• Title/Summary/Keyword: 삼중치

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Electronic Structure and Photoreactivity of N-Methyllutione (N-메틸루티돈의 電子構造와 光化學反應性에 關한 硏究)

  • Shim Sang Chul;Hyun Myung Ho;Chae Kyu Ho
    • Journal of the Korean Chemical Society
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    • v.21 no.6
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    • pp.434-439
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    • 1977
  • The electronic structures of 4-pyridone and lutidone are studied by the SCF MO-CI PPP method and by the configuration analysis method. The spectral data are consistent with the values calculated by the method. The polarization of $S_1({\pi},{\pi}^*)$ state is along the long molecular axis in both compounds. The lowest $({\pi},{\pi}^*)$1 state shows significant charge transfer (16∼18%) from ${\pi}$ bonding orbital of C=O moiety to ${\pi}^*$ antibonding orbital of divinyl amine moiety. The lowest triplet state shows much larger charge transfer (24∼29 %) but in opposite direction compared to that of $S_1({\pi},{\pi}^*)$ state.

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Variations of Catch and Fish Species in the Adjacent Fishing Ground of Ceramic Artificial Reefs Constructed on the Coastal Area of Geomun-do, Korea (한국거문도 연안에 시설된 세라믹 어초 인접 어장에서의 어획량과 어획종 변동)

  • Park, Seong-Wook;Kim, Dae-Kweon;Lee, Jeong-Woo;Ahn, Hee-Chun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.40 no.4
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    • pp.295-303
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    • 2004
  • In order to estimate the effect of ceramic artificial reefs on the fisheries resources enhancement, we have studied the variation of catch and species, which were caught by trammel net on the three fishing grounds of ceramic artificial reef, natural reef, and control(non-reef)in the coast of Geomun-do, Korea from 2001 to 2003. Catch per unit effort (CPUE ; g/panel) of fishing ground with the ceramic artificial reef area was 1,621.9g, it was about 67.9% higher than the natural reef area 333.3% higher than the control area. The catch of fish with the ceramic artificial and the natural reef area was not significantly different based on statistical analysis of Tukey test, whereas the relationship between the ceramic artificial reef and the control area was significantly different (p<0.05). Monthly mean number of species caught by the artificial reef area, the natural reef area and the control area was no difference by ANOVA test. The catch of fish was highest in November and lowest in May, whish was associated with the natural reef and the control area. The dominant species were demersal fishes living around rock such as Pagrus majir, Thamnaconus modestus, Stephanolepis sirrhifer, Pleuronichthys curntus, and Ostracion cubicus in the artificial reef area, but demersal of migratory fishes in the natural reef and the control area.

Numerical Analysis on the Determination of Head Loss by Perforated Vertical Walls (연직 유공벽의 수두손실 결정을 위한 수치해석)

  • Chun, In-Sik;Lee, Seong-Yeop;Park, Kyung-Soo;An, Dong-Keun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.3
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    • pp.194-204
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    • 2007
  • A numerical analysis and hydraulic experiments were undertaken to investigate the head loss occurring when a flow passes through vertical perforated walls. The numerical analysis applied continuity, momentum and energy equations to the control volumes that were set near the perforated wall. Non-dimensional equations were then derived to calculate both upstream depth and head loss for the given values of downstream depth and velocity. The hydraulic experiments were performed with several single and triple perforated plates varying their opening ratios and intervals. The numerical results with the single plates were compared with the experimental results, and it was shown that the contraction coefficient of the vertical line jet formed after the perforated plates relies on downstream Froude number as well as opening ratio. Based on the experimental results, empirical formulas were formulated. Finally, the formulas were applied to the triple plates sequentially from downstream side to upstream side, and it was found that in general the predicted values nicely agreed with the experimental results.

Effect of Intracanal Medicaments on Push-out Bond Strength of Calcium Silicate-based Materials (근관내 약제가 규산칼슘 기반 재료의 압출 강도에 미치는 영향)

