• Title/Summary/Keyword: 부분용융

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Pseudo Liquid Crystallinity and Characteristics of PHB/PEN/PET Melt Blend (PHB/PEN/PET 삼상계 용융혼합물의 의사액정상 및 특성연구)

  • 박재기;정봉재;김성훈
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.113-123
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    • 2000
  • Poly(p-hydroxybenzoate) (PHB)/poly(ethylene terephthalate) (PET) 8/2 thermotropic liquid crystalline copolyester, poly(ethylene 2,6-naphthalate) (PEN) and PET were mechanically blended to obtain the pseudo liquid crystalline (LC) phase of ternary blends. The torque values of blends with increasing PHB content were abruptly decreased above 40 wt% of PHB content, because the melt viscosity of ternary blends decreased. Tensile strength and initial modulus of blends containing above 30 wt% PHB were improved with increasing PHB content. Tensile strength and modulus of fiber were increased with PHB contents and take-up speed. Degree of transesterification and randomness of blends were increased with blending time. The blend of 40 wt% PHB was shown pseudo LC phase in the polarized optical photographs. Crystallinity of PHB/PEN/PET ternary blend were increased with PHB content.

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Analysis with Directional Solidification in Silicon Melting Process (실리콘 용융 공정에서 방향성 응고에 관한 특성 분석)

  • Cho, Hyun-Seob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.3
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    • pp.1707-1710
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    • 2014
  • This paper is the study for the directional solidification of the ingot through the thermal analysis simulation and structural change of casting furnace. The activation analysis of metal impurities were also detected the total number of 10 different metals, but the concentration distribution showed no significant positional deviations in the same position from the top to the bottom. With the results of thermal analysis simulation, the silicon as a whole has reached the melting temperature as the retention time 80 min. The best cooling conditions showed at the upper cooling temperature $1,400^{\circ}C$ and cooling time 60min. The fabricated wafers showed the superior etching result at the grain boundary than that of existing commercial wafers.

Geochemical Studies of Petrogenesis of Hornblende Gabbro-Lamprophyre-Diorite Complex in Guwoonri, Hwacheon (화천 구운리 일대에 분포하는 각섬석 반려암-황반암-섬록암 복합체의 성인에 대한 지화학적 연구)

  • Kim, Guan-Young;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.18 no.2
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    • pp.153-169
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    • 2009
  • Hornblende gabbro-lamprophyre-diorite Complex in Guwoonri, Hwacheon distributes in a zonal pattern, where the diorite distributed along the margin of the Complex encompasses the hornblende gabbro body in the central part of the Complex, and lamprophyre intruded in vein along the boundary between diorite and hornblende gabbro. The hornblende gabbro in the central part of the Complex also shows a zonal distribution pattern, where hornblende gabbro containing subspherical amphibole phenocrysts as a major mafic mineral(Sag) surrounds hornblende gabbro with prismatic amphiboles as a principal mafic mineral(Pag). The zonal distributions observed in hornblende gabbro-lamprophyre-diorite Complex in Guwoonri resulted from two different geological processes. The zonal distribution among diorite, lamprophyre, and hornblende gabbro was due to intrusions of three distinct magmas derived from different degree of partial melting of a common source rock, whereas the zonal distribution shown within the hornblende gabbro body occupying the central part of the Complex resulted from an inward fractional crystallization of a single magma. Geochemical characteristics and mineral mode of hornblende gabbro, lamprophyre, and diorite indicate that these rocks formed from hydrous mafic to intermediate magma derived from partial melting of enriched mantle, which has been caused by infiltration of volatiles including water into mantle in plate margin.

Petrology of the Taeheung-ri Lava in Southeastern Jeju Island (제주도 남동부 태흥리 용암에 대한 암석학적 연구)

  • 윤성효;고정선;박정미
    • The Journal of the Petrological Society of Korea
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    • v.11 no.1
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    • pp.17-28
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    • 2002
  • This study has been designed to elucidate the petrography and geochemical characteristics of the Taeheung-ri lava in southeastern Jeju Island. The lava is divided into the alkaline basalt and tholeiitic basalt. More than 4 layers of tholeiitic basalt are overlain by layers of alkaline basalt. Compared with alkaline basalt, tholeiitic basalt has lower contents of $K_2O$, $P_2O_5$, Ba and Ta, but slight higher contents of $SiO_2$ and CaO. The contents of Ba and Rb of all basalts are enriched, but those of Ni and Cr are depleted compared with primitive mantle compositions. All basalts show inclined chondrite-normalized REE patterns with LREE enriched more than HREE and alkaline basalt has relatively higher. The basalts of this study area are plotted in the field of within plate basalt on the tectonomagmatic discrimination diagram. Tholeiitic basalt has higher ratios of Zr/Nb, Y/Nb, and $Al_2O_3/P_2O_5$ than alkaline basalt. Both tholeiitic and alkaline basalt are similar in their K/Ba ratios. The geochemical data suggest that the parental magma of both basalts might be produced by different degrees of partial melting of similar source mantle. The tholeiitic basalt formed by higher degree of partial melting than the alkaline basalt.

