• Proceedings of the Korean Fiber Society Conference
• /
• 2007.11a
• /
• pp.27-30
• /
• 2007

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.10b
• /
• pp.277-278
• /
• 2003

키틴은 셀룰로오스와 더불어 자연계에 가장 많이 존재하는 천연고분자(선형다당)로서 $\beta$(1$\longrightarrow$4)-2-deoxy-2-acetamido-D-glucopyranose를 기본단위로 하고, 키토산(chitosan)은 천연적으로는 몇몇 미생물에서 발견되며, 키틴의 탈아세틸화반응(deacetylation)에 의해 생성되는 유도체로서 $\beta$(1$\longrightarrow$4)-2-deoxy-2-amino-D-glucopyranose를 기본단위로 한다는 점에서 상이하다. 하지만 키틴과 키토산은 각 기본단위가 반복된 homopolymer가 아니고 서로 일정 정도의 상대 기본단위를 함유하므로 일종의 공중합체 또는 heteropolymer라고 할 수 있으며, 그 조성비 즉 탈아세틸화도 (degree of deacetylation, 이하 DD)에 따라 키틴과 키티산으로 나누어진다.[1] (중략)

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.10b
• /
• pp.157-158
• /
• 2003

키틴은 N-acethyl-D-glucosamine이 $\beta$-(1$\longrightarrow$4) 결합한 천연 고분자이며, 게나 새우 등의 갑각류, 오징어 등의 연체류, 그리고 곤충류 및 균류의 세포벽 등에 광범위하게 분포되어 있다. 키틴은 지구상에 존재하는 천연 다당류 중에 셀룰로오스 다음으로 많은 양이 존재하며 흡착성, 보습성, 유화성 및 생분해성을 가진 무독성 물질이고 항균작용, 생체적합성 등 다양한 특성을 기능을 가진다. 그러나, 분자내에 존재하는 아세트아미노기가 분자간의 수소결합으로 매우 강하게 결합되어 있기 때문에 화학약품에 대한 내성이 강할 뿐만 아니라 물과 대부분의 일반 유기용매에 녹지 않기 때문에 그 용도가 한정되어 있다. (중략)

• Polymer(Korea)
• /
• v.37 no.5
• /
• pp.613-617
• /
• 2013

The effects of nano size kenaf cellulose fiber on mechanical property of polypropylene (PP) composite were investigated. The addition of nano-kenaf in place of natural kenaf showed higher tensile strength, flexural strength, impact strength, and heat deflection temperature compared to the natural kenaf filled PP composite, while it shows lower melt flow index, elongation%, and flexural modulus. These seemed to be due to the increased surface area of nano-kenaf fiber contacting PP matrix and reduced impurities such as volatile extractives on the fiber surface.

• Journal of the Korea Institute of Building Construction
• /
• v.7 no.3
• /
• pp.83-90
• /
• 2007

This study is to investigate the effects of nylon(NY) and cellulose(CEL) fiber contents on the mechanical properties of the concrete. The results were summarized as following. Test showed that increase of NY and CEL fiber contents decreased fluidity of fresh concrete, so the loss of the fluidity would be considered when they were over added. Air contents were slight increased, but they satisfied the target air content. Bleeding capacity of concrete containing fiber significantly was declined. In addition, concrete containing higher amounts of fiber retarded setting time remarkably. Plastic shrinkage crack was reduced with the use of fiber due to increasing fiber contents and changing fiber classes, and NY fibers to prevent the plastic shrinkage crack effectively. Compressive and tensile strength of almost specimens were increased when air contents of the fresh concrete were fixed according to fiber contents, and flexural strength was increased according to fiber contents. For the impact strength of specimens, the specimen containing $0.6kg/m^3$ of NY fibers, showed the most favorable impact strength, The fiber reinforced concrete using NY fibers exhibited superior mechanical performance, and it was considered that $0.6kg/m^3$ of was desirable as the most favorable adding amount.

