• Environmental Analysis Health and Toxicology
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• v.18 no.3
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• pp.193-197
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• 2003

슬러지로부터 발생하게 되는 인체에 유해하고 독성이 강한 악취물질들은, 대다수 슬러지내의 단백질, 탄수화물등의 물질들이 미생물의 호기성 및 혐기성 분해과정을 통해서 생성되는 유ㆍ무기 물질들을 포함하게 된다. 슬러지로부터 발생하는 주된 악취물질로서 hydrogen sulfide, methanethiol, dimethyl sulfide, dimethyldisulfide,dimethyltrisulfide등이 발견되어졌는데 이 다섯 종의 악취물질들은 모두가 황을 포함하는 물질들이다. 본 논문에서는 인체에 유해한 슬러지 악취의 강도 및 세기를 결정하고 비교하는 데 이용되어 질 수 있는 odor index(ODI)라는 방식이 제시되어졌다. 세가지 종류의 슬러지, 즉 hypochlorite 용액으로 처리한 슬러지와 향수 물질로 처리한 슬러지 및 아무런 처리를 하지 않은 슬러지 세 종류를 대상으로 30일이 넘는 기간동안 인체에 유해한 악취물질들에 대한 누적 odor index(ODI)값을 생성하여 비교하였다. 아무런 처리를 하지 않은 슬러지에서 가장 높은 odor index(ODI)값들이 나타났으며, 이것은 슬러지 처리에 있어서 심각한 단기 및 장기적인 유해 악취발생 문제가 야기될 수 있음을 나타낸다. 이에 대하여 hypochlorite용액으로 처리한 슬러지로부터는 인체에 유해한 악취 발생을 처리 즉시부터 30일이 넘는 기간동안 측정한계치 이하 단계로 낮출 수 있었다.

• Journal of Life Science
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• v.33 no.1
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• pp.82-90
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• 2023

Biological process is used worldwide to treat domestic and industrial wastewater. The process generally uses a mixed microbial culture of sludge. The growth of microorganisms in the sludge produces excess sludge from the wastewater treatment process. Some of the excess sludge is recycled as inoculum for wastewater treatment, but the rest is removed as waste from the process. As wastewater production is increasing worldwide every year, the number of wastewater treatment plants (WWTPs) is also in- creasing, resulting in the generation of large amount of waste sludge. The increasing amount of waste sludge from WWTPs has led to concerns about its management. Sludge disposal has been reported to account for 50~60% of the total operating costs of a WWTP. Sludge disintegration is a new technology that can minimize volume of waste sludge and recover useful components (e.g., P, N, and soluble organic compounds) from it. Various methods of sludge disintegration have been developed based on physical, chemical, and biological treatments or combinations of these. In this review, we focus on sludge disintegration by acid hydrolysis, which is less studied among sludge disintegration methods. Such information can be useful in the development and implementation of a new technology for better sludge treatment.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.401-401
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• 2022

우리나라 대규모 하수처리장에 상용화되어있는 응집공정의 운영상 난점을 극복하고자 대체공정으로 고안된 인 결정여과공정(HCF, Hydroxyapatite Crystallization-Filtration process)의 pilot plant를 구축하고 부산슬러지의 자원화를 위해 그 특성을 검토하였다. 기존의 hydroxyapatite(HAP) 결정화공정 내 탈탄산(decarbonation) 단계를 생략하는 HCF공정의 경우에 고농도의 Ca²⁺ 주입과 처리수내 탄산염으로 인해 HAP을 포함하는 석회계 슬러지가 발생하는데, 이는 산성화된 토양의 개량제(중화제)로 널리 사용될 수 있다. 본 연구를 위해 경기도 I하수처리장 2차침전지 후단에 구축된 처리용량 27.1 - 135.6 m³/day HCF pilot plant의 전처리 조건은 pH 10.0 - 11.0, Ca²⁺ 농도 80 mg/L이었다. 결정여과조는 선속도 1.0 - 5.0 m/hr, 상향류로 운전되며, 여재는 2.0 - 3.0 mm의 석회석 모래를 충전하였다. 역세척은 중앙에 Air lifting pipe를 설치하여 역세척수가 처리수와 분리배출되도록 설계하였고, 침전시켜 역세척 슬러지를 회수하였다. 처리수의 평균 T-P, PO₄-P 및 SS는 각각 0.05, 0.04, 1.1 mg/L으로 모든 항목에서 방류수 수질기준 이하로 안정적으로 유출되었다. 회수된 HCF 슬러지는 SEM-EDX, XRD, FT-IR을 활용하여 그 특성을 분석하였다. SEM-EDX로 분석된 슬러지의 원자분율은 CaCO₃ 또는 HAP으로 추측되었다. 또한, XRD spectrum 분석결과, 슬러지의 주요 구성성분은 calcite, HAP, phosphoric acid(H₃PO₄) 및 brusite로 나타났다. FT-IR 분석결과, 슬러지는 대부분 인산염 및 탄산염의 무기물로 구성되어 있으며, 유입수의 인 농도가 높을수록 슬러지 내 HAP의 함량이 calcite보다 높은 것으로 나타났다. 고농도의 Ca²⁺을 주입하여 탈탄산단계를 생략한 HCF의 부산슬러지는 HAP 이외에도 CaCO₃와 칼슘-인 화합물로 구성되어 있는 것으로 나타났다. 하수 인 고도처리를 위한 HCF공정의 하수처리시설 인 고도처리 적용이 검증되었으며, 부산슬러지를 산성화된 토양의 개량제(중화제) 또는 비료로서의 재활용 및 자원화 가능성이 시사되었다.

