• Title/Summary/Keyword: 석유 산업

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Development of a Deterministic Optimization Model for Design of an Integrated Utility and Hydrogen Supply Network (유틸리티 네트워크와 수소 공급망 통합 네트워크 설계를 위한 결정론적 최적화 모델 개발)

  • Hwangbo, Soonho;Han, Jeehoon;Lee, In-Beum
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.603-612
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    • 2014
  • Lots of networks are constructed in a large scale industrial complex. Each network meet their demands through production or transportation of materials which are needed to companies in a network. Network directly produces materials for satisfying demands in a company or purchase form outside due to demand uncertainty, financial factor, and so on. Especially utility network and hydrogen network are typical and major networks in a large scale industrial complex. Many studies have been done mainly with focusing on minimizing the total cost or optimizing the network structure. But, few research tries to make an integrated network model by connecting utility network and hydrogen network In this study, deterministic mixed integer linear programming model is developed for integrating utility network and hydrogen network. Steam Methane Reforming process is necessary for combining two networks. After producing hydrogen from Steam-Methane Reforming process whose raw material is steam vents from utility network, produced hydrogen go into hydrogen network and fulfill own needs. Proposed model can suggest optimized case in integrated network model, optimized blueprint, and calculate optimal total cost. The capability of the proposed model is tested by applying it to Yeosu industrial complex in Korea. Yeosu industrial complex has the one of the biggest petrochemical complex and various papers are based in data of Yeosu industrial complex. From a case study, the integrated network model suggests more optimal conclusions compared with previous results obtained by individually researching utility network and hydrogen network.

Performance Evaluation for the A/O Pure-Oxygen Biofilm (POB) Process on the Removal of Organics and TKN in the Industrial Wastewater (혐기/호기 순산소 생물막공법에 의한 산업폐수의 유기물 및 TKN 제거 성능평가)

  • Jang, Am;Kim, Hong Suck;Kim, In S.
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.837-847
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    • 2000
  • For the treatment of wastewaters generated from beer industry and petrochemical company with high organic and nitrogen contents, laboratory scale of A/O Pure-Oxygen Biofilm (POB) process was developed and studied by means of the comparative economic analysis with extended aeration process. When the wastewater of beer company was initially treated by the A/O POB process in the ranges of 70 to 150 mg TOC/L diluted with tap water, higher than 92% of TOC removal was accomplished in the all ranges. In case of petrochemical wastewater, the initial TOC removal was as low as 52%, though, it increased to 86% after 32 days of operation and also the TKN removal marked 71% after 27 days. Continuous high removal rates were monitored in both the TOC and TKN parameters during the experimental period. Due to the cost for PSA (Pressure Swing Adsorption) setting and biomass supporting media installation, the initial construction cost of A/O POB process was 2.9 times higher than that of extended aeration process. However, the advantages such as low sludge production, no need for sludge recycling and low energy consumption allow the A/O POB process to have 2.5 times lower operation and maintenance costs. Consequently, in the long term of operation, it is likely that A/O POB process would show higher performance as well as cost effectiveness compared to extended aeration process.

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Identification of Synthesized Pitch Derived from Pyrolyzed Fuel Oil (PFO) by Pressure (석유계 잔사유(PFO)의 피치 합성 시 압력조건에 따른 피치 특성 변화)

  • Seo, Sang Wan;Kim, Ji Hong;Lee, Young-Seak;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.652-656
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    • 2018
  • In this study, effects of the reaction pressure were studied for petroleum-based pitch synthesis. A two-stage reaction process was performed based on different reaction pressure conditions. Each stage experiments for the two-stage reaction were consecutively carried out. The first stage was consisted of three different pressure conditions; high (10 bar), normal and low (0.1 bar). And the second stage was carried out at the normal and low (0.1 bar) pressure. The pitch synthesis was realized at $400^{\circ}C$ for 2 h. Thermal properties and molecular weight distributions of each samples were investigated by analyzing the softening point and MALDI-TOF data. Volatilized components during the pith synthesis were measured by GC-SIMDIS. In case of the first-step reaction with the high pressure condition, the low molecular weight component participated to the pitch formation more effectively and the pitch with the low softening point was obtained. However, for the case of the first-step with the low pressure, the low molecular weight component was vent outside and the partial coke formation occurred. Eventually, pitch properties such as the softening point and yield were controlled effectively by changing the pressure in the pitch synthesis reaction.

