• Title/Summary/Keyword: 부식열화

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Assessment of Material Degradation of High-Temperature Components for Process Plant by Grain Boundary Etching Method (입계부식법에 의한 공정설비 고온요소의 재질열화 평가)

  • Han Sang In;Yoon Kee Bong;Kim Ji Yoon;Chung Se Hi
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.74-82
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    • 1998
  • The grain boundary etching method as a technique for assessing degradation of structural materials used at elevated temperature has received much attention since it is simple, inexpensive and easy to apply to real plant components. In this study, the technique is applied to some aged petroleum and chemical plant components such as reactors and drums. As a degradation parameter, intersection number ratio ($N_i/N_o$), is employed. The intersection number ratio ($N_i/N_o$) is defined as the ratio of intersection number ($N_i$) obtained from 5-minute picric acid etched surface to the number ($N_o$) obtained from Nital etched surface. In order to study degradation level, several relationships were measured such as the correlation between shift in ductile brittle transition temperature, $({\Delta}DBTT)_{sp}$ and intersection number ratio, ($N_i/N_o$) and the correlation between the measured ($N_i/N_o$) values and Larson-Miller Parameter values.

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Experimental Studies on Comparison of Stress Corrosion Cracking Generation Due to Pipe Material Degradation in the Primary Stage of the Nuclear Power Plant (원전 1차 측 배관재질의 열화에 따른 응력부식균열 발생 비교 실험 연구)

  • Park, Kwang-Jin;Lee, Gyu-Young;Bae, Dong-Ho
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.108-113
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    • 2007
  • In this report, stress corrosion cracking generation due to pipe material degradation in the primary stage of the nuclear power plant was investigated. Firstly, after artificially degrading the CF8A steel during 2, 4, and 6 months in actual temperature, $400^{\circ}C,$ assessed corrosion susceptibility of the degraded material following ASTM G5 standard. And next, the S.C.C. tests for the degraded material were conducted under the condition of $60^{\circ}C,$ 2wt.% H2BO3+Li70H solution, 0.8 oy. From the results, Corrosion rates linearly increased with degradation period and solution temperature increase. And both the raw material and the degraded materials were not failed in the S.C.C. test condition. In spite of long time test (about 3,900 hrs) under S.C.C. condition, surface pits or surface corrosion by the electro chemical reaction were not observed. And also, even though the nondestructive DCPD and ACPD methods were applied to on-line monitor the S.C.C. failure processes it was impossible because the surface pits and cracks were not generated.

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Fundamental Study on Developing Embedded Mini-Sensor for Nondestructive Diagnosis Corrosion of Rebar (비파괴 철근 부식 진단을 위한 매립형 미니센서 개발에 관한 기초적 연구)

  • Joh, Sung-Hyung;Lim, Young-Chul;Ismail, Mohamed;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.179-187
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    • 2010
  • Corrosion of rebar embedded reinforced concrete is the main cause of collapse and degradation of reinforced concrete structure. Degradation occurs in reinforced concrete structures from corrosion caused by the Chloride that the damage other than the severe degradation of the structure in terms of maintenance and construction when the huge expense required and deciding terms is hard. Therefore, early detection of rebar corrosion is important for efficient maintenance and repairing and planning. Meanwhile, how to evaluate the corrosion of the non-destructive measurements have been used a lot. In particular CM-II (corrosion meter) is used to measurement the natural potential, polarization resistance and the resistivity of the concrete, but has some disadvantages. Embedded mini-sensor has been developed in order to overcome these disadvantages. So Measurement corrosion for using the mini-sensor compares with the measured results CM-II (corrosion meter), the developed mini-sensor verify the validity.

입계부식법에 의한 고온플랜트 요소의 크리프 잔여수명 평가

  • 윤기봉;한상인;강태연;박종진
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1998.05a
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    • pp.71-76
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    • 1998
  • 고온플랜트 설비 고온요소의 재질열화 정도를 평가하기 위해서 사용되는 방법 중 입계부식법은 시험절차가 간단하고 실제 플랜트에서의 적용이 용이하여 안전 및 수명진단시에 많이 이용되어 왔다. 본 논문에서는 오랜 기간 고온에서 사용된 고온$\cdot$고압플랜트의 실기 요소에 입계부식법을 적용하여 재질의 고온에서의 장시간 노출에 의한 인성저하로 발생되는 잔여 수명을 평가한 결과를 제시하였다. (중략)

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Bond Behavior of Epoxy Coated Reinforced Concrete (에폭시수지 도막 철근콘크리트의 부착특성 연구)

  • 오병환;엄주용;권지훈
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.79-84
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    • 1993
  • 철근의 부식은 철근 콘크리트 구조물에 있어서 심각한 열화현상을 유발할 수 있으며 최근 들어 이로 인한 피해가 많이 보고되고 있다. 이와 같은 부식의 억제방안 중 철근에 직접 에폭시를 도막하는 것이 가장 효과적인 것으로 알려져 있다. 그러나 이 경우 에폭시 도막에 따른 부착성능의 저하가 우려되는 바 본 연구는 철근부식방지를 위해 에폭시를 도막한 철근의 부착특성을 고찰하기 위해 수행되었다. 주된 변수는 콘크리트 압축강도, 부착길이, 에폭시 도막두께이며 각 변수별로 부착특성의 변화를 관찰하였고 이를 통해 에폭시도막 철근의 사용성을 검토하였다. 본 실험결과에 기초하여 부착강도 예측식을 제안하였고 실험결과와 예측치를 비교하였다.

