• Title/Summary/Keyword: 부식억제

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A Study on the Effect of Corrosion Prevention in Water Distribution System by Galvanized Zinc-Brass Pipe (아연-황동관에 의한 배관 부식 억제 효과에 관한 연구)

  • Song, Seung-Joon;Cho, Young-Guen;Kim, Jin-Han
    • Journal of Urban Science
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    • v.7 no.1
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    • pp.23-27
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    • 2018
  • This research was carried out to investigate the corrosion prevention effect in the water distribution system by galvanized zinc-brass pipe which is using potential between brass and zinc. As a result of this study, pH and conductivity of influent were constant in spite of its installation, and it was difficult to estimate the effect of the installation with temporary increased and reduced concentration of Zn and Fe ions, respectively. However, since the corrosion rate of the steel coupon with galvanized zinc-brass pipe was relatively low, it has an effect of inhibiting corrosion.

The Study on the Micro Structure Change and Corrosion Resistance Improvement of AI Alloy by Nitrogen Ion Implantation (질소이온주입에 의한 AI 합금의 조직변화 및 내식성 향상에 관한 연구)

  • 엄기원;윤주선;한전건;연윤모
    • Journal of the Korean Vacuum Society
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    • v.4 no.2
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    • pp.183-188
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    • 1995
  • 고에너지(50-200KeV)로 가속된 이온을 모재표면에 물리적으로 투입하므로써 표면의 조성 및 조직을 변화시키는 공정인 이온주입기술을 이용하여 경량고강도소재로 각광받고 있는 AI2218 합금의 재식성 향상을 연구하였다. 질소이온주입은 DuoPIGatron 이온원을 사용하여 가속전압 100KeV, 조사량 $1{\times}10^{17}ions/\textrm{cm}^2$~$5{\times}10^{17}ions/\textrm{cm}^2$의 조건으로 행하였으며 AI합금의 열화를 방지하기 위하여 시편온도를 $60^{\circ}C$이하로 유지하였다. 질소이온 주입재의 재식성 평가를 위하여 3.5% NaCI 용액에서 양극분극시험 및 5% NaCI 용액에서 염수분무시험을 행하였다. Auger Electron Spectroscopy와 Transmission Electron Microscopy을 이용하여 표면의 질화물형성 여부를 조사하였으며, Scanning Electron Microscopy을 이용하여 부식된 표면을 관찰하였다. AI2218합금에 질소이온을 주입한 결과 표면에 미세한 AIN 석출물을 형성하였으며 이러한 질화물형성에 의해 공식(pitting)발생을 억제하고 부식전류밀도를 감소시켜 내식성이 향상되었다.

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Effect of Cathodic Protection on Erosion-Corrosion Control in Alloy Metals of Marine Bearing (舶용 베어링 합금재의 침식-부식억제에 미치는 음극방식의 효과)

  • 임우조;이진열
    • Tribology and Lubricants
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    • v.11 no.1
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    • pp.58-65
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    • 1995
  • When marine lubricating oil began to be emulsified and oxidized through ingressive water that have leaked from cooling pump seal systems, cooler, purifier system and piping system, the cavitation erosion-corrosion in alloy metals of bearings remains to the various troublesome problem at effective engine performance. Therefore, applied the cathodic protection to the control test of cavitation erosion-corrosion, and appointed the marine system oil containing 3% sea water as test environments, with different conductibility. Also, used the piezoelectric vibrator with 20 KHz, 24 $\mu$m as the cavity generation apparatus, and examined the weight loss, potential value, current density etc. in specimens with those condition. According to this testing data, investigated influence of cathodic protection on the control characteristics of cavitation erosion-corrosion, and will serve those as an elementary design data of marine bearing.

