• Journal of the Mineralogical Society of Korea
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• v.27 no.4
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• pp.271-281
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• 2014

The physicochemical properties of clay minerals have been investigated at the atomistic to nano scale. The microscopic studies are often challenging to perform by using experimental approaches alone. In particular, hydroxyl groups of octahedral sheets in 2:1 clay minerals have been hypothesized to impact the sorption process of metal cations; however, X-ray based techniques alone, a common tool for mineral structure examination, cannot properly test the hypothesis. The current study has examined whether computational mineralogy techniques can be applied to examine the hydroxyl structures of clay minerals. Based on quantum-mechanics and molecular-mechanics computational methods, geometry optimizations were carried out for representative dioctahedral and trioctahedral phyllosilicate minerals. Both methods well reproduced the experimental lattice parameters; however, for structural distortion occurring in the tetrahedral or octahedral sheets, molecular mechanics showed significant deviations from experimental data. The orientation angle of the hydroxyl with respect to (001) basal plane is determined by the balance of repulsion between the hydroxyl proton and Si cations of tetrahedral sites; the quantum-mechanics method predicted $25-26^{\circ}$ for the angle, whereas the angle predicted by the molecular-mechanics method was much higher by $10^{\circ}$ (i.e., $35^{\circ}$). These results demonstrate that computational mineralogy techniques are a reliable tool for clay mineral studies and can be used to further elucidate the roles of hydroxyls in metal sorption process.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1994.04a
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• pp.76-81
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• 1994

승용차에 있어 엔진의 공회전시나 주행중에 발생하는 여러 형태의 진동 및 소음의 저감은 승차감 및 차량의 안정성에 있어 중요한 과제가 되고 있다. 이러한 소음, 진동은 주로 엔진에서 발생하는 토크의 비주기적인 변동성분이 클러치(clutch), 변속기(transmission), 구동축을 거쳐 바퀴로 전달되는 과정에서 발생한다. 셔플(shuffle)은 주행중 가속페달(accelerator)을 급조작(tip-in, tip-out)하였을 때 차량이 전후로 과도적으로 울렁거리는 종진동 현상을 말하며, 이것은 가속페달의 급조작으로 인해 엔진토크가 큰 변동을 일으키고, 동력전달계를 통해 타이어에 전달된 이 토오크는 타이어축에서 구동측으로 역토오크를 발생시키기 때문에 발생한다. 여기서 팁-인(tip-in)이란 승용차를 저속으로 운전하다가 갑자기 가속페달을 밟는 경우를 말하며, 팁-아웃(tip-out)은 반대로 고속상태에서 갑자기 가속페달을 떼는 경우를 말한다. 실험과 시뮬레이션을 사용한 자동차 동력전달계의 비틀림 진동에 대한 연구는 이미 여러 연구자들에 의해 보고되었다. H.Arai은 2자유도 비선형 모델을 사용하여 클러치 접속시 발생하는 외란과 계의 안정성을 고려하여 시뮬레이션을 수행하였고, M.Kataoka는 기어의 공차(clearance)를 고려한 변속기의 강제 비틀림 진동을 실험과 시뮬레이션을 통하여 해석하였다. 그리고, Wu Hui-Le는 자동차 동력전달계의 비틀림 진동 현상을 실험과 이론적인 계산을 통해 연구하였고, R.J.Comparin는 치타음의 발생구조와 특성을 고찰하고 비서형 비틀림 공진 저감에 의한 치타음 저감 기법에 대하여 연구하였다. 또한 G.J.Fudala는 다자유도 모델을 이용하여 클러치의 비틀림 특서엥 따라 주파수분석을 수행하여 치타음 저감 방법을 연구하였고, T.Sakai는 5자유도 모델을 이용하여 엔진 공회전시 발생하는 치타음에 대해 이론과 실험을 통해 해석하고, 엔진 회전수 변동, 클러치 특성, 변속기의 드래그(drag) 토크의 영향과 치타음 저감을 위한 개선된 클러치 특성을 제시하였다. 이 외에도 Thomas C.T.와 E.P.Petkus는 특정 차량에 대한 동력전달계의 비틀림 진동 현상에 대해 연구하였다. 이러한 연구들로 볼 때, 자동차 동력전달계에서 발생하는 진동은 이론과 실험을 통해 그 해석이 가능하며 설계에 매우 유용하게 이용되고 있음을 알 수 있다. 따라서, 본 연구는 4 실린더 4 싸이클 1.5 L 엔진을 장착한 경승용차의 실차 주행실험을 통해 가속 페달의 급조작에 따른 차체의 종진동 현상을 측정하고, 엔진-변속기-타이어-차체의 반환정계 4자유도 진동모델로 시뮬레이션을 수행하여 실차 주행실험의 결과치와 비교, 분석한 후 클러치 비틀림 특성을 비롯한 자동차 동력전달계의 각 설계인자들이 차체의 종진동에 어떠한 영향을 미치는가를 해석하고자 한다.