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Concrete Sewerage and Counterplan of Bacteriostasis (하수도시설 콘크리트와 방균대책)

  • 길배수;김규용;성길모;남재현
    • Magazine of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.64-70
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    • 2002
  • 도시 주민생활에 없어서는 안될 주요한 사회간접자본시설로서 하수도, 하수도처리시설 등의 콘크리트 구조물에 대한 부식열화는 현재 세계 각국에서 급속히 진행되고 있다. 콘크리트 구조물이 반영구적이라는 것으로 인식되어 있으나, 실제로는 사용수명이 급속히 단축되어, 특히 콘크리트가 처해있는 환경 중에 황화수소(H$_2$S) 등의 황산화합물이 다량으로 존재하고 있는 환경에서는 하수관 콘크리트의 부식에 의해 도로가 함몰되는 사례도 보도되는 등 시민생활에 큰 위험성을 동반하는 가능성을 배제할 수 없다.(중략)

Mechanical Deterioration of Overhead Transmission Lines by Forest Fires (산불에 의한 가공 송전선로의 기계적 열화 특성)

  • 김영달;김성덕;심재명;정동화;강지원
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.14 no.6
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    • pp.26-34
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    • 2000
  • The considerations for remaining life of ACSR (Aluminum Stranded Conductors Steel Reinforced) in transmission lines have become gradually important to hold reliability and stability of power supply. The remaining life of ACSR exposed to the atmosphere for a long period may rely on deterioration caused by environmental indices such as atmospheric corrosion, galvanic corrosion, crevice corrosion and fatigue corrosion. One of reduction of useful life in overhead transmission lines built on the ridge of mountain is often caused by forest fires.This paper deals with investigation of strength deterioration performance of ASCR due to fires through several testing and analyzing data for tension load and extension of blazed ACSR. Test samples are ACSR 480[$\textrm{mm}^2$] conductors, which are artificially fired to regular durations. Mechanical properties such as tension load and extension for fired ACSR conductors are tested and estimation functions for mechanical performances corresponding to fire duration are determined. As a result, it can be verified that both tension load and extension of ACSR are reduced by increasing fire duration. Hence, it is obvious that ACSR due to forest fires may lead to mechanical deterioration.

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Corrosion Resistance of Cr-bearing Rebar in Concrete Subjected to Carbonation and Chloride Attack (중성화와 염해의 복합 열화 환경하의 콘크리트 내에서의 Cr강방식철근의 방식성)

  • Tae, Sung-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.115-122
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    • 2006
  • Ten types of steel bars having different Cr contents were embedded in concretes with chloride ion contents of 0.3, 0.6, 1.2, and $2.4kg/m^3$ to fabricate specimens assuming such deteriorative environments. After being carbonated to the reinforcement level, these concretes were subjected to corrosion-accelerating cycles of heating/cooling and drying/wetting. The time-related changes in the corrosion area and corrosion loss of the Cr-bearing rebars were then measured to investigate their corrosion resistance. The results revealed that in a deteriorative environment prone to both carbonation and chloride attack, corrosion resistance was evident with a Cr content of 7% or more and 9% or more in concretes with chloride ion contents of 1.2 and $2.4kg/m^3$, respectively.

Evaluation of Deterioration of Epoxy Primer for Steel Bridge Coating using Image Processing and Electrochemical Impedance Spectroscopy (화상처리 기법과 전기화학적 임피던스 분광법을 이용한 강교 도장용 에폭시 하도 도료의 열화 평가)

  • Lee, Chan Young;Lee, Sang Hun;Park, Jin Hwan
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.53-61
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    • 2009
  • In this study, both evaluations by visual imaging for exterior view of coating and by EIS were executed for epoxy primer coated specimens deteriorated by accelerated test, and comparison and analysis were carried out for 2 evaluation methods. In the comparison between total damaged area ratio acquired by image processing method and deterioration point, higher deterioration points were appeared for rusted specimens than for non-rusted specimens. It is attributed that deterioration point per unit area ratio given for rust is higher than for peeling. In the comparison between total damaged area ratio and EIS result, impedance of coating was largely decreased as about TEX>$10^4{\Omega}{\cdot}cm^2$ or less when rust area ratio is more than about 0.1%, and blistering area ratio is more than about 3%. Charge transfer resistance ($R_{ct}$) and double layer capacitance ($C_{dl}$) values were appeared for all specimens except 2 ones, which shows that water is accumulated and steel substrate is corroded at coated film-steel interface. In the comparison between deterioration point and EIS result, more than 10 points as deterioration point were given for specimens of below $10^6{\Omega}{\cdot}cm^2$ of impedance at low frequency. For specimens deteriorated by NORSOK cyclic test, impedance was lowest of all, though deterioration point was not high. It is thought to be attributed that coating system and accelerated deterioration condition of cyclic tested specimens were different from those of main specimens. From the result, it is thought that coating resistance can be relatively more decreased than deterioration degree estimated from exterior view under more severe corrosion environment or in the present of more complex deterioration factors.