• Polymer(Korea)
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• v.36 no.3
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• pp.287-294
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• 2012

ZnAl-LDH(layered double hydroxide) (Zn:Al=2:1 mole ratio) modified with stearic acid (SA) or oleic acid (OA) was synthesized by a coprecipitation method and compounded to SAN polymer at various contents. All the SAN composites were manufactured by a co-rotating twin-screw extruder and subsequently injection molded into several specimen. Morphology, transparency, and thermal resistance of these composites were evaluated by TEM, XRD(X-ray diffractometry), UV-Vis spectrophotometry, and thermogravimetric analysis. SAN nanocomposites containing OA-$Zn_2Al$ LDH showed better optical transmittance than SAN nanocomposites containing SA-$Zn_2Al$ LDH. All the SAN nanocomposites containing OA-$Zn_2Al$ LDH or SA-$Zn_2Al$ LDH exhibited improvement of thermal resistance at second stage of thermal oxidation. These results were explained by the fact that the interaction between organic modifier and polymer performed an important role in the property improvement of polymer nanocomposites.

• Polymer(Korea)
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• v.36 no.4
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• pp.461-469
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• 2012

The surface modification and characterization of Ar-plasma treated polypropylene (PP) blend are investigated using x-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and contact angle measurement. An increase in Ar-plasma treatment time leads to an increase in wettability, oxygen containing polar functional groups, the amount of talc, and surface roughness on the PP blend surface. A careful observation using SEM indicates that there exists a skin layer consisting of only PP component. The difference in viscosity between PP and rubber particles facilities the formation of skin layer. However, it is found that an increase in Ar-plasma treatment time helps to decrease the thickness of skin layer. Additional methodologies for the elimination of skin layer during injection molding are also discussed. The surface modification and morphological alteration induced by Ar-plasma treatment provides a hydrophilic state, followed by the improvement in wettability, on the PP blend surface.

• Journal of Adhesion and Interface
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• v.7 no.2
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• pp.26-31
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• 2006

In order to effectively improve interfacial adhesion strength between polypropylene (PP) and jute fiber, we particularly incorporated maleic anhydride grafted PP (MAPP) into the matrix through the environment-friendly process without an additional method of process and had better mechanical performances by providing the alignment into the natural fiber than those of the conventional fabrication technology such as an extrusion or injection molding. We also proposed hot pressing method which applied relatively low shear to the composites and confirmed the chemical bonds among the functional groups of MAPP and jute using FT-IR approach. The concentration of MAPP for maximum tensile strength and modulus was optimized at 3 wt%. Flexural properties had no noticeable tendency to increase with MAPP contents compared to tensile strength, which could probably be explained by the degree in wetting of PP/MAPP matrix.

• Journal of Adhesion and Interface
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• v.2 no.4
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• pp.24-31
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• 2001

Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.5
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• pp.3627-3632
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• 2015

We investigated mechanical, rheological and electrical properties of graphite/PP/LCP composites for a bipolar plate of the polymer electrolyte membrane fuel cell. The composites containing very low molecular weighted PP showed much higher electrical conductivity compared with other thermoplastics. This was attributed to the enhanced dispersion of graphite particles due to the low viscosity of the PP. The conductivity of the composites was increased in a great extent by incorporation of small amount of carbon nano tube (CNT). However, the acid treated CNT which contains oxygen atoms did not increase the conductivity of the composite. From this result, it is concluded that the CNT has higher affinity with non polar polymer. The composite with low molecular weighted PP provided good processability so that the composites can be processed by an injection molding while the mechanical strength is deficient compared to other polymers. In order to reinforce the low mechanical property, LCP/PP was used as a binder and the graphite/PP/LCP composite showed the higher conductivity and moderate mechanical strength maintaining suitable processability.

• Design & Manufacturing
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• v.15 no.3
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• pp.56-61
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• 2021

The increase in automation facilities in the injection molding industry is a very important process control item. The most important item when constructing an unmanned machine using a take-out robot is the "mold opening stroke" of the mold. The injection molding machine control method is divided into hydraulic type and electric type, and there have been few studies on the mold opening distance according to the control method. In this study, the correlation was confirmed by increasing the injection speed to 20, 50, 80, and 100% for the three types of hydraulic control method, open loop and close loop, and electric control method. Through the experiment, the following results were obtained. (1) It can be seen that the reproducibility is excellent with the electric, close loop, and open loop control methods. (2) When the injection speed is set to 50%, the mold opening distance is 263.10~263.27 mm, which is the most reproducible. (3) As a result of ANOVA, both injection speed and mold opening distance showed a significant difference in the hydraulic control method (p<0.05), but it was verified through experiments that there was no significant difference in the electric control method. Based on these results, when electric control is selected rather than hydraulic control, the reproducibility of the mold opening distance is excellent, so it is thought that the taking-out robot can take the object out of the mold more safely.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.1
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• pp.107-114
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• 2017

