• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.110-115
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• 2010

The experiment was designed to compare pyrolysis kinetics of two different classes of imported coal. The pyrolysis behaviors of the coals were first observed with thermogravimetric analyzer(TGA). The kinetic analysis was further done based on a new distributed activation energy model(New DAEM). During the analysis, weight loss curves measured at three different heating rates were used to obtain the activation energy distribution function curve f(E) of a given coal sample where a mean activation energy is determined by its peak. The results show a significant difference in the mean activation energy between two coals for the pyrolytic reaction. The prediction of a chemical percolation devolatilization(CPD) model where the kinetics obtained from the New DAEM method were incorporated is in much closer agreement with an experimental data of TGA particularly for the bituminous coal.

• Fire Science and Engineering
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• v.30 no.6
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• pp.84-91
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• 2016

In case of fire, vertically and intensively loaded rack warehouses are faced with a severe status due to the rapid increase in fires. In this regard, there have been trials to prevent fires from spreading by applying fire extinguishing systems, such as ESFR and In-Rack Sprinklers, vertical and horizontal barriers, etc.; however, it is difficult to calculate and design proper fire extinguishing systems caused by various composition conditions, such as the size and loading density of the rack, types of loading commodities, etc. Therefore, in this study, a standard rack was manufactured, incorporating a rack warehouse in Korea by site investigations, surveys, etc. In addition, a full scale fire test was executed to check the fire characteristics depending on the conditions of the ignition points. As a result, the extracted fire spread speed is expected to be utilized as a reference for performance comparisons of the fire extinguishing systems to be developed and applied in the future.

• Clinical and Experimental Pediatrics
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• v.53 no.4
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• pp.579-584
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• 2010

Purpose : The number of the repatriated Korean students who had overseas study at early ages is increasing. They received foreign education, they can speak international languages, but they have many difficulties in articulation and intonation of the Korean language. This study aims to measure closure and aspiration duration, length of consonants, length of subsequent vowels, and ratio of consonants against subsequent vowels in vowel-consonant-vowel (VCV) syllables. Methods : This study compares the acoustic and phonetic characteristics of repatriated and native students, the ratio of articulation error of Korean plosives, the closure and aspiration duration, and the ratio of the aspiration duration against the closure duration. Results : The ratio of articulation error of Korean plosives between repatriated and native students is 19% and 2%, respectively. The closure duration was significantly longer in repatriated students than in native students. The aspiration duration was significantly longer in repatriated students than in native students. No difference was found in the ratio of aspiration duration against closure duration between the native and repatriated students. Conclusion : This study can be a good reference for estimating the phonetic difficulties of Korean elementary students who had overseas study at early ages.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.790-803
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• 2019

The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

• Journal of Convergence for Information Technology
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• v.11 no.6
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• pp.33-39
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• 2021

Speech recognition technology is being combined with deep learning and is developing at a rapid pace. In particular, voice recognition services are connected to various devices such as artificial intelligence speakers, vehicle voice recognition, and smartphones, and voice recognition technology is being used in various places, not in specific areas of the industry. In this situation, research to meet high expectations for the technology is also being actively conducted. Among them, in the field of natural language processing (NLP), there is a need for research in the field of removing ambient noise or unnecessary voice signals that have a great influence on the speech recognition recognition rate. Many domestic and foreign companies are already using the latest AI technology for such research. Among them, research using a convolutional neural network algorithm (CNN) is being actively conducted. The purpose of this study is to determine the non-voice section from the user's speech section through the convolutional neural network. It collects the voice files (wav) of 5 speakers to generate learning data, and utilizes the convolutional neural network to determine the speech section and the non-voice section. A classification model for discriminating speech sections was created. Afterwards, an experiment was conducted to detect the non-speech section through the generated model, and as a result, an accuracy of 94% was obtained.

• Phonetics and Speech Sciences
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• v.13 no.2
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• pp.57-66
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• 2021

This study focuses on the issue of automatic severity classification of dysarthric speakers based on speech intelligibility. Speech intelligibility is a complex measure that is affected by the features of multiple speech dimensions. However, most previous studies are restricted to using features from a single speech dimension. To effectively capture the characteristics of the speech disorder, we extracted features of multiple speech dimensions: voice quality, prosody, and pronunciation. Voice quality consists of jitter, shimmer, Harmonic to Noise Ratio (HNR), number of voice breaks, and degree of voice breaks. Prosody includes speech rate (total duration, speech duration, speaking rate, articulation rate), pitch (F0 mean/std/min/max/med/25quartile/75 quartile), and rhythm (%V, deltas, Varcos, rPVIs, nPVIs). Pronunciation contains Percentage of Correct Phonemes (Percentage of Correct Consonants/Vowels/Total phonemes) and degree of vowel distortion (Vowel Space Area, Formant Centralized Ratio, Vowel Articulatory Index, F2-Ratio). Experiments were conducted using various feature combinations. The experimental results indicate that using features from all three speech dimensions gives the best result, with a 80.15 F1-score, compared to using features from just one or two speech dimensions. The result implies voice quality, prosody, and pronunciation features should all be considered in automatic severity classification of dysarthria.

