• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.802-807
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• 2012

The autothermal reforming of methane to syngas has been carried out in a reactor charged with both a Ni (15 wt%)-Ru (1 wt%)/$Al_2O_3$-MgO metallic monolith catalyst and an electrically-heated convertor (EHC). The standalone type reactor has a start-up time of less than 2 min with the reactant gas of $700^{\circ}C$ fed to the autothermal reactor. The $O_2/CH_4$ and $H_2O/CH_4$ ratio governed the methane conversion and temperature profile of reactor. The reactor temperature increased as the reaction shifted from endothermic to exothermic reaction with decreasing $H_2O/CH_4$ ratio. Also the amount of $CO_2$ in the products increases with increasing $H_2O/CH_4$ ratio due to water gas shift reaction. The 97% of $CH_4$ conversion was obtained and the reactor temperature was maintained $600^{\circ}C$ at the condition of $GHSV=10,000\;h^{-1}$ and feed ratio ($H_2O/CH_4=0.6$ and $O_2/CH_4=0.5$). In this condition, the maximum flow rate of the syngas generated from the reactor charged with 170 cc of the metallic monolith catalyst is $0.94\;Nm^3/h$.

• Journal of the Korean Wood Science and Technology
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• v.40 no.3
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• pp.204-211
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• 2012

In this study, fast pyrolysis of pitch pine (Pinus rigida) was performed in a fluidized bed reactor under the temperature ranges between 400 and $550^{\circ}C$ at the residence time of 1.9 sec. Essential pyrolytic products (bio-oil, biochar, and gas) were produced and their yield was clearly influenced by temperature. The maximum yield of bio-oil was observed to 64.9 wt% (wet basis) at the temperature of $500^{\circ}C$. As pyrolysis temperature increased, the yield of biochar decreased from 36.8 to 11.1 wt%, while gas amount continuously increased from 16.1 to 33.0 wt%. Water content as well as heating value of bio-oils were obviously sensitive to the pyrolysis temperature. The water contents in the bio-oil clearly decreased from 26.1 ($400^{\circ}C$) to 11.9 wt% ($550^{\circ}C$), with increasing the fast pyrolysis temperature, while their higher heating values were increased from 16.6 MJ/kg to 19.3 MJ/kg. According to GC/MS analysis, 22 degradation compounds were identified from the bio-oils and 10 compounds were derived from carbohydrate, 12 compounds were derived from lignin.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.1
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• pp.29-39
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• 2017

In this research, thermal design data such as heat transfer coefficient on the wall surface required for ventilation system design which is to prevent the temperature rise in the underground utility tunnel that three sides are adjoined with the ground was investigated in numerical analalysis. The numerical model has been devised including the tunnel lining of the underground utility tunnel in order to take account for the heat transfer in the tunnel walls. The air temperature in the tunnel, wall temperature, and the heating value through the wall based on heating value(117~468 kW/km) of the power cable installed in the tunnel and the wind speed in the tunnel(0.5~4.0 m/s) were calculated by CFD simulation. In addition, the wall heat transfer coefficient was computed from the results analysis, and the limit distance used to keep the air temperature in the tunnel stable was examined through the research. The convective heat transfer coefficient at the wall surface shows unstable pattern at the inlet area. However, it converges to a constant value beyond approximately 100 meter. The tunnel wall heat transfer coefficient is $3.1{\sim}9.16W/m^2^{\circ}C$ depending on the wind speed, and following is the dimensionless number:$Nu=1.081Re^{0.4927}({\mu}/{\mu}_w)^{0.14}$. This study has suggested the prediction model of temperature in the tunnel based on the thermal resistance analysis technique, and it is appraised that deviation can be used in the range of 3% estimation.

• Journal of Energy Engineering
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• v.23 no.3
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• pp.235-240
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• 2014

In this study, the torrefaction of food waste was conducted to characterize its product, to find out effect of the operating temperature and to assess the feasibility of being used as fuel. The operating temperature was varid from $180^{\circ}C{\sim}270^{\circ}C$ and heat was provided by using nitrogen gas or waste oil heat carrier. The solid yield and moisture content were reduced were reduced as temperature increased. The moisture content reduction and thermochemical conversion were observed at higher than $240^{\circ}C$. At low operating temperature, heat transfer efficiency was higher with wast oil heat carrier. As temperature increases, there was not difference in heat transfer efficiency of two different heating methods. The lower heating value product was increased from 660 to 6,400 Kcal/kg with nitrogen gas and 6,890 Kcal/kg with waste oil heat carrier. The elemental analysis indicates that, as temperature increases, the carbon content of product increases and oxygen content decreases. From the analysis of O/C and H/C, the torrefaction product was close to low grade coal. The characteristics of fuel converted from the food subsequent thermochemical treatment.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.75-84
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• 2018

