• Title/Summary/Keyword: 상분리

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Effect of X-ray Exposure on Phase Separation of Lysozyme-Water Mixture (X선 쬐임이 단백질-물 상분리에 미치는 영향)

  • Cho, Chang-Ho;Sung, Syng-Hoon;Lee, Sang-Soo;Cho, Kun-woo
    • The Journal of Natural Sciences
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    • v.11 no.1
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    • pp.23-26
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    • 1999
  • Phase separation temperature of lysozyme-water mixture increased with X-ray exposure on lysozyme and decreased with impurity of saponin. The intensity of light scattering in lysozyme-water mixture with X-ray exposure on lysozyme decreased as a function as a function of temperature, and decreased with impurity of saponin.

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Development of New Correlation and Assessment of Correlations for Two-Phase Pressure Drop in Rectangular Microchannels (사각 마이크로채널 내의 2 상 유동 압력강하 상관식의 검증 및 개발)

  • Choi, Chi-Woong;Yu, Dong-In;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.1
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    • pp.9-18
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    • 2010
  • There are two kinds of models in two-phase pressured drop; homogeneous flow model and separated flow model. Many previous researchers have developed correlations for two-phase pressure drop in a microchannel. Most correlations were modified Lockhart and Martinelli's correlation, which was based on the separated flow model. In this study, experiments for adiabatic liquid water and nitrogen gas flow in rectangular microchannels were conducted to investigate two-phase pressure drop in the rectangular microchannels. Two-phase frictional pressure drop in the rectangular microchannels is highly related with flow regime. Homogeneous model with six two-phase viscosity models: $Owen^{(21)}$'s, $MacAdams^{(22)}$'s, Cicchitti et ${al.}^{(23)}$'s, Dukler et ${al.}^{(24)}$'s, Beattie and ${Whalley}^{(25)}$'s, Lin et ${al.}^{(26)}$'s models and six separated flow models: Lockhart and $Martinelli^{(27)}$'s, ${Chisholm}^{(31)}$'s, Zhang et ${al.,}^{(15)}$'s, Lee and ${Lee}^{(5)}$'s, Moriyama and ${Inue}^{(4)}$'s, Qu and $Mudawar^{(8)}$'s models were assessed with our experimental data. The best two-phase viscosity model is Beattie and Whalley's model. The best separated flow model is Qu and Mudawar's correlation. Flow regime dependency in both homogeneous and separated flow models was observed. Therefore, new flow pattern based correlations for both homogeneous and separated flow models were individually proposed.

Phenomenological Study on Crystal Phase Separation in InGaN/GaN Multiple Quantum Well Structures (InGaN/GaN 다중 양자우물 구조에서의 결정상 분리 현상 연구)

  • Lee, S.J.;Kim, J.O.;Kim, C.S.;Noh, S.K.;Lim, K.Y.
    • Journal of the Korean Vacuum Society
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    • v.16 no.1
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    • pp.27-32
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    • 2007
  • We have investigated photoluminescence(PL) spectra of four $In_xGa_{1-x}N(x=0.15)/GaN$ multiple quantum well(MQW) structures with different well widths in order to study a phenomenon on crystal phase separation. The asymmetic behavior of PL spectra becomes stronger with increase of the well width from 1.5 nm to 6.0 nm, which indicates dual-peak nature. Analyzing the dual-peak fit PL spectra, we have observed that the intensity of low-energy shoulder peak rapidly becomes stronger, compared to that of high-energy peak corresponding to a transition in InGaN QW. It suggests that InGaN QW has two phases with tiny different In compositions, and that In-rich(InN-like) phase forms more and more relatively than stoichiometric InGaN(x=0.15) phase by the InN phase separation mechanism as the QW width increases. PL spectrum of 6.0-nm sample shows an additional peak at low-energy lesion(${\sim}2.0\;eV$) whose energy position is almost the same as a defect band of yellow luminescence frequently observed in GaN epilayers. It may be due to a defect resulted from In deficiency formed with development of the phase separation.

A Study on the Storage Stability of Waste Vinyl-Modified Asphalt (폐비닐로 개질된 아스팔트의 저장안정성에 관한 연구)

  • Kim, Kang-San;Hong, Young-Keun
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.191-198
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    • 2008
  • It is said that polymer modified asphalt using polyethylene as modifier would show phase separation due to density difference and incompatibility between asphalt and polyethylene. In this study, to prevent coalescence of polyethylene in asphalt, we employed peroxides as phase separation inhibitor. On microscope, peroxides (dicumyl peroxide, lauroyl peroxide) with waste vinyl (comprising low density polyethylene) did not show phase separation, however, rheometer test showed phase separation at molecular level, i.e., polyethylene and asphalt are immiscible ultimately. Mechanical properties (tensile strength, Marshall stability, dynamic stability) showed waste vinyl-modified asphalts are highly resistant to plastic deformation and these properties are even better than those of Superphalt.