A Report on Gneiss Dome in the Hongseong Area, Southwestern Margin of the Gyeonggi Massif (경기육괴 남서 연변부 홍성지역에 발달하는 편마암 돔에 대한 보고)

  • Park, Seung-Ik;Kim, Sung Won
    • Economic and Environmental Geology
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    • v.49 no.4
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    • pp.315-323
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    • 2016
  • This study reports a gneiss dome in the Hongseong area, southwestern margin of the Gyeonggi massif. This gneiss dome, named here as 'Oseosan dome' because it is located around the Oseosan, the highest peak along the western coastal area, is composed mainly of the Neoproterozoic to Paleozoic ortho- and paragneiss, mafic metavolcanic rock, and metadolerite. Migmatization affected these rock units, in which leucocratic(granitic) materials derived from anatexis frequently occur as patch and vein parallel to or cutting through internal foliation. The Oseosan dome shows overall concentric geometry and outward-dipping internal foliation, but also partly complicatedly changeable or inward-dipping foliation. Taking available petrological and geochronological data into account, the Oseosan dome is interpreted to be exhumed quickly into the upper crustal level during the Late Triassic, accompanied in part with anatexis and granite intrusion. In addition, extensional shear zone intruded by the Late Triassic synkinematic granite and sedimentary basin have been reported around the Oseosan dome. These evidences possibly suggest that the Oseosan dome formed in closely associated with the Late Triassic extensional movement and diapiric flow. Alternatively, 1) thrust- or reverse fault-related doming or 2) interference between independent folds during structural inversion of the Late Traissic to Middle Jurassic sedimentary basin can be also considered as dome-forming process. However, considering the northern limb of the Oseosan dome, cutting by the Late Traissic granite, and the southern limb, cutting by contractional fault reactivated after the Middle Jurassic, it is likely that the domal structure formed during or prior to the Late Triassic.

A Study on the Flame Pattern and the Electrical Properties of Electric Outlet Fired at Standby Mode (Standby Mode에서 출화된 콘센트의 화염 패턴 및 전기적 특성에 관한 연구)

  • 최충석;송길목;김형래;김향곤;김동욱;김동우
    • Fire Science and Engineering
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    • v.16 no.1
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    • pp.39-44
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    • 2002
  • In this paper, we analysed the flame patterns and the electrical characteristics of the electric outlet which was fired at standby mode. The carbonized patterns indicated that the flame had spread about 50 cm to 70 cm. After the combustibles on wall started to burn, the temperature went up to about $300^{\circ}c$ in 150 sec. The flame formed ceiling jet and spread quickly. The tracking was generated at the shortest distance between two electrodes and the resistance was about 100$\Omega$ to 300$\Omega$ As the result of analysis using metallurgical microscope, the normal part of a blade holder showed amorphous structure, but the melted part of a blade holder damaged by tracking showed dendrite structure and void evenly. When the blade holder of damaged outlet was analyzed by SEM and EDX, we found that the structure and components of the normal part were different from those of melted part.

Magma Pathway of Alkali Volcanic Rocks in Goseong, Gangwon-do, Korea (강원도 고성지역에 분포하는 알칼리 현무암질 마그마의 상승경로)

  • Kil, Young-Woo;Shin, Hong-Ja;Ko, Bo-Kyun
    • The Journal of the Petrological Society of Korea
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    • v.16 no.4
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    • pp.196-207
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    • 2007
  • Miocene basalt plugs in Goseong contain a large variety of crustal and mantle xenoliths and xenocrysts. One of basalt plugs, Unbongsan, are derived from 160 km depth. Whole-rock geochemistry and pressure and temperature conditions of mineral phases indicate that Unbongsan volcanic rocks are alkali basalts and the source magma of the alkali basalts was generated from about $0.2{\sim}2%$ partial melting of depleted garnet peridotite. Crystallization pressures and temperatures of mineral phases within ascending magma of Unbongsan alkali basalt indicate that olivines, clinopyroxenes, and plagioclases were crystallized at $75{\sim}110km,\;40{\sim}52km,\;37{\sim}54km$ depth, respectively. The ascending magma of Unbongsan alkali basalts enclosed mantle xenoliths at about $57{\sim}67km$ depth.

홍제사 화강암질편마암체의 성인과 공존하는 흑운모, 백운모 및 녹니석 사이의 화학적 평형

  • 이상헌
    • The Journal of the Petrological Society of Korea
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    • v.3 no.1
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    • pp.49-75
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    • 1994
  • The Hognjesa granitic rocks can be subdivided into biotite granitic gneiss and microcline- perthite granitic gneiss according to their mineralogy and textures, which change gradationally each other. They consist mainly of biotite, muscovite, chlorite, microcline, plagioclase, perthite and quartz accompanied with sillimanite, garnet, and tourmaline in places. The replacement and/or alteration phenomena and relationships of coexisting minerals suggest that the granitic gneisses might be formed by regional metamorphism of upper amphibolite facies and granitization by partial melting accompanied to the regional metamorphism, and again at later effected by regional metamorphism of epidote-amphibolite or greenschist facies. The biotite, muscovite and chlorite formed during these metamorphism, show nearly similar chemical compositions, respectively, regardless to the rock phases and stages of formation. They show relatively stable chemical equilibrium between coexisting pairs. The granitization which formed granitic gneisses may be seemed to occur regionally by partial melting accompanied to the first regional metamorphism.

