• Title/Summary/Keyword: 배기가스 정화

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배기재순환과 기관성능 및 배기조성

  • 이성렬
    • Journal of the KSME
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    • v.20 no.1
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    • pp.21-30
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    • 1980
  • 기관의 흡기에 배기의 일부를 혼입하는 배기재순환 (Exhaust Gas Recirculation, 약해서 EGR)은 배기중의 NOx 농도를 저하시키는 효과가 있기 때문에 자동차용 기관의 배기정화를 위한 유효한 수단의 하나로 생각된다. 배기가스의 공해성분인 CO, HC NOx 중에서 CO, HC는 실용적인 처 리방법이 각각 여러종류 개발되어 있지만 NOx를 기관으로부터 배출한 후의 단계에서 처리하는 실용적인 방법은 매우 어렵다, 따라서 이와 같은 단계에 있어서는 EGR를 유효하게 이용하는 것이 NOx 저감대책의 지름길이라 할 수 있다. 그러나 EGR를 시행하는 경우, 신기의 흡입량은 EGR에 의하여 제한을 받아 감소하므로 신기의 감소분만큼 출력이 저하하는 것을 막을 도리는 없다. 따라서 장래 대부분의 자동차용기관이 EGR시스템을 정착하게 되면 동력성능을 저하시 키지 않기 위하여 EGR에 상당하는 실린더용적의 증가를 하거나, 어떠한 대책이 필요할 것이다. 그러므로 저자는 장래 EGR시스템을 장착하게될 경우를 고려하는 기관에 EGR을 시해하는 경우, 기관사이클, 연소 및 배기성분 운전 Paramater와 EGR의 관계등에 대하여 기술하고저 한다.

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Acid Treatment Effect of Waste Automotive Catalyst on Catalytic Combustion of Acetaldehyde (아세트알데히드 촉매 연소에 대한 자동차 폐촉매의 산처리효과)

  • 서성규;문정선
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.231-232
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    • 2000
  • 자동차 보급의 증가에 의한 심각한 대기오염으로 인하여 국내 제작차(휘발유 자동차)의 경우 1987년부터 자동차 배기가스 정화용 촉매 전환기의 장착을 의무화하였다(환경부, 1998). 자동차용 촉매로 많이 사용되는 귀금속은 백금(Pt), 팔라듐(Pd), 로듐(Rh)이며, 수요비율은 백금이 전체 수요의 39%, 팔라듐이 16%, 로듐이 96%로 자동차용으로 많은 귀금속이 사용되고 있음을 알 수 있다. (중략)

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Temperature and exhaust gas conversion efficiency of catalytic converters for natural gas vehicles (천연가스자동차 촉매의 온도분포 및 배기정화 특성)

  • Choe, Byeong-Cheol;Kim, Yeong-Gil;Sakai, Takayuki
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.205-212
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    • 1998
  • Experiments were conducted to investigate the temperature profile and the emissions conversion efficiency of catalytic converters for natural gas vehicles. Two types of the catalyst structure and several transient engine operating conditions were used. The dual-bed catalyst effectively reduced the emissions in a transient period due to the low heat capacity of the front bed. The lanthanoid additives were effective in improving catalyst durability. When the natural gas fueled engine were operated outside of a very narrow window of excess air ratio (from 0.993 to 1.004), the HC and NOx conversion efficiency dropped off. The drop-off were especially fast on the lean side of the window.

A study on the pollutant reduction using catalyst in model furnace (모형소각로의 촉매에 의한 배기가스 정화특성에 관한 연구)

  • Lee, Yong-Hoo;Lee, Wha-Sin;Lee, Jin-Seok;Lee, Do-Hyung
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.8
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    • pp.870-876
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    • 2006
  • In proportion to the increase of industrial development, emission troubles were concerned as global issue. For these reasons, so many researchers and associated institutes effort to reduce pollution with new technology and various devices. As a kind of these methods, we used catalysts as a after-treatment system. At first, we made equipment of model furnace. And various catalysts were equipped at exhaust duct of combustion system, and excess air ratio(a), change cell numbers catalyst materials(Pt, Pd) were changed as experimental conditions. With these various condition, temperature. NOx, CO, HC, $CO_2$ and $O_2$ concentration were measured. As a result, NOx conversion increased with increasing of cell number in Pd catalyst. And Pt catalyst became 100% conversion at 200 and 300 cell. Also, Pt catalyst was better than Pd catalyst at a=1.5 in this condition. In addition, CO and HC concentrations were decreased at a = 1.5 with Pd catalyst.

