• Title/Summary/Keyword: 수전해

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A Prediction Scheme for Power Apparatus using Artificial Neural Networks (인공신경망을 이용한 수전설비 고장 예측 방법)

  • Ki, Tae-Seok;Lee, Sang-Ho
    • Journal of Convergence for Information Technology
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    • v.7 no.6
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    • pp.201-207
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    • 2017
  • Failure of the power apparatus causes many inconveniences and problems due to power outage in all places using power such as industry and home. The main causes of faults in the Power Apparatus are aging, natural disasters such as typhoons and earthquakes, and animals. At present, the long high temperature status is monitored only by the assumption that a fault occurs when the temperature of the power apparatus becomes higher. Therefore, it is difficult to cope with the failure of the power apparatus at the right time. In this paper, we propose a power apparatus monitoring system as an efficient countermeasure against general faults except for faults caused by sudden natural disasters. The proposed monitoring system monitors the power apparatus in real time by attaching a thermal sensor, collects the monitored data, and predicts the failure using the accumulated information through learning using the artificial neural network. Through the learning and experimentation of artificial neural network, it is shown that the proposed method is efficient.

A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
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    • v.29 no.2
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    • pp.1-9
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    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

A Study on the Analysis of Safety Standard and Evaluation of Safety Performance for the 5 Nm3 /hr Class Alkaline Water Electrolysis System (5 Nm3 /hr급 알카라인 수전해 시스템 안전기준 분석 및 안전성능 평가에 관한 연구)

  • Kim, Ji-Hye;Lee, Eun-Kyung;Kim, Min-Woo;Oh, Gun-Woo;Lee, Jung-Woon;Kim, Woo-Seop
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.65-75
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    • 2018
  • The wind energy produced at night is being discarded because of the excess power generated at night compared to daytime. To solve this problem, In this study, we analyzed the evaluation contents for evaluation of domestic and overseas water electrolysis systems and drew contents for safety performance contents test of the water electrolysis system based on the evaluation contents. The test contents produced the efficiency measurement test, the hydrogen generated pressure test, and the hydrogen purity test. And the safety performance evaluation of the alkaline water electrolysis system of $5Nm^3/hr$ was performed based on the results. As a result, the hydrogen generation was calculated as $5.10Nm^3/hr$ and the stack efficiency was $4.97kWh/Nm^3$. The purity of the hydrogen generated was 99.993% and it was confirmed that it produced high purity hydrogen. I think will help us assess and build safety performance of water electrolysis systems in the future.

Development of Molecular Dynamics Model for Water Electrolysis Ionomer (수전해용 이오노머 분자동역학 모델 개발)

  • Kang, Hoseong;Park, Chi Hoon;Lee, Chang Hyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.433-442
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    • 2020
  • In this study, in order to build a molecular dynamics simulation model of ionomer for water electrolysis, an ionomer model that reflects the characteristics of a water electrolysis system in which excess water molecules exist was compared to an ionomer built according to the conventional simulation method of the fuel cells membrane. The final ionomer MD models have a strong phase separation and water channel that is one of the important characteristics of the perfluorinated ionomer, and are stable and water-insoluble under excessive water and high temperature conditions. In the ionomer MD models built in this study, the excess water molecules decrease an ion conductivity due to the dilution of ions, but increase a hydrogen diffusivity. Therefore, it is necessary to design the molecular structure of ionomers for water electrolysis in experimental studies as well as molecular dynamics studies according to the characteristics of the water electrolysis system reported in this study.

Research and Development Trends in Seawater Electrolysis Systems and Catalysts (해수 수전해 시스템 및 촉매 연구 개발 동향)

  • Yoonseong Jung;Tuan Linh Doan;Ta Nam Nguyen;Taekeun Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.567-575
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    • 2023
  • Water electrolysis is undergoing active research as one of the promising technologies for producing effective green hydrogen. Using seawater directly as a raw material for a water electrolysis system can solve the problem of the limitations of existing freshwater raw materials, as seawater accounts for approximately 97% of the water on Earth. At the same time, abundant by-product materials can be obtained, representative examples of which are Cl2, ClO-, Br2, and Mg(OH)2 produced during electrolysis, depending on their composition and pH environment. In order to develop a successful seawater electrolysis system and oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) catalysts, it is necessary to understand the causes and consequences of reactions that occur in the seawater environment. Therefore, in this paper, we will investigate the reaction mechanism and characteristics of the seawater electrolysis system as well as the research and development trends of electrochemical catalysts used in anode and cathode electrodes.

