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Improvement of the Biological Process against Advanced Water Quality Standard in Winter Season (동절기 수질기준 강화에 대비한 생물학적 공정의 개선 방안)

  • Han, Man-Shin;Choi, Gye-Woon;Lee, Jin-Young;Lee, Min-Hee
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.478-478
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    • 2012
  • 국내의 하수도 보급률은 90%에 달하고 있으며, 하수의 고도처리와 처리기술이 향상된 신기술개발 등으로 수질개선 효과가 크게 개선되어 있고, 전국 각지에 활발하게 하수처리장의 건설이 추진 중에 있지만, 다양한 오염원의 증가와 함께 환경기준은 점차적으로 강화되고 있어 기존 하수처리장은 강화되고 있는 환경기준을 만족시키기 어려운 실정으로 새로운 처리법의 도입이 절실히 요구되고 있는 실정이다. 시설이 노후화된 하수종말처리장의 경우에는 경제적인 부담감을 이유로 기존 공법 개선을 통한 수질기준을 만족하기 위하여 노력하고 있으며, 특히, 방류수 수질 중에서 총질소(T-N)와 총인(T-P)의 기준을 평상시와 겨울철(12월 1일부터 3월 31일까지)로 구분하여 적용하여 왔지만, 2012년부터는 이를 동일하게 적용함으로써 겨울철 생물학적 처리 공정에서의 효율저하로 인한 기준치 만족이 어려운 상황이다. 본 연구에서는 인천의 하수처리장을 대상으로 동절기 수온의 저하에 따른 생물학적 공정을 개선시키기 위하여 운전조건을 변경하여 수질개선 증대 방안을 도출하고자 하였으며, 생물학적 공정인 MLE공법으로 동절기 외부 온도의 영향을 받는 조건을 갖는 사업소를 대상으로 실내 실험장치를 구성하여 조건을 변화하면서 개선 효과를 검토하였다. 생물반응조의 공정위치 변화, 미생물농도 그리고 체류시간변화 등의 실험조건으로 하수 처리 효율을 분석하였으며, 운전 중 외부반송 유량, 내부반송 유량 등의 운전인자는 일정하게 유지하였고, 동절기 온도인 $10^{\circ}C$로 유지하여 실험을 진행하였다. 실험 결과 대상 하수처리장의 생물학적 공정의 개선방향은 공정 배열을 변화하였을 때, 현재의 공정 배열 조건인 무산소조 1개, 호기조 4개의 공정보다 호기조 1개, 무산소조 1개, 호기조 3개로 수정하는 경우 현재 공정보다 질소는 7%, 유기물은 9.2% 처리효율이 개선되는 것으로 분석되었다. 미생물 농도 변화를 주어 수질 개선 효과를 검토한 결과 하수처리장 설계농도인 3,500ppm의 경우보다 미생물 농도를 5,970ppm으로 증가시킨 경우 17.4% 처리효율의 개선효과를 보여 질소 제거를 위해 미생물의 농도를 증가시키는 것이 바람직한 것으로 판단하였다. 또한, 체류시간(HRT)을 변화한 경우에는 현재 체류시간(HRT)인 8시간 보다 10시간으로 증가시켰을 경우 유기물은 3.2%, 질소는 2.6%의 처리효율이 개선되는 것으로 분석되었다.

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Self-Assembly Monolayers 처리 공정이 블록 공중합체를 이용한 나노패턴 제조에 미치는 영향

