• Journal of the Mineralogical Society of Korea
• /
• v.26 no.4
• /
• pp.299-312
• /
• 2013

Magnetite, a major constituent mineral of the Hongcheon carbonatite-phoscorite complex, was produced over three stages in each rock type and decreased in quantity toward the late stage. Electron microprobe analyses for magnetite revealed that Ti and V were detected in traces, but showed increasing tendency from early to late stage. On the contrary, Mg and Mn decreased distinctly, and it is the general differentiation trend of carbonatitic magma. Al also showed decreasing tendency in carbonatite and phoscorite, and Cr was mostly below detection limit except late phoscorite. In early stage, $Fe^{2+}$ was largely replaced by $Mg{2+}$ and $Mn^{2+}$, and $Fe^{3+}$ by $Al^{3+}$ in magnetite, but it has nearly pure composition in late stage. Tendency of increase in V and decrease in Mn toward late stage represents that magma differentiation progressed under the condition of decreasing oxygen fugacity. Low concentrations of Mg, Al, Cr and Ti, as well as the absence of olivine and phlogopite, suggest that the Hongcheon carbonatite-phoscorite complex was generated from depleted magma. Especially, lower concentrations of Mg in magnetite compared to other typical carbonatite-phoscorite complex, and abundant occurrence of Fe-carbonate minerals and quartz in late stage, suggest that magma differentiation of the Hongcheon carbonatite-phoscorite proceeded to the latest stage.

• Economic and Environmental Geology
• /
• v.35 no.4
• /
• pp.355-368
• /
• 2002

The multi-storied Daewonsa stone pagoda (Treasure No. 1112) in the Sancheong, Korea was studied on the basis of deterioration and geological safety diagnosis. The stone pagoda is composed mainly of granitic gneiss, partly fine-grained granitic gneiss, leucocratic gneiss, biotite granite and ceramics. Each rock of the pagoda is highly exfoliated and fractured along the edges. Some fractures in the main body and roof stones are treated by cement mortar. This pagoda is strongly covered with yellowish to reddish brown tarnish due to the amorphous precipitates of iron hydroxides. Dark grey crust by manganese hydroxides occur Partly, and some Part coated with white grey gypsum and calcite aggregates from the reaction of cement mortar and rain. As the main body, roof and upper part of the pagoda, the rocks are developed into the radial and linear cracks. Surface of this pagoda shows partly yellowish brown, blue and green patchs because of contamination by algae, lichen, moss and bracken. Besides, wall-rocks of the Daewonsa temple and rock aggregates in the Daewonsa valley are changed reddish brown color with the same as those of the pagoda color. It suggests that the rocks around the Daewonsa temple are highly in iron and manganese concentrations compared with the normal granitic gneiss which color change is natural phenomena owing to the oxidation reaction by rain or surface water with rocks. Therefore, for the attenuation of secondary contamination, whitening and reddishness, the possible conservation treatments are needed. Consisting rocks of the pagoda would be epoxy to reinforce the fracture systems for the structural stability on the basements.

• Applied Chemistry for Engineering
• /
• v.31 no.5
• /
• pp.481-486
• /
• 2020

To evaluate geochemical characteristics of surface sediments in Samcheok Port, the distribution characteristics of particle sizes, organic matters and heavy metals were investigated. The sediments showed a mixed property of sand, silt, and clay, however fine-grains dominated at the inner port and coarse-grains dominated at the outer port. The organic (COD, TOC, and IL) contamination of the sediment at the inner port were higher than that of the outer port, and the concentrations of total nitrogen and total phosphorus at the inner port was higher than those of the outer port. Also, heavy metals contamination of surface sediments at the inner port was higher than those of the outer port (except for As). From the results of high organic matter concentrations and C/N ratio at the inner port, it is considered that the contamination of organic matters was mainly derived from the land. The correlation analysis among the particle size, chemical composition, and heavy metals resulted in high correlation between silt-clay and heavy metals, and between organic matters and heavy metals. The sequential extraction results of heavy metals showed the sum of exchangeable, carbonate, and oxide fractions of Ni, Zn, Cu, Pb, Cd, and As were 14.8, 49.8, 39.1, 32.2, 51.8 and 26.6%, respectively.

