• Title/Summary/Keyword: 반응유동

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Pressure Drop and Catalytic Dehydrogenation of NaBH4 Solution Across Pin Fin Structures in a Microchannel Reactor (마이크로 Pin Fin 화학반응기에서 수소화붕소나트륨 수용액의 압력강하 및 탈수소 화학반응 연구)

  • Jung, Ki Moon;Choi, Seok Hyun;Lee, Hee Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.6
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    • pp.381-387
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    • 2017
  • Dehydrogenation from the hydrolysis of a sodium borohydride ($NaBH_4$) solution has been of interest owing to its high theoretical hydrogen storage capacity (10.8 wt.%) and potentially safe operation. An experimental study has been performed on the catalytic reaction rate and pressure drop of a $NaBH_4$ solution over both a single microchannel with a hydraulic diameter of $300{\mu}m$ and a staggered array of micro pin fins in the microchannel with hydraulic diameter of $50{\mu}m$. The catalytic reaction rates and pressure drops were obtained under Reynolds numbers from 1 to 60 and solution concentrations from 5 to 20 wt.%. Moreover, reacting flows were visualized using a high-speed camera with a macro zoom lens. As a result, both the amount of hydrogenation and pressure drop are 2.45 times and 1.5 times larger in a pin fin microchannel array than in a single microchannel, respectively.

A Numerical Analysis of Flame Liftoff Height and Structure with the Variation of Velocity Profiles at the Nozzle Exit (연료노즐 출구에서의 속도 형상에 따른 부상화염 높이 및 화염구조에 관한 수치해석 연구)

  • Ha, Ji-Soo;Kim, Tae-Kwon;Park, Jeong
    • Journal of the Korean Institute of Gas
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    • v.12 no.4
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    • pp.21-28
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    • 2008
  • A numerical analysis is achieved to elucidate the behavior of lifted flames and characteristics of flow near flame zone according to the exit velocity of triple flame, Poiseuille and uniform distribution. For the cases of Poiseuille and uniform nozzle exit velocity, we reviewed previous results with the present numerical results and investigated characteristics of the flame structure near the flame zone comparing with liftoff height generalized by momentum flux. In addition, a close inquiry into the combustion flow characteristics near flame zone was made with the characteristics of velocity, pressure, temperature and chemical reaction. From nozzle to flame zone, center line velocity profile traced well with the velocity profile of typical cold jet flow, but very near the flame zone, this study examined phenomenon that flow velocity decreases very quickly before the flame zone and then increases very quickly after the flame zone. Because flame zone acts as a barrier at the flow region which is before the flame zone and accelerate the flow velocity when it pass through the flame zone. This phenomenon was not clarified previous cold jet flow.

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A Study on the Flow Characteristics of the Catalytic Combustor for the Gas Turbine (가스터빈용 촉매 연소기의 유동 특성에 관한 연구)

  • Hong, Dong-Jin;Kim, Chong-Min;Kim, Man-Young
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.9
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    • pp.792-798
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    • 2007
  • catalytic combustion is accomplished by the chemical reaction between fuel and oxidizer at the catalyst surface, different from conventional combustion. Therefore, it is important that the fuel and air stream are well mixed and supplied uniformly prior to the combustion region. If the flow is maldistributed, a hot spot may occur that can lead to subsequent catalyst and substrate damage. Therefore, in order to enhance the mixing and flow uniformity, in this study, the perforated plate is used. A numerical simulation is performed to investigate the variation of flow characteristics by changing various parameters. Under each condition, the uniformity of the flow stream at the entrance of the catalyst section is evaluated and compared. The results show that the uniformity can be effectively improved for most of the case by using the well-designed perforated plates.