  • Hwang, Yeong-Hyeon;Gwon, Sun-Muk;Kim, Yeong-Hwan;Jo, Won-Ju;Kim, Yong-Tae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.339-339
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    • 2011
  • 기존의 광학리소그래피방법으로는 나노크기의 패턴을 형성하는데에 있어서 많은 제약이 있으며, 사실상 수십나노크기의 패턴을 형성하는데에는 전자빔리소그래피등 새로운 패턴형성 방법이 요구되고 있다. 블록 공중합체를 이용한 나노 패턴은 서로 다른 화학적 구조를 가지는 고분자들이 공유결합으로 연결되어 있는 분자구조를 이용하여, 하나의 분자 내에 서로 다른 블록들이 상분리를 일으키려는 것과 동시에 이들의 공유결합으로 인해 그 정도가 제한되는 것을 이용하여 라멜라, 실린더, 구 등의 주기적으로 배열된 형태의 구조물을 형성하는 패터닝 기술이다. 블록 공중합체를 이용한 나노크기의 패턴 형성은 열역학적으로 안정적인 구조이며, 대면적으로 구현 할 수 있어서 차세대 소자제작을 위한 제작기술로 많은 관심을 가지고 있다. 하지만 블록공중합체를 이용한 나노패턴 기술은 선행적으로 나노구조체를 결함이 없고, 원하는 형태로 제작 할 수 있는 공정의 확립이 필요하다. 따라서 본 연구에서는, 이러한 블록 공중합체을 이용한 나노패턴을 제조하는 공정에서, 폴리스틸렌과 실리콘 산화물 박막과의 표면반응을 막기 위한 Self-Assembly Monolayers (SAMs) 처리 공정이 패턴 형성에 미치는 영향을 알아보기 위하여 MPTS의 농도 및 처리시간을 변화시켰다. 나노패턴을 분석, 확인하기 위하여 Atomic Force Microscopic (AFM)과 Field Emission Scanning Electron Microscope (FESEM)을 이용하였다.

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A Study of Lens Design Technique for Proximity Exposure Using a UVA LED (UVA LED를 이용한 근접 노광용 렌즈 설계 기술 연구)

  • Lee, Jeong-Su;Jo, Ye-Ji;Lee, Hyun-Hwa;Kong, Mi-Seon;Kang, Dong-Hwa;Jung, Mee-Suk
    • Korean Journal of Optics and Photonics
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    • v.30 no.4
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    • pp.146-153
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    • 2019
  • The exposure system is a device that transfers a circuit pattern to a desired location. To display patterns on a substrate without deforming the optical characteristics, the characteristics of the optical exposure system are very important. Therefore, to form a microcircuit pattern, a small divergence angle should impinge on the irradiation area. Also, since the light from the source must react uniformly with the photosensitizer, it must have high luminance efficiency and uniformity of illumination. In this paper a parabolic reflector and an aspherical lens were designed to solve the problem of narrow-angle implementation, and it was confirmed by simulation analysis after their arrangement that the beam angle, uniformity, and maximum illuminance satisfied the target performance.

Development of an Electromagnetic Analysis Methodology for the Aspheric Ogival Radome (원뿔형 비구면 레이돔에 대한 전자파 해석 기법 개발)

  • Seo, Seung-Hee;Cho, Ji-Hyun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.7
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    • pp.617-624
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    • 2009
  • In this paper, an electromagnetic analysis methodology using reaction theorem based on reciprocity theorem is presented for the aspheric ogival radome applied to a missile and/or airborne radar. The presented analysis methodology is verified using actual measured data. The type of antenna assumed to develope the methodology is a waveguide slot array antenna, and has the structure of 2 axes monopulse of "X" type. The shape of radome is assumed as Von Karman and the ratio of length to base diameter(L/D) is assumed to be 2:1. The electrical characteristics of the radome are measured using radome measurement system and the results are compared to the values estimated using the presented analysis methodology. It is found that the comparison shows good agreement. It is expected that the presented methodology can be applied for the development of missile and airborne radome.

