• Title/Summary/Keyword: 미량성분원소

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보은 지역의 온천 변성염기성암에 대한 암석.지구화학적 연구

  • 권성택;이동호
    • The Journal of the Petrological Society of Korea
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    • v.1 no.2
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    • pp.104-123
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    • 1992
  • We present petrography, mineral chemistry of amphibole and plagioclase, and major and trace element chemistry for the Ogcheon metabasites occurring in the Poun and Mungyong areas to understand metamorphism, and to define chemical characteristics of parental rocks and their implication for tectonic environment. The Ogcheon metabasites often preserve relict igneous textures, although no primary phases are observed. They are mainly composed of amphibole (actinolite+hornblende)+plagioclase+epidote+chlorite+sphene+opaque oxides, indicating epidote amphibolite facies metamorphism. Coarse-grained amphiboles frequently have actinolitic composition in the core, and hornblende along the margin and cleavage, which can be interpreted either as miscibility gap or as result of polymetamorphism. Although presumed polymetamorphic events in the Ogcheon supergroup favor the latter possibility, further metamorphic studies are necessary to solve the problem. Amphibole and plagioclase chemistries suggest greenschist (epidote-amphibolite, if miscibility gap is present) to amphibolite facies metamorphism of possibly medium pressure. The major and trace element data of whole rocks indicate that the Ogcheon metabasites are transitional to tholeiitic basalts belonging to within-plate environment. Absence of evidences indicating deep sea environment suggests that the Ogcheon metabasites emplaced in an intra-cratonic, possibly rift environment which failed to proceed to an oceanic rift. Chemical variation of the metabasites toward a granitic pluton indicates K loss closer to the pluton, suggesting that caution should be taken when K is involved in a discussion.

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Petrology and Geochemistry of Miocene Alkaline Basalt (Huangsongpu Basalt) from the Mt. Baekdu Area (백두산 지역의 마이오세 알칼리 현무암(황송푸 현무암)의 암석학적/지화학적 특성)

  • Kim, Eunju;Hirata, Chiharu;Jeong, Hoon Young;Kil, Youngwoo;Yang, Kyounghee
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.307-324
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    • 2020
  • Major and trace elements, and Sr, Nd, isotopic composition analysis have been carried out on the Miocene basalt (Huangsongpu basalt, 20 Ma) 25 km to northeast from the Mt. Baekdu. The basalt has Na2O+K2O=3.5~4.7 wt.%, and MgO=9.9~11.1 wt.%, containing Mg-rich olivine (Mg#=75~86), clinopyroxene (Mg#=72~85) and Ca-rich plagioclase micro-phenocrysts. These data suggest that the basalt belongs to the alkaline magma series with a primitive nature, crystallized at a near-liquidus. The basalt is also characterized by high Cr (394~479 ppm) and Ni (389~519 ppm) contents, Nb-Ta enrichment anomalies and OIB-like trace elements patterns, displaying identical signatures to those of typical intraplate magmas. The rare earth element (REE) patterns of the basalt and high (Gd/Yb)sample/(Gd/Yb)PM ratio (=2.8~3.5) suggest the parental magma was derived from relatively low-degree (3~5%) partial melting of garnet peridotite. The 143Nd/144Nd and 87Sr/86Sr composition of the basalt are higher than those of BSE. The high 87Sr/86Sr (= ~0.7058) ratio of the basalt indicates a contribution of recycled ancient oceanic crust or continental crust on the Pacific slab suggesting that the Huangsongpu basalt was generated from metasomatized mantle.

