• Nuclear Engineering and Technology
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• v.26 no.3
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• pp.425-432
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• 1994

Voltammogram analysis of U(VI) reduction at electrochemically non-pretreated/pretreated Ti electrodes in nitric acid and hydrazine($N_2$H$_4$)/protonated hydrazine($N_2$H$_{5}$$^{＋}$) media was done in order to determine the effect of hydrazine form and Ti electrode condition on the reduction of U(VI) in nitric acid. In the case of non-pretreated Ti electrode, the reduction in nitric acid and hydrazine mono-hydrate solution needed a high activation overpotential and was affected by the ratio of hydrazine to nitric acid rather than by only absolute amount of hydrazine because of the decrease of solution conductivity and increase of iR drop, which were caused by proton consumption in the solution by the hydrazine. In the case of pretreated Ti electrode in nitric acid and protonated hydrazine solution, the reduction current peaks of U(VI) were clearer and higher enough to perform a kinetic analysis, compared with the case with the non-pretreated Ti electrode at the same potential, and the behavior was strongly affected by nitric acid. The presence of hydrazine was important in the reduction of U(VI) at the pretreated Ti electrode for preventing the reoxidation of U(IV), but the concentration of protonated hydrazine was not.t.

• Clean Technology
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• v.13 no.1 s.36
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• pp.16-21
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• 2007

This study estimated the effect of hydraulic residence time(HRT), influent total ammonia nitrogen(TAN) concentration, temperature and pH in the packed-bed bioreactor using immobilized nitrifiers. Removal rate of ammonia nitrogen was increased with decreasing HRT and the optimum HRT was 0.2 hour when influent TAN was $2g/m^3$. At this point, removal rate was $226.1\;g/m^3{\cdot}day$ and removal efficiency was 88.8%. Removal rate of ammonia nitrogen was Increased with increasing TAN concentration. Removal rate and efficiency of ammonia nitrogen were kept constant at $20{\sim}35^{\circ}C$ and pH $8{\sim}9$ value.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.121-132
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• 2000

This study is to investigate the performance of a new BNR process using predenitrification scheme focusing on nitrogen removal and the possibility of adapting a computer simulation scheme in BNR process development. By using a pre-denitrification basin, higher $COD/NO_3-N$ ratio could be sustained in this BNR process. The results of the investigation showed a SDNR value of 9.04mg/gMv/hr. In the anoxic tank, the average value of SPRR of 6.25mgP/gMv/hr was observed to be very sensitive to SCOD load of influents. By calibrating internal parameters (stoichiometric and kinetic parameters) of the simulation model, the results of simulation for various BNR processes gave good agreement with observed data. The major adjustment was given with three parameters, maximum specific growth rate of heterotrophic biomass, short chain fatty acid (SCFA) limit, and phosphorous release rate. With the series of simulations on varying operational conditions, the simulation by computer program can be a useful tool for process selection, and design and operation of municipal wastewater treatment plant.

• Applied Chemistry for Engineering
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• v.16 no.2
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• pp.217-225
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• 2005

Because of the limitation of controllable operation variables for the wastewater treatment process with variable hydrodynamic flow patterns, it may preclude the use of this type of nutrient removal activated sludge process. As the operation variables, only temperature and dissolved oxygen (DO) have been used to operate the process. This study made an effort to improve treatment efficiency and operability of the process by the following methodologies: 1) process and operation data analysis using process simulation, 2) determination of optimal control logic or algorithm using a pilot-scaled experimental apparatus and its operations, and 3) application of experimental and simulation results to find the optimal process operation modes. In this study, it was found that the optimal operation mode named 'save mode' in the basis of process variables, such as the ammonia-nitrogen concentration of inlet flow, temperature and flow rate, can reduce the operation cost comparing with the present normal operation mode. And the stable conditions in nitrification were also shown by the proportional control of DO with the inlet air flow rate of blower and the mixing rate of mechanical aeration.

• Korean Journal of Food Science and Technology
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• v.30 no.4
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• pp.902-907
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• 1998

In this study the anaerobic degradation of nitrate by in GFM (gel and foam matrix) and bead gel immobilized Paracoccus denitrificans DSM 65 in continous culture was conducted. A novel GFM immobilization system was developed in order to improve conventional system (bead). With increasing nitrate concentration in water, the nitrate reduction rate was increased. The observed maximum denitrification rate by in GFM immobilized cells was 177 mg/L h in buffered water, while that was 33 mg/L h in tap water. In comparison with bead system the reduction activity by GFM system showed $1.2{\sim}2.1$ times better. The denitrification activity was not changed after 16 days storage at $5^{\circ}C$ and also showed better activity than that of free cells or even bead immobilized cells.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.35 no.5
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• pp.469-475
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• 2002