In this study, the analysis of torrefaction products was carried out for fueling of sewage sludge. The mixed samples were composed as follows : 50% of sewage sludge and 50% of rice husk and CR(Coffee Residue). In this experiment, the reaction time(30min, 60min) and temperature($200^{\circ}C$, $250^{\circ}C$, $300^{\circ}C$) were expressed as a single variable using SF(Severity Factor). As a result, it was confirmed that as the SF increased, the heating value and fuel ratio increased, but the CI(Combustibility Index) decreased. The heating value was similarly increased as CR(Coffee Residue) and SF increased. The fuel ratio range of mixed samples was equal to that of lignite(0.5~1.0) in case of SF lower than 6.19 and that of bituminous coal(1.0~1.8) in case of SF higher than 7.36 or above. The CI showed a stable range(3,000~5,500kcal/kg) in low SF as the content of mixed samples contained more rice husk than CR.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.292-298
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• 2016

In this research, considering the practical situation of separated placing method for mass concrete structure, an efficient method of controlling the heat of hydration is suggested by comparing between the simulated values and actual measurements conducted with the optimum mix design obtained from the various mix conditions with different types and amount of supplementary cementitious materials(SCMs). As the result of the research, firstly, the optimum mix designs for top and bottom layers were determined by Midas gen as OPC to FA of 85 to 15, and OPC to FA to BS of 50 to 20 to 30, respectively. The concrete mixtures prepared with the mix designs determined from the simulation satisfied the target performance range in slump, air content and compressive strength. Additionally, from temperature measurement for the actual mass concrete placed during spring, the maximum temperature difference between surface and core was about $10^{\circ}C$ with 59 and $49^{\circ}C$ for top and bottom layers, respectively, and 1.4 of cracking index was obtained. Therefore, considering the practical conditions of mass concrete construction, it is considered that the different heat of hydration method using different mix designs with SCMs can be an efficient method for controlling thermal cracking and settling cracking of mass concrete.

• Korean Journal of Food Science and Technology
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• v.29 no.2
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• pp.326-336
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• 1997

Four ice nucleation-active bacteria (INA-bacteria), Pseudomonas syringae, Xanthomonas campestris, Escherichia coli JM109/pEIN229 and Gluconobacter oxydans/pKIN230, were treated with heat, pressure and gamma-irradiation to compare viability and their ice nucleation activity (INA) after sterilization. Gamma-irradiated INA-bacteria showed the least decrease in T90 value (the temperature at which the 90% of drops are frozen). According to cumulative INA spectra, gamma-irradiated INA-bacteria showed little decrease in class A ice nuclei $(nucleate\;H_{2}O\;at\;higher\;than\;-5^{\circ}C)$, pressurized INA-bacteria showed more than 90% decrease in class A ice nuclei, and heat-treated INA-bacteria barely showed class A ice nuclei. Differential scanning calorimetry (DSC) was used to examine the effect of INA-bacteria on the thermophysical properties of water at freezing temperature. Freezing peaks were appeared at about $11{\sim}15^{\circ}C$ higher on thermograms and enthalpies of phase change were decreased for the water containing INA-bacteria compared with the pure water, while melting peaks were not shifted. INA measured by DSC method were significantly correlated with INA measured by drop freezing method $(R^{2}>0.993,\;p<0.0001)$, indicating that DSC can be used as a new, simple and precise method for measuring INA.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.76.2-76.2
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• 2011