The Study of Natural Background of Geologic Units for Stream Sediments in the Gurye Area (구례지역 하상퇴적물의 지질집단별 자연배경치에 대한 연구)

  • 박영석;장우석;김종균
    • Economic and Environmental Geology
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    • v.36 no.4
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    • pp.275-284
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    • 2003
  • We collected the samples of stream sediments from primary channels in order to establish natural background of major and minor elements for geologic units in the Gurye area. Stream sediments samples having no possibility of contamination effect and representing drainage basins composed of uniform geology, were collected from April to May in 1999, the chemical analysis of which was carried out. The tolerable level was used to investigate the enrichment degree of harmful elements. The contents of Ni and Cr exceeded the tolerance level in some sections. The tolerance level excess of those elements was regarded as the effect of the metamorphic rock which constituted the bed rock of the area. In order to identify the comprehensive enrichment pattern, the tolerable level was used in calculating the enrichment index. The enrichment index of harmful heavy metals showed that Granite gneiss area is 0.39, Porphyroblastic granite gneiss area 0.32, Biotite gneiss area 0.42, Migmatitic gneiss area 0.41, Tuff area 0.30, Andesite area 0.46, Conglomerate area 0.42, and Granite area 0.26. Those results showed that natural background of Gurye area had not been exposed to harmful heavy metal elements.

Studies on Inorganic Components of Korean Wild Edible Mushrooms - Trace Mineral Elements of Armillariella Mella, Hygrophorous russula, Armillariella tabescens, Lepista nuda and lepista sordida, Hygrocybe conica. - (한국산 야생(野生) 식용버섯의 무기성분에 관한 연구 - 뽕나무버섯, 뽕나무버섯부치, 벚꽃버섯, 민자주방망이버섯, 자주방망이버섯아재비, 붉은산무명버섯의 미량금속원소 -)

  • Park, Wan-Hee
    • The Korean Journal of Mycology
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    • v.21 no.4
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    • pp.273-278
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    • 1993
  • In order to determine of trace mineral elements of wild edible mushrooms in Korea, the dried carpophores of Armillariella mella(Vahl.ex Fr.) karst., Armillariella tabescens(Scop.) Sing., Lepista nuda(Bull.ex Fr.) Cooke and Lepista sordida(Schum.ex Fr.) Sing., Hygrophorus russula (Schaeff.ex Fr.) Qu'el., Hygrocybe conica(Scop.ex Fr.) Kummur were incinerated and analyzed by an atom adsorption spectrophotometry. The six mushrooms contained ubiquitously potassium, iron, zinc, sodium, manganase, copper and calsium in that order, and the content of potassium was the highest than other inorganic components and the content of zinc in Hygrocybe conica was especially the most than the other five mushrooms. Total contents of inorganic components(except Cd) were universally the highest in Hygrocybe conica than other five mushrooms, and decrease in order Hygrophorus russula, lepista nuda, lepista sordida, Aarmillariella mella and Armillariella tabescens. Calsium was not present in Amillariella mella and lepista nuda, and copper not in Hygro­cybe conica, and content of cadimium in Hygrophorus russula and Hygrocybe conica were trace.

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Characteristics of Lead isotope ratios and Trace elements of Excavated Bronze weapons in Pre-historical Age (선사시대 출토 청동 무기류의 납동위원소비 및 미량원소 특성)

  • Kim, So Jin;Hwang, Jin Ju;Han, Woo Rim
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.4
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    • pp.219-226
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    • 2021
  • We examined component analysis and lead isotope ratio analysis to find out the relationship between the excavation and the production site of 25 bronze weapons from prehistoric ages. All 25 bronze weapons are ternary alloys of copper-tin-lead and lead is artificially added. The lead isotope ratios of 25 bronze weapons show that bronze are made by raw materials in the southern regions of the Korean Peninsula, including northern China. The raw materials of narrow-shaped bronze dagger are supplied in zone 1-3 and northern China. In addition, provenance of lead for bronze halberd and pearhead are the rest of the region except for zone 1 and zone 4. Silver are enriched in most samples and zinc and cobalt are deficient. Arsenic and antimony detected only specific samples and can be used as critical parameter for provenance study. Lead isotopes and trace elements of archaeological bronzes will provide conservation scientist with useful tool to study the provenance of raw materials

