• Title/Summary/Keyword: 소다

Search Result 319, Processing Time 0.021 seconds

Studies on the Sequestering Agents to Replace Silicate in Peroxide Bleaching System (과산화수소 보존표백시 Silicate 대체 약품에 관한 연구)

  • Kim, Sung-Kwon;Choung, Sung Wook;Michalowski, R.J.
    • Applied Chemistry for Engineering
    • /
    • v.9 no.5
    • /
    • pp.754-757
    • /
    • 1998
  • This study was carried out to investigate the effect of replacing silicate by Versenate PS peroxide stabilizer in a peroxide bleaching system of deinked pulp process. To evaluate the possibility of replacement, optimization of pretreatment and caustic in bleaching for stock treated with silicate and Versenate PS were performed. After these performance, residual peroxide content and brightness were measured. Results obtained form this study were summarized as follows : 1. Caustic concentration in bleaching system treated with silicate was optimized at 2.5~3.0%. 2. Caustic concentration in bleaching system treated with Versenate PS was optimized at 1.0~1.5%. 3. Versenate PS alone did not provide satisfying bleaching effect. 4. Bleaching system treated with Versenate PS had potential to reduce silicate. 5. DTPA pretreatment provided higher bleaching efficiency.

  • PDF

Analysis of the relationship between soda-lime glass composition and viscosity calculated by Lakatos model (Lakatos 모델로 계산한 소다석회유리 점도와 조성과의 관계 분석)

  • Kang, Seung Min;Kim, Chang-sam
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.32 no.6
    • /
    • pp.246-250
    • /
    • 2022
  • An estimation method of glass viscosity using Lakatos model is one of the best way to calculate the viscosity of soda-lime glass. The glass viscosity is obtained by inputting a glass composition consisting of SiO2, Al2O3, Na2O, K2O, CaO and MgO to the Lakatos model. A series of composition of glass bottles was obtained once a month for 10 months from a soda-lime glass bottle fabrication line and isokom temperatures at the viscosity of log η = 3, 6.6, 10 and 12.3 were calculated. It was found that the isokom temperature at log η = 3 and log η = 6.6 was closely related to the value of (Si+Al)/O and 1/Na, respectively.

The Role of Geocrete and Soluble Sodium Silicate as a Substitute to Control Leachate Leaking from Landfill Side Wall (Geocrete와 규산소다액을 이용한 매립지 사면 침출수 누출제어)

  • 조재범;현재혁;나진성;김자영
    • Journal of the Korean Geotechnical Society
    • /
    • v.17 no.6
    • /
    • pp.47-51
    • /
    • 2001
  • There are two strategies to cope with the troubles in landfill site after closure. The first method is active in a way that the wastes are dug up and the recyclable materials are reutilized, meanwhile the materials not recyclable are incinerated in order to minimize the volume of residues to be disposed of. The second method is rather passive and defensive in a way that the source of contamination, that is, buried wastes are not treated. Instead, the transport of leaking leachate and gases generated from the wastes are intercepted and controlled. In this study, as a passive way of the efficient leachate blocking process, applicabilities of geocrete and soluble sodium silicate as a substitute to control leachate leaking from landfill sidewall were investigated. In case of compression test, the strength of mixture I (Geocrete:Sodium silicate=1:3.9 v/v) and mixture II (Geocrete:Sodium silicate=1:2.5 v/v), even after 7 days' curing was higher than the minimum allowance to tolerate the loading(5 kg/$\textrm{cm}^2$). Soaking in the acid fur 4 days and 7 days respectively, the compressive strength of the specimens reduced seriously. The toxicity of geocrete is not detected through the bioassay test, once it was mixed with sodium silicate and the complex was formed. The hydraulic conductivity of the mixtures even after 7 days' curing was lower than the threshold limit $(1.0\times10_{-7}cm/s)$.