A Study on the Mechanical Properties of Polymer Repair-Mortars with CFBC Ash (순환유동층 보일러애시를 활용한 폴리머 보수 모르타르의 역학적 특성에 대한 연구)

  • Kang, Yong Hak;Lim, Gwi Hwan;Shin, Dong Cheol;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.127-132
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    • 2018
  • The amount of generated Circulating Fluidized Bed Combustion ash (CFBC ash) is annually increasing, but most CFBC ash has been landfilled and discarded due to the limited utilization. The major chemical compositions of CFBC ash are $SiO_2$, CaO and $CaSO_4$, which could form hydration products by reacting with water as self-cementing property such as cement. The purpose of the this study is to derive the optimal mix proportions to improve polymer-modified mortar with the use of CFBC ash which has the self-cementing property. In order to develop polymer-modified mortar, three mix proportions were determined, and fundamental properties for the mixtures were obtained. As a result, the optimal mixture containing 10 percent of silica fume, 1.0 percent of polymer and 3.5 percent of expansive additives were proposed in this study.

Treatment of Fluoride in Semiconductor Wastewater by using Fluidized Bed Reactor (유동상 반응기를 이용한 반도체 폐수의 불소 처리)

  • An, Myeong-Ki;Kim, Keum-Yong;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.5
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    • pp.437-442
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    • 2010
  • This work was initiated both to maximize purity of calcium fluoride sludge and to minimize water content in the settled sludge. The sludge was produced in the process of fluoride removal of semiconductor wastewater by the addition of $Ca^{2+}$ ion. Fludized bed reactor(FBR) using calcium fluoride as a seed was adapted. Optimum pH and molar ratio of $Ca^{2+}/F^-$ were determined in lab-scale study. The experimental results showed that fluoride removal was increased as pH and molar ratio of $Ca^{2+}/F^-$ increased, with the best removal of 79.8% in an optimum condition. In the optimum point of fluoride removal, very low ${PO_4}^{3-}$-P removal of 9.3% was observed. It indicates forming $CaF_2$ crystal of high purity, when side reaction of calcium with phosphate was minimized. In addition, water content of settled sludge was 19.3%, which is relatively low compared to other fluoride removal processes. Consequently, the FBR process proposed in this study was very effective in fluoride removal, producing good sludge of high purity and less water content.

Refractory Textile Wastewater Treatment Using Cell-Immobilized Polyethylene glycol Media (PEG 포괄고정화담체를 이용한 난분해성 염색폐수 처리)

  • Han, Duk-Gyu;Cho, Young-Jin;Bae, Woo-Keun;Hwang, Byung-Ho;Lee, Yong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.345-350
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    • 2006
  • This study investigated the removal of recalcitrant organics in dyeing wastewater using a fluidized bed reactor(FBR) that contained cell-immobilized pellets. The pellets were manufactured and condensing the gel phase by mixing PEG-polymer and cells to form micro-porous PEG-polymer pellets whose size were ${\Phi}\;4mm{\times}H\;4mm$ on average. An industrial activated sludge without any pre-adaptation was used for the cell immobilization because it gave an equivalent removal efficiency to a pre-adapted sludges. The feed was obtained from an effluent of a biological treatment plant, which contained $SCOD_{Cr}$ of 330 mg/L and $SBOD_5$ of 20 mg/L. The $SCOD_{Cr}$ removal efficiency was over 45% and the effluent $COD_{Mn}$ concentration was less than 100 mg/L at HRTs from 6 to 24 hrs. The optimum HRT in the FBR was determined as 12 hrs considering the removal efficiency and cost. When a raw wastewater containing 768 mg/L of $COD_{Cr}$ was fed to the FBR, the effluent $COD_{Cr}$ concentration increased only slightly, giving a 70% of $COD_{Cr}$ removal or a 97% of $BCOD_5$ removal. This indicated that the FBR had an excellent capability of biodegradable organics removal also. In conclusion, the FBR could be applied to textile wastewater treatment in place of an activated sludge process.

A Model on a Bubbling Fluidized Bed Process for CO2 Capture from Flue Gas (연소기체로부터 CO2를 포집하는 기포 유동층 공정에 관한 모델)