A Comparative Analysis on the Role of the Oil Refinery Industry in the Korean and Japanese National Economy (한국 및 일본 정유산업의 국민경제적 역할 비교 분석)

  • Jin, Se-Jun;Ahn, So-Yeon;Yoo, Seung-Hoon
    • Journal of Energy Engineering
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    • v.25 no.4
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    • pp.37-52
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    • 2016
  • This study attempts to compare the role of the oil refinery industry in the Korean and Japanese national economy using an inter-industry analysis. First of all, the study conducts a comparative analysis on production-inducing effects and value-added creation effects of the oil refinery industry based on demand-driven model. Moreover, we investigate the supply shortage effects and sectoral pervasive effects of price change by using supply-driven model and Leontief price model, respectively. These analyses have been done by specifying the oil refinery industry as not endogenous but exogenous. The results show that1 won of production or investment in the oil refinery industry induces 0.2620 won and 0.6537 won of production in other industries of Korea and Japan, respectively. The former is less than the latter. It also creates 0.0946 won and 0.0536 won of value-added in other industries of Korea and Japan, respectively. The first is larger than the second. The effects of 1 won of supply shortage in oil refinery industry on other industries are computed to be 0.9657 won and 1.4476 won for Korea and Japan, respectively, and thus the former is smaller than the latter. Finally, the pervasive effects of 10% price change in oil refinery industry are estimated to be 0.3819% and 0.3409% in Korea and Japan, respectively, and thus the first is larger than the second.

Human Health Risk, Environmental and Economic Assessment Based on Multimedia Fugacity Model for Determination of Best Available Technology (BAT) for VOC Reduction in Industrial Complex (산업단지 VOC 저감 최적가용기법(BAT) 선정을 위한 다매체 거동모델 기반 인체위해성·환경성·경제성 평가)

  • Kim, Yelin;Rhee, Gahee;Heo, Sungku;Nam, Kijeon;Li, Qian;Yoo, ChangKyoo
    • Korean Chemical Engineering Research
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    • v.58 no.3
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    • pp.325-345
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    • 2020
  • Determination of Best available technology (BAT) was suggested to reduce volatile organic compounds (VOCs) in a petrochemical industrial complex, by conducting human health risk, environmental, and economic assessment based on multimedia fugacity model. Fate and distribution of benzene, toluene, ethylbenzene, and xylene (BTEX) was predicted by the multimedia fugacity model, which represent VOCs emitted from the industrial complex in U-city. Media-integrated human health risk assessment and sensitivity analysis were conducted to predict the human health risk of BTEX and identify the critical variable which has adverse effects on human health. Besides, the environmental and economic assessment was conducted to determine the BAT for VOCs reduction. It is concluded that BTEX highly remained in soil media (60%, 61%, 64% and 63%), and xylene has remained as the highest proportion of BTEX in each environment media. From the candidates of BAT, the absorption was excluded due to its high human health risk. Moreover, it is identified that the half-life and exposure coefficient of each exposure route are highly correlated with human health risk by sensitivity analysis. In last, considering environmental and economic assessment, the regenerative thermal oxidation, the regenerative catalytic oxidation, the bio-filtration, the UV oxidation, and the activated carbon adsorption were determined as BAT for reducing VOCs in the petrochemical industrial complex. The suggested BAT determination methodology based on the media-integrated approach can contribute to the application of BAT into the workplace to efficiently manage the discharge facilities and operate an integrated environmental management system.

Properties of Recycled PET Fabrics by Scouring Treatment (리싸이클 PET 직물의 정련처리에 따른 특성변화 분석)

  • Choi, H.N.;Lee, T.S.;Yang, J.W.;Lee, J.B.;Lee, S.G.
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.70-70
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    • 2011
  • 최근 산업 발달에 의한 환경문제와 석유자원 감소에 따라 섬유시장에는 Eco-friendly 바람이 강하게 불고 있으며 리싸이클 제품이 급부상하고 있다. 폴리에스터계 고분자 제품, 그 중에서도 PET 병의 재자원화를 살펴보면 기계적, 열적으로 처리하여 물질을 바꾸지 않고서 회수하는 방법인 Mechanical Recycling과 원료를 분해하여 회수하는 방법인 Chemical Recycling이 있다. 이러한 리싸이클을 통하여 에너지 절감, 저탄소, 유해물질 감소, 환경정화 및 폐기물 감소로 환경부하가 완화되며, 자원의 효율적 재사용이 가능하다. 리싸이클 PET 섬유제품은 의류 인테리어용과 같은 한정된 용도뿐만 아니라 자동차용 부품소재 및 내장 부품 등 산업용으로도 사용가능하다. 본 연구에서는 리싸이클 PET로 제직한 직물에 정련과 호발가공을 하여 이러한 전처리에 따른 물리적 열적 특성의 변화를 비교 분석하였다. 그 결과 정련과 호발가공을 한 리싸이클 PET 직물의 인장 인열 강도가 미처리 직물과 비교하여 감소하는 결과를 보였으며 마모 파열강도는 큰 차이를 보이지 않았다. 반면에 TGA와 DSC를 이용한 열분석 결과 열적 특성 및 결정화도는 일부 차이를 나타내었다.