석탄으로부터 합성석유를 생산하는 상용기술을 도입하여 건설하고 이와 더불어 원천기술 개발을 위한 국산화 기술 개발을 병행하여 향후 고유가 시대를 대비한 국가 에너지 안보 확립과 국내 기술 개발의 가속화를 추구해야 할 필요성이 대두되고 있다. 본 타당성 조사는 3종류의 석탄(호주 Wyong탄, 인도네시아 NTC탄, 인도네시아 KBB탄)으로부터 가스화에 의하여 합성석유스를 생산하는 공정에 대한 타당성 조사(Feasibility Study, FS)를 Class 5(하한 -50~-20%, 상한 30~100%)의 정확도로 수행하는 것을 내용으로 하고 있다. 플랜트의 규모는 합성석유 기준으로 20,000배럴/일이다. 플랜트의 건설을 위해서 광양제철소 슬래그처리장 내 12만평 부지에 조성 중인 포스코 SNG 생산공장 부지의 일부를 사용하는 것을 기준으로 하였다. 일반적으로 석탄의 종류에 따라서 가스화기의 종류 및 성능이 결정된다. 본 타당성 조사 연구에서 선정된 3종류의 석탄의 조성, 발열량, 회분 함량 등의 특성을 고려하여 각각의 석탄에 적합한 현존하는 상용급 가스화기를 선정하였다. 해당 석탄이 가스화기 종류에 따라 적절한 전처리 과정(건조, 분쇄, 슬러리화)을 거친 후 가스화기에 공급되는 것을 가정하여 석탄의 원소분석 조성, 발열량, 회분함량, 회분조성, 회 용융점 등의 변수에 따라서 각각 해당 가스화기에서 가스화되었을 때의 생성되는 합성가스의 조건을 시뮬레이션을 통하여 얻었다. 가스화기 시뮬레이션 결과를 토대로 합성석유 및 합성천연가스 생산을 위한 공정의 물질수지식 및 에너지수지식이 계산되었으며 이로부터 각 공정에서 발생되는 부생성물과 폐기물에 대한 양이 결정되고 이를 처리하는 방안 등도 제시되었다. 실증시설은 20,000배럴/일 규모의 CTL 및 전기 병산 시설이 적합하다. 더 큰 규모 공장은 투자비가 너무 커서 유가 또는 석탄가 변동에 따라 사업의 수익성이 크게 변하여 위험도가 큰 단점이 있기 때문이다. CTL 공장에 전기 병산이 추천되는 이유는 산소생산공장(APU), 압축 등 석탄전환공장에는 자체적인 전기수요가 막대하여 따로 스팀터빈용 발전소를 운영하므로 이를 효율적으로 대체하고자 하기 때문이다. 즉, 석탄가스화에 의해 기름을 최대한 만들고 미반응가스는 가스터빈 및 스팀터빈의 복합발전에 의해 고효율로 전기를 생산하면 최소의 비용으로 최대한 전기를 생산하여 자체소비 전력을 충당하고 남는 전기는 판매하여 수익률을 높일 수 있다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.503-510
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• 2020

Eco-friendly mountain railways operate on concrete rack tracks embedded on existing sharp curved and steep roads to preserve the environment in mountainous areas. Owing to the narrow roads, single lines are inevitable, and many branches are required. In branches, previous switchers and heating devices cannot be applied, because of the limited spacing for the rack and the slow removal of thick ice. To solve these problems, a switch and a heating device have been developed. The switcher changes the line by moving the block of concrete track with hydraulic actuators. The lack of discontinuity reduces the derailment risk and makes locking simple. The heating device uses high frequency induction coils to increase the efficiency and melt the thick ice rapidly. The prototype switcher and heating device were produced and operated to prove their performance. The heating device yielded a 10 times greater efficiency than the previous one. The switcher and heating device are the essential core technologies for the operation of mountain trams in winter and contribute to the spread of mountain railways to domestic or foreign resort areas by enhancing safety and efficiency. In addition, they can provide transportation rights to local residents in poor winter traffic, and bring about tourism and local economic growth.

• Pediatric Infection and Vaccine
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• v.15 no.2
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• pp.167-173
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• 2008

Purpose : We evaluated the prevalence and clinical, microbiological features of extrapulmonary tuberculosis (EPT) in pediatric patients. Methods : We retrospectively reviewed medical records of pediatric patients diagnosed with EPT at The Catholic University of Korea, Incheon St. Mary's Hospital between 2000 and 2007. Results : Of 109 patients diagnosed with tuberculosis (TB), 12 patients (11%) were admitted with EPT. At 2006-2007, the proportion of patients with EPT among patients with TB was the highest (20%) comparing with last 6 years. The ratio of male to female patients was 1.4:1 and the mean age was 9.2 years (range, 3 months-15 years). The involved sites were pleura in 5 (41.6%), central nervous system in 3 (25%), miliary TB in 2 (16.7%), gastrointestinal tract in 1 (8.3%) and bone and joint in 1 (8.3%). The most common symptom at admission was fever (91.6%) and mean duration of fever was 15.8 days (range, 0-47 days) in spite of the proper treatment. Confirmed rate for acid fast bacillus stain, culture, and polymerase chain reaction were 33.3%, 41.6% and 41.6%. Of 5 culture proven cases, 4 (80%) were resistant to more than one antituberculosis drugs. Eleven patients recovered without complication and 1 patient died. Conclusion : Total incidence of TB decreased steadily according to the nationwide survey. However, our results suggest that the proportion of diagnosis with EPT among diagnosis with TB in children has increased. Microbiological diagnosis of EPT in children was more difficult than that of pulmonary TB. And drug resistance rate has increased.