Comparative Study on Geochemical Characteristics of Stream Sediments and Mylonitic Granites in the Unbong Area (운봉지역 하상퇴적물과 압쇄상화강암류의 지구화학적 특성 비교연구)

  • Park, Young-Seog;Park, Dae-Woo;Kim, Jong-Kyun;Kim, Sung-Won
    • Economic and Environmental Geology
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    • v.40 no.6
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    • pp.727-738
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    • 2007
  • The present study investigation the geochemical characteristics of the stream sediments in the Unbong area was conducted to enable a understanding the natural background and a prediction the prospects of geochemical disaster as a result of that bed rocks(mylonitic granites, Kim et al., 1992). We systematically collected seventy three stream sediments samples by wet sieving along the primary channels. Major, trace and rare earth element(REE) concentrations, combined with mineralogical characteristics, were determined by XRD, XRF, ICP-AES and NAA analysis methods. Major element concentrations for the stream sediments in the Unbong area were $SiO_2\;36.94{\sim}65.39wt.%,\;Al_2O_3\;10.15{\sim}21.77wt.%,\;Fe_2O_3\;3.17{\sim}10.90wt.%,\;CaO\;0.55{\sim}5.27wt.%,\;MgO\;0.52{\sim}4.94wt.%,\;K_2O\;1.38{\sim}4.54wt.%,\;Na_2O\;0.49{\sim}3.36wt.%,\;TiO_2\;0.39{\sim}1.27wt.%,\;MnO\;0.04{\sim}0.22wt.%,\;P_2O_5\;0.08{\sim}0.54wt.%$. Trace and REE concentrations for the stream sediments were $Cu\;4.8{\sim}134ppm,\;Pb\;24.2{\sim}82.5ppm,\;Sr\;95.9{\sim}739ppm,\;V\;19.9{\sim}124ppm,\;Zr\;52.9{\sim}145ppm,\;Li\;25.2{\sim}3.3ppm,\;Co\;3.87{\sim}50.0ppm,\;Cr\;17.4{\sim}234ppm,\;Hf\;3.93{\sim}25.2ppm,\;Sc\;4.60{\sim}20.6ppm,\;Th\;3.82{\sim}36.9ppm,\;Ce\;45.7{\sim}243ppm,\;Eu\;0.89{\sim}2.69ppm,\;Yb\;1.42{\sim}5.18ppm$. According to the comparison of average major element concentrations, CaO, $Na_2O\;and\;K_2O$ contents are higher in stream sediments than in bed rocks(mylonitic granites, Kim et al., 1992) $Al_2O_3\;and\;SiO_2$ contents show good correlation both stream sediments and bed rocks(mylonitic granites, Kim et al., 1992). Yb and Eu in the stream sediments show a positive correlation with $SiO_2$. In contrast, the stream sediments display a negative correlation.

A provenance study of roof tiles & potteries using Neutron Activation Analysis from Katap-Ri, the Korea (부여 가탑리유적 토기.기와의 산지연구)

  • Jung, Kwang-Yong;Kim, Myung-Jin;Oh, Kuy-Jin
    • 한국문화재보존과학회:학술대회논문집
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    • 2002.11a
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    • pp.7-14
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    • 2002
  • In Katap-ri, South Korea, potteries and roof tiles are excavated with the assumed raw materials. Using NAA, the provenance of these cultural remains was examined among the neighboring others, and the correlation the assumed raw materials with potteries and roof tiles also was examined. From the results of statistics it is concluded that this cultural site is distingushed from others by several trace elements, Ba, Cr, Sc, Yb, Eu, and Rb with 93.2 % accuracy. Also it turned out that the assumed raw materials wasn't raleted to potteries and roof tiles with 96.3% accuracy.