A study on electric facilities of water supply according to the revisions of electric field standard (전기분야 관련기준 개정에 따른 수도사업장 수전설비 구성방안 연구)

  • Sul, Jae-Hun;Park, Jong-Sun;Cho, Yong-Sung
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.414-415
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    • 2011
  • 한국전력공사의 전기공급약관 개정('10.11.01)으로 저압 수전범위가 현행 계약전력 100kW 미만에서 500kW 미만으로 확대됨에 따라 500kW 미만의 경우 수용가에서 저압 또는 고압 수전방식 선택이 가능하여 수도사업장 수전방식 선정 기법 및 저압 수전설비 표준구성방안을 수립하였으며, '10.1.8. "전기설비기술기준의 판단기준"의 개정으로 서지보호기 설치의무사항이 신설되어 수도사업장 구내 배전계통 서지보호기 설치구성방안을 수립하였다.

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Synthesis and Characterization of Oxygen Evolution Nanofiber electrocatalyst for Water Electrolysis (수전해 산소발생을 위한 나노섬유 전기화학 촉매 합성 및 특성분석)

  • Won, Mi-So;Jang, Myeong-Je;Lee, Gyu-Hwan;Choe, Seung-Mok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.186-186
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    • 2016
  • 수소는 연료전지 등의 에너지원으로 사용될 경우 NOx, SOx, $CO_2$ 등의 한경오염물질, 온실가스를 발생시키지 않기 때문에 친환경 에너지원으로 각광을 받고 있다. 수전해는 수소를 생산하는 가장 간단하고 효율적인 방법 중의 하나로서, 잉여전력 또는 신재생에너지에 의한 전기에너지를 통해 환경오염물질 발생 없이 고순도의 수소를 얻을 수 있으며 분산/대량 생산이 용이하다. 수전해에서 환원전극에서는 수소발생반응이 일어나고, 산화전극에서는 산소발생반응이 일어난다. 이때 주로 산소발생전극 촉매로는 과전압이 작게 걸리고 활성이 우수한 귀금속 계열의 $IrO_2$$RuO_2$ 등의 촉매가 현재 사용되고 있다. 본 연구에서는 고분자 용액을 만들어 전기방사를 이용하여 공정변수에 따른 직경과 morphology를 확인하였고, 고가의 귀금속 산화물 대신 저렴한 전이금속산화물인 Cu와 Co를 이용하여 1D 나노섬유를 산소발생 촉매로 합성하였다. 합성된 나노섬유의 구조적, 물리화학적 특성을 분석하고 산소발생반응(OER)에 대한 전기화학적 활성 및 내구성을 평가하였다.

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The thermal stabilization characteristics of electrolyte membrane in high temperature electrolysis[HTE] (고온 수전해 전해질 막의 열안정화 특성 고찰)

  • Choi, Ho-Sang;Son, Hyo-Seok;Sim, Kyu-Sung;Hwang, Gab-Jin
    • Journal of Hydrogen and New Energy
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    • v.16 no.2
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    • pp.150-158
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    • 2005
  • Added ratio of 8YSZ powder and organic compounds (solvent, plasticizer, dispersant, binder) properly. It manufactured electrolysis membrane by wet process that make slurry and dry process that do not use organic compounds. In the case of wet process, harmony combination and method of organic compound are an importance element in slurry manufacture. This slurry did calcine at temperature of 140$^{\circ}C$ in Furnace and manufactured electrolyte disk by Dry pressing method. Like this, manufacturing disk sintered at temperature of $1300^{\circ}C,\;1400^{\circ},\;1500^{\circ}C$ in Furnace and completed electrolysis membrane. Confirmed change of crystal structure and decision form through analysis of density, SEM, XRD according to change of sintering temperature, and considered relation with ion conductivity.

Economic Evaluation of Domestic Low-Temperature Water Electrolysis Hydrogen Production (국내 저온수전해 수소생산의 경제성 평가)

  • Gim, Bong-Jin;Kim, Jong-Wook;Ko, Hyun-Min
    • Journal of Hydrogen and New Energy
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    • v.22 no.4
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    • pp.559-567
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    • 2011
  • This paper deals with an economic evaluation of domestic low-temperature water electrolysis hydrogen production. We evaluate the economic feasibility of on-site hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ by the alkaline and the polymer electrolyte membrane water electrolysis. The hydrogen production prices of the alkaline water electrolysis, the polymer electrolyte membrane water electrolysis, and the steam methane reforming hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ were estimated as 18,403 $won/kgH_2$, 22,945 $won/kgH_2$, 21,412 $won/kgH_2$, respectively. Domestic alkaline water electrolysis hydrogen production is evaluated as economical for small on-site hydrogen fueling stations, and we need to further study the economic evaluation of low-temperature water electrolysis hydrogen production for medium and large scale on-site hydrogen fueling stations.

High Temperature Characteristics of Commercially Available Anion Exchange Membrane for Alkaline Water Electrolysis (알칼리 수전해를 위한 상용 음이온교환막의 고온 특성)

  • JANG, SU-YOEN;RYU, CHEOL-HWI;HWANG, GAB-JIN
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.330-336
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    • 2022
  • In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.