• Korean Journal of Environment and Ecology
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• v.30 no.4
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• pp.745-750
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• 2016

Morphological characteristics and population characteristics of the Rhynchocypris kumgangensis were investigated at Taehwa River from April 2014 to April 2015. This is the first record on R. kumgangensis not only from Guksu stream (the upstream region of Taehwa River, Ulsan-si Ulchu-gun Beomseo-eup Kuksu-ri) but also from the stream flowing into the Gangneungnamdae stream, in the southern part of East Sea, Korea. The morphometric characteristics of R. kumgangensis in the Taehwa River and the Han River are very similar except that the population at Taehwa River showed shorter caudal peduncle length than caudal peduncle depth when compared with the population at Han River. In terms of meristic character the population at Taehwa River showed fewer numbers of scales at the lateral line, above the lateral line and below the lateral line. Other than that, the two populations showed the same meristic characters. The fish cohabiting with R. kumgangensis mainly composed of Zacco platypus (25.2%), Rhynchocypris oxycephalus (24.1%) and Zacco koreanus (21.8%). Length frequency distribution analysis indicated that the length of the group ranged between 45~65 mm and the average length was 54.3 mm. Calculation of the length-weight relation of R. kumgangensis showed the value of constant a as 0.000002 and b as 3.34, and the Condition factor (K) was 1.10 an on average.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.14 no.5
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• pp.249-254
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• 2014

In this paper, minimizing of a parabolic edge planar monopole antenna by scaling method is presented. With the aid of a matching step and discontinuous CPW, the antenna easily adjusts the impedance matching. We used an FR4 dielectric substrate with a dielectric constant of 4.4. The dimensions of the antenna are $26mm{\times}31mm{\times}1.6mm$. A return loss value of more than 10dB was found in the 2.37GHz to 10.52GHz (8.15GHz) range of the antenna fed by the discontinuous CPW. The radiation pattern is about the same as that of the dipole antenna at all frequencies. Configuration elements of the antenna except feed part were reduced into the same rate. So, the size of the antenna was decreased and a broadband property was maintained. Therefore, the self-complementary characteristic of the antenna was confirmed. While satisfying the UWB band, having the smallest size in the antenna miniaturized by scaling;when scale was 0.6. The dimensions of the antenna are $15.6mm{\times}18.6mm{\times}1.6mm$. The return loss was more than 10 dB of the measured result in the range of 3.07GHz to 12.59GHz (9.52GHz).

• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.61-68
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• 2006

Soil washing techniques coupled with high pressure air jet were applied for diesel-contaminated soils sampled by an underground oil reservoir of which the initial total petroleum hydrocarbon (TPH) ($2,828{\pm}206\;mg/kg$) exceeded 5 times of current standard level (500 mg/kg) regulated by the Soil-Environment Conservation Law. Through several tests, we found that the position of impeller has a critical impact for washing efficiencies. The highest washing efficiency was obtained at an oblique angle (30 degree) for the impeller and optimized mixing speed (300 rpm) that could have high shearing forces. Considered economical and feasible aspects, the optimum mixing time was 10 min. Rate constants of TPH removal derived from the first-order equation were not linearly increased as mixing speed increased, indicating that mechanical mixing has some limits to enhance the washing efficiencies. Application of high-pressure air jet in washing process increased the washing efficiency. This increase might be caused by the fact that the surface of micro-air bubbles strongly attached hydrophobic matters of soil particles. As the pressure of air jet increased, the separation efficiencies of TPH-contaminated soil particles increased. In the combined process of high-pressure air jet and mixing by impeller, the optimum mixing speed and air flow-rate were determined to be 60 rpm and $2\;kg/cm^2$, respectively. Consequently, the washing technique coupled with high-pressure air jet could be considered as a feasible application for remediating petroleum-contaminated soils.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.9 no.3
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• pp.115-124
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• 1997

We measured the variance of eddy diffusion and associated ‘diffusion coefficients’ in coastal regions of Korea by observing the separation distances among multiple drifters deployed simultaneously at the same initial position. The variance of eddy diffusion was found to be proportional to $t^m$, where t is the time and m is a non-integer scaling exponent between 1.5 and 3.5. The observed scaling exponent of eddy diffusion cannot be reproduced by diffusion models employing constant eddy diffusivity. In this study, we applied fractal theory in simulating exponential increase of variance of eddy diffusion. We employed the fGn(fractional Gaussian noise) as a ‘modified’ random walks corresponding to the oceanic eddy diffusion. The variance of eddy diffusion, which corresponds to the fBm(fractional Brown motion) of our diffusion model, is proportional to $t^{2H}$, where H is Hurst scaling exponent. The temporal increase of the variance. with scaling exponent between 1 and 2, was successfully reproduced by our fractal diffusion model. However, our model cannot reproduce scaling exponent greater than 2. The scaling exponents greater than 2 are associated with the velocity shear of the mean flow.

