• Journal of the Korean Institute of Gas
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• v.7 no.4 s.21
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• pp.7-13
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• 2003

This study was carried out to optimize premixed burner and heat exchanger of the condensing gas boiler which can save energy by utilizing latent heat of combustion gas and reduce pollutant in exhaust gas. The heat exchanger of the gas boiler was composed of three parts, which were an upper, lower, and coil heat exchanger. The upper heat exchanger was placed outside of the premixed burner and a lower heat exchanger was located under the upper heat exchanger. And, coil heat exchanger rounded the outer surface of an upper and lower heat exchanger. The boiler designed by this research reaches turn-down ratio 4:1 in the domain of equivalence ratio 0.75${\~}$0.8 and thermal efficiency of $97\%$. Emission of NOx and CO concentration was under 20ppm and 140ppm at equivalence ratio 0.8. When diameter of the burner is replaced from 60mm to 50mm, emission of CO was reduced about 50ppm remarkably.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.24 no.1
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• pp.44-49
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• 2020

Recently, one of the major issues of shipbuilding and marine is the reduction of air and marine pollution emission to ships. In response, the International Maritime Organization (IMO) has concluded an international convention (MARPOL) to prevent pollution from ships. A Annex Six of The Convention restricts and regulates air and marine pollution of ship from exhausting gases. To this end, it is required to apply EEDI (Energy Efficiency Design Indicators) to the construction of new ships, and to minimize the emission of environmental pollutants by recommending the application of EEOI (Energy Efficiency Operation Indicators) to operational ships. Therefore, in this study, we propose to calculate the grade of operating efficiency (EG) of ships based on actual operational data for transport ships and to provide energy-efficient optimal path search information through analysis of marine environment data.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.52-58
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• 2023

With the increasing awareness of the importance of carbon neutrality in response to global climate change, the utilization of hydrogen as a carbon-free fuel source is also growing. Hydrogen is commonly used in fuel cells (FC), but it can also be utilized in internal combustion engines (ICE) that are based on combustion. Particularly, ICEs that already have established infrastructure for production and supply can greatly contribute to the expansion of hydrogen energy utilization when it becomes difficult to rely solely on fuel cells or expand their infrastructure. However, a disadvantage of utilizing hydrogen through combustion is the potential generation of nitrogen oxides (NOx), which are harmful emissions formed when nitrogen in the air reacts with oxygen at high temperatures. In particular, for the EURO-7 exhaust regulation, which includes cold start operation, efforts to reduce exhaust emissions during the warm-up process are required. Therefore, in this study, the characteristics of nitrogen oxides and fuel consumption were investigated during the warm-up process of cooling water from room temperature to 88℃ using a 2-liter direct injection spark ignition (SI) engine fueled with hydrogen. One advantage of hydrogen, compared to conventional fuels like gasoline, natural gas, and liquefied petroleum gas (LPG), is its wide flammable range, which allows for sparser control of the excessive air ratio. In this study, the excessive air ratio was varied as 1.6/1.8/2.0 during the warm-up process, and the results were analyzed. The experimental results show that as the excessive air ratio becomes sparser during warm-up, the emission of nitrogen oxides per unit time decreases, and the thermal efficiency relatively increases. However, as the time required to reach the final temperature becomes longer, the cumulative emissions and fuel consumption may worsen.

• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.597-609
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• 2018

