT and gas loading rate was more important than increasing filling depth simply. 1m filling depth was sufficient in treating BTEX without controlling other operational parameters greatly.

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Time-Dependence of the Rheological Properties of Concentrated PVA Solution in DMSO (고농도 폴리비닐 알코올/디메틸 설폭사이드 용액의 유변학적 특성의 시간의존성)

  • 김남희
    • The Korean Journal of Rheology
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    • v.9 no.3
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    • pp.118-123
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    • 1997
  • 검화도와 분자량이 상이한 폴리비닐 알코올을 디멜틸 설폭사이드에 녹여 폴리비닐 알코올/디멜틸 설폭사이드 용액을 준비하고 동적 유변학적 특성에 대한 시간과 온도 의존성 을 고찰하였다. 고농도 폴리비닐 알코올 용액의 유변학적 특성은 시간 의존성을 보여주었다. 복합점도와 저장탄성률은 시간에 따라 증가하였다. 또한 저장 탄성률과 손실탄성률의 그래 프에서 저장탄성률은 신간에 따라 증가하였으나 기울기는 시간에 따라 증가하였다. 또한 저 장탄성률과 손실탄성률의 그래프에서 저장탄성률은 시간에따라 증가하였으나 기울기는 시간 에 따라 감소하였다. 유변학적 특성의 시간 의존성은 분자량이 높을수록, 측정온도가 높을수 록 더 두드러지게 나타났다.

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