• Title/Summary/Keyword: 비응집

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Preset State of Thermoreversible Poly(vinylidene fluoride)/propylene Carbonate Gel System: 1. Core-Shell Model (열가역적인 Poly(vinylidene fluoride)/Propylene Carbonate(PC) 겔 시스템에서의 Pregea 상태 : 1. Core-Shell 모델)

  • 박일현
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.227-236
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    • 2002
  • The structure of pregel state in thermoreversible poly(vinylidene fluoride)(PVDF) /propylene carbonate(PC) system was investigated by laser light scattering. It was found that the PVDF chain did not exist as a separate chain even in a very dilute concentration(i.e. 100 times more dilute than the gel formation concentration) but as a large spherical aggregate with the radius of gyration $R_G$, of 232 nm and the effective hydrodynamic radius $R_H$= of 407 nm at $40^{\circ}C$. Based upon experimental results such as $R_H/R_G$=ratio of 1.75 and the pattern of scattering intensity with a minimum, a core-shell type sphere model was suggested as a structure of the aggregate. According to this model, the radius of core part was estimated as 215 nm, the shell thickness as 192 nm, and the ratio of monomer density of the shell part to that of the core part as about 0.075.

Observation of Effects of Phosphatidylcholine and Al Salts Concentration on the Formation of Vesicles by TEM (베시클 생성에 미치는 Phosphatidylcholine과 알루미늄 염 농도의 영향에 관한 TEM 관찰)

  • Jeong, Jong Jae;Kim, Chang Hyeon;Lee, Byeong Gyo;Lee, Hae Uk
    • Journal of the Korean Chemical Society
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    • v.40 no.3
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    • pp.173-179
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    • 1996
  • Transmission Electron Microscopy (TEM) was used to monitor the response of vesicle size and the intervesicle agglomeration with a variety of experimental parameters. Considered parameters are: (a) reaction temperture, (b) concentration of phosphatidylcholine, (c) concentration of aluminum ion with fixed concentration of phosphatidylcholine at 0.39 mM, and (d) mixed concentration of aluminum and phosphatidylcholine when fixing the weight ratio of phosphatidylcholine to aluminum at 0.01. Controlling these parameters, vesicle size changed and intervesicle agglomeration observed. As reaction temperature and the concentration of phosphatidylcholine increase, vesicle size decreases. With 0.2 M of aluminum ion, abnormal vesicle growth led by intervesicle agglomeration and coalescence was observed. When weight ratio of phosphatidylcholine to aluminum is 0.01, optimal vesicle size and size distribution can be obtained.

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Plug-in Diverse Parsers Within Code Visualization System with Redefining the Coupling and Cohesion in the Object-Oriented Paradigm (객체지향 관점의 결합도 & 응집도 재정의와 코드 가시화 시스템내 파서 플러그인화 구현)

  • Lee, Jin Hyub;Park, Ji Hun;Byun, Eun Young;Son, Hyun Seung;Seo, Chae Yun;Kim, R. Young Chul
    • KIPS Transactions on Software and Data Engineering
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    • v.6 no.5
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    • pp.229-234
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    • 2017
  • Because of the invisible nature of software and the bad coding habits (bad smell) of the existing developers, there are many redundant codes and unnecessary codes, which increases the complexity and makes it difficult to upgrade software. Therefore, it is required a code visualization so that developers can easily and automatically identify the complexity of the source code. To do this, it is necessary to construct SW visualization tool based on open source software and redefine the coupling and cohesion according to the object oriented viewpoint. Specially to identify a bad smell code pattern, we suggest how to plug-in diverse parsers within our tool. In this paper, through redefining coupling and cohesion from an object oriented perspective, we will extract bad smell code patterns within source code from inputting any pattern into the tool.