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Geochemical Composition of Surface Sediments from the Saemangeum Tidal Flat, West Coast of Korea (새만금 조간대 표층퇴적물의 성분원소 함량과 지화학적 특성)

  • Cho, Yeong-Gil;Ryu, Sang-Ock;Khu, Yeong-Kyeong;Kim, Joo-Yong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.1
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    • pp.27-34
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    • 2001
  • To investigate the processes governing the distribution of elements in the tidal flat, thirty-eight sediment samples collected from the Saemangeum tidal flat of the Korean west coast were analyzed for their contents of major (Al, Fe, Mg, Ca, Na, K, Ti) and trace (P, Mn, Ba, Sr, V, Cr, Co, Cu, Ni, Zn, Pb) elements. Most elements showed generally lower contents compared to data published for other tidal flats of Korea, and the effect of anthropogenic input could not be recognized in the sediments. The relative abundance and distribution of most of the elements varied significantly with the grain size of sediments. High contents of Al, Fe, Mg, Ti, P, Mn, V, Co, Cr, Cu, Ni and Zn were found in the finer sediments in the upper tidal flat of the study area, suggesting that tidal sedimentation processes play an important role in controlling the distribution of these elements. However, sediment grain size does not impose any significant effect on the abundance and distribution of Ca, Na, K, Ba, Sr and Pb. It appears that the clastic mineralogy in the coarse-grained fractions is the dominant factor determining the distribution of these elements in the study area.

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Chemical Analysis of Fly Ashes from Municipal Solid Waste Incinerators (생활폐기물 처리시설 배출 비산재의 조성분석)

  • Jang, Seong-Ki;Choi, Duk-Il;Lim, Chang-Ho;Lee, Jin-Sook
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.215-221
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    • 2000
  • Analysis of fly ashes from the MSW incinerators was carried out using XRF, ICP-MS and ICP-AES. It was found that the major elements of fly ash were Ca, K, Na, Si, Al, S, Cl and O by the XRF analysis. The XRD spectra showed that the fly ashes were mainly consisted with the chlorides, hydroxides, carbonates and also oxides of former elements. For the determination of minor elements such as Zn, Pb, Cu, Cr, and Cd, we used ICP-AES and ICP-MS after microwave digestion and the results were compared with the result of XRF.

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Major, Rare-Earth and Trace Geochemistry of Ulleungdo Volcanic Rocks (울릉도 화산암의 주원소, 휘토류 및 미량원소 지구화학)

  • 송용선;박계헌;박맹언
    • The Journal of the Petrological Society of Korea
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    • v.8 no.2
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    • pp.57-70
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    • 1999
  • The volcanic rocks of Ulleungdo reveal very high alkali element abundances and most of them have high K20/Na20 ratios and belong to potassium-series. Ulleungdo volcanics show very wide range of variation in their composition from basalts to trachytic basalt, basaltic trachyandesite, trachyandesite, and finally to trachyte on total alkali-silica diagram. Such a general trend of compositional variation can be explained well by differentiation due to fractional crystallization of various minerals. Olivine, clinopyroxene, plagioclase, ilmenite, and apatite are suggested as the major fractionated minerals. Ulleungdo volcanics show Nb/U and PbICe ratios similar to oceanic volcanics such as MORB and OIB, but significantly different .from volcanic rocks of island arc environments, which suggest that they are not directly related with subduction along the Japanese arc. LREE abundances of Ulleungdo volcanics are highly enriched compared with HREE abundances ((La)N=193-420, (L~)~=7.5-19.5).O nly trachyte-1 show appreciable negative Eu anomalies among various rock types, which suggests significant amount of plagioclase were fractionated. However, trachyte-2, trachyte-3, phonolite, and pumice reveal quite different variation trend of trace and rare earth element abundances from trachyte-1, which suggest that they have originated from different magma batches and have experienced different differentiation processes. A prominent bimodal distribution, thus lacking of intermediate composition, is observed from the Ulleundo volcanics.

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