• Title/Summary/Keyword: 부식액

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강재의 압연유

  • 김재중
    • Journal of the KSME
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    • v.31 no.4
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    • pp.389-400
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    • 1991
  • 압정가공은 열간압정과 냉간압정으로 크게 나눌 수 있으며, 압정기와 피압정재의 종류에 따라 서도 분류한다. 열간압정에서는 알루미늄과 알루미늄합금을 제외하고는 종래에 오직 물만이 냉각겸 윤활제로 사용되어 왔다. 그러나 근년에 와서 열간압정에서도 윤활유를 사용하게 됨으 로서 롤(roll)의 수명연장, 전력소비량의 저감 및 사상(finishing) 강판의 표면품질향상등에 극히 유효하다는 것을 인식하게 되었다. 한편 냉각압정에서는 압정유를 사용해 온 것이 100년 가까이 되는 역사가 있고, 특히 과거 십 수년간에는 상당히 광범위하게 연구가 이루어져서, 많은 실적을 갖게 되었다. 예컨대, 석도원판으로 대표되는 박판압정에 있어서는 고속고압하에서 판의 형상 및 표면정쟁성 향상은 물론이고 저온(에너지 절감, 작업성 개선) 저농도사용(원단위감소)이 이루어 지고, 나아가 장수명(액의 오염이 적은 것)의 압정유가 개발되었다. 또한 마대강 압정에 있어 서는 고윤활이면서도 ECL(electric cleaning line)의 성략도 가능한 압정유 즉 밀크린시트(mill clean sheet) 압정유의 연구도 활발히 진행되고 있다. 압정유의 역할을 살펴보면 열간 또는 냉 간을 불문하고, 롤과 재료간의 감마작용이 주가 되지만 기타 실용적으로는 (1)냉각성 (2)판의 끝맺음(finishing)성 (3)선정선 (4)방장성,비부식성 (5) 내노화성 (6) 오일.스테인(oil stain) (7) 급 유성 (8)액관리성 (9)비수처리성 10) 안전위생 (11)경제성 등을 열거할 수 있다.

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Nitrogen fractionation of organic materials applied to Korean ginseng (고려인삼(高麗人蔘) 유기질비료의 질소성장(窒素性狀)에 대하여)

  • Hong, Jung-Kook;Park, Hoon;Lee, Chong-Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.12 no.2
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    • pp.91-97
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    • 1979
  • 1. Nitrogenous compounds of-organic materials as nitrogen sources for Korean ginseng were characterized according to their solubility and chemical forms. 2. The extractable fractionation was as follows : Yakto group : non-extractable N > acid hydrolyzable N > acid nonhydrolyzable N > water sol. N, Litter group : acid hydrolyzable N > non-extractable N > water sol. N > acid non-hydrolyzable N, Bone meal : acid hydrolyzable N > water sol. N > acid non-hydrolyzable N. 3. Nitrogenous compounds in the water sol. fraction were : Yakto group and Litter group : humus N > amino acid N > nitrate N (recognized only in Yakto group) > ammonia N > hexosamine N > amide N, Bone meal : amino acid N > humus N > ammonia N > amide N. And nitrogenous compounds in the acid hydrolyzable fraction were : amino acid N > humus N ${\simeq}$ ammonia N > hexosamine N. 4. Availability was discussed about the major nitrogenous compounds (amino acid, humus and inorganic N) and the solubility.

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Effect of Vanadium Addition on the Cavitation Erosion Resistance of Fe-Cr-Ni-Si-C Hardfacing Alloy (Fe-Cr-Ni-Si-C계 경면처리 합금의 Cavitation Erosion 저항성에 미치는 Vanadium 첨가의 영향)

