• Title/Summary/Keyword: 수화학해석

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Halloysite Formation by the Alteration of Trachytic Glass in Ulleung Island (울릉도 조면암질 유리의 변절에 의한 할로이사이트의 생성)

  • Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.2
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    • pp.111-118
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    • 2011
  • Hydrated halloysite was formed by the low temperature alteration of trachytic tuff in onion-like spherical or curly platy forms. The Si content was higher than that of ideal kaolin minerals, indicating the possible presence of amorphous materials. The high Fe content is responsible for the platy morphology of halloysite. The leached ions precipitated as halloysite filling the interparticle pores, while trachytic glass was replaced by Si-rich amorphous materials in an hemispherical form, which was further evolved into spherical halloysite. Halloysite is one of the major alteration products of the volcanic ash in Ulleung Island underwent intense trachytic volcanism.

Hydraulic Reaction Analysis of C3A in Ordinary Portland Cement with Mineral Additions by Rietveld Method (리트벨트법에 의한 혼합재 첨가 보통 포틀랜드 시멘트 중 C3A 수화반응 해석)

  • Lim, Young-Jin;Lee, Seung-Heun;Cho, Jae-Woo
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.82-87
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    • 2014
  • Due to the revised Korean standard KS L 5201 for Ordinary Portland Cement (OPC), the use of mixed cement has grown from 5% to 10%. This study investigates the hydration behavior of $C_3A$, asit is a cement mixture that is more commonly used than granulated blast furnace slag or limestone alone. Paste samples were prepared with either granulated blast furnace slag or limestone alone. Each sample was compared with the widely used Rietveld method with a cement mixture containing blast furnace slag or limestone. The hydration behavior of $C_3A$ in each OPC sample was assessed and results were analyzed. Granulated blast furnace slag promotes a high initial level of ettringite, but as the days passed, it promotes an increase in monosulfate, leading to cracks and expansion due to the penetration of sulfates in the solution. However, when limestone is added to the mixture, a transformation of ettringite to monosulfate occurs in the presence of the $CaCO_3$ in the limestone. It is considered that this produces hemi-carbonate and mono-carbonate and thus maintains the ettringite level.

Design and Construction of the Burj Dubai Concrete Building Project (버즈 두바이 콘크리트 건물의 설계와 시공)

  • Abdelrazaq, Ahmad
    • Magazine of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.28-35
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    • 2008
  • The Burj Dubai Project will be the tallest structure ever built by man; when completed the tower will be more than 700 meter tall and more than 160 floors. While the early integration of aerodynamic shaping and wind engineering considerations played a major role in the architectural massing and design of this multi-use/residential tower, where mitigating and taming the dynamic wind effects was one of the most important design criteria, the material selection for the structural systems of the tower was also a major consideration and required detailed evaluation of the material technologies and skilled labor available in the market at the time Concrete was selected for its strength, stiffness, damping, redundancy, moldability, free fireproofing, speed of construction, and cost effectiveness. In addition, the design challenges of using concrete for the design of the structural system components will be addressed. The focus on this paper will also be on the early planning of the concrete works of the Burj Dubai Project.

Preliminary Study on the Formation Environment of Serpentinite occurring in Ulsan Area (울산지역 사문암의 형성환경 해석을 위한 예비연구)

  • Koh, Sang-Mo;Park, Choong-Ku;Soh, Won-Ju
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.325-336
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    • 2006
  • Domestic serpentinite is one of the important industrial minerals utilizing in the iron manufacturing company such as POSCO in Korea. Serpentinite is distributed in the Ulsan Fe deposit, Andong, Hongseong-Cheongyang, and Gapyeong areas. This study tries to interpret the relationship among the formation of carbonate rocks, iron mineralization, and serpentinite alteration throughout the study of field occurrence, mineralogy, and chemical compositions. Serpentine is formed by the break-down of olivine and pyroxene of parent peridotite. The serpentinization is inferred to be formed by the hydrothermal fluid derived from intruded Cretaceous granite and the addition of meteoric water. Variation of major oxides such as $SiO_2,\;Fe_2O_3$, and MgO in serpentinized rocks are controlled by the degree of serpentinization and Fe mineralization. Variation of $Al_2O_3$ and CaO contents of altered rocks is dependent on the amount of the residual minerals such as calcite and homblende, and on the degree of chloritization. The presence of carbonate rocks reported in the sedimentary origin or igneous origin (carbonatite) provided a geological environment to form skarn type Fe deposit regardless of its origin. The geological processes of Ulsan Fe deposits are inferred to be formed as the order of the formation of carbonate rocks ${\to}$ the intrusion of Cretaceous granite ${\to}$ serpentinization ${\to}$ Fe mineralization by the interprelation of field occurrence and mineralogical characteristics.