• Journal of the Society of Disaster Information
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• v.17 no.1
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• pp.10-24
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• 2021

Purpose: The purpose of this study is to determine the dangers of biodiesel and general diesel mixtures currently used as alternative fuels by equipment (tag method and penski Marten method) and to determine the difference between flash point and combustion point (closed, open) according to test methods. It is intended to be used as a reference material for identification and evaluation of firecausing substances by confirming the risk of mixtures by comparative analysis and measurement, and establishing a risk assessment method for chemical substances. Method: Flash point test method and result treatment were tested based on ASTM and KS M mode, which are tag sealing and pen schematense test methods used as flash point and combustion point test methods for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was a test equipment that satisfies the test standards of KS M 2010 with equipment produced by TANAKA of Japan. The flash point and combustion point were measured, and the flash point according to the test method of biodiesel and general diesel mixture ( Closed, open), and the ignition point of a mixture of biodiesel and general diesel was compared and analyzed for ignition risk compared with conventional diesel. Results: Looking at the experimental results, first, as an analysis of the risk of flammability of the mixture, the flash point of a substance containing 70% biodiesel was found to be about 92℃ based on general diesel with a flash point of 64.5℃, and gasoline and biodiesel or When the biodiesel mixture was synthesized, it was confirmed that the flash point tends to decrease. In addition, the difference between the flash point and the combustion point was analyzed as about 20 ~ 30℃, and when a small amount of gasoline or methanol was mixed, the flash point was lowered, but it was confirmed that the combustion point was similar to that of the existing mixture. Conclusion: In this study, in order to secure the effectiveness of the details of the criteria for judging dangerous materials in the existing Dangerous Materials Safety Management Act, and to secure the reliability and reproducibility of the judgment of dangerous materials, we confirm the criteria for judging the risk of the mixture through an experimental study on flammable mixtures. It will be able to provide reference data for experimental criteria for flammable liquids that are regulated in the field. In addition, if this study accumulates know-how on experiment by test method, it is expected that it can be used as a basis for research on risk assessment and research on dangerous goods.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.1
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• pp.537-544
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• 2011

This work was conducted to investigate the oxidation characteristics of methane having the highest ignition temperature among the other hydrocarbon gases using transition metal catalysts. The catalyst used for methane oxidation was manganese oxide having a various oxidation number, such as MnO, $MnO_2$, $Mn_2O_3$, $Mn_3O_4$, $Mn_4O_5$. The manganese oxide(MnxOy) catalyst is impregnated on $TiO_2$, $Al_2O_3$ for methane oxidation. To enhanced both of activity and life time of catalysts, Ni and Co was used as a promoter. In this study, various co-catalysts were synthesized by using excess wet impregnation method. The effect of reaction temperature and space velocity was measured to calculate the activity of catalysts such as, activation energy of $T_{50}$, and $T_{90}$. The life time of bi-metallic manganese mixture, such as Mn-Co and Mn-Ni catalysts, were increased more 10 % than manganese oxide catalyst, but activity of those was decreased slightly.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.9 no.1
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• pp.74-78
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• 1976

In this paper, the author experimented, by using the C. F. R. engine, how the functions of engine is changed when the compression ratio is raised. In the process of these experiments, by using three kinds of fuel, such as cetane number 95, 61, 33, and set the engine speed as 900 r. p. m., fuel injection time is determined as B. T. D. C. $13^{\circ}$. As the result of test, the best compression ratio is disernable in proportion to each fuel, and acknowledges that if the higher compression ratio were to exist other than the above one, efficiency of heat gets rather lower, and that the maximum output of engine decreases. Andthe best compression ratio changed according to supply calorie per each hour, and this change is more remarkable in the fuel of low cetane number. Consequently, the best compression ratio cannot be regardless of output in the fuel of low cetane number.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.04a
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• pp.180-187
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• 2011

본 논문은 다중이용업소와 목조건축물에 자주 사용되는 미송합판에 방염처리를 하여 유사 화재를 구현하고, 그 화염 세기에 따른 방염의 실효성을 실험한 것이다. 방염처리를 하면 화재 시 가연물의 초기착화시간을 지연시켜 화재성장속도를 늦출 수 있고, 원활한 소화활동을 가능하게 해준다. 하지만 어느 정도 화재가 진행되어 화염이 거세지면, 45도 연소시험을 통한 방염기준을 충족하여도 그 성능을 기대하기 어렵다고 한다. 따라서 45도 연소시험 시 사용되는 65mm의 불꽃보다 큰 화염상태(초기착화 이후의 상태)에서 방염처리한 내장재(미송합판)의 방염성능이 유지되는지의 여부를 실제로 입증하고 그 근거를 뒷받침하기 위하여 본 연구를 시작하게 되었다. 실험에서는 화재의 규모(화염의 세기)를 달리하여 각기 다른 종류의 방염제로 방염 처리한 미송합판의 착화 시 화염온도, 복사열 유속 그리고 착화지연시간을 파악하였으며, 45도 연소시험과 관련하여 방염성능을 분석하였다. 45도 연소시험의 경우 실험에 사용한 방염 처리 합판은 방염성능 기준을 만족하는 것으로 나타났으며, 소규모 유사 화재로 직경 10cm 연소용기를 사용한 연소실험에서는 방염 처리한 합판의 착화지연시간이 평균적으로 대규모 유사 화재실험보다 길어 어느 정도는 방염효과를 갖는 것으로 나타났다. 하지만 대규모 유사 화재로 1단위 유류화재 연소용기를 사용한 연소실험의 경우 열방출율이 커 형성된 탄화막이 무분별하게 박리되고 발화가 일어나 착화지연시간의 차이를 구별하기 어려웠기 때문에 방염효과를 기대할 수 없었다.