  • 김경오;김준기;장세기;김선진;강성군
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.11a
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    • pp.72-72
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    • 1998
  • 원자력발전소 1차계통내 밸브의 경면처리(hardfa따1잉에 사용되는 재료는 $90~343^{\circ}C$의 고온과 높은 접촉응력 그리고 급격한 압력변화가 일어나는 환경에서 사용되기 때문에 내마모성과 내식성 그리고 cavitation erosion 저항성이 우수한 Co계 Stellite 합금이 현재 사용되어진다. 그러나 Co가 원력발전소 1차계통의 방사선장을 형성하는 주요 원소로 알려지면서 S Stellite 합금을 대체할 수 있는 Fe계 경면처리용 합금을 개발하려는 연구가 진행되고 있다. 현재 Fe계 경면처리용 합금의 개발은 적절환 팝금원소를 첨가하여 적충결함에너지를 낮춤 으로써 전위의 교차슬립을 억제하여 표면을 경화시키고, 소성변형을 억제하여 마모저항성을 향상시키려는 방법으로 연구가 진행되고 있다. 본 연구에서는 Fe-Cr-Ni-Si-C 합금에 Fe계 합금의 적충결함에너지를 감소시키는 것으로 알려진 vanadium을 0, 1, 2wt%첨가하여 첨가량의 변화가 cavitation erosion 저항성에 미치 는 영향을 조사하였다. Cavitation erosion 실험은 초음파를 이용하여 미세한 기포를 발생시키는 vibratory type으로 A ASTM G-32 규격에 따라 제작된 실험장치를 이용하여 $25{\pm}2^{\circ}C$의 온도의 증류수 속에 잠긴 상태에서 실시하였다. 시면은 지름 16mm, 두게 7mm의 버턴형태로 vanadium 첨가량을 변화시킨 조성을 아크 용융 방법을 이용하여 제작하였으며 hom끝단부에 부착하여 cavitation e erosion 저항성 살험을 하였다. 시편의 cavitation erosion 실험시간에 따른 무게감소량을 측 정하였으며 cavitation erosion 시킨 시편의 표면을 SEM으로 관찰하였다.겨지는 열전달 매체액 과 신규 부식억제제가 적용된 시스템 등 객관적으로 확인된 부식억제제 시스랩에 대 하여 다양한 평가 방법을 동원 비교분석하고자 하였다. 실험은 KSM 2142에 의한 무게감량법, 분극곡선 측정에 의한 $E_P$(공식개시전위), $E_R$(재부동태화전위) 측정, 시간에 따른 자연전위 변화 측정 빛 이때의 부식속도(선형분극법), 인위적인 피막 파괴 전,후 의 전위 변화 및 부식속도 측정법에 의한 국부부식 발달 저지능 등을 평가하여 각 실험결과를 비교분석하여 보았다. 수록 민감하여 304 의 IGSCC 와 매우 유사한 거동을 보인다. 본 강연에서는 304 와 600 의 고온 물에서 일어나는 IGSCC 민감도에 미치는 환경, 예민화처리, 합금원소의 영향을 고찰하고 이에 대한 최근의 연구 동향과 방식 방법을 다룬다.다.의 목적과 지식)보다 미학적 경험에 주는 영향이 큰 것으로 나타났으며, 모든 사람들에게 비슷한 미학적 경험을 발생시키는 것 이 밝혀졌다. 다시 말하면 모든 사람들은 그들의 문화적인 국적과 사회적 인 직업의 차이, 목적의 차이, 또한 환경의 의미의 차이에 상관없이 아름다 운 경관(High-beauty landscape)을 주거지나 나들이 장소로서 선호했으며, 아름답다고 평가했다. 반면에, 사람들이 갖고 있는 문화의 차이, 직업의 차 이, 목적의 차이, 그리고 환경의 의미의 차이에 따라 경관의 미학적 평가가 달라진 것으로 나타났다.corner$적 의도에 의한 경관구성의 일면을 확인할수 있지만 엄밀히 생각하여 보면 이러한 예의 경우도 최락의 총체적인 외형은 마찬가지로 $\ulcorner$순응$\lrcorner$의 범위를 벗어나지 않는다. 그렇기 때문에도 $\ulcorner$

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Real-time measurement of dentinal fluid flow during desensitizing agent application (상아질 지각과민 처치제의 적용 중에 일어나는 상아세관액 유동의 실시간 측정)