열분해법을 이용한 실리콘 나노입자 형성과정 수치해석 연구

  • U, Dae-Gwang;Ha, Su-Hyeon;Kim, Myeong-Jun;Hang, Zhang;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.117-117
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    • 2010
  • 나노입자 제조 기술이 점차 발전하면서 금속산화물, 반도체용 및 태양전지용, 신소재 등 다양한 응용분야에 사용하고 있다. 따라서 이와 같은 나노입자 제조방법으로는 펄스 레이저 용사법(pulsed laser ablation), 플라즈마 아크 합성법(plasma arc synthesis), 열분해법(pyrolysis), plasma-enhanced chemical vapor deposition (PECVD)법 등과 같은 기상공정이 많이 사용되고 있다. 기상공정은 기존의 공정에 비해 고순도 입자의 대량 생산, 다성분 입자의 화학적 균질성 유지, 비교적 간단하고 깨끗한 공정 등의 장점을 가지고 있다. 기상공정에서 일반적인 입자 형성 메커니즘은 기체 상태의 화학 물질이 물리적 공정 혹은 화학 반응에 의해 과포화상태에 도달하게 되며, 이 때 동질 핵생성(homogeneous nucleation)이 일어나고 생성된 핵(nuclei)에 기체가 응축되고 충돌, 응집하면서 입자는 성장하게 된다. 열분해법은 실리콘 나노입자를 생산하는 기상공정 중 하나이다. 일반적으로 열분해 공정은 지속적으로 열이 가해지는 반응기 내에 반응기체인 $SiH_4$을 주입하고, 운반기체는 He, $H_2$, Ar, $N_2$ 등을 사용하였을 때, 높은 열로 인해 $SiH_4$가 분해되며, 이 때 가스-입자 전환 현상(gas to particle conversion)이 일어나 실리콘 입자가 형성된다. 그러나 입자 형성과정은 $SiH_4$ 농도, 유량, 작동 압력, 온도 등 매우 다양한 요소에 영향을 받는다. 고, 복잡한 화학반응 메커니즘에 의해 명확히 규명되지는 못하고 있다. 이에 본 연구에서는 복잡한 화학반응을 해석하는 상용코드 CHEMKIN 4.1.1을 이용하여 열분해 반응기 내에서의 실리콘 입자 형성, 성장, 응집, 전송 모델을 만들고 이를 수치해석하였다. 표면 반응, 응집, 전송에 의한 입자 성장 메커니즘을 포함하고 있는 aerosol dynamics model을 method of moment법으로 해를 구하였으며, 이를 실험 결과와 비교하여 모델링을 검증하였다. 또한 반응기의 온도, 압력, 가스 농도, 유량 등의 요소를 고려하여 실리콘 나노입자를 형성하는 최적의 조건을 연구하였다.

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Physicochemical Quality Characteristics of Tofu Prepared with Mesangi(Capsosiphon Fulvescens) Powder (매생이 가루 첨가 두부의 이화학적 품질 특성)

  • Jung, Bok-Mi;Shin, Tai-Sun;Kim, Du-Woon;Chong, Kyu-Wha
    • Korean journal of food and cookery science
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    • v.24 no.5
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    • pp.691-698
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    • 2008
  • In this study, we assessed the quality characteristics of soybean curds (tofu) prepared with Mesangi (Capsosiphon fulvescens) powder (0, 2, 4, 6%, w/w) were investigated. The yields of the curds containing Mesangi were higher than those of the control, and the yield increased with increasing quantities of Mesangi powder. The most abundant mineral in Mesangi tofu was calcium, followed by magnesium. The Mesangi tofu had a slightly lower pH than the control. The addition of Mesangi powder to curd evidenced a significantly lower L value (lightness) and a value (redness) than was detected in the control (p<0.05). The hardness level was highest in the tofu to which 2% Mesangi powder was added. However, this level decreased with increasing concentrations of Mesangi powder. Although the 4% Mesangi tofu evidenced higher adhesiveness than was detected in the control, we noted no significant differences among the Mesangi-treated curds. The soybean curds added to which 2% Mesangi powder was added had evidenced the highest level of cohesiveness, but the tofu containing 4 and 6% Mesangi powder was significantly reduced as compared with the control and 2% Mesangi tofu. Springiness, gumminess, and brittleness were higher in the 2% Mesangi tofu than in the others (p<0.05). The soybean curds prepared with Mesangi powder evidenced a lower total plate count than the controls during over 12 days of storage.

Reusing of dye wastewater by membrane process (분리막을 이용한 염료폐수재활용)

  • 김건태;임성균;최광호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.127-129
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    • 1998
  • 국내 산업폐수 발생량 중 소량이지만 오염도가 높고 난분해성이 다량 함유되어 있는 염료폐수는 일반적인 응집침전 + 생물학적처리로는 폐수 방류기준치인 COD_{MN} 100ppm이하로 처리하기가 불가능하다. 따라서 S화학에서는 방류수 수질 기준을 만족시키기 위하여 생물학적 처리 후단에 3차 처리로서 분말 활성탄 설비와 같은 고도처리설비를 도입하여 운전하고 있으나 운전비가 과다하고, 분말활성탄의 주입시 미분의 비산으로 인하여 주위시설에 영향을 미치는 것으로 나타났다. S화학에서는 활성탄처리설비의 문제점을 해결하고 폐수를 공업용수로 재활용하기 위해 일일 $1500m^3$의 폐수 중 $750m^3$에 고도처리설비인 역삼투설비를 적용하였다.