  • PDF

Characteristic Analysis of Chemical Compositions for Ancient Glasses Excavated from the Sarira Hole of Mireuksaji Stone Pagoda, Iksan (익산 미륵사지 석탑 사리공 내 출토 고대 유리 유물의 성분특성 분석)

  • Han, Min Su
    • Journal of Conservation Science
    • /
    • v.33 no.3
    • /
    • pp.215-223
    • /
    • 2017
  • The purpose of this study is to reveal the characteristics, correlations, and colorant materials of those using the chemical compositions of 30 glasses excavated from the Sarari hall of the Mireuksaji stone pagoda, and to determine the correlations between them and other glass excavated from the Wanggungri site. The results of the chemical analysis of the 11 glass beads show that they are a soda glass group with high contents of $SiO_2$ and $Na_2O$; these can be further subdivided into soda-alumina groups ($Na_2O-Al_2O_3-CaO-Si_2O$). The characteristics of the stabilizer are classified as being of the high alumina glass group (LCHA), except for two glasses. It was concluded that colorant materials affected the coloring for glass beads by various components including Ti, Mn, Fe, Cu and Pb. In addition, we examined six lead glasses which are glass plate and unknown fragments that are of a common lead glass system ($PbO-SiO_2$) with respect to the average contents of PbO (70wt.%) and $SiO_2$ (30wt.%). As a result of comparing these relics with those of the glass beads excavated by Wanggungri, there is a similarity in that they belong to the soda glass group. However, the contents of $Na_2O$ are relatively higher than that of the glass beads in the Mireuksaji pagoda, and most of relics include glasses with a low content of $K_2O$ and CaO. In addition, the PbO and $SiO_2$ contents are slightly different in the lead glass. It seems that the glass relics made at two different sites may have used different raw materials or techniques.

Potential of Coal Gasification Slag as an Alkali-activated Cement (석탄가스화 복합발전 슬래그의 알칼리 활성 시멘트로서의 가능성)

  • Kim, Byoungkwan;Lee, Sujeong;Chon, Chul-Min;Choi, Hong-Shik
    • Resources Recycling
    • /
    • v.27 no.2
    • /
    • pp.38-47
    • /
    • 2018
  • Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.

CFD Analysis on the Internal Reaction in the SNCR System (SNCR 시스템 내부의 물질 반응에 관한 전산해석적 연구)

  • Koo, Seongmo;Yoo, Kyung-Seun;Chang, Hyuksang
    • Clean Technology
    • /
    • v.25 no.1
    • /
    • pp.63-73
    • /
    • 2019
  • Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

Composition Classification of Korea Ancient Glasses by Using Raman Spectroscopy (라만분광분석법을 이용한 한국 고대 유리의 조성 분류)

  • Sim, Woo Seok;Kim, Eun A;Lim, Soo Yeong;Kim, Hyung Min;Kim, Gyu Ho
    • Journal of Conservation Science
    • /
    • v.38 no.2
    • /
    • pp.117-123
    • /
    • 2022
  • In this study, investigated the possibility of quantitatively and qualitatively analyzing Korean ancient glasses via Raman Spectroscopy. We subjected four categories of Korean traditional glasses, namely, lead-BaO, lead, potash, and soda glasses (3, 3, 10, and 10 pieces, respectively), to this analytical technique. The results showed significant differences between the stretching and bending Raman vibration regions corresponding to these different Korean ancient glass types. Specifically, the stretching vibration regions corresponding to lead-BaO and lead glasses showed peaks at 1040 and 1000 cm-1, respectively; the stretching vibration region of normal glass appears at 1100 cm-1. The bending vibration regions corresponding to potash and soda glass showed Raman peaks at 490 and 560 cm-1, respectively. Furthermore, the Raman spectra of the lead and lead-BaO glasses showed red shifts, which depended on the amount of PbO present. Thus, our findings highlighted the possibility of quantitatively determining the amount of PbO, a major component of lead glasses, via Raman Spectroscopy.

지식 365$^+$: 평가원 리포트1 - 등급판정결과로 살펴본 육우사육 현황

  • Baek, Jang-Su
    • KAPE Magazine
    • /
    • s.189
    • /
    • pp.6-9
    • /
    • 2012
  • 육우는 일반적으로 홀스타인의 수소나 미경산 암소를 비육하여 출하하는 고기소다. 홀스타인 자체가 우유생산을 목적으로 개량되어 옴에 따라 다른 육용종 소에 비해 육질적인 측면에서 불리한 부분이 있지만 사양관리 방법에 따라 등급판정결과는 크게 달라질 수 있다. 따라서 지난해 등급판정결과에 대한 분석을 통해 육우사육의 현황과 앞으로의 방향에 대해 살펴보기로 하자.

  • PDF