Lithium Distribution in Thermal Groundwater: A Study on Li Geochemistry in South Korean Deep Groundwater Environment (온천수 내 리튬 분포: 국내 심부 지하수환경의 리튬 지화학 연구)

  • Hyunsoo Seo;Jeong-Hwan Lee;SunJu Park;Junseop Oh;Jaehoon Choi;Jong-Tae Lee;Seong-Taek Yun
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.729-744
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    • 2023
  • The value of lithium has significantly increased due to the rising demand for electric cars and batteries. Lithium is primarily found in pegmatites, hydrothermally altered tuffaceous clays, and continental brines. Globally, groundwater-fed salt lakes and oil field brines are attracting attention as major sources of lithium in continental brines, accounting for about 70% of global lithium production. Recently, deep groundwater, especially geothermal water, is also studied for a potential source of lithium. Lithium concentrations in deep groundwater can increase through substantial water-rock reaction and mixing with brines. For the exploration of lithim in deep groundwater, it is important to understand its origin and behavior. Therefore, based on a nationwide preliminary study on the hydrogeochemical characteristics and evolution of thermal groundwater in South Korea, this study aims to investigate the distribution of lithium in the deep groundwater environment and understand the geochemical factors that affect its concentration. A total of 555 thermal groundwater samples were classified into five hydrochemical types showing distinct hydrogeochemical evolution. To investigate the enrichment mechanism, samples (n = 56) with lithium concentrations exceeding the 90th percentile (0.94 mg/L) were studied in detail. Lithium concentrations varied depending upon the type, with Na(Ca)-Cl type being the highest, followed by Ca(Na)-SO4 type and low-pH Ca(Na)-HCO3 type. In the Ca(Na)-Cl type, lithium enrichment is due to reverse cation exchange due to seawater intrusion. The enrichment of dissolved lithium in the Ca(Na)-SO4 type groundwater occurring in Cretaceous volcanic sedimentary basins is related to the occurrence of hydrothermally altered clay minerals and volcanic activities, while enriched lithium in the low-pH Ca(Na)-HCO3 type groundwater is due to enhanced weathering of basement rocks by ascending deep CO2. This reconnaissance geochemical study provides valuable insights into hydrogeochemical evolution and economic lithium exploration in deep geologic environments.

Prediction of the Minimum Required Pressure of Soundless Chemical Demolition Agents for Plain Concrete Demolition (무근콘크리트 해체시 무소음화학팽창제의 최소요구팽창압 예측)

  • Kim, Kyeongjin;Cho, Hwangki;Sohn, Dongwoo;Koo, Jaehyun;Lee, Jaeha
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.5
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    • pp.251-258
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    • 2018
  • In construction site, conventional methods such as jackhammer or explosive methods(dynamite) have been often used for the demolition of structures. Use of those methods are more carefully treated in environmentally and historically sensitive area. For those reasons, use of Soundless Chemical Demolition Agent(SCDA) is getting the spotlight. The SCDA is a powder which has expansive strength when it is mixed with water. In these Characteristics, SCDA can destroy the concrete or rock as it is poured into boreholes of the concrete or rock structures. However, there is no industrial standard for the use of SCDA effectively yet. In this study, experimental study to measure the expansive pressure was conducted depending on various boundary conditions such as waterproof, length of the steel pipe, submerged of steel pipe. Furthermore, computational analysis using damage plasticity model to predict the minimum required pressure of the SCDA for the concrete demolition depending on spacing between holes(k-factor) and compressive strength of the concrete was conducted. Obtained results indicates that water heat dissipation with submerged steel pipe shows the stable pressure for measuring the SCDA and hole distance(k-factor) is the most important factor for crack initiation of concrete.