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A Study on the Strength Characteristics of the Ground Contaminated with the Industrial Oil (산업용 기름으로 오염된 지반의 강도 특성에 관한 연구)

  • 조태룡;이영생
    • Journal of the Korean Geotechnical Society
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    • v.16 no.2
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    • pp.125-134
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    • 2000
  • 지반이 산업용 기름으로 오염될 때 지반의 강도변화 특성을 연구하기 위하여 모래와 실트질 모래 및 카오리나이트를 대상으로 함수비아 함유비를 변화시키며 다짐실험, 투수실험, 비배수상태에서 삼축압축실험을 실시하였다. 실험결과에 의하면 밀도가 같은 모래의 경우는 기름을 혼합하였을 경우가 물을 혼합하였을 경우에 비해 약 7%정도 전단 강도가 떨어지고 실트질 모래와 카오리나이트 경우는 기름을 혼합하였을 경우가 물을 혼합하였을 경우에 비해 점토입자와 기름의 화학적, 물리학적인 상호 작용으로 5~15%정도 강도가 증가하는 현상을 보였다. 일반적으로 산업용 기름 유출에 따라 토양오염 및 수질오염으로 동.식물에 큰 영향을 주고 있으나 토질역학적 거동은 초기 상태 및 모래에서는 전단 강도가 감소하였으나 점성토의 경우는 기름 유출 또는 유입에 따라 응집성, 부착성이 생겨 강도증가 현상을 가져와 큰 문제점이 없는 것으로 판단된다.

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Sediment Transport Prediction Model in a Harbor by Finite Element Method (유한요소법(有限尿素法)에 의한 항만(港灣)에서의 토사이송추정모형(土砂移送推定模型))

  • Yoon, Tae Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.2
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    • pp.19-28
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    • 1982
  • The development of unsteady, depth-averaged two dimensional sediment transport prediction model in estuaries and harbors by the Galerkin finite element technique is presented. The model consists of two submodels, flow induced circulation model and sediment transport model. The sediment transport submodel is formulated by incorporating sediment continuity equation and sediment diffusion equation. Numerical experiments of the model, which were carried out in one dimensional channel under different conditions for circulation and sediment transport, show the adaptability of the formulation for predicting the migration of both cohesive and noncohesive sediments. The model was applied to Busan harbor to simulate circulation and sediment transport for simplified conditions. Of the results by the model the flow pattern are shown to be similar to observed data.

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Design and Implementation of Publish/Subscribe Model Based RPC Middleware (Publish/Subscribe 모델 기반 RPC 미들웨어 설계와 구현)

  • Park, Sanghyun;Choi, Junesung;Kook, Kwangho
    • Journal of IKEEE
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    • v.19 no.3
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    • pp.327-334
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    • 2015
  • Various types of middle-ware were created for integration between legacy systems and newly built systems. RPC(Remote Procedure Call), MOM(Message Oriented Middle-ware) and TM(Transaction processing Monitor) are the typical types of middle-ware. One of the most known MOM type middle-ware is PS(Publish/Subscribe). PS enables to create a system which has low coupling and high scalability. But PS based systems also have low cohesiveness. On the contrary, RPC has high cohesiveness but also has high coupling. This paper proposed design and implementation of hybrid model which offset disadvantages of RPC and PS.

Effect of Antifoam Agents on $\Delta^1$-Dehydrogenation of Hydrocortisone (Hydrocortisonee 의 $\Delta^1$-Dehydrogenation 에서 소포제의 영향)

  • Chung, Bong-Hyun;Son, Jung-Duk;Park, Young-Hoon
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.219-223
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    • 1989
  • Effect of antifoam agents, silicone oil and neolin 302, was investigated on the production of prodnisolone by microbial $\Delta$$^1$-Dehydrogenation of hydrocortisone. The microbial process was conduct-ed by using a pseudo-crystallofermentation. By the hydrophobic-hydrophobic interaction, the steroid crystals aggregated with the antifoam agents. The aggregation resulted in a decrease of total mass transter area of substrate particles which is proportional to the dissolution rate of the solid substrate, and it consequently led to a significant decrease of the bioconversion rate. The bioconversion with neolin proceeded more slowly than with silicone oil. Increase of the concentration of the antifoam agents also yielded a significant decrease of the bioconversion rate.

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