Phase Separation Behaviors of 3,3y-Dimethyldiphenyl 4,4y-diisocyanate(TODI) Based Polyurethanes (3.3‘- Dimethyldipheny1-4,4′-diisocyanate (TODI)Based 폴리우레탄의 상분리 거동)

  • 김정호;이한섭
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.466-469
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    • 2002
  • Polyurethane(PU)은 segmented 블록공중합체로써 상온보다 높은 유리전이온도(glass transition temperature, Tg)를 갖는 hard segment(H.S)와 상온보다 낮은 Tg를 갖는 soft segment (S.S)로 구성되어 있다. 이들 두 segment간의 열역학적 불친화성으로 인해 미세 상분리 구조를 갖는다$^1$. 그 결과 hard segment-rich hard domain과 soft segment-rich soft matrix의 구조를 이룬다. 이중 hard domain(HD)은 상온에서 glassy한 성격을 띄므로 물리적 가교점과 충진제의 역할을 하며 soft domain(SD)은 rubbery한 성질을 가지므로 polurethane에 탄성을 부여하는 역할을 한다. (중략)

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Separation Properties of Silk Sericin by Using Ultrafiltration Membrane (UF분리막을 이용한 견 세리신의 분리 특성)

  • 이태상;홍영기;배기서
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.119-122
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    • 2002
  • 섬유 공정의 특성상 산업적으로 배출되는 상당한 양의 폐수는 피할 수 없는 현실이며, 폐수에는 dyes, sizing agents, electrolytes, soaps, fat, oils, proteins 등 여러 혼합물질을 포함하여 이들은 각각 오염원으로 작용하게 된다. 따라서 이러한 폐수의 처리에 드는 비용도 나날이 증가하고 있는 추세이다. 근래에 들어서는 상당한 비용을 감수하더라도 물의 재활용을 위해 이들 오염원을 제거하거나 물의 재활용 방법을 개발하고 있으며 실질적으로 도입되어 실용화되고 있는 실정이다. (중략)

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Nonlinear optical behavior of binary mixture protein and water near the phase separation temperature (상분리 온도 근방에서 섞임체 단백질-물의 비선형 광학적 특성)

  • 조창호;김태균;서영석
    • Korean Journal of Optics and Photonics
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    • v.8 no.6
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    • pp.461-465
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    • 1997
  • The 3rd order nonlinear optical susceptibility was measured through the self-induced ellipse rotation. The phase separation temperature increases with the increase of salt and it decreases with the increase of glycerol.

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An Analysis for the Characteristics of Headward Erosion and Separation Zone due to Bed Discordance at Confluence (합류부 하상고 불일치에 의한 두부침식 및 분리구역 특성분석)

  • Choi, Heung Sik;Mo, Sun Jea;Lee, Sam Hee
    • Journal of Korea Water Resources Association
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    • v.48 no.11
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    • pp.879-889
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    • 2015
  • The pattern of headward erosion at tributary and the separation zone formation in a loosed bed at confluence according to the confluence angle, discharge ratio, and dredging depth ratio have been analyzed. The separation zone is defined the inside of zero velocity boundary at downstream of confluence. The limit of separation zone occurrence is presented with dredging depth ratio. The propagation length of knickpoint increases as the confluence angle, discharge ratio, and dredging depth ratio increase in general and its regression equation has been suggested. The length and width ratios of separation zone in a loosed bed increase as discharge ratio and confluence angle increase as well as in a fixed bed. The length ratio decreases and the width ratio increases as dredging depth ratio increases results in great increase of shape factor and backwater rise by the conveyance reduction at confluence. The regression equation of shape factor with confluence angle, discharge ratio, and dredging depth ratio has been suggested.

Segmentation of the Korean speech signals into phonetic units using the super resolution pitch determination (고해상 피치검출을 이용한 한국어 음성신호의 음소분리)

  • 이응구;이두수
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.2
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    • pp.270-278
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    • 1993
  • This paper is presented the phonetic segmentation alg9rithm of the Korean speech signals which is finded the exact pitch using the super resoluton pitch determination and is compared corss-correlation to threshold each pitch period. The features of the proposed algorithm are infinite resolution and high reliability, and also can separate transient or silent segment. The algorithm is instrumental to speech processing applications which require vector quantization and speech recognition. The presented algorithm is implemented by 386-MATLAB on PC 386/DX and is verified the exact pitch period and the phonetic segmentation of speech signals.

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막분리법을 이용한 산소부화공기의 제조와 연소장치에의 응용

  • 박준택
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.38-41
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    • 1994
  • 막분리(membrane separation)법은 막 전후의 압력차, 농도차 등을 추진력(driving foroe)으로 하여 분리대상물질에 대한 막의 선택투과성 차이를 이용, 분리를 행하는 것이다. 이 분리법은 기존의 분리공정인 심냉법(cryogenic separation)과는 달리 상변환 공정이 필요없어 에너지가 적게 들고 또한 PSA(pressure swing adsorption)법에서와 같은 cycle 운전이 필요없어 연속적으로 분리가 가능하며 시스템도 간단하다. 최근 기체 막분리의 경우 수소 및 탄산가스의 회수정제, 공기중의 산소와 질소의 분리 등에 실용화되고 있다. 여기서는 공기중의 산소를 분리하여 30-40% 산소부화공기(oxygen enriched air)를 간편하게 제조할 수 있는 산소부화막장치와 연소장치에의 응용기술 및 연구결과에 대해 간략히 소개하고자 한다.

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