  • Jeong, Hyuntae;Yang, Sunmi;Kim, Seonmi;Choi, Namki;Kim, Jaehwan
    • Journal of the korean academy of Pediatric Dentistry
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    • v.45 no.4
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    • pp.455-463
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    • 2018
  • The purpose of this study was to evaluate the effect of the intracanal medicaments on the push-out bond strength of the calcium silicate-based materials. Forty extracted single-root human mandibular premolars were sectioned below cementoenamel junction. Standardized root canal dimension was obtained with a parallel post drill. The specimens were randomly divided into a control group (no medicament), and experimental groups received medicaments with either CH (calcium hydroxide), DAP (double antibiotic paste; a mixture of ciprofloxacin and metronidazole), or TAP (triple antibiotic paste; a mixture of minocycline, ciprofloxacin and metronidazole). Following removal of medicaments with irrigation, roots were cut into sections with 1-mm-thickness. Thereafter, calcium silicate-based materials are applied to the specimens : (i) ProRoot MTA$^{(R)}$ and (ii) Biodentine$^{(R)}$. A push-out bond strength was measured and each specimen was examined to evaluate failure mode. Intracanal medication using CH significantly increased the bond strength to the root dentin. But there are no significant differences on the bond strength of ProRoot MTA$^{(R)}$ or Biodentine$^{(R)}$ among TAP, DAP and control groups. The dislodgement resistance of Biodentine$^{(R)}$ from root dentin was significantly higher than that of ProRoot MTA$^{(R)}$ regardless of the type of intracanal medicaments.

Development of Greenhouse Cooling and Heating Load Calculation Program Based on Mobile (모바일 기반 온실 냉난방 부하 산정 프로그램 개발)

  • Moon, Jong Pil;Bang, Ji Woong;Hwang, Jeongsu;Jang, Jae Kyung;Yun, Sung Wook
    • Journal of Bio-Environment Control
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    • v.30 no.4
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    • pp.419-428
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    • 2021
  • In order to develope a mobile-based greenhouse energy calculation program, firstly, the overall thermal transmittance of 10 types of major covers and 16 types of insulation materials were measured. In addition, to estimate the overall thermal transmittance when the cover and insulation materials were installed in double or triple layers, 24 combinations of double installations and 59 combinations of triple installations were measured using the hotbox. Also, the overall thermal transmittance value for a single material and the thermal resistance value were used to calculate the overall thermal transmittance value at the time of multi-layer installation of covering and insulating materials, and the linear regression equation was derived to correct the error with the measured values. As a result of developing the model for estimating thermal transmittance when installing multiple layers of coverings and insulating materials based on the value of overall thermal transmittance of a single-material, the model evaluation index was 0.90 (good when it is 0.5 or more), indicating that the estimated value was very close to the actual value. In addition, as a result of the on-site test, it was evaluated that the estimated heat saving rate was smaller than the actual value with a relative error of 2%. Based on these results, a mobile-based greenhouse energy calculation program was developed that was implemented as an HTML5 standard web-based mobile web application and was designed to work with various mobile device and PC browsers with N-Screen support. It had functions to provides the overall thermal transmittance(heating load coefficient) for each combination of greenhouse coverings and thermal insulation materials and to evaluate the energy consumption during a specific period of the target greenhouse. It was estimated that an energy-saving greenhouse design would be possible with the optimal selection of coverings and insulation materials according to the region and shape of the greenhouse.

Size selectivity of round traps for greenling (Hexagrammos otakii) in the western sea of Korea (원통형 통발에 대한 서해안 쥐노래미 (Hexagrammos otakii)의 망목선택성)

  • 신종근;박해훈
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.3
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    • pp.174-180
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    • 2003
  • This study investigated the size selectivity of the round traps for greenling (Hexagrammos otakii) in the western sea of Korea. The selection curve for the greenling from the experiments on Oct. 2000 and Ar. 2001 was fitted by Kitahara's method to a polynomial equation and two parameter logistic selection curve. The selectio curve of the latter was more reasonable than that of the former. The equation of selectivity curve obtained using a logistic function with least square method was , s(R)=1/1+exp(-1.1169R+6.4565), where R=1/m, and 1 and m are total length and mesh size, respectively. The size selectivity curve showed that the current regulated mesh size(35mm) in case of the round trap was close to the L50 (37.0mm) of the selection curve for the biological minimum length (21.4cm) of the greenling.

Species Composition of Fish in Coastal Water off Goeje Island (거제도 연안해역의 어류 종조성)

  • Cha, Byung-Yul
    • Korean Journal of Ichthyology
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    • v.11 no.2
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    • pp.184-190
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    • 1999
  • A total of 43 species, 493 individuals, and 89,367.1 g of fishes were collected by a gill net in the coastal water off Goeje Island. Samples were collected by bimonthly from February to October, 1996. The dominant species were Stephanolepis cirrhifer, Ditrema temmincki, Hexagrammos otakii, Limanda yokohamae, Sebastes schlegeli, Paralichthys olivaceus, which accounted for 61.7% of the total numbers and 66.3% of biomass of fish collected. Fishes collected in the study area were mainly consisted of coastal species, but a few fishes were migratory species including Stephanolepis cirrhifer, Pleuroniohthys cornutus, Paralichthys oliuaceus, Thamnaconus modestus, Pagrus major, Engraulis japonicus. The number of species and abundance showed a peak in October, and low in February. Monthly species diversity indices ranged between 1.99 and 2.81, and high in June.