Korea Forest Service has supplied 76 industrial wood pellet boilers from 2011 to 2015 through subsidy programs. Since carbon monoxide (CO) and nitrogen oxides ($NO_x$) generated during boiler combustion are substances that lead to death in the case of acute poisoning, it is very important to reduce emissions. Therefore, the CO and $NO_x$ emission values of 63 boilers excluding the hot air blower and some boilers initially supplied were analyzed. The emission factor was also calculated from the measured exhaust gas concentration (based on exhaust gas $O_2$ concentration of 12%). The average value of CO emitted from industrial wood pellet boilers was 49 ppm and it was confirmed that the CO concentration was decreasing as the years passed. The emission factor of CO was 0.73 g/kg. The average value of $NO_x$ emitted from industrial wood pellet boilers was 67 ppm and the emission factor of $NO_x$ was 1.63 g/kg. Unlike CO, there was no tendency to decrease according to the installation year. Both CO and $NO_x$ measurements met the limits of the Ministry of Environment. These $NO_x$ emission factors were compared with the $NO_x$ emission factors produced by certified low $NO_x$ burners. The $NO_x$ emission factor of industrial wood pellet boilers was about 1.9 times that of certified low $NO_x$ LNG combustors and about 0.92 times that of coal combustion.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.8
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• pp.683-691
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• 2015

Circulating Fluidized Bed(CFB) combustion has the several advantages which are the fuel flexibility, the economy, the efficiency and the environment. It is necessary to apply a renewable energy to produce electricity due to the Renewable Portfolio Standard(RPS) mandates recently. So, in this study, co-combustion with a coal and a wood pellet was investigated to evaluate the combustibility and the environment as function of blending ratio of them in a Lab-scale CFB reactor. To investigate the characteristics of the co-combustion, the blending ratio which is the weight of wood pellet by the total calorific value of the supplied, was considered. Bed material was a river sand(No. 7). As increasing the blending ratio, the exhausted gas emissions such as CO, NOx, HC and SOx were decreased. But in case of wood pellet over 30%, CO, HC and SOx emission were increased. And the gas temperatures at the downstream were decreased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.6
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• pp.587-597
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• 2010

Air-staged combustion is known to be one of the techniques of NOx reduction. The objective of this study is to determine the optimal ratio of air flow distributed for CCOFA and SOFA; at this optimal ratio, the combustion and exhaust emission characteristics of a pulverized coal-fired boiler are maintained at a satisfactory level. A numerical investigation was performed at various airflow ratios of 16.7/83.3%, 25/75%, 50/50%, 75/25%, and 83.3/16.7%. An inert gas was considered as a substitute for air to isolate the effects of the cooling process and chemical reaction on NOx reduction; during NOx reduction in air-staged combustion, both the effects typically occur simultaneously. The results of our study show that the optimum condition, under which the maximum NOx reduction and highest boiler efficiency can be obtained, corresponds to the equal splitting of the over-fire air between CCOFA and SOFA.

• Environmental and Resource Economics Review
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• v.13 no.1
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• pp.133-160
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• 2004

This paper analyzes the long-run effects of an environmental tax levied on motor vehicles. If the government charges their consumers the tax as much as the monetary value of the external damage due to the pollutants emitted from motor vehicles, the operation of vehicles is reduced to the socially optimal level, alike to ordinary Pigouvian taxes. Thus, air pollution abatement is realized in the short run. Moreover, in the long run, the tax leads the consumers to prefer cleaner vehicles owing to the tax burden, and so the firms produce the motor vehicles with less pollutants emitted to meet the change of demand. Therefore, the tax has the additional effect on air pollution abatement. This result is obtained from the simulation in the oligopoly model which has an interior solution when the vehicles are horizontally and vertically differentiated.

• Proceedings of the KOR-BRONCHOESO Conference
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• 1972.03a
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• pp.6-7
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• 1972

