• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2014.11a
• /
• pp.83-83
• /
• 2014

선박건조에 사용되는 도료 중 SPC(self-polishing copolymer) A/F(anti-fouling) 도료의 주된 기능은 해양생물의 부착 등 해양생물에 의한 오염을 방지하는 방오성능으로 인식되어 왔으나, 최근 방오성능 뿐 아니라 선박의 운항 시 선체저항을 줄임으로써 발생되는 연료절감효과와 선박의 미관을 위한 변색지연 등 SPC A/F 도료의 다른 기능에 많은 관심을 가지게 되었다. 이러한 관심과 사용자의 요구에 따라 도료사에서는 항력의 감소를 가져 올 수 있는 Silyl acrylate copolymer로 디자인 된 Silyl acrylate SPC A/F 도료를 개발하였으나 SPC A/F 도료의 방오제(biocides) 종류에 따른 방오성능 차이를 비교 평가 할 수 있는 객관적 자료가 부족하여, 본 연구를 통해 SPC A/F 도료의 종류 별 방오성능을 평가하고자 한다.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.22 no.2
• /
• pp.253-258
• /
• 2016

The $MnO_x-WO_3-TiO_2$ nanoscale powders were synthesized by sol-gel method in order to prevent the biological fouling on the ships and offshore structures. Powder characteristics and antifouling performance were investigated with respect to the crystalline, microstructure and surface property for application in self-polishing copolymer resins. The high antifouling activity of $TiO_2$-system biocide was attributed to its redox potential and soluble metal ions originating from tungsten oxides according to the improvements in the powder characteristics. Based on their physio-chemical characterizations, the specific surface areas of powders were about $90m^2/g$ and the grain size was in the region 100 ~ 150 nm. Powder characteristics and surface properties were improved by the addition of $WO_3$. Antifouling performance were analyzed according to their surface properties and static immersion tests to determine the effects of the $TiO_2$-system compounds. The surface of 2 wt. % added sample was clean for 5 month. This may be attributed to the ability of $MnO_x-WO_3-TiO_2$ powders to act as a promoter in antifouling agents.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.16 no.4
• /
• pp.361-367
• /
• 2010

The use of antifouling(AF) paints is the effective method for the protection of underwater structures from the development of marine fouling organisms. The ban on harmful substances in antifouling paints requires the development of new antifouling strategies although Tributyitin (TBT) compound had been used extensively as an active ingredient Alternatives should be as effective as conventional paints but have lower toxicity. In the present study, a TBT-free self-polishing (Cu SPC) AF paint containing $Cu_2O$, a Cu free SPC AF paint, and a Foul-release silicone AF paint, which were commercially available, were examined to investigate environmental erects of leakage waters employing Sebastes shlegeli and Artemia. Survival rates were inversely proportional to the concentration of leakage waters from AF paints and the acute toxicity of SPC AF paints was relatively higher than that of foul release AF paints.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.27 no.5
• /
• pp.1-8
• /
• 2023

Marine and hydraulic structures are subject to durability damage not only due to the penetration of sea water but also due to the attachment of marine organisms. Therefore, in this study, we tried to develop an antifouling coating agent with self-cleaning function for marine concrete. It was confirmed that the antifouling coating agent mixed with AKD, cellulose nanofibers and BADGE had sufficient antifouling performance at a well hydrophobicity of around 140° in contact angle and an inclination angle of 15°. In the abrasion resistance test of the surface, only a maximum loss of 0.015 g occurred. In the durability test, as a result of the chloride ion permeation test, almost no chloride ion permeation occurred in the variable where the coating agent was applied, and carbonation and freeze-thaw damage also rarely occurred, so it was analyzed that it was effective in securing durability of concrete.

• Polymer(Korea)
• /
• v.39 no.1
• /
• pp.122-129
• /
• 2015

Recently, the development of a new class of anti-fouling paint resin which has excellent anti-fouling performance and no persistence in the marine ecology is necessary. In this study, we first polymerized polyurethanes (PUs) as the other type of matrix which have carboxylic acid groups by using poly(ethylene glycol) (PEG), 4,4'-diphenylmethane diisocyanate (MDI), and 2,2'-bis(hydroxyl methyl)-propionic acid (DMPA). And next, we synthesized final resins having quaternary ammonium salts on pendant acid groups of PUs. After synthesis, the physical self-polishing property of resin by the measurement of reduced thickness in sea water was tested. The mechanical property of antifouling paint resin was good when the molecular weight of PEG was 600 or less. It was confirmed that the adhesion of PU resin was deteriorated when the content of quaternary ammonium salt was incorporated over specific value.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.8 no.3
• /
• pp.356-364
• /
• 2020