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Comparison of digitalized fabrication method for interim removable partial denture: case reports (두 가지 프린팅 방식으로 제작한 임시 가철성 의치의 비교: 증례 보고)

  • Yoon-Jeong Shin;Cheong-Hee Lee;Du-Hyeong Lee
    • The Journal of Korean Academy of Prosthodontics
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    • v.61 no.4
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    • pp.379-385
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    • 2023
  • With the recent development of digital dentistry, fully digitalized methods for fabricating dentures, using intraoral scans and computer-aided design/computer-aided manufacturing (CAD-CAM), are getting popular. Digital methods have the advantage of simplifying the fabrication process in the clinic and laboratory, supplementing digital data. This case report shows a fully digital fabrication method for interim removable dentures in a patient with anterior tooth loss in which implant placement is impossible or delayed. Interim removable dentures were fabricated using two methods. One method is printing tooth and base parts separately and combining, and the other method is printing the whole denture at one time and coloring on the base part. Afterward, dentures were delivered and adaptation was evaluated using the triple scan technique. The extracted site was scanned intraorally (first scan) and the interim removable denture was digitally scanned both intraorally (second scan) and, after removal extraorally (Third scan). In both method, denture adaptation was shown favorable. We report this case report as both the patient and the operator were satisfied with a simplified process using a fully digital method in the clinic.

Development of Eggs, Larvae and Juveniles of Smooth Lumpsucker, Aptocyclus ventricosus (Pallas) (뚝지의 난발생과 자치어)

  • KIM Yong-Uk;PARK Yang-Sung;MYOUNG Jung-Goo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.2
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    • pp.157-165
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    • 1987
  • On January 16, 1986, mature adults of smooth lumpsucker, Aptocyclus ventricosus (Pallas) were collected from the coastal water of Okkye, Myongju-gun, Kangwon-do, Korea. The authors carried out artificial insemination on the boat. The eggs were incubated and the larvae were reared in laboratory. During the incubation period water temperature fluctuated between $7.5^{\circ}C$ and $21.4^{\circ}C$. The eggs of smooth lumpsucker are demersal and adhesive. The eggs diameters were varied from 2.28 to 2.36 mm. The hatching took place in ca. 725 hours after fertilization. The newly hatched larvae were 6.0-6.9 mm in total length. The features of the hatched larvae lie in the tadpole-like body form and in the well developed sucking disk, namely the ventral fins. 17 days after hatching, the larva attained 9.1 mm in total length. The gill opening retained a small opening at its upper part. Melanophores were developed on the tail. 31 days after hatching, the larva attained 10.6 mm in total length, and became juvenile. The first dorsal fin was disappeared. 105 days after hatching, the larvae attained 15.4-17.5 mm in total length.

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Breakthrough Curves and Elution Patterns of Heavy Metals in Sandy Clay Loam and Clay Soils (사질식양토와 식토토양에서의 중금속의 용탈과 파쇄곡선)

  • Chung, Doug-Young;Noh, Hyun-H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.1
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    • pp.21-28
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    • 2006
  • We investigated the mobilization of Cd, Pb, and Cr in two different soils in response to sorption capacities and competition for available sorption site while they moved under saturated water conditions. Two soil samples that were clay and sandy clay loam were collected within 20 cm from the upland surface. To do this, we used three different systems of heavy metal combinations such as single, binary, and ternary as solution phase. And then we observed the breakthrough curve (BTC) and elution as a function of pore volume by applying heavy metal solution and displacing K solution until these curves reached to maximum and minimum. The results showed that BTC and elution curves were not symmetric and it required more pore volumes with increasing species of heavy metals in solution phase, as well as longer tailings. Compared the areas over and under BTC and elution curve, relatively small amount of heavy metal was displaced by K even though there were differences in electronegativity among heavy metals. Conclusively, we assumed that heavy metals transport in soil could be influenced by soil physical nonequilibrium and chemical equilibrium in solution as far as there were more than two species of heavy metals existed.