• The Korean Journal of Petroleum Geology
• /
• v.3 no.1 s.4
• /
• pp.28-39
• /
• 1995

The objective of this study is to investigate the origin of the dolomite in the Pungchon Formation of the Choseon Supergroup near Taebaeg City, Kangwondo, Korea. The Pungchon Formation is composed of limestone, dolomitic limestone, and dolomite with thin beds of flat pebble conglomerate (FPC) and mudrock. Texturally, the dolomite in the Pungchon Formation can be divided into four types; 1) coarse-sized, xenotopic dolomite in massive dolomite, 2) medium-siEed, idiotopic dolomite in flat pebble conglomerate, 3) xenotopic dolomite replacing ooids, algalnodules, and echinoderms, and 4) the dolomite in mottled fabric. The dolomite in mottled fabric can be subdivided into three types; a) coarse-sized, xenotopic saddle dolomite cement, b) medium-sized, idiotopic, cloudy-centered, clear-rimmed (CCCR) dolomite, and c) coarse-sized, idiotopic dolomite. The carbon isotopic composition of the Pungchon dolomite is in the range of $-2.8-1.4\%_{\circ}(PBD)$, suggesting that the carbon isotopic composition was buffered by the preexisting marine carbonates. Lighter oxygen isotopic values ($\delta^{18}O-15.7-8.7\%_{\circ}, PBD$) indicate that the Pungchon dolomite may have formed under high temperature in a burial diagenetic environment. The higher initial $^{87}Sr/^{86}Sr$ ratio of the Pungchon dolomite (0.7010-0.7161) than that of the coeval Cambrian seawater (0.7088-0.7092) indicates that dolomitizing fluids had been modified from the isotopic exchange with continental crust. Low Sr and Na contents(<200 ppm) of dolomite agree well with previously reported data for burial dolomite. Hifh Fe and Mn contents of the dolomite support the idea that the Pungchon dolomite may have formed in a deep burial diagenetic environment.

• Analytical Science and Technology
• /
• v.33 no.6
• /
• pp.274-284
• /
• 2020

This study described the analytical method for simultaneous determination of 89Sr and 90Sr in liquid sample using automated separation system. Radiostrontium in 0.5 kg of liquid sample was concentrated as SrCO3 to reduce the volume of sample, and purified from the sample using Sr-resin 2 mL (BV, Bed volume). The behavior of Sr and interferences such as Ba, Ca and Y were estimated with various flow rate ranging from 1 to 4 mL min-1. The detailed procedure for the purification of Sr on Sr-resin was presented. The purified radiostronitum was measured in Cerenkov mode and then measured in Scintillation mode by mixing scintillation cocktail. The measured value in both modes were used to calculate the activity of 89Sr and 90Sr. The performance tests were carried out the lab-control-sample having various activity ratio of between 89Sr and 90Sr. The recovery of Sr was ranged from 68 to 94 %. The relative bias of 89Sr activity was ranged from -5 to 20 %, and it was ranged from -10 to 10 % for 90Sr.

• Journal of the Korean Geotechnical Society
• /
• v.23 no.6
• /
• pp.103-114
• /
• 2007

Sands distributed in Jeju island's coastal areas, Korea, can be classified as silicate sand derived from volcanic rock, carbonate sand derived from shells, and mixed sands containing both silicate and carbonate sands. These three types of sands typically exist in Jeju coastal areas. Samples of silicate, carbonate and mixed sands were obtained from Samyang beach, Gimnyeong beach, and Jeju harbor area, respectively. Compression tests were conducted to assess the compression characteristics of these sands. As a result of these tests, each sand showed different behaviors. For Samyang beach sand, it appeared that initial compression is a larger than the other two sands. For Cimnyeong and Jeju harbor sands, however, the additional compression occurred after initial compression. This could result from the crushing, shattering, and rearrangement of sand particles. In addition, settlement behavior of Jeju harbor ground according to the construction stages was analyzed using the measured data. It showed that in addition to the initial elastic compression, a considerable additional compression occurred with time. The settlements of Jeju harbor ground were predicted by using the elastic settlement calculation methods (empirical methods) and the compression test method. The empirical methods, which did not consider the crushing, shattering, and rearrangement of particles could show smaller result than that occurring actually.