  • Kim, Sun-Young;Kim, Eun-Joo;Lee, In-Bog
    • Restorative Dentistry and Endodontics
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    • v.35 no.5
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    • pp.313-320
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    • 2010
  • Objectives: The aim of this study was to examine changes in the dentinal fluid flow (DFF) during desensitizing agent application and to compare permeability after application among the agents. Materials and Methods: A Class 5 cavity was prepared to exposure cervical dentin on an extracted human premolar which was connected to a sub-nanoliter fluid flow measuring device (NFMD) under 20 cm water pressure. DFF was measured from before application of desensitizing agent (Seal&Protect, SP; SuperSeal, SS; BisBlock, BB; Gluma desensitizer, GL; Bi-Fluoride 12, BF) through application procedure to 5 min after application. Results: DFF rate after each desensitizing agent application was significantly reduced when compared to initial DFF rate before application (p < 0.05). SP showed a greater reduction in DFF rate than GL and BF did (p < 0.05). SS and BB showed a greater reduction in DFF rate than BF did (p < 0.05). Conclusions: Characteristic DFF aspect of each desensitizing agent was shown in NFMD during the application procedure.

Failure Mode of the Positive Plate on Charging Voltage in Gel Type Valve Regulated Lead Acid Batteries (충전전압에 따른 겔형 VRLA전지 양극판의 파손방식)

  • Oh Sanghyub;Kim Myungsoo;Lee Heung Lark
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.90-95
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    • 2000
  • Cycle life test was carried out to evaluate the failure modes of the gel type nth batteries at $C_5$ currents and $100\%$ DOD. When the batteries were charged at constant voltage of 2.40 V and 2.50 Vi respectively, cycle lift was over 1,000 cycles. The batteries lost 426.4 g and 391.2 g of electrolyte far each case after the weight measurement. The battery charged at 2.50 V was shown to have a better cyclic performance than charged at 2.40 V, and the amounts of electrolyte loss was proportional to charge factor. After cycle test, the micro-structure of positive active material was completely changed and the corrosion layer of positive grid was about $50{\mu}m$. Failure mode of the positive plate of the gel type battery was a shedding of the positive active material, and the cause of discharge capacity decrease was found to be a electrolyte loss.

Application of Surfactant added DHF to Post Oxide CMP Cleaning Process (계면활성제가 첨가된 DHF의 Post-Oxide CMP 세정 공정에의 적용 연구)

  • Ryu, Chung;Kim, You-Hyuk
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.608-613
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    • 2003
  • In order to remove particles on surface of post-oxide CMP wafer, new cleaning solution was prepared by mixing with DHF (Diluted HF), nonionic surfactant PAAE (Polyoxyethylene Alkyl Aryl Ether), DMSO (Dimethylsulfoxide) and D.I.W.. Silicone wafers were intentionally contaminated by silica, alumina and PSL (polystylene latex) which had different zeta potentials in cleaning solution. This cleaning solution under megasonic irradiation could remove particles and metals simultaneously at room temperature in contrast to traditional AMP (mixture of $NH_4OH,\;H_2O_2$ and D.I.W) without any side effects such as increasing of microroughness, metal line corrosion and deposition of organic contaminants. This suggests that this cleaning solution would be useful future application with copper CMP in brush cleaning process as well as traditional post CMP cleaning process.

THE EVALUATION OF MICROLEAKAGE OF PIT AND FISSURE SEALANT BY USAGE OF SELF-ETCHING ADHESIVE SYSTEM (자가 산부식 접착제를 이용한 치면열구전색의 미세누출 평가)