A study on the pollutant reduction using catalyst in model furnace (모형소각로의 촉매에 의한 배기가스 정화특성에 관한 연구)

  • Lee, Yong-Hoo;Lee, Jin-Seok;Lee, Hwa-Sin;Kang, In-Gu;Lee, Do-Hyung
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.154-159
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    • 2005
  • In proportion to the increase of industrial development, emission troubles were concerned as global issue. For these reasons, so many researchers and associated institutes effort to reduce pollution with new technology and various devices. As a kind of these methods, we used catalysts as a after-treatment system. At first, we made equipment of model furnace. And various catalysts were equipped at exhaust duct of combustion system, and excess air ratio( ), change cell numbers, catalyst materials(Pt, Pd) were changed as experimental conditions. With these various condition, temperature, NOx, CO, HC, $CO_2$ and $O_2$ concentration were measured. As a result, NOx conversion were increased with increasing of cell number in Pd catalyst. And Pt catalyst were became 100% conversion at 200 and 300 cell. Also, Pt catalyst was better than Pd catalyst ${\alpha}$=1.5 in this condition. In addition, CO and HC concentrations were decreased${\alpha}$=1.5 with Pd catalyst.

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Flow measurement in engine cylinder (기관 실린더 내의 가스 유동 계측)

  • 이창식
    • Journal of the korean Society of Automotive Engineers
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    • v.9 no.1
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    • pp.9-14
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    • 1987
  • 왕복동 내연 기관 실린더 내의 가스 유동은 기관의 성능 향상, 연소 개선, 배기 정화 등에 직접적 으로 영향을 미치는 인자로 되며, 최근 각종 유동의 측정 방법 및 측정 장치의 개발은 가스 유동 계측에 많은 발전을 가져 왔다. 특히 각종 열기관의 연소 성능 향상을 위한 노력은 기관의 성능 향상과 더불어 여소 배출물의 유해 성분 저감을 위한 연구에 더욱 박차를 가하게 되었다. 이에 따라서 기관의 최적 제어 운전, 자동 제어 연료 공급 및 분사장치 등에 이르기까지 많은 노력이 경주되어 왔다. 이러한 연구 개발에 못지 않게 중요한 것은 실린더 내의 연소 성능을 향상시키 는 것이며 이를 위해서는 먼저 기관 실린더 내부의 가스 유동을 밝히고, 유동의 모델링, 유동장의 계측, 연소장의 유동 측정 등의 연구가 매우 중요한 것으로 생각된다. 실린더 내의 연소 및 유 동장의 연구는 주로 연소 특성치를 관한 연구와 유동장을 중심으로 하는 흐름의 시뮬레이션을 비롯 유동장의 계측으로 크게 나눌 수 있다. 여기서는 주로 실린더 내의 가스 유동의 측정 방 법과 최근의 연구 동향에 대하여 몇 가지 측정의 보기를 중심으로 다루기로 한다.

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Effect of Operating Condition Change on the Conversion Efficiency of TWC with HCNG Engine (운전조건 변화가 HCNG 엔진용 삼원촉매 전환효율에 미치는 영향)

  • Kim, Chang-Gi;Lee, Sung-Won;Yi, Ui-Hyung;Park, Cheol-Woong;Lee, Sun-Youp;Choi, Young;Lee, Jang-Hee
    • Journal of the Korean Institute of Gas
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    • v.19 no.6
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    • pp.40-46
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    • 2015
  • Stoichiometric combustion engine with Three-way catalyst had an advantage that can reduce the harmful emissions effectively. Fuel equivalence ratio controlled from engine is very important because Fuel equivalence ratio with high conversion efficiency was narrow. This study analyzed the conversion efficiency under whole range of operating area for to evaluate the performance of three-way catalyst. In order to identify the Optimum conversion efficiency, the conversion efficiency due to change the control value of fuel equivalence ratio was investigated. The result show that conversion efficiency of emissions(more than 95%) has discovered by means of fuel equivalence ratio control at each test condition. As engine power increases, optimal fuel equivalence ratio tended to increase linearly under operating conditions of similar exhaust gas temperature.