• Journal of the Korean Geosynthetics Society
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• v.11 no.2
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• pp.1-9
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• 2012

In order to review the utility of Lade's single hardening constitutive model, a series of isotropic compression-expansion tests and consolidated drained triaxial tests including as CTC, TC, RTC, and OSP were performed by Baekma river sand with various of stress path. Parameters required in model were determined using these tests. The accuracy of analysis was reviewed by back analysis of test results used to determine the 11 parameters of soil property through the test of each stress path. Also. for verifying the accuracy of prediction for the stress-strain behavior using failure criterion related 9 parameters with correlational equation and constant and yield criterion related parameters h, ${\alpha}$ and ${\eta}_1$, when stress path is different with each other, it has been obtained in the review result of stress path dependent characteristics of the constitutional model through the analyzing results of CTC, TC, RTC, OSP, and fine silica sand tests.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.19-26
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• 1986

A titanium oxide thin films were prepared by air oxidation and vapour oxidation and a $TiO_2$ single crystal was reduced by heating in an argon atmosphere. All the electrode characteristics of the Ti$O_{2-x}$, thin films are not different from those of slightly reduced single crystal rutile. In cyclic voltammogram of oxygen containing electrolyte solution at Ti$O_{2-x}$ electrodes, cathodic peaks were observed at between -0.8V and -1.0V vs. SCE. The cathodic current near 0V vs. SCE in saturated solution with nitrogen was observed to be greater than in saturated solution with air. The chronoamperogram was represented by the equation of i = $i_0e^{-kt}$, when the rate constant k was represented by the equation of k =$k_0{[H^+]}^nexp(A{\eta}+E_a/RT)$ The values of activation energy $E_a $were found to be 4.6~4.8kcal/mole in overpotential range of 0.035∼0.145 V and 1.6kcal/mole in overpotential range of 0.2∼0.5V. The values of n and A were found to be 0. 1 and 5.4~5.6/V in range of 0.035~0.145V, and in range of 0.2~0.5V, to be 0.04 and 1.3/V, respectively. This can be interpreted as an totally irreversible reduction of oxygen.

• Korean Journal of Optics and Photonics
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• v.8 no.6
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• pp.445-449
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• 1997

The complex refractive indices of $Ge_2Se_2Te_5$ which show reversible phase change between the crystalline phase and an amorphous one depending upon the annealing process have been determined in the spectral range of 0.7-4.5 eV. The $Ge_2Se_2Te_5$ films were DC sputter deposited on the crystalline silicon substrate. The spectro-ellipsometry data of a thick film were analyzed following the modelling procedure where the quantum mechanical dispersion relation were used for the complex refractive indices of both the cryastalline phase $Ge_2Se_2Te_5$ and and amorphous phase $Ge_2Se_2Te_5$, respectively. On the other hand, with the surface micro-roughness layer whose effective thickness was determined from AFM analysis, the spectro-ellipsometry data were numerically inverted to yield the complex refractive index of $Ge_2Se_2Te_5$ at each wavelength. With these set of complex refractive indices, the reflectance spectra were calculated and those spectra obtained from the numerical inversion showed better agreement with the experimental reflection spectra for both the cryastalline phase and an amorphous phase. Finally, the thin $Ge_2Se_2Te_5$ film which has the optimum thickness of 26 nm as the medium for optical recording was also analyzed and the quantitative result of the film thickness and the surface microroughness has been reported.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.1
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• pp.81-94
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• 2010

This paper deals with the fracture simulation of UHPFRC girder with the interface type model. Based on the existing numerical simulation of quasi-brittle fracture in normal strength concrete, constitutive modeling for UHPFRC I-girder has been improved by including a tensile hardening at the failure surface. The finite element formulation is based on a triangular unit, constructed from constant strain triangles, with nodes along its sides and neither at the vertex nor the center of the unit. Fracture is simulated through a hardening/softening fracture constitutive law in tension, a softening fracture constitutive law in shear as well as in compression at the boundary nodes, with the material within the triangular unit remaining linear elastic. LCP is used to formulate the path-dependent hardening-softening behavior in non-holonomic rate form and a mathematical programming algorithm is employed to solve the LCP. The piece-wise linear inelastic yielding-failure/failure surface is modeled with two compressive caps, two Mohr-Coulomb failure surfaces, a tensile yielding surface and a tensile failure surface. The comparison between test results and numerical results indicates this method effectively simulates the deformation and failure of specimen.