The air pollutants can be classified into the irritant gas and the asphixation gas, and the irritant gas is closely related to the otorhinolaryngological diseases. The common irritant gases are nitrogen oxides, sulfur oxides, hydrogen carbon compounds, and the potent and irritating PAN (peroxy acyl nitrate) which is secondarily liberated from photosynthesis. Those gases adhers to the mucous membrane to result in ulceration and secondary infection due to their potent oxidizing power. 1. Sulfur dioxide gas Sulfur dioxide gas has the typical characteristics of the air pollutants. Because of its high solubility it gets easily absorbed in the respiratory tract, when the symptoms and signs by irritation become manifested initially and later the resistance in the respiratory tract brings central about pulmonary edema and respiratory paralysis of origin. Chronic exposure to the gas leads to rhinitis, pharyngitis, laryngitis, and olfactory or gustatory disturbances. 2. Carbon monoxide Toxicity of carbon monoxide is due to its deprivation of the oxygen carrying capacity of the hemoglobin. The degree of the carbon monoxide intoxication varies according to its concentration and the duration of inhalation. It starts with headache, vertigo, nausea, vomiting and tinnitus, which can progress to respiratory difficulty, muscular laxity, syncope, and coma leading to death. 3. Nitrogen dioxide Nitrogen dioxide causes respiratory disturbances by formation of methemoglobin. In acute poisoning, it can cause pulmonary congestion, pulmonary edema, bronchitis, and pneumonia due to its strong irritation on the eyes and the nose. In chronic poisoning, it causes chronic pulmonary fibrosis and pulmonary edema. 4. Ozone It has offending irritating odor, and causes dryness of na sopharyngolaryngeal mucosa, headache and depressed pulmonary function which may eventually lead to pulmonary congestion or edema. 5. Smog The most outstanding incident of the smog occurred in London from December 5 through 8, 1952, because of which the mortality of the respiratory diseases increased fourfold. The smog was thought to be due to the smoke produced by incomplete combustion and its byproduct the sulfur oxides, and the dust was thought to play the secondary role. In new sense, hazardous is the photochemical smog which is produced by combination of light energy and the hydrocarbons and oxidant in the air. The Yonsei University Institute for Environmental :pollution Research launched a project to determine the relationship between the pollution and the medical, ophthalmological and rhinopharyngological disorders. The students (469) of the "S" Technical School in the most heavily polluted area in Pusan (Uham Dong district) were compared with those (345) of "K" High School in the less polluted area. The investigated group had those with subjective symptoms twice as much as the control group, 22.6% (106) in investigated group and 11.3% (39) in the control group. Among those symptomatic students of the investigated group. There were 29 with respiratory symptoms (29%), 22 with eye symptoms (21%), 50 with stuffy nose and rhinorrhea (47%), and 5 with sore thorat (5%), which revealed that more than half the students (52%) had subjective symptoms of the rhinopharyngological aspects. Physical examination revealed that the investigated group had more number of students with signs than those of the control group by 10%, 180 (38.4%) versus 99 (28.8%). Among the preceding 180 students of the investigated group, there were 8 with eye diseases (44%), 1 with respiratory disease (0.6%), 97 with rhinitis (54%), and 74 with pharyngotonsillitis (41%) which means that 95% of them had rharygoical diseases. The preceding data revealed that the otolaryngological diseases are conspicuously outnumbered in the heavily polluted area, and that there must be very close relationship between the air pollution and the otolaryngological diseases, and the anti-pollution measure is urgently needed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.9
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• pp.474-481
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• 2018

The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.400-407
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• 2019

Oxy-combustion with a circulating fluidized bed (Oxy-CFBC) technology has been paid attention to cope with the climate change and fuel supply problem. In addition, Oxy-CFBC technology as one of the methods for carbon dioxide capture is an eco-friendly that can reduce air pollutants, such as $SO_2$, NO and CO through a flue gas recirculation process. The newly developed $100kW_{th}$ pilot-scale Oxy-CFBC system used for this research has been continuously utilizing to investigate oxy-combustion characteristics for various fuels, coals and biomasses to verify the possibility of fuel diversification. The anthracite is known as a low reactivity fuel due to a lot of fixed carbon and ash. Therefore, this study aims not only to improve combustion efficiency of an anthracite, but also to capture carbon dioxide. As a result, compared to air-combustion of sub-bituminous coal, oxy-combustion of anthracite could improve 2% combustion efficiency and emissions of $SO_2$, CO and NO were reduced 15%, 60% and 99%, respectively. In addition, stable operating of Oxy-CFBC could capture above 94 vol.% $CO_2$.