Study on the Crack Control Effect of Moist Curing Equipment in Side Wall of Building (습윤양생 장치를 이용한 아파트 측벽 균열제어에 관한 연구)

  • Kim, Dae-Geon;Lee, Dong-Woon
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.127-134
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    • 2017
  • In this study, moist curing equipment was used in the exist gang-form system. By achieving sufficient spray curing, the quality of the concrete was improved and the cracking occurred in building's side wall was decreased. The following results could be made as the conclusion. For the compressive strength, all zones showed the similar results. Comparing with the zone without using moist curing equipment, the zone used moist curing equipment showed higher rebound hardness results. For the cracking, the zone utilized moist curing equipment showed the cracking averaged as 6.6 m and the zone without using moist curing equipment showed the cracking averaged as 10.3m. The effectof reducing cracking by utilizing moist curing equipment is about 36 %. Using moist curing equipment is considered as a good solution to reduce the cracking in the structure. Considering all the factors analysed, using moist curing equipment improved the quality of the concrete and decreased the cracking. When this equipment was used in the construction site, it is expected that the construction periodcan be shrunk and the ratio of defect caused by drying shrinkage can be decreased. In this research conditions, The 0.3mm sized moist curing equipment provided the most desirable results on concrete quality and preventing cracking.

Interpretation of Kim Hwan-ki's Curvilinear Signifier -Centered on New York Period- (수화 김환기의 만곡기표의 해석 -뉴욕시대를 중심으로-)

  • Lee Hyun-Kyung
    • Journal of Science of Art and Design
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    • v.6
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    • pp.5-32
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    • 2004
  • Kim Hwan-ki's New York Period works consistently present, as the central signifier, a curvilinear paradigm which has been derived from his creative consciousness. The purpose of this study is to bring to light what exists behind curvilinear paradigms; a fusion of history and society with the artist's individual consciousness as a fused aspect of history and society. To make this aspect suitably understood, this study focuses on curvilinear signifier which are analyzed and considered objectively. The results of which are as follows: It is a representative example of transforming a curved line which is the modern quotation of traditional Korean art, most directly works done in porcelain. He takes the aesthetic consciousness of Korean art as the power of his works and takes aim at the collective consciousness of all races. Looking through the background of his times, his artistic subject was to find the ethic characteristics of our excellent tradition and highlight them in his art. To him, art is not about making the most of a skill but instead about allowing one's inner spirit sing it's own song. This thought is conveyed in curvilinear signifier of his works. Therefore this study has asserted that Kim Hwan-ki's curvilinear signifier in his New York Period works has strong ties to the cultural vein of Korean history and society at it's base as well as simply in his individual level. This assertion is not to set form in a superior position as a Formalist but to show form as having the will to deal with the significance of an artist's mode by interpreting the experience of the interpreter.

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The Study of Facial Hair Weakening Ability Using Urea or Anti-oxidants for Shaving (우레아 및 항산화제를 이용한 면도를 위한 수염 강도 약화 연구)

  • Kim, Il Gu;Han, Na Kyung;Kim, Sun Young;Han, Jong Sub
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.3
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    • pp.279-284
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    • 2016
  • In this study, facial hair weakening ability of urea and anti-oxidants for shaving was investigated. The hair weakening ability and cross-section increase of hair depends on concentration of urea. The results showed that urea affects swelling of hair and this is related to the hair weakening ability. Anti-oxidants showed outstanding weakening ability despite of their low concentrations by breaking disulfide bond in facial hair. To evaluate the suitability of urea and anti-oxidants for facial cosmetic products, in vitro safety tests were proceeded. The results showed that urea and glutathione were safe for face. As a result, urea and glutathione were safe and outstanding as hair weakening agent for cosmetic shaving products.

Mineralogical Properties and Paragenesis of H-smectite (H-스멕타이트의 광물학적 특성과 생성관계)

  • Noh, Jin-Hwan;Hong, Jin-Sung
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.377-393
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    • 2010
  • Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.