• Korean Chemical Engineering Research
• /
• v.52 no.4
• /
• pp.430-435
• /
• 2014

Physical and chemical barriers, caused by the close association of the main components of cellulosic biomass, hinder the hydrolysis of cellulose to fermentable sugars. Since the main goal of pretreatment is to increase the enzyme accessibility improving digestibility of cellulose, development of an effective pretreatment process has been considered to be important. In this study, SAA (Soaking in Aqueous Ammonia) was chosen as pretreatment because this is the simple and low-cost method. Rice straw of which the production is outstandingly high in domestic agriculture residues in Korea was chosen as raw material. SSA pretreatment with various reaction time of 3 h to 72 h was tested. The enzymatic hydrolysis and SSF (Simultaneous Saccharification and Fermentation) were performed at three different temperature (30, 40 and $50^{\circ}C$) to investigate performance of SSF upon various pretreatment conditions. As a result, this SAA treated-rice straw was found to have great potential for effective enzymatic hydrolysis and SSF with lower enzyme dosage at lower temperature ($30^{\circ}C$) than its conventional SSF. In SAA addition, SAA reduced fermentation time to 24 h owing to increase the initial hydrolysis rate substantially.

• Journal of the Korean Wood Science and Technology
• /
• v.44 no.3
• /
• pp.398-405
• /
• 2016

The cellulose nanofibers (CNFs) were prepared by wet disk-milling (WDM) and fractionated by settling method into supernatant, middle and sediment fractions. The diameter and its distribution of the fractionated CNFs were investigated. With increasing WDM passing number, precipitation became delayed. Weight fraction at sediment fraction was decreased, whereas those at supernatant and middle fractions were increased with increasing WDM passing number. Diameter distribution of CNFs at supernatant fraction was narrowest and became broaden at middle and sediment fraction. Filtration time was longer in order of supernatant, middle and sediment fraction.

• Korean Journal of Agricultural Science
• /
• v.3 no.2
• /
• pp.225-234
• /
• 1976

To elucidate ${\beta}$-glucosidase formation on various carbon scurces by cellulolytic bact-eia, Cellulomonas sp. CS1-1, the strain was grown on Nutrient Yeast Broth, carboxymethyl cellulose, avicel and cellobiose using a Ouickfit FVIL fermentor operated in batch, and the growth characteristics on those substrates and ${\beta}$-glucosidase distribution of extra and intracellular enzyme components were studied. The results were: 1) ${\beta}$-glucosidase was always intracellular, and was formed under all growth conditions tested, ii) but levels of relative activities were higher when the culture was grown on cellobiose and on avicel, iii) the relative activities were always maximum during the growth phase of the organism irrespective of the substrate used.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.10a
• /
• pp.311-314
• /
• 1999

This study is aim to evaluate of the flexural performance of specialty cellulose fiber reinforced concrete. Flexural test is proceeded by third-point loading method and the size of the test specimens is 15$\times$15$\times$55cm. The rate of loading was 0.006mm/min. The effects of differing fiber volume fraction(0.08%, 0.1%, 0.15%) were studied. The results of test on the specialty cellulose fiber reinforced concrete were compared with plain and polypropylene fiber reinforced concrete. Results indicated that specially cellulose fiber reinforcement showed an improvement of flexural performance.

• Textile Coloration and Finishing
• /
• v.4 no.3
• /
• pp.91-96
• /
• 1992

The crystalline character of NaOH and KOH-cellulose complex having different tension ratio was studied using X-ray diffraction analysis. Cellulose crystalline lattices in tension alkali treatment cotton were identified by measuring and indexing the 101, 101, and 002 reflections. According as alkali treatment tension ratio increased on, cellulose gave rise to the formation of I rather than cellulose II. It seemed that a part of the fine structure of cellulose increased orientation with antiparaell and parallel chain crystal structure. The high tension ratio alkali treatment cotton resulted in lower dye sorption and in higher breaking strength and crease recovery.