Changes of Understory Vegetation Structure for 10 Years in Long-Term Ecological Research Site at Mt. Gyebang (계방산 장기생태조사지에서 10년간 하층식생구조변화)

  • Cheon, Kwang Il;Chun, Jung Hwa;Yang, Hee Mun;Lim, Jong Hwan;Shin, Joon Hwan
    • Journal of Korean Society of Forest Science
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    • v.103 no.1
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    • pp.1-11
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    • 2014
  • This study was conducted to investigate the changes understory vegetation composition (shrub and herb layers) in Mt. Gyebang as a northern-temperate deciduous broadleaf forest. Tracheophytes were 146 taxa, consisting 56 families, 93 genera, 124 species, 17 varieties, 3 forma, 2 sub-species and 1 unknown taxa in research subject area. As species area curve analysis, herbaceous layer and shrub species have been decreased over time. As a result of Mantel-test, basal area of upper layer affects to understory vegetation change (p<0.0001). Mean importance value was dominated Lindera obtusiloba (21.585%), Rhododendron schlippenbachii (19.774%) in the shrub layer, identified Sasa borealis (14.082%) and Lindera obtusiloba (7.921%) in the herb layer. According to NMS analysis of shrub layer, Species characterized by strong correlation have been reduced as time goes by. And it reports different species as an increasing in basal area of the upper layer. Herb layer plots of the NMS analysis, Rhododendron schlippenbachii and Rhododendron mucronulatum consistently were affected in shrub layer. In consequence of MRPP-test for changes in vegetation composition, It was analyzed that there are no significant differences for vegetation composition changes on shrub layer in 5-10 years. As a changes of vegetation composition on herb layer were analyzed significantly, composition change of herb layer species was larger than shrub layer species in understory vegetation.

Development of New BNR Process Using Fixed-Biofilm to Retrofit the Existing Sewage Treatment Plant (고정생물막을 이용한 기존 하수처리장의 생물학적 영양염 제커 신공정개발)

  • Kim, Mi-Hwa;Lee, Ji-Hyung;Chun, Yang-Kun;Park, Tae-Joo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1093-1101
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    • 2000
  • The object of this study was to develop new BNR process using fixed-biofilm which could be applied to retrofit the existing wastewater treatment plant or to introduce as tertiary treatment plant. To achieve complete denitrification from typical raw sewage in Korea, external carbon source must be supplied because $SCOD_{cr}/T-N(NH_4{^+}-N+NOx-N)$of raw sewage was lower than other countries. In this study, the ratio of $SCOD_{cr}/NH_4{^+}-N$ was 2.49 and the influent $NH_4{^+}$-N concentration during the experimental period was varied from 25 to 37 mg/L. To enhance nitrogen removal from the sewage, the two processes using fixed biofilm were adopted as R-Hanoxic/mid.settler/aerobic/anoxic/ aerobic) and R-2(aerobic/mid.settlerlanoxic/anoxic/aerobic), respectively. In the comparison of $NH_4{^+}$-N, T-N effluent quality and T-N removal efficiency in both processes without external carbon source, R-1 process was better than R-2 process for nitrogen removal from raw sewage. With respect to $SCOD_{cr}$/NOx-N ratio and total nitrogen removal in each anoxic reactor of two processes, R-1's was more effective than R-2's for distributing organic matters of raw sewage. In the both processes using fixed biofilm, the amount of required alkalinity to remove unit $NH_4{^+}$-N were 5.18 and 5.76($g{\cdot}CaCO_3/g{\cdot}NH_4{^+}-N_{removed}$), respectively and were lower than activated sludge BNR process(7.14).

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Synthesis and Characterization of Some Transition Metal Complexes of Unsymmetrical Tetradentate Schiff Base Ligand (비대칭 Tetradentate Schiff 염기 리간드의 전이금속 착물에 대한 합성 및 특성)