A turbocharger is an engine supercharger that is driven by exhaust gas. It improves the output and fuel efficiency by increasing the charging efficiency of the mixture gas, which is achieved by changing the rotatory power of the turbine connected to the exhaust passage. It is important to control the supercharging for this purpose. A nozzle slide joint is one of the core parts. Austenitic stainless steel is currently used as the material for this part, and its excellent mechanical properties include high heat resistance and corrosion resistance. However, because of its poor machinability, there are many difficulties in producing products with complicated shapes. Machining is used in the production of nozzle slide joints for high dimensional accuracy after metal powder injection molding. As design variables in this study, we investigated the sintering temperature, product stress, deformation rate, radius of curvature of the punch, and angle of the chamfer punch, which are related to the strain and shapes. The goal is to suggest a forming process using Nitronic 60 that does not require machining to manufacture a nozzle slide joint for a turbocharger. Accordingly, we determined the best process environment using finite-element analysis, the signal-noise ratio, and the Taguchi method for experiment design. The relative density and hydrostatic pressure of the final product were in accordance with the results of the finite element analysis. Therefore, we conclude that the Taguchi method can be applied to the design process of metal powder injection molding.

• Journal of the Korean Academy of Esthetic Dentistry
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• v.30 no.2
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• pp.71-90
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• 2021

The virtual patient dataset is a collection of diagnostic data from various sources acquired from a single patient into a coordinate system of three-dimensional visualization. Virtual patient dataset makes it possible to establish a treatment plan, simulate various treatment procedures, and create a treatment planning delivery device. Clinicians can design and simulate a patient's smile on the virtual patient dataset and select the optimal result from the diagnostic process. The selected treatment plan can be delivered identically to the patient using manufacturing techniques such as 3D printing, milling, and injection molding. The delivery of this treatment plan can be linked to the final prosthesis through mockup confirmation through provisional restoration fabrication and delivery in the patient's mouth. In this way, if the diagnostic data superimposition and processing accuracy during the manufacturing process are guaranteed, 3D digital smile design simulated in 3D visualization can be accurately delivered to the real patient. As a clinical application method of the virtual patient dataset, we suggest a decision-making method that can exclude occlusal adjustment treatment from the treatment plan through the digital occlusal pressure analysis. A comparative analysis of whole-body scans before and after temporomandibular joint treatment was suggested for adolescent idiopathic scoliosis patients with temporomandibular joint disease. Occlusal plane and smile aesthetic analysis based on the virtual patient dataset was presented when treating patients with complete dentures.

• Composites Research
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• v.36 no.2
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• pp.126-131
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• 2023

Growing environmental concerns regarding pollution caused by conventional plastics have increased interest in biodegradable polymers as alternative materials. The purpose of this study is to develop a 100% biodegradable nanocomposite material by introducing organic nucleating agents into the biodegradable and thermoplastic resin, poly(lactic acid), to improve its properties. Accordingly, cellulose nanofibers, an eco-friendly material, were adopted as a substitute for inorganic nucleating agents. To achieve a uniform dispersion of cellulose nanofibers (CNFs) within PLA, the aqueous solution of nanofibers was lyophilized to maintain their fibrous shape. Then, they were subjected to primary mixing using a twin-screw extruder. Test specimens with double mixing were then produced by injection molding. Differential scanning calorimetry was employed to confirm the reinforced physical properties, and it was found that the addition of 1 wt% CNFs acted as a reinforcing material and nucleating agent, reducing the cold crystallization temperature by approximately 14℃ and increasing the degree of crystallization. This study provides an environmentally friendly alternative for developing plastic materials with enhanced properties, which can contribute to a sustainable future without consuming inorganic nucleating agents. It serves as a basis for developing 100% biodegradable green nanocomposites.

• Journal of the Microelectronics and Packaging Society
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• v.30 no.2
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• pp.1-12
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• 2023

In the current era of the global mobile smart device revolution, electronic devices are required in all spaces that people interact with. The establishment of the internet of things (IoT) among smart devices has been recognized as a crucial objective to advance towards creating a comfortable and sustainable future society. In-mold electronic (IME) processes have gained significant industrial significance due to their ability to utilize conventional high-volume methods, which involve printing functional inks on 2D substrates, thermoforming them into 3D shapes, and injection-molded, manufacturing low-cost, lightweight, and functional components or devices. In this article, we provide an overview of IME and its latest advances in application. We review biomimetic nanomaterials for constructing self-supporting biosensor electronic materials on the body, energy storage devices, self-powered devices, and bio-monitoring technology from the perspective of in-mold electronic devices. We anticipate that IME device technology will play a critical role in establishing a human-machine interface (HMI) by converging with the rapidly growing flexible printed electronics technology, which is an integral component of the fourth industrial revolution.