• Economic and Environmental Geology
• /
• v.24 no.2
• /
• pp.131-150
• /
• 1991

The Weolseong diatreme was temporally and spatially related to the intrusion of the Gadaeri granite, and was -mineralized by meteoric aqueous fluids. In the Nokdong As-Zn deposit, pyrite, aresenopyrite and sphalerite are the most abundant sulfide minerals. They are associated with minor amount of magnetite, pyrrhotite, chalcopyrite and cassiterite, and trace amounts of Pb-Sb-Bi-Ag sulphosalts. The AsZn ore probably occurred at about $350^{\circ}C$ according to fluid inclusion and compositional data estimated from the arsenic content of arsenopyrite and iron content of sphalerite intergrown with pyrrhotite + chalcopyrite + cubanite. Heating studies of fluid inclusions in quartz indicate a temperature range between 180 and $360^{\circ}C$, and freezing data indicate a salinity range from 0.8 to 4.1 eq.wt % NaCl. The coexisting assemblage pyrite + pyrrhotite + arsenopyrite suggests that $H_2S$ was the dominate reduced sulfur species, and defines fluid parameter thus: $10^{-34.5}$ < ${\alpha}_{S_2}$ < $10^{-33}$, $10^{-11}$ < $f_{S_2}$ < $10^{-8}$, -2.4 < ${\alpha}_{S_2}$ < -1.6 atm and pH= 5.2 (sericte stable) at $300^{\circ}C$. The sulfur isotope values ranged from 1.8 to 5.5% and indicate that the sulfur in the sulfides is of magmatic in origin. The carbon isotope values range from -7.8 to -11.6%, and the oxygen isotope values from the carbonates in mineralized wall rock range from 2 to 11.4%. The oxygen isotope compositions of water coexisting with calcite require an input of meteoric water. The geochemical data indicate that the ore-forming fluid probably was generated by a variety of mechanisms, including deep circulation of meteoric water driven by magmatic heat, with possible input of magniatic water and ore component.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.44 no.5
• /
• pp.702-708
• /
• 2015

The aim of this study was to investigate the physicochemical characteristics of commercial Mukeunji product along with its sensory properties. Six different types of commercial Mukeunji products were purchased through an on-line market, and each product had a different fermentation period. General commercial Baechu Kimchi was compared with commercial Mukeunji products in order to standardize quality properties of Mukeunji. As a result, commercial Mukeunji showed a lower pH value (pH 3.96, mean value) than commercial Baechu Kimchi (pH 5.92), whereas commercial Mukeunji samples showed higher acidity and salinity. Color values (L, a, and b) of commercial Mukeunji decreased as the storage period increased. Hardness and thickness of commercial Mukeunji showed a lower range compared to Baechu Kimchi. The reducing sugar content decreased as the storage period of commercial Mukeunji increased. Acetic, lactic, and succinic acids were detected in commercial Mukeunji samples, whereas citric acid and malic acid were additionally detected in Baechu Kimchi. Commercial Mukeunji samples showed lower contents of acetic and succinic acid and higher content of lactic acid than Baechu Kimchi. Commercial Mukeunji samples showed a significant difference in all descriptive sensory attributes except for bitterness. Overall intensity, sourness, moldy odor, redness, sour smell, saltiness, and carbonated taste increased as the storage period increased, whereas cabbage flavor, crispiness, sweetness, firmness, and savory taste decreased as the storage period increased.