Developments in metal matrix composites for automotive parts (자동차용 금속복합재료의 개발동향)

  • 박익민;김낙준
    • Journal of the korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.36-44
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    • 1994
  • 최근의 자동차산업의 과제로는 연비향상, 배기가스정화, 리싸이클링 등이 지적되고 있다. 이들과제와 재료기술은 밀접한 관계를 가지고 있어, 이 과제들을 해결하기 위해서는, 재료의 개발이 필수적이라 하겠다. 자동차에 사용되는 재료로는 철강, 알루미늄, 플라스틱 등이 있지만, 경량화 및 부품기능의 향상등을 위해서는 금속기 복합재료의 개발적용이 절실히 요구되고 있다. 본 자료에서는 자동차용 금속기복합재료의 특성, 제조기술 및 개발현황 등을 소개한다.

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Technical Trends of Rare Metal Recycling in the Next Generation Automobile (차세대 자동차용 희소금속 리싸이클링 기술동향)

  • Hwang, Young-Gil;Kil, Sang-Cheol;Kim, Jong-Heon
    • Resources Recycling
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    • v.23 no.2
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    • pp.3-16
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    • 2014
  • Car exhaust $CO_2$ gas reduction and fuel efficiency of the car lighter for the current era is a big challenge. The developments of high-performance Nd magnets, Li-ion secondary battery and exhaust gas purification performance of PGM catalysts used in the lightweight EV and HEV are activated. Country in order to improve the car lighter and function that use the resources of rare metals are ubiquitous imported from China because of export supply control, as soaring prices have unstable supply and demand. Compared to the emissions from the next-generation automotive recycling, waste scarce resources need to be. This study investigated the recycling technology analysis and development of the information technology, or delivered to the researchers by giving national car industry aims to contribute to the development. Findings, pulmonary high-performance motor vehicle emissions in the exhaust gas purification PGM Catalysts, Li-ion battery and Nd magnets recycling technology, such as pre- and post-processing techniques to classify technology, pre-urban mining technology mechanical separation by screening techniques under development, the study and post-processing technology has, pyro and hydro metallurgical smelting technology is established. Waste Recycling in terms of economic efficiency of mechanical components for the intensive study of screening techniques is needed.

Catalytic Oxidation of Volatile Organic Compounds Over Spent Three-Way Catalysts (배기가스 정화용 폐 자동차 촉매를 이용한 휘발성 유기화합물의 제거)

  • Shim, Wang Geun;Kim, Sang Chai
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.574-581
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    • 2008
  • The optimum regeneration conditions for the regeneration of three way spent catalysts (TWCs), which were taken from automobiles with different driving conditions, were investigated to evaluate the suitability as alternative catalysts for removing VOCs. The spent catalysts were washed with five different acids ($HNO_3$, $H_2SO_4$, $C_2H_2O_4$, $C_6H_8O_7$, and $H_3PO_4$) to remove contaminants and examine the optimum conditions for recovering the catalytic activity. The physicochemical properties of spent and its regenerated TWCs were evaluated by using nitrogen adsorption-desorption isotherms, XRD, and ICP. The relative atomic ratios of contaminants and platinum group metals (PGMs) of the spent TWCs were greatly dependent on the placed positions. The main contaminants formed were lubricant oil additives and metallic components. Also, the regeneration treatment increased the PGMs ratio, BET surface area, and average pore diameter of TWCs. The catalytic activity results indicated that the spent TWCs have the possibility for removing VOCs. Moreover, the employed acid treatments greatly enhanced the catalytic activity of the spent TWCs. Especially, nitric and oxalic acids provided the most improvement in the catalytic behavior. The catalytic activities of the regenerated TWCs were significantly influenced by the containing platinum ratios rather than the removal ratios of contaminants and the changes in the structural properties offered by the acid treatments.