The Effects of Fluorine Passivation on $SF_6$ Treatment for Anti-corrosion after Al(Cu 1%) Plasma Etching (Al(Cu 1%)막의 플라즈마 식각후 부식 억제를 위한 $SF_6$ 처리시 fluorine passivation 효과)

  • 김창일;권광호;백규하;윤용선;김상기;남기수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.3
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    • pp.203-207
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    • 1998
  • After etching Al-Cu alloy films using $SiCl_4/Cl_2/He/CHF_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS (X-ray photoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, the $SF_6$ plasma treatment subsequent to the etch has been carried out. A passivation layer is formed by fluorine-related compounds on etched Al-Cu alloy surface after $SF_6$ treatment, and the layer suppresses effectively the corrosion on the surface as the RF power of $SF_6$ treatment increases. The corrosion could be suppressed successfully with $SF_6$ treatment in the RF power of 150watts.

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EFFECT OF MAGNETIC FIELD STRUCTURE NEAR CATHODE ON THE ARC SPOT STABILITY OF FILTERED VACUUM ARC SOURCE OF GRAPHITE (자장 여과 진공 아크 소스에서 음극 부근의 자기장에 따른 아크 스팟 안정성 연구)

  • 김종국;이광렬;은광용;정기형
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.138-138
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    • 1999
  • 자장 여과 진공 아크법(Filtered Vacuum Arc :FVA)에 의해 증착된 비정질 다이아몬드 박막은 기계적, 광학적 특성이 매우 우수하여 많은 연구자들의 관심의 대상이 되어 왔다. 그러나 아크의 불안정성은 자장 여과 아크 소스의 연속적인 운전을 제한하고, 결과적으로 낮은 생산성을 가져왔다. 본 연구에서는 음극의 형태 및 음극 부근에서의 자기장의 구조를 음극 부식 거동의 관점에서 수치모사 및 실험을 통해서 조사하였다. 소스 전자석과 인출 전자석의 자극 방향이 평행하게 된 구조에서 (magnetic mirror configuration), 음극 후면에 반대 방향의 자극을 가지는 영구자석을 돔으로서 아크 불안정성을 억제할 수 있었다. 또한 소스 전자석에 진동하는 전류를 인가함으로써 아크 스팟의 운동 면적을 효과적으로 확장할 수 있었다. 시간 변화에 따른 빔 전류의 변화로부터 테이프형 음극이 우물형 음극에 비하여 더 안정하다는 것을 확인하였다. 진동하는 소스 전자석의 전류와 직경 80mm의 테이퍼형 음극을 사용하여, 아크 전류 60A에서 약 2000분 동안 사용하였으며, 이때 부식된 부피는 사용 가능한 음극 부피의 약 90%였다. 그리고 약 350mA의 안정한 빔 전류를 현재의 조건에서 얻었다.

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Research of Energy Efficiency for Power Plant Performance Improvement (발전성능 향상을 위한 에너지 효율 연구)

  • Lee, Jae-Keun;Moon, Jeon-Soo
    • Journal of Hydrogen and New Energy
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    • v.21 no.3
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    • pp.220-226
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    • 2010
  • The heat transfer performance improvement in closed cooling water system of an electric power generation can be achieved by a corrosion control using corrosion inhibitors. The effect of trisodium phosphate and sodium nitrite upon carbon steel at various $Cl^{-1}$ ion containing water concentrations was examined by an integrated corrosion monitoring system. Nitrite was found to be the most effective inhibitor among tested inhibitors for carbon steel. The inhibiting process is considered as adsorption of nitrite ions in oxide layer which form a passive film on the carbon steel surface.

Antibiosis Evaluation of Antimicrobial Mortar by Artificial Accelerating Test for Biochemical Corrosion (생화학적 부식 인공촉진시험에 의한 항균모르타르의 항균성능 평가)

  • Koo, Kyung-Mo;Shin, Kwan-Soo;Roh, Kyung-Min;Lee, Eui-Bae;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.33-36
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    • 2007
  • In this study, an antibiosis of antimicrobial mortar developed to reduce biochemical corrosion of sewage facilities concrete was evaluated. First, artificial acceleration test reflecting similarly biochemical corrosion of mortar was developed. Antimicrobial mortar specimen were experimented in this test and antibiosis of it was evaluated by SEM and EDX. As a results of the study, sulfur-oxidizing bacteria on the plain specimen were survived for 20 weeks in this test. But sulfur-oxidizing bacteria on antimicrobial specimen were survived less than the plain, and sulfur-oxidizing bacteria were externally distorted and destroyed. So the antibiosis of an antimicrobial mortar was verified by it.