An experimental study to investigate the effect of self-cleaning of mortar mixed with photocatalyst was performed out in this study. Test parameters included the photocatalyst content and surface roughness of the specimens. The experimental mortar specimens were manufactured by mixing a photocatalyst by cement weight of 2.5%, 5.0%, 7.5% and 10.0%. In addition, the surface roughness was categorized into three cases. They included flat surface condition, little surface roughness(medium roughness), and high surface roughness. After mortar specimens were cured for 28 days, they were illuminated by an ultraviolet lamp for 24 hours and immersed in a methylene blue conditioning solution for 12 hours. Thereafter, an ultraviolet(UV) lamp was illuminated on the specimens for 48 hours in an experimental chamber and then the color change of methylene blue solution was measured by using a spectrophotometer over illuminating time of UV lamp. The color change of methylene blue tended to increase as photocatalyst contents increased. Test results meant that photocatalyst was effective for self-cleaning in mortar. However, the color change of the methylene blue solution did not show a noticeable tendency at different surface roughness conditions. It might be due to the uneven photocatalyst distribution on the surface of mortar specimens.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.25 no.5
• /
• pp.609-616
• /
• 2019

When the fouling of a vessel occurs, its resistance at sea increases and there is a corresponding increase in fuel consumption. The maintenance cost of the vessel also increases because it is time-consuming to remove the fouling. To solve this problem and minimize environmental contamination of sea-water, there have been recent developments in anti-fouling paints as self-polishing copolymers that not include toxic elements such as tin. When these conventional techniques are applied to vessels, polishing is promoted during the operation whereby friction or vibration with seawater occurs. This leads to enhanced anti-fouling performance. However, when fouling is intensified such as during an anchorage, there is no flow of seawater and polishing is suppressed. This leads to a deterioration of the performance of anti-fouling. To solve these problems, we developed a system that induces vibration in a vessel during anchorage. As such, the deterioration of polishing due to insuf icient flow of seawater is inhibited. The reliability of the ultrasonic antifouling system was evaluated by calculating its repeatability. The removal efficiency of fouling of the proposed system was qualitatively evaluated using test specimens. The test revealed that the value of the coefficient of variation for the reproducibility of the frequency and amplitude was 0.2 % and 4.0 % on average. The degree of fouling of the specimens was the highest at 73.3 g in the No.5 sepcimen. Moreover, efficiency of fouling removal was 93.2 % on average compared to the specimens without the proposed system.

• Journal of the Korean Society of Visualization
• /
• v.11 no.2
• /
• pp.18-26
• /
• 2013

An accurate and reliable performance evaluation technique is indispensable for the development of marine antifouling coatings. The existing standard practice is however, based on the visual observation of biofouling settlement area, which is prone to the subjective judgment of the inspector. In spite of the above mentioned importance, a systematic and objective fouling evaluation technique has not yet been introduced. In this study, a novel quantitative antifouling performance evaluation method for marine antifouling paints is devised based on the image analysis of panel immersion test results. The present image analysis method is to quantify settlement area for each fouling category by distinctive color. The fouling categories are set as unfouled, biofilm, green algae, brown algae, calcareous animal and spongy animal with specific HSL (Hue, Saturation, Lightness) color ranges. In order to assess the effectiveness of the proposed method, static immersion tests for three antifouling coatings were undertaken for two years.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2008.04a
• /
• pp.207-209
• /
• 2008

본 연구는 PFOA 규제대응 발수제(불소고분자의 탄소수가 6개)와 신규합성한 $TiO_2$ sol을 부피비로 혼용한 후 그에 따른 발수성과 방오성 향상에 관한 연구이다. 발수제 단독 처리 시 발수제의 사용량이 점차 줄어듬에 따라 발수도는 100에서 50${\sim}$70으로 점차 감소하였으며, 방오성은 5에서 2로 감소하였다. 그러나 $TiO_2$ sol을 발수제와 혼용하였을 경우 발수제의 사용량이 줄어듬에 따라 발수도가 100에서 80으로 방오성은 5에서 3.5로 감소하였으나, 발수제 단독 처리 시보다 우수한 결과가 나왔다.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.4
• /
• pp.469-477
• /
• 2021

In this study, the mechanical property of anti-fouling coating using CNF was evaluated to prevent the durability and stability of structure exposed the marine environment. Anti-fouling coating using CNF was prepared by CNF, AKD and waste glass powder, and contact angle test, drying time, viscosity analysis and microstructure were performed. When coating on one number of times, It was showed to relatively high hydrophobic performance in steel. And It was confirmed that the contact angle increased as the content of AKD increased in cement mortar. When coating on three number of times, the surface was confirmed super-hydrophobic at maximum of 151.6°. When mixing waste glass powder, the surface was showed to relatively high hydrophobic. It is pseudo plastic fluid when CNF and distilled water were prepared in a ratio of 1:1, And Anti fouling coating is judged to be suitable for use as coating on marine structure.