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Design and Test of Slag Tap Burner System for Prevention of Molten Slag Solidification in Coal Gasifier (석탄가스화기 용융슬랙의 고형화 방지를 위한 슬랙탭 버너시스템 설계 및 시험)

  • Chung, Seokwoo;Jung, Kijin;Lee, Sunki;Byun, Yongsu;Ra, Howon;Choi, Youngchan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.74.2-74.2
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    • 2011
  • 석탄가스화 기술은 고온, 고압 조건에서 석탄과 산소의 불완전연소 및 가스화 반응을 통해 일산화탄소(CO)와 수소($H_2$)가 주성분인 합성가스를 제조하여 이용하는 현실적인 에너지원의 확보를 위한 방법인 동시에 이산화탄소를 저감할 수 있는 기술이다. 석탄가스화기 공급되는 석탄은 산소와의 부분 산화, 수증기 및 $CO_2$와의 반응에 의하여 합성가스로 전환되는데, 일반적으로 슬래깅 방식 석탄가스화기의 정상운전 중에 가스화기 내부 온도는 $1,400{\sim}1,600^{\circ}C$ 정도의 고온이며, 운전압력은 20~60 기압으로 매우 고압 상태에서 운전이 이루어지는데, 공급되는 석탄 시료의 성분들 중 가연성 물질의 99% 이상이 합성가스로 전환되는 반면, 회분에 해당되는 무기물의 대부분은 용융 슬랙 형태로 가스화기의 벽을 타고 흘러내리다가 슬랙탭을 통해 하부의 냉각조로 떨어지면서 급냉이 이루어지게 된다. 그러므로, 석탄가스화기 정상운전중 슬랙탭 주변의 온도를 고온으로 유지함으로써 용융슬랙의 고형화를 방지하는 것은 석탄가스화기의 안정적인 연속운전을 위하여 중요한 기술 중의 하나라고 할 수 있다. 따라서, 본 연구에서는 저급탄 가스화를 위한 1 톤/일급 고온, 고압 습식 석탄가스화기의 정상운전중 슬랙탭 부근에서 용융슬랙의 고형화를 방지하기 위한 슬랙탭 버너시스템의 설계를 진행하였으며, 안정적인 운전조건 도출을 위하여 보조연료(CNG)와 산소의 공급비율에 따른 화염특성 시험을 진행하였다.

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A Study on Heat Transfer Characteristics of Humidifier/HRU for MCFC (MCFC용 가습기 및 HRU의 열전달 특성 연구)

  • Park, Sungho;Kal, Hanjoo;Jeong, Youngsik;Lee, Sanghoon;Lee, Jaejun;Oh, Yongmin;Kim, Seonhwa
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.97.2-97.2
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    • 2011
  • 본 연구는 연료전지 중 용융탄산염을 전해질로 하는 MCFC의 MBOP에 포함된 부품으로 매우 중요한 역할을 하는 가습기와 이때 발생되는 폐열을 회수하기 위한 장치인 HRU에 관한 것이다. 가습기는 연료와 물이 가습기 상부로 유입되어 가습기 하부로 유입되는 배가스와 열교환을 하면서 물이 스팀화 되어 연료가 가습된 상태로 가습기 출구로 일정온도를 유지하며 배출된다. 또한 HRU는 가습기에서 배출된 고온의 배가스를 물을 이용하여 열교환을 통해서 열을 회수하여 난방 및 온수로 사용할 수 있는 열교환 장치를 말한다. 먼저 이들의 특성을 파악하기 위해 가습기 및 HRU를 설계, 제작하여 각각의 특성을 확인하였다. 가습기와 HRU의 성능 향상을 위해 먼저 열교환부에 적용될 튜브의 수치해석적 분석을 통해서 최적의 열전달 성능을 얻을 수 있는 가습기 및 HRU를 설계, 제작하였으며 이들의 성능을 파악하기 위해 120,000kcal/h 용량을 테스트 할 수 있는 장치를 구축하여, 이들의 열전달 특성, 압력강하, 회수 열량, 가습기 온도 등의 특성을 파악하였다. 이 장치를 통해서 확인된 가습기와 HRU의 특성은 수치해석을 통해서 얻은 값과 거의 유사함을 확인할 수 있었으며, 가습 성능도 효과적으로 달성할 수 있었다. 가습기와 HRU의 특성 중 압력강하 부분은 지속적인 연구가 필요한 부분이며, 가습기와 HRU의 일체화를 통하여 소형화 및 설치공간 축소 효과를 얻을 것으로 본다.

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