The rotating biological contactor (RBC) was tested for treatment of aquacultural water in a pilot-scale recirculating aquaculture system. Performance of RBC on the treatment of nitrogen source such as total ammonia nitrogen (TAN), nitrite nitrogen and nitrate nitrogen and chemical oxygen demand (CODcr.) was evaluated. A system was stocked with nile tilapia at an initial rearing densities of $5\%$ and $7\%$ over 30 days. As increasing rearing density from $5\%$ to $7\%$, the TAN removal rates was increased from $39.4 g/m^3{\cdot}day$ to $86.0 g/m^3{\cdot}day$. But TAN removal efficiency was decreased from $24.5\%$ to $16.0\%$. The removal rate of $COD_Cr$ was higher than TAN. The RBC as an aerator was also evaluated for increasing dissolved oxygen concentration. For $5\%$ and $7\%$ of rearing density, the average aeration rate were $280 g/m^3{\cdot}day$ and $255 g/m^3{\cdot}day$, respectively.

• Korean Journal of Microbiology
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• v.50 no.2
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• pp.164-168
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• 2014

The ecosystem of the Arctic region has been increasingly affected by global warming. Archaeal ammonia monooxygenase alpha subunit coding gene (amoA) which is a key enzyme for nitrification was used to investigate the effect of runoff water of ice melt on microbial community of nitrogen cycle. The archaeal amoA genes at coastal area of Svalbard, Arctic region were PCR-amplified and sequenced after clone library construction. Analysis of archaeal amoA gene clone libraries suggested that the station 188 which is in the vicinity to the area of runoff water harbor lower ammonia-oxidizing archaeal diversity than the station 176 and 184. The average amino acid sequence identity within all archaeal amoA gene clones was 94% (with 91% nucleotide sequence identity). While all the clones of the station 188 were affiliated with Nitrosoarchaeaum clade containing strains isolated from low-salinity and terrestrial environments, about 45% of total clones of the station 176 and 184 were related to marine Nitosopumilus clade. Interestingly, other typical archaeal amoA gene clones of thaumarchaeal I.1b clade frequently retrieved from terrestrial environments was identified at station 188. Microbial community of nitrogen cycle in marine sediment might be affected by input of sediments caused by runoff glacier melt waters.

• Journal of Wetlands Research
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• v.19 no.1
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• pp.90-102
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• 2017

In this study, various types of nutrient models were tested by using two tears's water quality data collected from the stormwater wetland in Korea. Based on results, most important factor influencing nitrogen removal was hydraulic loading rate, which indicates that surface area of wetland is more important than its volumetric capacity, and model proposed by WEF was found to give a least error between measured and calculated values. For the phosphorus, in case assuming a power relationship between rate constant and temperature, the best prediction result were obtained, but temperature was most sensitive parameter affecting phosphorus removal. In addition, denitrification was always a limiting step for the nitrogen removal in this particular wetland mostly due to the lack of carbon source and high dissolved oxygen concentration. In this paper, several alternatives to improve nitrogen removal, including proper arrangement and designation of wetland elements and use of floating plants or synthetic fiber mat to control oxygen level and to capture the algal particles were proposed and discussed.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.32 no.2
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• pp.180-185
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• 1999

Rotating Biological Contactor (RBC) was tested for the treatment of artificial rearing water in n simulated aquaculture system. Performance of RBC on the removal of TAN and COD was evaluated by controlling hydraulic residence time (HRT). As HRT of RBC was increased, TAN removal rate ana removal efficiency of RBC and TAN concentration of rearing water were increased, but COD removal rate was decreased. Total alkalinity consumption rate was increased by increasing HRT of RBC. Ratio between total alkalinity consumption rate and TAN removal rate was 7.73. HRT for maintaining lowest TAN and COD concentration of artificial rearing water was 14,6 minutes and at that condition TAN and COD concentration of the water was 1.28 and $5.59 g/m^3$, respectively.

• Microbiology and Biotechnology Letters
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• v.47 no.4
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• pp.630-638
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• 2019

Nitrous oxide (N₂O) is a greenhouse gas with a global warming potential 310 times higher than that of carbon dioxide. In this study, an N₂O-reducing consortium was obtained by enrichment culture using advanced treatment sludge as the inoculum. The dominant bacteria in the consortium were Sulfurovum (17.95%), Geobacter (14.63%), Rectinema (11.45%), and Chlorobium (8.24%). The consortium displayed optimal N₂O reducing activity when acetate was supplied as the carbon source at a carbon/nitrogen ratio (mol·mol^-1) of 6.3. The N₂O reduction rate increased with increasing N₂O concentration at less than 3,000 ppm. Kinetic analysis revealed that the maximum N₂O reduction rate of the consortium was 163.9 ㎍-N·g-VSS^-1·h^-1. Genes present in the consortium included nosZ (reduction of nitrous oxide to N₂), narG (reduction of nitrate to nitrite), nirK (reduction of nitrite to nitric oxide), and norB (reduction of nitric oxide to nitrous oxide). These results indicate that the N₂O-reducing consortium is a promising bioresource that can be used in denitrification and N₂O mitigation.