  • Kim, Hyun-Jin;Lee, Nan-Young;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.2
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    • pp.216-224
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    • 2008
  • The purpose of this study was to evaluate the effectiveness of fissurotomy and double application time of acidic primer of self-etching adhesive system of acid treatment on enamel surfaces for prevention of microleakage of pit and fissure sealants. The microleakage of pit and fissure sealants was evaluated by measuring the penetration depth of methylene blue solution. Specimens were divided by 4 groups according to the method of treatment. Group I: 35% phosphoric acid etching, 20 seconds. Group II: Priming with self-etching primer, 20 seconds. Group III: Priming with self-etching primer, 40 seconds. Group IV: Priming with self-etching primer, 20 seconds, after fissurotomy. The etched pattern produced on enamel was observed using a scanning electron microscope. Obtained data were analysed statistically using Kruscal-Wallis test followed by Mann-Whitney test for comparison of groups. The results are as follows: 1. Microleakage scores of group IV priming with self-etching primer 20 seconds after fissurotomy was the lowest. 2. Microleakage scores between group II and group III were not shown significant difference. 3. Enamel for 20 seconds etching with 35% phosphoric acid was observed the most effective etching pattern. And the etching pattern on the fissure enamel with self-etching adhesive 20 seconds after fissurotomy was more prominent than group II, III only using self-etching primer.

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Evaluation of Properties of Sulfur-Oxidizing Bacteria Growth and Resistance to Biochemical Corrosion by Simulation Test (시뮬레이션 시험에 의한 황산화세균의 생장 특성 및 생화학적 부식 저항성 평가)

  • Kim, Gyu-Yong;Lee, Eui-Bae;Khil, Bae-Su;Lee, Seung-Hun
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.495-502
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    • 2008
  • To analyze the growth of SOB(Thiobacillus novellus) and biochemical corrosion of concrete, simulation test method and device were developed, and basic conditions for SOB growth were established. Two types of simulation tests were conducted according to a transplant method and a concentration of $H_2SO_4$. As a result, the SOB growth in distinct manners and antibiosis of specimen were observed. In the case of the specimens indirectly transplanted with SOB through culture solution submersion at a hydrogen sulfide level of 120 ppm, the rapid activation of SOB and the resulting sulfuric acid production were observed. However, SOB were shown to grow rapidly and then die out in a relative short period of time. Meanwhile, in the case of the specimens directly transplanted with SOB at a hydrogen sulfide level of 50 ppm, the long-term growth of SOB was possible, but the production of sulfuric acid by SOB did not progress. In the case of the antibiotic metal-mixed specimens, SOB with destroyed cell membranes and internal organizations were observed.

Effects of Sealing Solution for Anodized Mg-Al Alloys and Its Corrosion Resistance Property (양극산화한 Mg-Al합금에 대한 봉공처리액 조성의 효과와 그 내식성)

  • 장석기;김정일;김성종
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.5
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    • pp.782-792
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    • 2004
  • The effects of sealing solution for anodized Mg-Al alloys and their corrosion resistance property were investigated. focusing on the effects of anodizing potentials aluminum contents and sealing solutions. All of the anodized specimens showed better corrosion resistance than that of non-anodized specimens, regardless of applied potentials. It was found that the anodic film formed at 4 V had the best corrosion resistance. The sealing effects were improved by increasing the temperature of distilled water. the pH of solution and the relative intensity ratio of $Mg(OH)_2$.

A Study on Etching Patterns of Copper Surface by Chemical Corrosion (동(銅) 표면(表面)의 화학부식(腐蝕)에 의한 식각(蝕刻) 패턴 연구)

  • Kim, Min-Gun;Seo, Bong-Won
    • Journal of Industrial Technology
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    • v.20 no.B
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    • pp.77-86
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    • 2000
  • In order to observe the pattern forming of copper plate and chemical corrosion reaction, a study on the effect of the process parameters on the formation of micro-pattern by a photochemical etching of copper plate was carried out. The results are as follows : 1) Etching rate increases as the concentration of etchant increases under the regular condition of the temperature by the increasing of diffusion rate to surface. 2) Etching rate increases as the temperature of etchant increases by the fast acting of the material delivery of diffusion to surface under the regular condition of concentration. 3) It was found that etching speed increases as the material delivery of convection rising increased when the aeration speed of etchant increases. This result was from the fact acted by the material delivery of convection rising rather than material delivery of diffusion to the surface.

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