  • Choi, Jeong-Hoo;Youn, Pil-Sang;Kim, Ki-Chan;Yi, Chang-Keun;Jo, Sung-Ho;Ryu, Ho-Jung;Park, Young-Cheol
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.516-521
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    • 2012
  • This study developed a simple model to investigate effects of important operating parameters on performance of a bubbling-bed adsorber and regenerator system collecting $CO_2$ from flue gas. The chemical reaction rate was used with mean particles residence time of a reactor to determine the extent of conversion in both adsorber and regenerator reactors. Effects of process parameters - temperature, gas velocity, solid circulation rate, moisture content of feed gas - on $CO_2$ capture efficiency were investigated in a laboratory scale process. The $CO_2$ capture efficiency decreased with increasing temperature or gas velocity of the adsorber. However, it increased with increasing the moisture content of the flue gas or the regenerator temperature. The calculated $CO_2$ capture efficiency agreed to the measured value reasonably well. However the present model did not agree well to the effect of the solid circulation rate on $CO_2$ capture efficiency. Better understanding on contact efficiency between gas and particles was needed to interpret the effect properly.

Design and Simulation of Fluidized Bed System for Waste Propellant Treatment by Computational Fluid Dynamics (폐 추진제 소각을 위한 유동층 반응기 설계 및 CFD 공정 모사)

  • Lee, Jiheon;Lee, Inkyu;Kim, Hyunsoo;Park, Jungsoo;Oh, Min;Moon, Il
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.84-89
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    • 2018
  • Recently, many studies have focused on the explosive waste treatment in terms of the safety and environmental pollution. A combustion process using fluidized bed incinerator has several profits : continuous process, low pollutive gases such as NOx, and high process efficiency. This study focused on the design of the propellant combustion reactor by using computational fluid dynamics(CFD) simulation technique. As a result, the reactions are successfully simulated in cylindrical incinerator, and. The study will influence to the research about treatment of explosive wastes.

Study on optimum structure of air-lift bio-reactor using numerical analysis of two-phase flow (이상 유동 수치해석을 이용한 기포 구동 생물 반응기 내부 최적 구조에 관한 연구)

  • Kim, San;Chung, Ji Hong;Lee, Jae Won;Sohn, Dong Kee;Ko, Han Seo
    • Journal of the Korean Society of Visualization
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    • v.17 no.3
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    • pp.24-31
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    • 2019
  • Recently, an air-lift bio-reactor operated by micro bubbles has been utilized to product hydrogen fuel. To enhance the performance, characteristics of hydrodynamics inside the bio-reactor were analyzed using a numerical simulation for two-phase flow. An Eulerian model was employed for both of liquid and gas phases. The standard k-ε model was used for turbulence induced by micro bubbles. A Population Balance Model was employed to consider size distribution of bubbles. A hollow cylinder was introduced at the center of the reactor to reduce a dead area which disturbs circulation of CO bubbles. An appropriate diameter of the draft tube and hollow cylinder were optimized for better performance of the bio-reactor. The optimum model could be obtained when the cross-sectional area ratio of the hollow cylinder to the reactor, and the width ratio of the riser to the downcomer approached 0.4 and 3.5, respectively. Consequently, it is expected that the optimum model could enhance the performance of the bio-reactor with the homogeneous distribution and higher density of CO, and more effective mixing.

Forward Osmosis Membrane to Treat Effluent from Anaerobic Fluidized Bed Bioreactor for Wastewater Reuse Applications (하수재이용을 위한 혐기성 유동상 생물반응기 처리수의 정삼투 여과막의 적용)

  • Kwon, Dae-eun;Kim, Jeonghwan
    • Membrane Journal
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    • v.28 no.3
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    • pp.196-204
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    • 2018
  • The anaerobic fluidized bed bioreactor (AFBR) treating synthetic wastewater to simulate domestic sewage was operated under GAC fluidization to provide high surface area for biofilm formation. Although the AFBR achieves excellent COD removal efficiency due to biological activities, concerns are still made with nutrient such as nitrogen remaining in the effluent produced by AFBR. In this study, forward osmosis membrane was applied to treat the effluent produced by AFBR to investigate removal efficiency of total nitrogen (TN) with respect to the draw solution (DS) such as NaCl and glucose. Permeability of FO membrane increased with increasing DS concentration. About 55% of TN removal efficiency was observed with the FO membrane using 1 M of NaCl of draw solution, but almost complete TN removal efficiency was achieved with 1 M of glucose of draw solution. During 24 h of filtration, there was no permeate flux decline with the FO membrane regardless of draw solution applied.