  • Munde, A. S.;Jagdale, A. N.;Jadhav, S. M.;Chondhekar, T. K.
    • Journal of the Korean Chemical Society
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    • v.53 no.4
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    • pp.407-414
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    • 2009
  • The solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with 4-hydroxy-3-(1-{2-(2-hydroxybenzylidene)- amino phenylimino}-ethyl)-6-methy-pyran-2-one (H2L) derived from o-phenylenediamine, 3-acetyl- 6-methyl-(2H) pyran, 2,4 (3H)-dione (dehydroacetic acid or DHA) and salicylic aldehyde have been synthesized and characterized by elemental analysis, conductometry, magnetic susceptibility, UV-visible, IR, $^1H$-NMR spectra, X-ray diffraction, thermal analysis, and screened for antimicrobial activity. The IR spectral data suggest that the ligand behaves as a dibasic tetradentate ligand with ONNO donor atoms sequence towards central metal ion. From the microanalytical data, the stoichiometry of the complexes has been found to be 1:1 (metal: ligand). The physico-chemical data suggests square planar geometry for Cu(II) and Ni(II) complexes and octahedral geometry for Co(II), Mn(II) and Fe(III) complexes. The x-ray differaction data suggests orthorhombic crystal system for Cu(II) complex, monoclinic crystal system for Ni(II), Co(II) and Fe(III) and tetragonal crystal system for Mn(II) complex. Thermal behaviour (TG/DTA) of the complexes was studied and kinetic parameters were determined by Coats-Redfern method. The ligand and their metal complexes were screened for antibacterial activity against Staphylococcus aureus and Escherichia coli and fungicidal activity against Aspergillus Niger and Trichoderma.

Expression of p21, p27 in Osteosarcoma and Its Prognostic Significance (p21, p27 단백질의 발현과 골육종 예후와의 관련성)

  • Oh, Joo-Han;Lee, Sang-Hoon;Cho, Whan-Seong;Yoo, Kwang-Hyun;Kim, Jin-Sam;Gong, Hyun-Sik;Suh, Sung-Wook;Kim, Ji-Eun;Kim, Han-Soo
    • The Journal of the Korean bone and joint tumor society
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    • v.9 no.2
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    • pp.169-177
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    • 2003
  • Purpose: The purpose of the current study is to evaluate the correlation between the expressions of p21 and p27 in osteosarcoma, and prognostic impact such as local recurrence, distant metastasis and survival rate. Materials and methods: Between 1988 and 2001, forty patients who underwent surgery, followed more than 12 months, and whose pathologic blocks were available, were evaluated retrospectively. Their formalin-fixed and paraffin-embedded tumor specimens were investigated. The correlation between expressions of p21, p27, local recurrence, distant metastasis and survival rate was statistically evaluated. Results: p21 protein was expressed in 38 (95%) patients. p27 protein was expressed in 14 (35%) patients. Patients with high expression of p21 had more frequent metastasis and poorer results (p=0.024). In contrast with these findings, patients with positive staining of the p27 had the significant lower distant metastasis (p=0.028). Conclusion: The prognosis of the osteosarcoma according to the expression level of p21 and p27 had inverse relationship which had unknown mechanism. Further work will be needed to define the relationship between p21 and p27.

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Correlation interpretation for surface-geophysical exploration data-Chojeong Area, Chungbuk (지표물리탐사 자료의 상관해석-충북 초정지역)

  • Gwon, Il Ryong;Kim, Ji Su;Kim, Gyeong Ho
    • Journal of the Korean Geophysical Society
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    • v.2 no.1
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    • pp.75-88
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    • 1999
  • A recent major subject of geophysical exploration is research into 3-D subsurface imaging with a composite information from the various geophysical data. In an attempt to interpret Schlumberger sounding data for the study area in 2-D and 3-D view, resistivity imaging was firstly performed and then pseudo-3-D resistivity volume was reconstructed by interpolating several 1-D resistivity plots. Electrical resistivity discontinuities such as fracture zone were successfully clarified in pseudo-3-D resistivity volume. The low resistivity zone mainly associated with fracture zone appears to develop down to granitic basement in the central part of the study area. Seismic velocity near the lineament is estimated to be approximately as small as 3,000 m/s, and weathering-layer for the southeastern part is interpreted to be deeper than for the northwestern part. Geophysical attributes such as electrical resistivity, seismic velocity, radioactivity for the Chojeong Area were analysed by utilizing a GIS software Arc/Info. The major fault boundaries and fracture zones were resolved through image enhancement of composite section (electrical resistivity and seismic refraction data) and were interpreted to develop in the southeastern part of the area, as characterized by low electrical resistivity and low seismic velocity. However, radioactivity attribute was found to be less sensitive to geological discontinuities, compared to resistivity and seismic velocity attributes.

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