• Economic and Environmental Geology
• /
• v.50 no.4
• /
• pp.287-302
• /
• 2017

The carbonate rocks of the Daegi Formation are composed of the limestone at the upper and lower zones, and the dolomite at the middle zone, in which the upper zone has higher CaO content than others. The colors of carbonate rock in the Daegi Formation can be divided into five types; white, light brown, light gray, gray, and dark gray. The white to light gray colored rocks correspond to the high purity limestone with 53.15 ~ 55.64 wt. % CaO, and the light brown colored rocks contain 20.71 ~ 21.67 wt. % MgO. The bleaching of carbonate rocks are not related to CaO composition of the rocks, as light gray rocks tend to be higher in CaO content than those of the white rocks at the lower zone. The pelitic components are also occasionally increased in white limestone than light grey one. $Al_2O_3$ is one of the most difficult content to remove during hydrothermal processes, so the interpretation that the limestone is purified together with hydrothemral bleaching, has little merit. The wide range (over 16 ‰) of ${\delta}^{18}O_{SMOW}$, smaller variation (within 2 ‰) of ${\delta}^{13}C_{PDB}$ are apparent in both the upper and lower zones, which indicate the Daegi Formation had been affected overall by hydrothermal fluids. The K-Ar isotopic age of hydrothermal alteration in the GMI limestone mine is $85.1{\pm}1.7Ma$. Gradual change from grey through light grey to white limestone is accompaned by lower oxygen stable isotope values, which is major evidence that the hydrothermal effect is the main process of the bleaching. Although the Daegi Formation has suffered from hydrothermal activity and increase in whiteness, there is no clear evidence demonstrating the relationship between bleaching and high purity of limestone. The purification of limestone has nothing to do with the hydrothermal activity in this area. Instead, it should be considered that the change of sedimentary environment related to see-level fluctuation which can prevent deposition of pelitic components especially $Al_2O_3$ contrbuted to the formation of the high purity limestone in the upper zone of the Daegi Formation. Considering the evidences such as increase in CaO content of limestone by depth, gradual change from calcite to dolomite at the lower zones, and occurring the high purity limestone at the upper zone, the interpretation of sequence stratigraphic aspect to the formation of the high purity Daegi limestone appears to be more suitable than that of hydrothermal alteration origin.

• Korean Journal of Soil Science and Fertilizer
• /
• v.34 no.6
• /
• pp.373-379
• /
• 2001

The weathering rates and change of chemical composition of 6 residual Entisols derived from granite, granite-gneiss, limestone, sandstone, shale, amd basalt in Korea were studied. The chemical composition of each profile with parent rocks were determined using XRF with the physico-chemical properties and the morphology of soils. In the A horizons of all the soils except Euiseong series, the content of clay, organic matter and cation exchange capacity(CEC) showed higher than those of C horizon, but bulk density and pH showed lower than C horizon. Clay content in the soil from sandstone was decrease with soil depth, which may caused by the elluriation. In total element analysis. $SiO_2$ was high in the soil from granite. granite-gneiss, sandstone and compare with basalt and limestone. $Fe_2O_3$ and MgO was high in the soil from basalt, limestone and shale compare with granite. granite-gneiss and sandstone. And ignition loss was particularly high in the soil from basalt and limestone. The rate of element loss was higher in base cations(Ca, K, Mg, Na) than Si, Al, Fe in the soils. The concentrations of $TiO_2$ in the A horizon compare with that of the C horizon was due to resulting from losses of other less stable elements existed. Considering with relative rate of each elements in soils, $SiO_2$ and $Al_2O_3$ which originated from sandstone and granite, granite-gneiss, sandstone, shale, and basalt were lost higher than those from lime tone, but loss of basic cations were more in the soil from limestone which may be rapid weathering of calcite. The magnitude of losses of the overall elements were increased in the order of the soils from sandstone and granite ${\gg}$ limestone and shale) granite-gneiss and basalt.