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증기발생기 전열관의 1차측 및 2차측 응력부식균열에 대한 온도효과 분석

  • 박인규;황일순;박원석;이상학;임승재
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.515-520
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    • 1996
  • 원자력 발전소 증기발생기의 1차측 및 2차측 응력부식균열에 대한 온도감소 효과를 고리 1호기의 현장 데이터를 근간으로 분석하였다. 고리 1호기의 경우 출력을 100%에서 85%로 감소시키므로써, 고온관 온도는 320.5$^{\circ}C$에서 313.5$^{\circ}C$로 7$^{\circ}C$ 감소하였으며, 이와 같은 온도감소 효과로 PWSCC 손상률은 약 40%, ODSCC 손상률은 약 33% 감소하는 것으로 산출되었다. PWSCC의 경우 Weibull 기울기는 b = 5.6 에서 b : 3.8로 감소한 것으로 나타났다. PWSCC의 억제방안으로는 출력감발에 의한 온도감소가 가장 효과적이지만, ODSCC의 경우에는 틈새 분위기의 변환이 큰 역할을 하는 것으로 나타났다.

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Effect of Hybrid Inhibitor on the Mitigation of Corrosion Initiation in SCP Solution Contaminated 3.5 wt.% NaCl (3.5 wt.% NaCl로 오염된 SCP 용액의 부식 개시 완화에 대한 하이브리드 억제제의 효과)

  • Tran, Duc Thanh;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.65-66
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    • 2021
  • In this study, the optimum amount of hybrid inhibitors i.e. L-Arginine (LA) and sodium phosphate tribasic dodecahydrate (SP), applied for carbon steel rebar in simulated pore concrete (SCP) solution contaminated with 3.5 wt.% NaCl, was discovered. The corrosion inhibition performance of hybrid inhibitors was investigated by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization. The highest corrosion inhibition efficiency was found as 99.52% corresponding to 2% LA and 0.25% SP after 210 h exposure. Anodic type inhibition action was confirmed by potentiodynamic polarization study. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate with electrochemical studies.

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Grain Boundary Character Changes and IGA/PWSCC Behavior of Alloy 600 Material by Thermomechanical Treatment (가공열처리에 의한 Alloy 600 재료의 결정립계특성 변화와 입계부식 및 1차측 응력부식균열 거동)

  • Kim, J.;Han, J.H.;Lee, D.H.;Kim, Y.S.;Roh, H.S.;Kim, G.H.;Kim, J.S.
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.919-925
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    • 1999
  • Grain boundary characteristics and corrosion behavior of Alloy 600 material were investigated using the concept of grain boundary control by thermomechanical treatment(TMT). The grain boundary character distribution (GBCD) was analyzed by electron backscattered diffraction pattern. The effects of GBeD variation on intergranular at tack(JGA) and primary water stress corrosion cracking(PWSeC) were also evaluated. Changes in the fraction of coinci dence site lattice(CSL) boundaries in each cycle of TMT process were not distinguishable, but the total eSL boundary frequencies for TMT specimens increased about 10% compared with those of the commercial Alloy 600 material. It was found from IGA tests that the resistance to IGA was improved by TMT process. However, it was found from PWSCC test that repeating of TMT cycles resulted in the gradual decrease of the time to failure and the maximum load due to change in grain boundary characteristics, while the average crack propagation rate of primary crack increased mainly due to suppression of secondary crack propagation. It is considered that these corrosion characteristics in TMT specimens is attributed to 'fine tuning of grain boundary' mechanism.

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