• Clean Technology
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• v.13 no.2
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• pp.87-98
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• 2007

As the interest in environmental problems increased, the guideline of effluent qualities becomes strict and the amount of sludge produced from the wastewater treatment facilities steeply increased. The revised Korean acts prohibit the direct reclamation of the sludge exhausted in sewage treatment works from 2003, and the ocean dump of sludge will be also prohibited from 2012. Therefore, the sludge must be recycled, incinerated or composted. To properly perform the utilization and disposal operations, the establishment of well-defined procedures for the characterization of sludge by physical, chemical and biological method and setting up of guidelines for different treatment and disposal routes has become necessary. However, there have not been such standardized methods for sludge characterization in Korea. This review analyzes the present status of establishment and problems of sludge characterization method of Korea. Finally, it was proposed total 15 items of standardized characterization methods suitable to our country for proper sludge recycling and disposal, which was based on the more systematic standard methods of Germany (DIN 38414) and those of advanced nations.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.05a
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• pp.113-116
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• 2003

1) 지렁이를 이용한 하수슬러지의 분변토화 공정에서 실험실 규모의 처리에서는 장기간의 부숙 기간이 필요하였으나 개방된 대형 비닐하우스 시설을 사용한 처리 시스템에서는 전처리 공정의 생략이 가능하였다. 2) 하수슬러지의 이화학적 특성을 분석한 결과 지렁이 생육 조건은 만족하였으나 중금속 함량은 부숙토 원료기준을 초과하는 경우가 있었다. 3) 인위적으로 사육상 온도 조절이 없는 비닐하우스내 사육상의 온도는 기상 조건의 영향을 직접 받고 있으므로 계절별로 슬러지 처리기간 및 지렁이 성장밀도에 차이를 나타내었다. 4) 지렁이를 이용하여 하수슬러지를 처리하고자 할 때 유해성분에 의한 지렁이의 생육에는 문제가 없었다. 그러나 슬러지와 분변토의 중금속 함량을 부숙토의 원료기준 및 제품기준과 비교하였을 때 기준을 초과하는 경우가 있었다. 따라서 지렁이를 이용하여 하수슬러지를 처리하고자 할 때 원료 및 분변토의 특성개량과 재활용성을 높이기 위하여 부원료의 개발과 활용이 필요하였다.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.9
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• pp.636-643
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• 2011

Sludge solubilization using sonification has been increasingly used for sludge volume reduction along with enhancing digestion efficiency during anaerobic biogas production. In this study, either electric field or ultrasonification or in combination with were investigated using three types of sludge (return, excess and mixed at G sewage treatment facility) for the most efficient solubilization. As a the closed loop, 200 L of sludge was continuously passing through the solubilization system at an average flow rate of $0.7m^3/h$, which is equivalent to 3.5 times treated per hour for up to 84 times (24 h). Only implying electric field showed no variation for sCOD/tCOD before and after treatment on sludge solubilization regardless of types of sludge. However, employing the ultrasonic or combined system could both increasingly solubilize sludge with regard to the number of passing-through, which more enhanced by the combined. In addition, VSS/TSS was lowered to in the range of 2 and 6% while its particle size, diameter (0.9) and diameter (0.5) were more minimized than that of raw sludge. For return sludge, ultrasonification was more efficiently facilitated for solubilization, whereas electric field-ultrasonification was more preferably applied for excess and mixed sludge. It is concluded that depending on types of sludge, solubilization system must be selectively applied for the most efficient break-up of them.

