• Proceedings of the Materials Research Society of Korea Conference
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• 1994.11a
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• pp.81-82
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• 1994

히토류 불화물인 SmF$_3$, PrF$_3$, 및 TbF$_3$를 ZnS 모체에 첨가한 박막 EL소자를 Fig.1과 같이 제작하고 발광중심의 농도변화, 열철, 증착시의 기판온도, 증착되는 막의 두께 등의 조건을 변화시켜서 각 조건에 의존하는 소자의 특성을 X-선회절분석과 분광 스펙트럼 분석으르 바탕으로 해석했다. 광학적 스펙트럼은 발광중심과 모체에 의존하며 기판온도의 변화는 발광층의 결정성 향상에 기여한다는 것을 알았다. 기판 온도의 변화에 의한 막의 결정성 향상과 열처리에 의한 발광중신의 모체내 열확산에 따른 재결정화나 비 방사성이완(non-radiative relaxation)을 일으키는 격자결함의 감소는 EL소자의 발광층내 전도전자에 영향을 미쳐 휘도와 효율의 개선이 이루어짐을 알았다. 소자의 발광층에 흐르는 전도전류와 이동전하량을 각각 Chen-Krupka회로와 Sawyer-Tower회로로 측정했다

• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.134-135
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• 2002

Sm$^{2＋}$가 도핑된 불화물 결정은 실온에서 영구적 스펙트럼 홀 생성이 나타나며, 이러한 실온에서의 영구적 스펙트럼 홀 생성은 새로운 광 메모리의 개발에 매우 중요하므로 많은 관심을 받고 있다. 본 연구에서는 Sm$^{2＋}$가 도핑된 10Al$_2$O$_3$.90SiO$_2$ 박막을 제조하여 SEM 및 발광 스펙트럼(Photo-Luminescence; PL)을 측정함으로서 제조된 박막의 구조적, 광학적 특성을 조사하였다. (중략)

• Journal of the Korean Ceramic Society
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• v.36 no.10
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• pp.1087-1093
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• 1999

Bioglass which is one of the surface active bionmaterials has a good biocompatibility but a poor mechanical strength, In the present work therefore two types of fluoride-containing bioglasses were coated on an alumina to improve mechanical strength. Crystallization of the coating layer and the hydroxyapatite formation on the bioactive glass coatings in tris-buffer solution were studied. When bioactive glass coated alumina was heat-treated Na2CaSi3O8 crystal was formed on the layer at lower temperature while wollastonite(CaSIO3) was obtained at higher temperature. Hydroxyapatite forming rate on the coating layer with Na2CaSi3O8 crystal was delayed with SiO2 contents in glass composition. However the hydroxyapatite was developed in 20minutes regardless SiO2 contents when the coating layer crystallized into wollastonite. More amount of P3+ ions were leached out of the coating layer with wollastonite than that with Na2CaSi3O8 crystal while Na+ and Ca2+ ions were leached out more easily from the Na2CaSi3O8 crystal containing coating layer.

• The Safety technology
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• no.198
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• pp.26-28
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• 2014

2년 전인 지난 2012년 9월 27일 경북 구미4공단에 소재한 휴브글로벌에서 불화수소가 누출되는 사고가 발생했다. 이 사고로 근로자 5명이 사망하고 23명이 부상을 당했다. 사고 후 불화수소가 공기를 통해 대량 퍼지면서 인근 지역도 막대한 피해를 입었다. 사고는 안전관리측면에서 많은 허점을 드러냈다. 사업장은 물론 관할 소방서, 구미시 모두에서 화학사고에 대한 대응 매뉴얼과 협조체계가 제대로 구축되지 않아 피해의 확산을 막지 못했다. 너무나 허술한 화학사고 대응체계의 현실에 구미시민은 물론 전 국민이 분노했다. 이에 정부는 화학물질관리 및 사고대응 시스템 전면에 대한 대대적인 개선에 돌입했다. 그리고 그 결과물이 지난해 12월 초 모습을 드러냈다. 관계부처, 지자체, 소방당국, 안전보건공단까지 한데 모여 효과적인 화학사고 예방과 대응을 전담하는 화학재난 합동방재센터가 전국에서 처음으로 구미에 문을 연 것이다. 그로부터 반년이 흐른 지금 구미에는 어떤 변화가 생겼을까. 달라진 화학재난 안전관리체계를 확인해보고자 구미119화학구조센터를 찾아가봤다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.190-191
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• 2014

마그네슘 합금을 생체재료로 사용되는데 두가지 중요한 문제점을 가지고 있다. 매우 빠른 부식을 가지고 있으며, 초기 빠른 부식으로 수소기체를 발생하여 인체 내 피부나 골조직의 괴사를 동반한다. 이러한 문제점을 해결하기 위해 생체적합성이 뛰어난 아노다이징 방법을 개발 하였으며, 새롭게 개선된 방법의 특징을 비교하기 위해 이번 실험에서는 불화물이 포함된 전해액으로 아노다이징 처리한 샘플을 제조하여 형태학 분석을 진행 하였고, Hank's solution(생체모사용액)을 사용하여 부식 특성을 분석하였다. 또한 L929 세포를 이용하여 세포독성 평가를 진행하였다. 새롭게 제조한 방법은 기존의 방법과 비교하였을 때, 부식 성능은 비슷하고 생체적합성이 높아 생분해성 금속의 표면처리에 적합하다고 판단된다.