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Resources of Polymer Wastes produced from Electrical Industry (전력산업분야에서 배출되는 폴리머 절연 폐기물의 자원화)

  • Chun, Sung-Nam;Park, Chul-Bae;Chu, Cheol-Min
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.58-60
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    • 2008
  • 발전소에서 만들어진 전력을 소비자까지 수송하는 송변전변 및 배전설비를 주 대상으로 하는 전력계통 설비의 운영에는 전력의 수송과 이를 위해 설치되는 각종 기자재로부터 인체 및 재산의 안전을 확보하기 위해 많은 종류의 절연재를 사용하고 있다. 지금까지 전력분야에서 사용되어 온 절연재는 자기재(porcelain)가 주종을 이루어 왔으나 재료기술의 발달과 함께 폴리머 절연재료들이 속속 개발되면서 자기재에 비해 가격 및 시공성 등에서 이점이 많은 폴리머 절연재가 자기재를 대체하고 있다. 그러나 폴리머 절연재료는 기들의 재질 및 사용 환경 등에 따라 일정 수명을 가지는 것으로 나타나 수명종기에 이르면 폐기물로 배출되게 된다. 전력산업 중 배전분야에서는 2007년 구매한 기자재를 기준으로 연간 13만연 톤의 전력폐기물이 발생될것으로 예측되었으며 이들은 PE, XLPE, FRP, PVC, EPDM, Silicone 등 유기성분이 약 40%, Cu, Al, 철 등 금속과 무기성분이 약 60% 인 것으로 조사되었다. 그러나 전선 및 케이블류를 제외한 기자재를 대상으로 한 분석에서는 유기성분의 함량이 90%에 이르며 이들은 석유화학공업의 원료로부터 만들어지는 특성상 높은 에너지를 함유하는 것으로 나타난 바, 이들을 적정하게 처리하는 방안의 확보는 폐기물의 처리 외에 폐기물로부터 에너지를 회수하여 자원화하는 것이 가능한 것으로 보여진다.

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A Study on the 3-Dimensional Simulation System using Industrial Source Complex Model (Industrial Source Complex Model을 이용한 3차원 모사에 관한 연구)

  • Lim Dong Yun;Kim Sung Bin;Ko Jae Wook
    • Journal of the Korean Institute of Gas
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    • v.4 no.2 s.10
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    • pp.15-19
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    • 2000
  • This study compared and analyzed existing research on dispersion models and selected the EPA's Industrial Source Complex(ISC) model as a model suitable for the domestic petrochemical industry for 3-dimensional simulation and developed a simulation system applying. 3-dimensional algorithm with this ISC dispersion model as a basis As a result of this study, the 3D dispersion model based on ISC can help estimate a exact accident damage zone, make a emergency plan and control a ignition source.

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A Study on the Estimation Depreciation Rate on Petrochemical Equipments (석유화학 제조설비의 경제적 감가상각률 산정)

  • Oh, Hyun-Seung;Kim, Chong-Su;Lee, Hahn-Kyou;Cho, Jin-Hyung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.32 no.1
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    • pp.130-136
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    • 2009
  • Estimation of mortality behavior of a industrial property are useful for calculating depreciation and making management decisions relating to property. The common methods of computing depreciation require an estimation of service life, and some methods may require an estimate of life expectancy. Estimation of service life and life expectancy can be computed from a smoothed and extended life table of original life tables developed through life analysis techniques. Several actuarial techniques are available to construct a life table for depreciation application. Of these methods, the graphic approach and graduation by mathematical formula are the most widely used in the field of depreciation. A commonly used technique of smoothing and of extending the life table is to fit a lows type survivor curves to the observed retirement rate by the least square method. In this paper, estimates of depreciation rate based on directly observed data of the domestic petrochemical equipments are presented.

An effect of ignition timing on exhausting property of LPG Engine (점화시기가 LPG 엔진의 배기특성에 미치는 영향)

  • Han, Duck-Su;Jang, Young-Min;Chun, Bong-Jun;Kim, Sung-Joon
    • Journal of Industrial Technology
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    • v.26 no.A
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    • pp.39-46
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    • 2006
  • As an automobile fuel, LPG has many environmental advantages compared to gasoline or diesel. However, current LPG engine which is provided with LPG fuel as gas form has lower power and worse fuel efficiency than gasoline engine. These problems of low power and bad fuel efficiency come from lower volumetric efficiency. Also there is a new rising problem of high failure ratio in an engine emission test. Although there are many factors which affect engine performance of exhaust gas emission, one believes that the fact that ECM of gasoline engine is used for LPG engine when retrofitting gasoline engine to LPG engine is one of the main problems, which lower engine power and emit more noxious gas due to wrong ignition timing. To solve these problems, one studied the effects of ignition timing on the exhaust gas to find out the optimum condition of ignition timing. The experimental results show that noxious exhaust gas is reduced and engine power is increased if the optimum control of ignition timing is applied in accordance to the revolution speed of engine.

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