• Proceedings of the Membrane Society of Korea Conference
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• 1991.10a
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• pp.41-42
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• 1991

본 연구는 활성슬러지공법의 침전조를 막으로 대체하여 고액분리를 효과적으로 수행하도록 하는 막분리 활성슬러지 공법에 관한 것이다. 이와같은 방법은 공정자체가 간략화되는 동시에 종래법에서 슬러지 팽화(bulking)등에 의해 침전조에서 SS carry-over, 슬러지 침강성 향상을 위한 고부하처리의 곤란성, 침전조 처리수에의 SS 유출등 고액 분리의 문제점을 해소하므로, 여과, 응집침전, 혹은 활성탄흡착등의 고도처리설비없이 양질이 처리수를 얻을 수 있다고 보고 되고 있다.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.103-109
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• 2010

Anaerobic digestion has been widely used for the treatment of sludge, which is generated from the municipal and industrial wastewater treatment, for its volume reduction and methane production. Many researches on sludge pre-treatment have been carried out in order to enhance the performance of anaerobic digestion by increasing the hydrolysis of sludge which is the rate limiting step of anaerobic digestion. In this study, the effect of pre-treatment on sludge hydrolysis(solubilization), methane production and sludge reduction by anaerobic digestion after thermal, ultrasonic, and thermal-alkali sludge treatment were compared. Thermal-alkali treatment showed 67 and 70% solubilization with municipal and industrial wastewater sludge, respectively, while ultrasonic treatment and thermal treatment gave similar solubilization efficiency of 40% or more. Methane content of the anaerobic digestion gas reached 45~70% and pretreated sludge gave higher methane content than the control sludge. Methane production of thermal, ultrasonic, and thermal-alkali pre-treatment gave 2.6, 2.7, 3.5 times of municipal control sludge and 3.5, 4.1, 4.2 times of industrial control sludge, respectively. Sludge reduction of pre-treated sludge after anaerobic digestion gave 5~19% point higher than that of control sludge, and thermal-alkali treatment showed higher reduction efficiency than thermal and ultrasonic treatment. The results proved that pre-treatment contributed significantly not only for the methane production but also for the cost reduction of sludge treatment and disposal, and thermal-alkali treatment gave the best performance for the sludge treatment.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.93-100
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• 2005

Comparative thickening and dewatering characteristics of municipal wastewater sludge were investigated in terms of separated and combined treatment of primary and secondary BNR sludge. Also, various conditioning methods such as cation polymer addition, steam and ultrasonication treatment were examined to improve dewaterability of sludge. The dewaterability was measured by using specific resistant test, wedge zone simulator and centrifuge. The result of the sludge thickening test revealed that separated thickening was better in terms of solids recovery and supernatant quality. Particularly, the thickening of primary sludge with high solids (about 3.5% TS) showed very poor solid separation. The addition of cation polymer showed better conditioning characteristic for dewatering and the optimal polymer dosage was 0.26% for primary sludge, 0.43% for secondary sludge and 0.38% for combined sludge. Contrary to the result of the thickening, the dewatering test revealed that dewatering of the combined sludge is better than that of separated sludge, representing better solids separation and filtrate quality. The polymer addition was essential to improve dewaterability in filter (belt) press type dewatering but it was inefficient for the dewatering of secondary sludge only. The centrifuge type dewatering showed better performance and the dewaterability was slightly improved when the polymer was added. Based on the results of this research a sustainable sludge treatment process, particularly in terms of the recycle water quality and solids recovery, was proposed.

• Applied Chemistry for Engineering
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• v.29 no.5
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• pp.613-619
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• 2018

In this study, various influent sludge pre-treatment methods and the internal recirculation of thickened sludge from effluents using a liquid/solid separation unit were adopted to investigate their effects on the sludge digestion and methane production in a combined mesophilic anaerobic and thermophilic aerobic sludge digestion process. A lab-scale combined sludge digestion process was operated during 5 phases using different feed sludge pre-treatment strategies. In phase 1, the feed sludge was pre-treated with a thermal-alkaline method. In contrast, in phases 2, 3 and 4, the internal recirculation of thickened sludge from the effluent and thermal-alkaline, thermal, and alkaline pre-treatment (7 days) were applied to the combined process. In phase 5, the raw sludge without any pre-treatment was used to the combined process. With the feed sludge pre-treatment and internal recirculation, the experimental results indicated that the volatile suspended solid (VSS) removal was drastically increased from phases 1 to 4. Also, the methane production rate with the thermal-alkaline pre-treatment and internal recirculation was significantly improved, showing an increment to 285 mL/L/day in phase 2. Meanwhile, the VSS removal and methane production in phase 5 were greatly decreased when the raw sludge without any pre-treatment was applied to the combined process. Considering all together, it was concluded that the combined process with the thickened sludge recirculation and thermal-alkaline pre-treatment can be successfully employed for the highly efficient sewage sludge reduction and methane gas production.