• Journal of Preventive Medicine and Public Health
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• v.4 no.1
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• pp.31-34
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• 1971

This study was conducted by the Dept. of Preventive Medicine, Kyung Hee University, School of Medicine as a preliminary test for the effects of Fluorine Compounds to the Plants from April through August, 1971. Fluorine was measured with Zirconium-Alizarine method and the following findings could be obtained: 1. Most high densities (25.7 pptm) was found around the industrial areas and lowest (19.3 pptm) around residential sections in Seoul. 2. Average density of Fluorine in the atmosphere of Seoul City was 22.3 pptm which can damage such plants as Pine, Strawberry, Peach and Grapes. 3. Fluorine contents (22.3 pptin) in Seoul area atmosphere shows about 4 times more than that of Cincinnati, Ohio, U. S. A.

• Proceedings of the Materials Research Society of Korea Conference
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• 1993.11a
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• pp.69-71
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• 1993

Fluoride compound potentiometric cell oxygen sensors were fabricated for the measurement of oxygen pressure in the low temperature range (300。K-500。K). The disk type sensors consist of a reference Air(0$_2$):Ag, a solid electrolyte SrF$_2$, and a sensing metel Ag electrode. And the buried reference electrode type sensor have a NiO/Ni reference electrode. The open circuit emf of the cell showed high sensivity to oxygen gas (60mv) at the measuring temperature 20$0^{\circ}C$. Also, The buried reference electrode type sensor showed 30mv from 1% to 10% oxygen pressure range.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.704-710
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• 2017

Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.2
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• pp.127-137
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• 2019

Zr electrorefining is demonstrated herein using Zirlo tubes in a chloride-fluoride mixed molten salt in the presence of $AlF_3$. Cyclic voltammetry reveals a monotonic shift in the onset of metal reduction kinetics towards positive potential and an increase in intensity of the additional peaks associated with Zr-Al alloy formation with increasing $AlF_3$ concentration. Unlike the galvanostatic deposition mode, a radial plate-type Zr growth is evident at the top surface of the salt during Zr electrorefining at a constant potential of -1.2 V. The diameter of the plate-type Zr deposit gradually increases with increasing $AlF_3$ concentration. Scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDX) and X-ray photoelectron spectroscopy (XPS) analyses for the plate-type Zr deposit show that trace amount of Al is incorporated as Zr-Al alloys with different chemical compositions between the top and bottom surface of the deposit. Addition of $AlF_3$ is effective in lowering the residual salt content in the deposit and in improving the current efficiency for Zr recovery.

• Journal of Industrial Convergence
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• v.21 no.10
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• pp.57-63
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• 2023

This study aims to elucidate the effect of glycyrrhizic acid on smooth muscle contraction and to determine the detailed mechanism incorporated. We hypothesized that glycyrrhizic acid played a role in the agonist-sensitive management of smooth muscle contraction. Stripped smooth muscles of Sprague-Dawley rats were prepared in organ baths and isometric tensions were converted, stored and analyzed by using isometric transducers, a physiograph and one way ANOVA. Interestingly, glycyrrhizic acid attenuated the thick filament regulating agonist (fluoride or thromboxane mimetic)-sensitive contraction (p=0.113, 0.008, 0.004 (Student's t-test), p=0.113, 0.008, 0.004 (One way ANOVA) at 0.01, 0.03, 0.1 mM fluoride, and p=0.156, 0.004, 0.003 (Student's t-test), p=0.156, 0.004, 0.003 (One way ANOVA) at 0.01, 0.03, 0.1 mM thromboxane mimetic) and did not attenuate the thin filament regulating agonist (phorbol ester)-induced contraction (p=0.392, 0.086, 0.065 (Student's t-test), p=0.392, 0.086, 0.065 (One way ANOVA) at 0.01, 0.03, 0.1 mM phorbol ester). It is suggesting that endothelial EDRF (NO) synthesis and accessory pathways besides endothelial EDRF (NO) synthesis such as ROCK restriction might be incorporated in the glycyrrhizic acid-induced modulation of smooth muscle contraction inhibiting acto-myosin interaction.