• Title/Summary/Keyword: 방향족 탄화 수소

Search Result 340, Processing Time 0.045 seconds

Isolation and Identification of Klebsiella oxytoca C302 and Its Degradation of Aromatic Hydrocarbons (Klebsiella oxytoca C302의 분리 동정 및 방향족 탄화수소물질의 분해특성)

  • 김기필;이정순;박송이;이문수;배경숙;김치경
    • Korean Journal of Microbiology
    • /
    • v.36 no.1
    • /
    • pp.58-63
    • /
    • 2000
  • A bacterial isolate capable of degrading benzoate was selected from wastewater of Yocheon industrial complex and examined its biochemical characteristics and fatty acid composition. The isolate was identified as Klebsiella oxytoca strain C302. The strain C3O2 degraded catechol, protocatechuate, and 4-hydroxybenzoate as well as benzoate. The strain grew on and degraded 0.5 to 1.0 mM catechol most actively in MM2 medium at pH 7.0 and $30^{\circ}C$.

  • PDF

A DFT Study for the Reaction Pathway(s) of Polycyclic Aromatic Hydrocarbons I: Phenanthrene Degradation with two OH Radicals (다고리 방향족 탄화수소의 반응 경로에 대한 DFT 연구 I: 2개의 OH 라디칼에 의한 페난트렌의 분해 반응)

  • Lee, Min-Joo;Lee, Byung-Dae
    • Journal of the Korean Chemical Society
    • /
    • v.65 no.1
    • /
    • pp.9-14
    • /
    • 2021
  • In this study, the DFT calculation was performed using the B3LYP/6-31G(d,p) basis sets for the reaction process in which phenanthrene decomposes due to the chain reaction of two OH radicals on phenanthrene in the gaseous state of 298 K at 1 atm. As a result of the calculation, even when two OH radicals act on phenanthrene in a chain, the reaction for producing phenanthren-9-ol is predicted to be more advantageous than the reaction for producing phenanthren-1-ol. On the other hand, it was predicted that the OH addition process at room temperature would be advantageous for the priority of the OH addition and H abstraction process.

Viscosity Reduction by Catalytic Aquathermolysis Reaction of Vacuum Residues (접촉식 가수열분해 반응에 의한 감압잔사유의 점도 강하에 대한 연구)

  • Ko, Jin Young;Park, Seung-Kyu
    • Applied Chemistry for Engineering
    • /
    • v.29 no.4
    • /
    • pp.468-473
    • /
    • 2018
  • In this study, the reforming reaction of vacuum residues (VR), high viscosity oil residues produced from vacuum distillation process of petroleum oil, was carried out using catalytic aquathermolysis reaction. VR showed a prone to decrease the amount of resins and asphaltenes in the constituents, and to increase saturates and aromatics when reacting with steam at 30 bar and above $300^{\circ}C$ for 24 h. When the amount of steam is not enough at this reaction, the asphaltene content in the products was rather increased after the reaction. As a result of the catalytic aquathermolysis using the metal oxide-zeolite catalyst with the decaline as a hydrogen donor, a 10% decrease in resin and asphaltene as well as a 10% increase in the aromatic hydrocarbon were observed. Consequently, the viscosity of VR decreased by 70% after the reaction. GC-Mass spectroscopy showed that the aquathermolysis of VR resulted in the decomposition of the resins and asphaltens into a low molecular weight material.

Structures and Properties of Semi-blown Petroleum Asphalt (세미-브로잉 공정에서 석유 아스팔트의 구조, 물성 변화)

  • Min, Kyung Eui;Jeong, Han Mo
    • Applied Chemistry for Engineering
    • /
    • v.22 no.6
    • /
    • pp.664-671
    • /
    • 2011
  • The vacuum residue of petroleum refinery, i.e. asphalt, was modified through a non-catalytic air blowing process to prepare the semi-blown asphalt. Changes in composition, chemical structure, and physical properties of asphalt were examined. The result from the thin layer chromatography showed that the asphaltene content in asphalt was increased by the air blowing on account of the aromatization of aliphatic hydrocarbon and condensation. These changes in molecular structure were also confirmed by $^1H-NMR$, differential scanning calorimetry, and thermogravimetry. Because of the molecular structure changes, the penetration of asphalt was decreased and the softening point and the flash point of asphalt were increased.

BTX의 폭발특성에 관한 연구

  • 김종복;오규형;이성은;류창하
    • Proceedings of the Korean Institute of Industrial Safety Conference
    • /
    • 2000.11a
    • /
    • pp.140-145
    • /
    • 2000
  • BTX는 석유화학곧업에서 생산되는 방향족탄화수소 화합물의 주요 생산품목인 Benzene, Toluene, Xylene을 일컫는 말로서 석유화학공정에서 간단히 줄여서 쓰는 용어이다. 벤젠, 톨루엔, 크실렌 등은 페인트 희석제로 쓰이는 유기용매의 주성분들이며, 인체에 중독성을 나타내는 유해물질이기도 하며 소방법상에서는 인화성액체인 4류 위험물로 취급하고 있다.(중략)

  • PDF